PD_CEE BEE A-235 Paint.docx

U.S Air Force

Product Description and Specifications for Commodities Maintenace Group (CMXG) CEE BEE A-235 Paint stripper

532 CMMXS

6/11/2024

CEE-BEE A-235

i

TABLE OF CONTENTS

Description Of Product CEE-BEE Remover A-235 is a diphase, solvent-base, alkaline, cold-tank carbon and paint remover. It has been modified to work in landing gear production line of 309 CMXG. The SDS identifies this chemical at: 65% - 75% Methylene Chloride, 15% - 20% Phenol and 0.1% - 1.0% Sodium Chromate (see MSDS 23077 Appendix B).

Background CEE-BEE A-235 is modified formula to be used to remove the paint from landing gear production line in building 507 of 309 CMXG. The following Technical Orders (T.O.’s) call out this material: T.O. 4S-1-182.

DELIVERY

Ship to:

309 CMXG 532 CMMXS

5760 Southgate Ave Bldg 507 Hill AFB, UT 84056-5733

WARRANTY

Standard commercial warranty shall apply.

Appendix A Acronyms and Abbreviations

Appendix B image2.emf

Copy of SDS-23077-CEE-BEE A-235 (SDS - S23077 - 1 - 5) - 1.PDF

Page 1/18 Safety Data Sheet acc. to OSHA HCS

Printed on: 06/15/2022 Revision date: 06/15/2022

54.2.3

1 Identification

· Product identifier

· Trade name: Cee-Bee A-235

· Article number: 23077

· Restrictions This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(5)) or processed (as defined in TSCA section 3(13)) for consumer paint or coating removal.

· Application of the substance / the mixture Paint remover

· Uses advised against

· Details of the supplier of the safety data sheet

· Manufacturer/Supplier:

McGean-Rohco, Inc.

38521 Schoolcraft Road Livonia, MI 48150-1085

USA

sds.info@mcgean.com

· Information department: Environmental, Health, and Safety

· Emergency telephone number:

ChemTel: 1-800-255-3924 within the United States, Canada, Puerto Rico, and the U.S. Virgin Islands. Internationally 1-813-248-0585

2 Hazard(s) identification

· Classification of the substance or mixture d~� GHS06 Skull and crossbones

Acute Toxicity - Inhalation 3 H331 Toxic if inhaled.

d~� GHS08 Health hazard

Sensitization - Respiratory 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Germ Cell Mutagenicity 1B H340 May cause genetic defects.

(Contd. on page 2) mailto:sds.info@mcgean.com

Page 2/18

Trade name: Cee-Bee A-235

(Contd. of page 1)

Carcinogenicity 1B H350 May cause cancer.

Toxic to Reproduction 1B H360 May damage fertility or the unborn child.

Specific Target Organ Toxicity - Repeated Exposure 2

H373 May cause damage to organs through prolonged or repeated exposure.

d~� GHS05 Corrosion

Skin Corrosion 1B H314 Causes severe skin burns and eye damage.

Eye Damage 1 H318 Causes serious eye damage.

d~� GHS07

Acute Toxicity - Oral 4 H302 Harmful if swallowed.

Sensitization - Skin 1 H317 May cause an allergic skin reaction.

Flammable Liquids 4 H227 Combustible liquid.

Aquatic Acute 3 H402 Harmful to aquatic life.

Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.

· Label elements

· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

· Hazard pictograms d~�

GHS05

d~�

GHS06

GHS08

· Signal word Danger

· Hazard-determining components of labeling:

dichloromethane

(Contd. on page 3)

Page 3/18

(Contd. of page 2) phenol sodium dichromate, dihydrate potassium hydroxide

· Hazard statements H227 Combustible liquid.

H302 Harmful if swallowed.

H331 Toxic if inhaled.

H314 Causes severe skin burns and eye damage.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

H340 May cause genetic defects.

H350 May cause cancer.

H360 May damage fertility or the unborn child.

H373 May cause damage to organs through prolonged or repeated exposure.

H402 Harmful to aquatic life.

H412 Harmful to aquatic life with long lasting effects.

· Precautionary statements P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P210 Keep away from flames and hot surfaces. – No smoking.

P260 Do not breathe dusts or mists.

P264 Wash thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing must not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P284 [In case of inadequate ventilation] wear respiratory protection.

P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.

P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a poison center/doctor.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P321 Specific treatment (see on this label).

P314 Get medical advice/attention if you feel unwell.

(Contd. on page 4)

Page 4/18

(Contd. of page 3)

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P342+P311 If experiencing respiratory symptoms: Call a poison center/doctor.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use CO2, powder or water spray to extinguish.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/ international regulations.

