SDS - T7000 Part A.pdf

SAFETY DATA SHEET

Issuing Date 29-May-2015 Revision date 12-Nov-2018 Revision Number 4

1. Identification

Product identifier

Product Name Thermosil T7000 Part A

Other means of identification

Synonyms None

Recommended use of the chemical and restrictions on use

Recommended use Abradable air tight seal

Restrictions on use Consumer use

Details of the supplier of the safety data sheet

Emergency telephone number

Emergency Telephone CHEMTREC: +1-703-527-3887 (INTERNATIONAL)

1-800-424-9300 (NORTH AMERICA)

2. Hazard(s) identification

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Hazards not otherwise classified (HNOC) Not applicable

Label elements

Other information Silica: When encapsulated in polymer is not expected to pose a health hazard when processed under normal conditions of use Carbon black: When encapsulated in polymer is not expected to pose a health hazard when processed under normal conditions of use Titanium dioxide: When encapsulated in polymer is not expected to pose a health hazard when processed under normal conditions of use Glass: When encapsulated in polymer is not expected to pose a health hazard when processed under normal conditions of use

Supplier Address FMI Chemical, Inc.

4 Northwood Drive Bloomfield, CT 06002 T: 860-243-3222

Hazard statements Not a hazardous substance or mixture according to the Globally Harmonized System (GHS)

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CHEMTREC: +1-703-741-5970 (INTERNATIONAL) 1-800-424-9300 (NORTH AMERICA)

Thermosil T7000 Part A Revision date: 12-Nov-2018

3. Composition/information on ingredients

Substance

Not applicable.

Mixture

Chemical name CAS No Weight-% Trade secret soda lime borosilicate glass 65997-17-3 13-17 *

Quartz 14808-60-7 1-5 * Titanium dioxide 13463-67-7 1-3 *

Carbon black 1333-86-4 1-5 *

*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. First-aid measures

Description of first aid measures

Inhalation Remove to fresh air.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if symptoms occur.

Skin contact Wash skin with soap and water. Get medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water.

Most important symptoms and effects, both acute and delayed

Symptoms None known.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. Fire-fighting measures

Suitable Extinguishing Media Alcohol resistant foam. Dry chemical. Carbon dioxide (CO2).

Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.

Specific hazards arising from the chemical

During fire, gases hazardous to health may be formed. This material may generate formaldehyde at temperatures greater than 150°C in the presence of oxygen.

Explosion data Sensitivity to mechanical impact None.

Sensitivity to static discharge None.

Special protective equipment for fire-fighters

Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.

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6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation. Extremely slippery when spilled. Avoid contact with skin, eyes or clothing.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.

7. Handling and storage

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep/store only in original container. Store at ambient conditions.

8. Exposure controls/personal protection

Control parameters

Exposure Limits .

Chemical name ACGIH TLV OSHA PEL NIOSH IDLH soda lime borosilicate glass

65997-17-3 TWA: 1 fiber/cm3 respirable fibers: length >5 µm, aspect ratio >=3:1, as determined by the membrane filter method at 400-450X magnification [4-mm objective], using phase-contrast illumination TWA: 5 mg/m3 inhalable particulate matter

Quartz 14808-60-7

TWA: 0.025 mg/m3 respirable particulate matter

TWA: 50 µg/m3

(vacated) TWA: 0.1 mg/m3 respirable dust : (250)/(%SiO2 + 5) mppcf

TWA respirable fraction : (10)/(%SiO2 + 2) mg/m3 TWA respirable fraction

IDLH: 50 mg/m3 respirable dust TWA: 0.05 mg/m3 respirable dust

Titanium dioxide 13463-67-7

TWA: 10 mg/m3 TWA: 15 mg/m3 total dust (vacated) TWA: 10 mg/m3 total dust

IDLH: 5000 mg/m3

TWA: 2.4 mg/m3 CIB 63 fine TWA: 0.3 mg/m3 CIB 63 ultrafine, including engineered nanoscale

Carbon black TWA: 3 mg/m3 inhalable TWA: 3.5 mg/m3 IDLH: 1750 mg/m3

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1333-86-4 particulate matter (vacated) TWA: 3.5 mg/m3 TWA: 3.5 mg/m3

TWA: 0.1 mg/m3 Carbon black in presence of Polycyclic aromatic hydrocarbons PAH

Appropriate engineering controls

Engineering controls Showers Eyewash stations Ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/face protection If splashes are likely to occur: Goggles.

Hand protection Impervious gloves.

Skin and body protection Apron.

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical properties

Information on basic physical and chemical properties Physical state Liquid Appearance Black paste Color Black Odor No information available Odor threshold No information available

Other information Explosive properties No information available.

Oxidizing properties No information available.

Property Values Remarks • Method pH No data available None known Melting point / freezing point No data available None known Boiling point / boiling range No data available None known Flash point > 110 °C / > 230 °F Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limit in Air None known

Upper flammability or explosive limits

No data available

Lower flammability or explosive limits

No data available

Vapor pressure No data available None known Vapor density No data available None known Relative density 0.74 @ 25°C

Water solubility insoluble Solubility(ies) No data available None known Partition coefficient No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known

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Softening point No information available Molecular weight No information available VOC Content (%) No information available Liquid Density No information available Bulk density No information available

10. Stability and reactivity

Reactivity No information available.

