Attachment_1_SOW_Water_and_Sediment_Analysis_(1).pdf

Attachment – 1 Statement of Work

Document No.

140R3024Q0078

Document Title Water and Sediment Analysis

Laboratory Analysis of Water and Sediment Samples

1. Introduction

The Bureau of Reclamation (Reclamation), Interior Region 8: Lower Colorado Basin Regional Office monitors water and sediment for environmental contaminants as part of the Colorado River Water Quality Improvement Program (CRWQIP) and the Lake Mead/Las Vegas Wash (LMLVW) program. This data supports regional oversight and complements data collected by local agencies. Reclamation is seeking an accredited lab to test water and sediment samples for nutrients, metals, organic carbon, and commonly occurring contaminants. Up to 20 water and 20 sediment samples will be collected under each program each year depending on funding availability and sampling needs identified in previous years. No samples will be collected under the CRWQIP in Year 1.

2. Background Under P.L. 93-320, the Colorado River Basin Salinity Control Act of 1974, the Bureau of Reclamation (Reclamation) is authorized to enhance and protect the quality of water in the Colorado River and its tributaries. Results of laboratory analysis described herein will contribute to a long-term study tracking changes in water quality associated with rapid population growth in the Lower Colorado Basin. This information will support robust management decisions to ensure water quality remains high through changing climate, drought, and land use conditions.

Under P.L. 106-541, the Water Resources Development Act of 2000, Reclamation was directed to participate in implementing the Lake Mead/Las Vegas Wash program in accordance with the Comprehensive Adaptive Management Plan (CAMP). The CAMP includes 44 specific action items related to water quality, habitat management, and erosion control along the Las Vegas Wash (Wash). Results of laboratory analysis described herein will be used to investigate whether contaminants stored in sediment pose a risk to water quality in Lake Mead and the Lower Colorado River.

3. Scope

(1) The contractor is responsible for providing all labor, equipment, methods, standards, materials, and supplies necessary to meet the requirements of this Statement of Work. The contractor shall provide coolers containing sample bottles with necessary preservatives one week before each sampling event. The contractor will also provide a Chain of Custody form which will serve as documentation of the number and types of samples submitted for analysis. The chain of custody form must become part of the complete report of analysis.

(2) The contractor will measure concentrations of the contaminants listed in Table 1 and provide a report of results to the Contracting Officer’s Representative (COR) within 30 calendar days of sample receipt.

Batch quality assurance/quality control (QAQC) data (spikes, replicates, lab-fortified samples, etc.) for each analyte must accompany each report of analysis. Successful offeror must maintain appropriate laboratory certifications (e.g. National Environmental Laboratory Accreditation Program (NELAP) and Environmental Laboratory Accreditation Program (ELAP)) throughout the duration of the contract.

Table 1: Analytes and desired reporting limits

Analysis Group Analyte Description Units Units Sediment - Nutrients Phosphorus, Total 0.5 mg/Kg Total Kjeldahl Nitrogen 200 mg/Kg Nitrate as N 1 mg/Kg Nitrite as N 1 mg/Kg Sediment - Metals Antimony 1 mg/Kg Arsenic 0.5 mg/Kg Barium 0.5 mg/Kg Beryllium 0.3 mg/Kg Cadmium 0.5 mg/Kg Chromium 1 mg/Kg Cobalt 0.5 mg/Kg Copper 1 mg/Kg Lead 0.5 mg/Kg Molybdenum 1 mg/Kg Nickel 1 mg/Kg Selenium 1 mg/Kg Silver 0.5 mg/Kg Thallium 0.5 mg/Kg Vanadium 1 mg/Kg Zinc 10 mg/Kg Mercury 0.0833 mg/Kg Sediment - Perchlorate Perchlorate 20 ug/Kg Sediment - PAHs 1-Methylnaphthalene 0.02 mg/Kg 2-Methylnaphthalene 0.02 mg/Kg Acenaphthene 0.02 mg/Kg Acenaphthylene 0.02 mg/Kg Anthracene 0.02 mg/Kg Benzo[g,h,i]perylene 0.02 mg/Kg Benzo[k]fluoranthene 0.02 mg/Kg Benzo[a]anthracene 0.02 mg/Kg Benzo[a]pyrene 0.02 mg/Kg Benzo[b]fluoranthene 0.02 mg/Kg Chrysene 0.02 mg/Kg Dibenz(a,h)anthracene 0.02 mg/Kg Fluoranthene 0.02 mg/Kg Fluorene 0.02 mg/Kg Indeno[1,2,3-cd]pyrene 0.02 mg/Kg Naphthalene 0.02 mg/Kg

