S02- ATTACHMENT B-MSDS Yellow Paint.pdf

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name EP95120B WATERBORNE PAINT

Product Code(s) 980912

Recommended Use Traffic paint

Product Technology W/B

Chemical Emergency Phone Number Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION

Potential Health Effects Principle Routes of Exposure Eye contact. Skin contact. Inhalation.

Acute Toxicity Eyes May cause irritation.

Skin Harmful if absorbed through skin. May cause irritation.

Inhalation Harmful by inhalation. May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Sanding and grinding dust may be harmful if inhaled.

Ingestion Harmful if swallowed. May cause blindness if swallowed. May cause additional affects as listed under "Inhalation".

Chronic Effects Inhalation exposure to respirable levels of crystalline silica may cause respiratory impairment and lung damage. Crystalline silica (quartz) has been classified by the International Agency for Research on Cancer (IARC) as a known human carcinogen (Group 1). Titanium dioxide has been classified by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to humans (Group 2B) by inhalation. Inhalation, ingestion, or skin absorption of methanol can cause blindness.

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Revision Date Revision Number 0

Supplier Address Ennis Paint Inc.

5910 North Central Expressway Suite 1050 Dallas TX 75206 T: 800.331.8118

800.331.8118 (For Technical Inquiries)

DANGER!

Issuing Date 04-May-2011

Emergency Overview

Harmful by inhalation, in contact with skin and if swallowed Causes central nervous system depression.

May cause skin, eye, and respiratory tract irritation May adversely affect liver and kidney.

Cancer hazard WARNING! This product contains a chemical known in the State of California to cause cancer.

Material Safety Data Sheet

Appearance Yellow Physical State Emulsion. Odor Slight, Ammonia

Aggravated Medical Conditions Respiratory disorders. Lungs. Skin disorders. Liver disorders. Kidney disorders. Central nervous system. Pre-existing eye disorders.

Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.

Environmental Hazard Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

See Section 12 for additional Ecological Information.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No Weight % Methyl alcohol 67-56-1 5-10

Titanium dioxide 13463-67-7 3-7 Propylene glycol 57-55-6 1-5 2-Butoxyethanol 111-76-2 1-5

Quartz 14808-60-7 0.1-1

4. FIRST AID MEASURES

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician.

Skin Contact Wash off immediately with plenty of water. Remove and wash contaminated clothing before re-use. If symptoms persist, call a physician.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician.

Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. If symptoms persist, call a physician.

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Flammable Properties Not flammable.

Flash Point > 201°F / 93.8°C

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Explosion Data Sensitivity to Mechanical Impact None Sensitivity to Static Discharge None

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

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Physical and Chemical Hazards -

HMIS

NFPA

Health Hazard 2* Flammability 1

WPS-ENN-980912 - EP95120B WATERBORNE PAINT

Physical Hazard 0 Personal Protection -

Health Hazard 1 Flammability 1

Revision Date

Instability 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing.

Environmental Precautions Prevent product from entering drains. Do not flush into surface water or sanitary sewer system.

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Use personal protective equipment. Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Clean up promptly by sweeping or vacuum. Keep in suitable and closed containers for disposal.

7. HANDLING AND STORAGE

Handling Ensure adequate ventilation. Avoid breathing vapors or mists. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product.

Storage Keep container tightly closed in a dry and well-ventilated place. Keep in properly labeled containers. Keep out of the reach of children.

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Revision DateWPS-ENN-980912 - EP95120B WATERBORNE PAINT

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH 2-Butoxyethanol

111-76-2 TWA: 20 ppm TWA: 50 ppm

TWA: 240 mg/m3

(vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3

(vacated) S*

IDLH: 700 ppm TWA: 5 ppm

TWA: 24 mg/m3

Methyl alcohol 67-56-1

STEL = 250 ppm TWA: 200 ppm

S*

TWA: 200 ppm TWA: 260 mg/m3

(vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3

(vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3

(vacated) S*

IDLH: 6000 ppm TWA: 200 ppm

TWA: 260 mg/m3

STEL: 325 mg/m3

STEL: 250 ppm

Quartz 14808-60-7

TWA: 0.025 mg/m3respirable fraction TWA: 0.1 mg/m3 (vacated) IDLH: 50 mg/m3 respirable dust TWA: 0.05 mg/m3 respirable dust

Titanium dioxide 13463-67-7

TWA: 10 mg/m3 TWA: 15 mg/m3total dust (vacated) TWA: 10 mg/m3total dust

IDLH: 5000 mg/m3

ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.

Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).

Engineering Measures Showers Eyewash stations Ventilation systems

Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields.

Skin and Body Protection Protective gloves.

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

Hygiene Measures Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Provide regular cleaning of equipment, work area and clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES

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Decomposition Temperature No information available.

WPS-ENN-980912 - EP95120B WATERBORNE PAINT

Boiling Point/Boiling Range No information available

Odor Threshold

Melting Point/Range No information available

No information available

Revision Date

Physical State Emulsion

Specific Gravity 1.55-1.75

Appearance

Solubility Insoluble pH No information available.

Evaporation Rate No information available

Yellow.

Vapor Pressure No data available Vapor Density No data available EPA VOC (g/l) <100

Flash Point > 201°F / 93.8°C

Odor

Autoignition Temperature No information available.

Slight, Ammonia.

Explosion Limits No information available.Flammability Limits in Air No information available.

10. STABILITY AND REACTIVITY

Stability Stable under recommended storage conditions.

Incompatible Products None known based on information supplied.

Conditions to Avoid None known based on information supplied.

Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx).

Hazardous Polymerization Hazardous polymerization does not occur.

11. TOXICOLOGICAL INFORMATION

Acute Toxicity

Product Information No acute toxicity information is available for this product.

Component Information

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Propylene glycol 20000 mg/kg ( Rat ) = 20800 mg/kg ( Rabbit ) - 2-Butoxyethanol = 470 mg/kg ( Rat ) = 400 mg/kg ( Rabbit )

= 2270 mg/kg ( Rat ) = 2.21 mg/L ( Rat ) 4 h = 450 ppm ( Rat ) 4 h

Methyl alcohol 5628 mg/kg ( Rat ) 15800 mg/kg ( Rabbit ) 83.2 mg/L ( Rat ) 4 h 64000 ppm ( Rat ) 4 h

Quartz 500 mg/kg ( Rat ) Titanium dioxide > 10000 mg/kg ( Rat ) > 6820 mg/m3

Chronic Toxicity

Chronic Toxicity Inhalation exposure to respirable levels of crystalline silica may cause respiratory impairment and lung damage. Crystalline silica (quartz) has been classified by the International Agency for Research on Cancer (IARC) as a known human carcinogen (Group 1). Titanium dioxide has been classified by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to humans (Group 2B) by inhalation. Inhalation, ingestion, or skin absorption of methanol can cause blindness.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical Name ACGIH IARC NTP OSHA Titanium dioxide Group 2B X 2-Butoxyethanol A3 Group 3

Quartz A2 Group 1 Known X

ACGIH: (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen A4 - Not Classifiable as a Human Carcinogen IARC: (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans NTP: (National Toxicity Program) Known - Known Carcinogen OSHA: (Occupational Safety & Health Administration) X - Present

Target Organ Effects Respiratory system. Central nervous system (CNS). Liver. Kidney.