· Other hazards

· Results of PBT and vPvB assessment

· PBT: Not applicable.

· vPvB: Not applicable.

3 Composition/information on ingredients

· Chemical characterization:

· Description: Mixture of the substances listed below with nonhazardous additions.

· Dangerous components:

CAS: 75-09-2 dichloromethane 50-85% CAS: 108-95-2 phenol 10-20% CAS: 1310-58-3 potassium hydroxide 1-<2% CAS: 10588-01-9 sodium dichromate anhydrate 0.5-<1%

4 First-aid measures

· Description of first aid measures

· General information:

Immediately remove any clothing soiled by the product.

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

Remove breathing apparatus only after contaminated clothing have been completely removed.

In case of irregular breathing or respiratory arrest provide artificial respiration.

· After inhalation:

Supply fresh air or oxygen; call for doctor.

In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.

(Contd. on page 5)

Page 5/18

(Contd. of page 4)

· After eye contact:

Rinse opened eye for several minutes under running water. Then consult a doctor.

· After swallowing:

Do not induce vomiting; immediately call for medical help.

Drink copious amounts of water and provide fresh air. Immediately call a doctor.

· Information for doctor:

· Most important symptoms and effects, both acute and delayed No further relevant information available.

· Indication of any immediate medical attention and special treatment needed

5 Fire-fighting measures

· Extinguishing media

· Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

· Special hazards arising from the substance or mixture

· Advice for firefighters

· Protective equipment: Mouth respiratory protective device.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away.

· Environmental precautions:

Do not allow product to reach sewage system or any water course.

Inform respective authorities in case of seepage into water course or sewage system.

Do not allow to enter sewers/ surface or ground water.

· Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Use neutralizing agent.

Dispose contaminated material as waste according to item 13.

Ensure adequate ventilation.

· Reference to other sections See Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

(Contd. on page 6)

Page 6/18

(Contd. of page 5)

7 Handling and storage

· Handling:

· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.

Open and handle receptacle with care.

· Information about protection against explosions and fires:

Keep respiratory protective device available.

· Conditions for safe storage, including any incompatibilities

· Storage:

· Requirements to be met by storerooms and receptacles: No special requirements.

· Information about storage in one common storage facility: Not required.

· Further information about storage conditions:

Do not allow product to freeze.

Keep receptacle tightly sealed.

· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.

· Control parameters

· Components with limit values that require monitoring at the workplace:

The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.

At this time, the remaining constituent has no known exposure limits.

CAS: 75-09-2 dichloromethane PEL Short-term value: 125 ppm

Long-term value: 25 ppm see 29 CFR 1910.1052

REL See Pocket Guide App. A TLV Long-term value: 50 ppm

BEI, A3

(Contd. on page 7)

Page 7/18

(Contd. of page 6)

CAS: 108-95-2 phenol PEL Long-term value: 19 mg/m³, 5 ppm

Skin REL Long-term value: 19 mg/m³, 5 ppm

Ceiling limit value: 60 mg/m³, 15.6 ppm 15-min; Skin

TLV Long-term value: 5 ppm Skin; BEI, A4

CAS: 1310-58-3 potassium hydroxide REL Ceiling limit value: 2 mg/m³ TLV Ceiling limit value: 2 mg/m³ CAS: 7789-12-0 sodium dichromate, dihydrate PEL Long-term value: 0.005 mg/m³

Ceiling limit value: 0.1 mg/m³ as Cr(VI) as CrO3; see 29 CFR 1910.1026

REL Long-term value: 0.0002 mg/m³ as Cr; See Pocket Guide Apps. A and C

TLV Short-term value: 0.0005 mg/m³ Long-term value: 0.0002 mg/m³ as Cr(VI); inhalable, Skin; BEI, DSEN, RSEN

· Ingredients with biological limit values:

BEI 0.3 mg/L

Medium: urine Time: end of shift Parameter: Dichloromethane (semi-quantitative)

BEI 250 mg/g creatinine

Time: end of shift Parameter: Phenol with hydrolysis (background, nonspecific)

(Contd. on page 8)

Page 8/18

(Contd. of page 7)

CAS: 7789-12-0 sodium dichromate, dihydrate BEI 25 µg/L

Time: end of shift at end of workweek Parameter: Total chromium (fume)

10 µg/L

Time: increase during shift Parameter: Total chromium (fume)

· Additional information: The lists that were valid during the creation were used as basis.

· Exposure controls

· Personal protective equipment:

· General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing.

Wash hands before breaks and at the end of work.

Store protective clothing separately.

Avoid contact with the eyes and skin.

· Breathing equipment:

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.

· Protection of hands:

_S Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

· Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.