Phenanthrene 0.02 mg/Kg Pyrene 0.02 mg/Kg 2-Fluorobiphenyl Nitrobenzene-d5 p-Terphenyl-d14 Sediment - SOCs 1,2,4-Trichlorobenzene 0.5 mg/Kg 1,2-Dichlorobenzene 0.5 mg/Kg 1,3-Dichlorobenzene 0.5 mg/Kg 1,4-Dichlorobenzene 0.5 mg/Kg 1-Methylnaphthalene 0.5 mg/Kg 2,4,5-Trichlorophenol 0.5 mg/Kg 2,4,6-Trichlorophenol 0.5 mg/Kg 2,4-Dichlorophenol 0.5 mg/Kg 2,4-Dimethylphenol 0.5 mg/Kg 2,4-Dinitrophenol 2 mg/Kg 2,4-Dinitrotoluene 0.5 mg/Kg 2,6-Dichlorophenol 0.5 mg/Kg 2,6-Dinitrotoluene 0.5 mg/Kg 2-Chloronaphthalene 0.5 mg/Kg 2-Chlorophenol 0.5 mg/Kg 2-Methylnaphthalene 0.5 mg/Kg 2-Methylphenol 0.5 mg/Kg 2-Nitroaniline 0.5 mg/Kg 2-Nitrophenol 0.5 mg/Kg 3,3'-Dichlorobenzidine 2.5 mg/Kg 3 & 4 Methylphenol 1 mg/Kg 3-Nitroaniline 0.5 mg/Kg 4,6-Dinitro-2-methylphenol 2.5 mg/Kg 4-Bromophenyl phenyl ether 0.5 mg/Kg 4-Chloro-3-methylphenol 0.5 mg/Kg 4-Chloroaniline 0.5 mg/Kg 4-Chlorophenyl phenyl ether 0.5 mg/Kg 4-Nitroaniline 0.5 mg/Kg 4-Nitrophenol 0.5 mg/Kg Acenaphthene 0.5 mg/Kg Acenaphthylene 0.5 mg/Kg Aniline 0.5 mg/Kg Anthracene 0.5 mg/Kg Azobenzene 0.5 mg/Kg Benzidine 5 mg/Kg

Benzo[a]anthracene 0.5 mg/Kg Benzo[a]pyrene 0.5 mg/Kg Benzo[b]fluoranthene 0.5 mg/Kg Benzo[g,h,i]perylene 0.5 mg/Kg Benzo[k]fluoranthene 0.5 mg/Kg Benzoic acid 2.5 mg/Kg Benzyl alcohol 0.5 mg/Kg Bis(2-chloroethoxy)methane 0.5 mg/Kg Bis(2-chloroethyl)ether 2.5 mg/Kg bis (2-Chloroisopropyl) ether 0.5 mg/Kg Bis(2-ethylhexyl) phthalate 0.5 mg/Kg Butyl benzyl phthalate 0.5 mg/Kg Chrysene 0.5 mg/Kg Dibenz(a,h)anthracene 0.5 mg/Kg Dibenzofuran 0.5 mg/Kg Diethyl phthalate 0.5 mg/Kg Dimethyl phthalate 0.5 mg/Kg Di-n-butyl phthalate 0.5 mg/Kg Di-n-octyl phthalate 0.5 mg/Kg Fluoranthene 0.5 mg/Kg Fluorene 0.5 mg/Kg Hexachloro-1,3-butadiene 0.5 mg/Kg Hexachlorobenzene 0.5 mg/Kg Hexachlorocyclopentadiene 1.5 mg/Kg Hexachloroethane 0.5 mg/Kg Indeno[1,2,3-cd]pyrene 0.5 mg/Kg Isophorone 0.5 mg/Kg Naphthalene 0.5 mg/Kg Nitrobenzene 2 mg/Kg N-Nitrosodimethylamine 0.5 mg/Kg N-Nitrosodi-n-propylamine 0.5 mg/Kg n-Nitrosodiphenylamine(as diphenylamine) 0.5 mg/Kg Pentachlorophenol 2.5 mg/Kg Phenanthrene 0.5 mg/Kg Phenol 0.5 mg/Kg Pyrene 0.5 mg/Kg Pyridine 0.5 mg/Kg 2,4,6-Tribromophenol 2-Fluorobiphenyl 2-Fluorophenol