Chemical stability Stable under normal conditions.

Possibility of hazardous reactions None under normal processing.

Conditions to avoid Incompatible materials.

Incompatible materials Strong acids. Strong oxidizing agents. Strong alkalis.

Hazardous decomposition products Carbon dioxide (CO2). Silicon oxides. Formaldehyde.

11. Toxicological information

Information on likely routes of exposure

Inhalation Specific test data for the substance or mixture is not available.

Eye contact Specific test data for the substance or mixture is not available. Contact with eyes may cause irritation.

Skin contact Specific test data for the substance or mixture is not available.

Ingestion Specific test data for the substance or mixture is not available. May cause gastrointestinal discomfort if consumed in large amounts.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms No information available.

Acute toxicity

Numerical measures of toxicity No information available

Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Titanium dioxide

13463-67-7 > 10000 mg/kg ( Rat ) - -

Carbon black 1333-86-4

> 15400 mg/kg ( Rat ) > 3 g/kg ( Rabbit ) -

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation No information available.

Serious eye damage/eye irritation No information available.

Respiratory or skin sensitization No information available.

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Germ cell mutagenicity No information available.

Carcinogenicity Classification based on data available for ingredients. Contains a known or suspected carcinogen. Silica: When encapsulated in polymer is not expected to pose a health hazard when processed under normal conditions of use. Titanium dioxide: When encapsulated in polymer is not expected to pose a health hazard when processed under normal conditions of use. Carbon black: When encapsulated in polymer is not expected to pose a health hazard when processed under normal conditions of use.

Chemical name ACGIH IARC NTP OSHA soda lime borosilicate glass 65997-17-3

- Group 3 - -

Quartz 14808-60-7

A2 Group 1 Known X

Titanium dioxide 13463-67-7

- Group 2B - X

Carbon black 1333-86-4

A3 Group 2B - X

ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Group 3 - Not Classifiable as to Carcinogenicity in Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present

Reproductive toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available.

Aspiration hazard No information available.

Other adverse effects No information available.

Interactive effects No information available.

12. Ecological information

Ecotoxicity The environmental impact of this product has not been fully investigated.

Chemical name Algae/aquatic plants Fish Toxicity to microorganisms

Crustacea

Carbon black 1333-86-4

- - - EC50: >5600mg/L (24h, Daphnia magna)

Persistence and degradability No information available.

Bioaccumulation There is no data for this product.

Other adverse effects No information available.

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13. Disposal considerations

Waste treatment methods

Waste from residues/unused products

Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.

Contaminated packaging Do not reuse empty containers.

14. Transport information

DOT Not regulated

TDG Not regulated

MEX Not regulated

ICAO (air) Not regulated

IATA Not regulated

IMDG Not regulated

RID Not regulated

ADR Not regulated

ADN Not regulated

15. Regulatory information International Inventories TSCA Contact supplier for inventory compliance status.

DSL/NDSL Contact supplier for inventory compliance status.

EINECS/ELINCS Contact supplier for inventory compliance status.

ENCS Contact supplier for inventory compliance status.

IECSC Contact supplier for inventory compliance status.

KECL Contact supplier for inventory compliance status.

PICCS Contact supplier for inventory compliance status.

AICS Contact supplier for inventory compliance status.

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

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SARA 311/312 Hazard Categories Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate classifications. Under the amended regulations at 40 CFR 370, EPCRA 311/312 Tier II reporting for the 2017 calendar year will need to be consistent with updated hazard classifications.

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42).

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.

US State Regulations

California Proposition 65 This product contains the following Proposition 65 chemicals:.

Chemical name California Proposition 65 Quartz - 14808-60-7 Carcinogen

Carbon black - 1333-86-4 Carcinogen Titanium dioxide - 13463-67-7 Carcinogen

U.S. State Right-to-Know Regulations

US State Regulations

Chemical name New Jersey Massachusetts Pennsylvania Quartz

14808-60-7 X X X

Carbon black 1333-86-4

X X X

Titanium dioxide 13463-67-7

X X X

U.S. EPA Label Information

EPA Pesticide Registration Number Not applicable

16. Other information

Key or legend to abbreviations and acronyms used in the safety data sheet

Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Key literature references and sources for data used to compile the SDS U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency)

NFPA Health hazards 0 Flammability 1 Instability 0 Physical and chemical properties -

HMIS Health hazards 0 Flammability 1 Physical hazards 0 Personal protection X

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation

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Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organization for Economic Co-operation and Development Environment, Health, and Safety Publications Organization for Economic Co-operation and Development High Production Volume Chemicals Program Organization for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization

Issuing Date 29-May-2015

Revision date 12-Nov-2018

Revision Note SDS sections updated. 2, 3, 11, 12, 15.

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

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