(Contd. on page 9)

Page 9/18

(Contd. of page 8)

· Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

· Eye protection:

Safety glasses

_R Tightly sealed goggles

9 Physical and chemical properties

· Information on basic physical and chemical properties

· General Information

· Appearance:

Form: two-phase liquid Color: According to product specification

· Odor: Phenol-like

· Odor threshold: Not determined.

· pH-value: Not determined.

· Change in condition Freezing point: -3 °C (26.6 °F) Boiling point/Boiling range: 40 °C (104 °F)

· Flash point: 74 °C (165.2 °F)

· Flammability (solid, gaseous): Not applicable.

· Ignition temperature: 595 °C (1,103 °F)

· Decomposition temperature: Not determined.

· Auto igniting: Product is not selfigniting.

· Danger of explosion: Not determined.

· Explosion limits:

Lower: 1.3 Vol % Upper: 22 Vol %

(Contd. on page 10)

Page 10/18

(Contd. of page 9)

· Vapor pressure at 20 °C (68 °F): 453 hPa (339.8 mm Hg)

· Density at 20 °C (68 °F): 1.26372 g/cm³ (10.54574 lbs/gal)

· Relative density Not determined.

· Vapor density Not determined.

· Evaporation rate Not determined.

· Solubility in / Miscibility with Water: Not miscible or difficult to mix.

· Partition coefficient (n-octanol/water): Not determined.

· Viscosity:

Dynamic: Not determined.

Kinematic: Not determined.

· Solvent content:

Organic solvents: 85.9 % VOC content: 14.72 %

186.0 g/l / 1.55 lb/gal

Solids content: 16.8 %

· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity No further relevant information available.

· Chemical stability

· Thermal decomposition / conditions to be avoided:

No decomposition if used according to specifications.

· Possibility of hazardous reactions No dangerous reactions known.

· Conditions to avoid No further relevant information available.

· Incompatible materials: No further relevant information available.

· Hazardous decomposition products: No dangerous decomposition products known.

(Contd. on page 11)

Page 11/18

(Contd. of page 10)

11 Toxicological information

· Information on toxicological effects

· Acute toxicity:

· LD/LC50 values that are relevant for classification:

CAS: 75-09-2 dichloromethane Oral LD50 1,600 mg/kg (rat) Inhalative LC50/4 h 88 mg/l (rat) CAS: 108-95-2 phenol Oral LD50 317 mg/kg (rat) Dermal LD50 850 mg/kg (rabbit)

· Primary irritant effect:

· on the skin: Caustic effect on skin and mucous membranes.

· on the eye: Strong caustic effect.

· Sensitization:

Sensitization possible through inhalation.

Sensitization possible through skin contact.

· Additional toxicological information:

The product shows the following dangers according to internally approved calculation methods for preparations:

Toxic Harmful Corrosive Irritant Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.

Carcinogenic.

The product can cause inheritable damage.

· Carcinogenic categories

· IARC (International Agency for Research on Cancer) CAS: 75-09-2 dichloromethane 2B CAS: 108-95-2 phenol 3 CAS: 10588-01-9 sodium dichromate anhydrate 1

(Contd. on page 12)

Page 12/18

(Contd. of page 11)

· NTP (National Toxicology Program) CAS: 75-09-2 dichloromethane R CAS: 10588-01-9 sodium dichromate anhydrate K CAS: 7664-93-9 sulfuric acid K

· OSHA-Ca (Occupational Safety & Health Administration)

12 Ecological information

· Toxicity

· Aquatic toxicity: No further relevant information available.

· Persistence and degradability No further relevant information available.

· Behavior in environmental systems:

· Bioaccumulative potential No further relevant information available.

· Mobility in soil No further relevant information available.

· Ecotoxical effects:

· Remark: Harmful to fish

· Additional ecological information:

· General notes:

Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities.

Must not reach bodies of water or drainage ditch undiluted or unneutralized.

Danger to drinking water if even extremely small quantities leak into the ground.

Harmful to aquatic organisms

· Results of PBT and vPvB assessment

· PBT: Not applicable.

· vPvB: Not applicable.

· Other adverse effects No further relevant information available.

13 Disposal considerations

· Waste treatment methods

· Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

(Contd. on page 13)

Page 13/18

(Contd. of page 12)

· Uncleaned packagings:

· Recommendation: Disposal must be made according to official regulations.

14 Transport information

· UN-Number

· DOT, IMDG, IATA UN2810

· UN proper shipping name

· DOT Toxic, liquids, organic, n.o.s. (Dichloromethane, Phenol)

· IMDG, IATA T O X I C L I Q U I D , O R G A N I C , N . O . S .