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WPS-ENN-980912 - EP95120B WATERBORNE PAINT Revision Date

12. ECOLOGICAL INFORMATION

Ecotoxicity Product Information LC50/96h/Fathead minnows = >750 mg/L

Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Methyl alcohol - LC50 96 h: 13500 - 17600 mg/L flow-through (Lepomis macrochirus)

LC50 96 h: 18 - 20 mL/L static (Oncorhynchus mykiss)

LC50 96 h: 19500 - 20700 mg/L flow-through

(Oncorhynchus mykiss) LC50 96 h: = 28200 mg/L flow-through (Pimephales promelas) LC50 96 h: > 100 mg/L static

(Pimephales promelas)

EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min

Propylene glycol EC50 96 h: = 19000 mg/L (Pseudokirchneriella subcapitata)

LC50 96 h: 41 - 47 mL/L static (Oncorhynchus mykiss)

LC50 96 h: = 51400 mg/L static (Pimephales promelas)

LC50 96 h: = 51600 mg/L static (Oncorhynchus mykiss)

LC50 96 h: = 710 mg/L (Pimephales promelas)

EC50 = 710 mg/L 30 min EC50 48 h: > 1000 mg/L Static (Daphnia magna)

EC50 24 h: > 10000 mg/L (Daphnia magna)

2-Butoxyethanol LC50 96 h: = 1490 mg/L static (Lepomis macrochirus)

LC50 96 h: = 2950 mg/L (Lepomis macrochirus)

EC50 24 h: 1698 - 1940 mg/L (Daphnia magna)

EC50 48 h: > 1000 mg/L (Daphnia magna)

Chemical Name Log Pow Methyl alcohol -0.77

2-Butoxyethanol 0.81

13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.

Contaminated Packaging Do not re-use empty containers.

Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Methyl alcohol - 67-56-1 Included in waste stream:

F039 U154

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste Methyl alcohol Toxic

Ignitable

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14. TRANSPORT INFORMATION

DOT Not regulated

TDG Not regulated

MEX Not regulated

ICAO Not regulated

IATA Not regulated

IMDG/IMO Not regulated

15. REGULATORY INFORMATION

International Inventories TSCA All components are listed on the TSCA Inventory.

DSL All components are listed either on the DSL or NDSL.

Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

U.S. Federal Regulations

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

Chemical Name CAS-No Weight % SARA 313 - Threshold Values %

2-Butoxyethanol 111-76-2 1-5 1.0 Methyl alcohol 67-56-1 5-10 1.0

SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).

CERCLA

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs

RQ

Methyl alcohol 5000 lb RQ= 2270 kg final RQ RQ= 5000 lb final RQ

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U.S. State Regulations

California Proposition 65 California Proposition 65

Chemical Name CAS-No California Prop. 65 Quartz 14808-60-7 Carcinogen

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania Illinois Rhode Island Propylene glycol X - X - X 2-Butoxyethanol X X X X X Titanium dioxide X X X - X Methyl alcohol X X X X X

Quartz X X X - X

International Regulations

Chemical Name Carcinogen Status Exposure Limits Methyl alcohol Mexico: TWA= 200 ppm

Mexico: TWA= 260 mg/m3

Mexico: STEL= 250 ppm Mexico: STEL= 310 mg/m3

2-Butoxyethanol Mexico: TWA 26 ppm Mexico: TWA 120 mg/m3

Mexico: STEL 75 ppm Mexico: STEL 360 mg/m3

Quartz Mexico: TWA= 0.1 mg/m3

Titanium dioxide Mexico: TWA= 10 mg/m3

Mexico: STEL= 20 mg/m3

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS Hazard Class D1A Very toxic materials D1B Toxic materials D2A Very toxic materials D2B Toxic materials

Chemical Name NPRI Methyl alcohol X

2-Butoxyethanol X

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16. OTHER INFORMATION

Prepared By Product Stewardship 23 British American Blvd.

Latham, NY 12110 1-800-572-6501

Issuing Date 04-May-2011 Revision Date Revision Note Initial Release.

General Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication and it does not purport to be all inclusive and shall be used only as a guide. We urge each customer or recipient of this MSDS to study it carefully to become aware of and understand the potential hazards associated with the product. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification.

The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. Any use of the product not in conformance with this MSDS or in combination with any other product or process is the responsibility of the user. Customary precautionary measures for handling chemicals should be followed.

Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Remove all soiled and contaminated clothing immediately.

End of Safety Data Sheet

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Revision DateWPS-ENN-980912 - EP95120B WATERBORNE PAINT