(DICHLOROMETHANE, PHENOL)

· Transport hazard class(es)

· DOT

dc̀k|�

· Class 6.1 Toxic substances

· Label 6.1

· IMDG, IATA

dc̀k|

· Class 6.1 Toxic substances

· Label 6.1

· Packing group

· DOT, IMDG, IATA III

· Environmental hazards:

· Marine pollutant: No

(Contd. on page 14)

Page 14/18

(Contd. of page 13)

· Special precautions for user Warning: Toxic substances

· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.

· Transport/Additional information:

· DOT

· Quantity limitations On passenger aircraft/rail: 60 L

On cargo aircraft only: 220 L

· IMDG

· Limited quantities (LQ) 5L

· Excepted quantities (EQ) Code: E1

Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml

· UN "Model Regulation": UN2810, Tox ic , l i qu ids , o rgan ic , n .o .s .

(Dichloromethane, Phenol), 6.1, III

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture

· Sara

· Section 355 (extremely hazardous substances):

CAS: 7664-93-9 sulfuric acid

· Section 313 (Specific toxic chemical listings):

CAS: 10588-01-9 sodium dichromate anhydrate

· TSCA (Toxic Substances Control Act):

(Contd. on page 15)

Page 15/18

(Contd. of page 14)

CAS: 1310-58-3 potassium hydroxide

· Proposition 65

· Chemicals known to cause cancer:

· Chemicals known to cause reproductive toxicity for females:

· Chemicals known to cause reproductive toxicity for males:

· Chemicals known to cause developmental toxicity:

· Carcinogenic categories

· EPA (Environmental Protection Agency) CAS: 75-09-2 dichloromethane L CAS: 108-95-2 phenol D, I CAS: 10588-01-9 sodium dichromate anhydrate A(inh), D(oral), K/L(inh), CBD(oral)

· TLV (Threshold Limit Value) CAS: 75-09-2 dichloromethane A3 CAS: 108-95-2 phenol A4 CAS: 10588-01-9 sodium dichromate anhydrate A1 CAS: 7664-93-9 sulfuric acid A2

· NIOSH-Ca (National Institute for Occupational Safety and Health)

· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

(Contd. on page 16)

Page 16/18

(Contd. of page 15)

· Hazard pictograms

GHS05

d~�

GHS06

GHS08

· Signal word Danger

· Hazard-determining components of labeling:

dichloromethane phenol sodium dichromate, dihydrate potassium hydroxide

· Hazard statements H227 Combustible liquid.

H302 Harmful if swallowed.

H331 Toxic if inhaled.

H314 Causes severe skin burns and eye damage.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

H340 May cause genetic defects.

H350 May cause cancer.

H360 May damage fertility or the unborn child.

H373 May cause damage to organs through prolonged or repeated exposure.

H402 Harmful to aquatic life.

H412 Harmful to aquatic life with long lasting effects.

· Precautionary statements P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P210 Keep away from flames and hot surfaces. – No smoking.

P260 Do not breathe dusts or mists.

P264 Wash thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing must not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P284 [In case of inadequate ventilation] wear respiratory protection.

(Contd. on page 17)

Page 17/18

(Contd. of page 16)

P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.

P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a poison center/doctor.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P321 Specific treatment (see on this label).

P314 Get medical advice/attention if you feel unwell.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P342+P311 If experiencing respiratory symptoms: Call a poison center/doctor.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use CO2, powder or water spray to extinguish.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/ international regulations.

· National regulations:

· Information about limitation of use:

Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases.

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Department issuing SDS: Environment Health and Safety

· Contact: Jason Wheeler

· Date of preparation / last revision 06/15/2022 / 8

· Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances

(Contd. on page 18)

Page 18/18

(Contd. of page 17)

ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit BEI: Biological Exposure Limit Flammable Liquids 4: Flammable liquids – Category 4 Acute Toxicity - Oral 4: Acute toxicity – Category 4 Acute Toxicity - Inhalation 3: Acute toxicity – Category 3 Skin Corrosion 1B: Skin corrosion/irritation – Category 1B Eye Damage 1: Serious eye damage/eye irritation – Category 1 Sensitization - Respiratory 1: Respiratory sensitisation – Category 1 Sensitization - Skin 1: Skin sensitisation – Category 1 Germ Cell Mutagenicity 1B: Germ cell mutagenicity – Category 1B Carcinogenicity 1B: Carcinogenicity – Category 1B Toxic to Reproduction 1B: Reproductive toxicity – Category 1B Specific Target Organ Toxicity - Repeated Exposure 2: Specific target organ toxicity (repeated exposure) – Category 2 Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard – Category 3 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3 image1.jpeg