Nitrobenzene-d5 p-Terphenyl-d14 Phenol-d6 Sediment - Pesticides 4,4'-DDD 1 ug/Kg 4,4'-DDE 1 ug/Kg 4,4'-DDT 1 ug/Kg Aldrin 1 ug/Kg alpha-BHC 1 ug/Kg alpha-Chlordane 1 ug/Kg beta-BHC 1 ug/Kg Chlordane 5 ug/Kg delta-BHC 1 ug/Kg Dieldrin 0.2 ug/Kg Endosulfan I 1 ug/Kg Endosulfan II 1 ug/Kg Endosulfan sulfate 1 ug/Kg Endrin 1 ug/Kg Endrin aldehyde 1 ug/Kg Endrin ketone 1 ug/Kg gamma-Chlordane 1 ug/Kg gamma-BHC 1 ug/Kg Heptachlor 1 ug/Kg Heptachlor epoxide 1 ug/Kg Methoxychlor 1 ug/Kg Toxaphene 5 ug/Kg Tetrachloro-m-xylene DCB Decachlorobiphenyl Sediment - PCBs Aroclor-1016 10 ug/Kg Aroclor-1221 10 ug/Kg Aroclor-1232 10 ug/Kg Aroclor-1242 10 ug/Kg Aroclor-1248 10 ug/Kg Aroclor-1254 10 ug/Kg Aroclor-1260 10 ug/Kg Tetrachloro-m-xylene DCB Decachlorobiphenyl Sediment - BPA Bisphenol A 0.01 mg/Kg Sediment - TOC Total Organic Carbon 1 mg/L Sediment - Dioxins and Furans 2,3,7,8-TCDD 10 pg/L

2,3,7,8-TCDF 10 pg/L 1,2,3,7,8-PeCDD 50 pg/L 1,2,3,7,8-PeCDF 50 pg/L 2,3,4,7,8-PeCDF 50 pg/L 1,2,3,4,7,8-HxCDD 50 pg/L 1,2,3,6,7,8-HxCDD 50 pg/L 1,2,3,7,8,9-HxCDD 50 pg/L 1,2,3,4,7,8-HxCDF 50 pg/L 1,2,3,6,7,8-HxCDF 50 pg/L 1,2,3,7,8,9-HxCDF 50 pg/L 2,3,4,6,7,8-HxCDF 50 pg/L 1,2,3,4,6,7,8-HpCDD 50 pg/L 1,2,3,4,6,7,8-HpCDF 50 pg/L 1,2,3,4,7,8,9-HpCDF 50 pg/L OCDD 100 pg/L OCDF 100 pg/L Total TCDD 10 pg/L Total TCDF 10 pg/L Total PeCDD 50 pg/L Total PeCDF 50 pg/L Total HxCDD 50 pg/L Total HxCDF 50 pg/L Total HpCDD 50 pg/L Total HpCDF 50 pg/L 13C-2,3,7,8-TCDD 2000 pg/L 13C-2,3,7,8-TCDF 2000 pg/L 13C-1,2,3,7,8-PeCDD 2000 pg/L 13C-1,2,3,7,8-PeCDF 2000 pg/L 13C-2,3,4,7,8-PeCDF 2000 pg/L 13C-1,2,3,4,7,8-HxCDD 2000 pg/L 13C-1,2,3,6,7,8-HxCDD 2000 pg/L 13C-1,2,3,4,7,8-HxCDF 2000 pg/L 13C-1,2,3,6,7,8-HxCDF 2000 pg/L 13C-2,3,4,6,7,8-HxCDF 2000 pg/L 13C-1,2,3,7,8,9-HxCDF 2000 pg/L 13C-1,2,3,4,6,7,8-HpCDD 2000 pg/L 13C-1,2,3,4,6,7,8-HpCDF 2000 pg/L 13C-1,2,3,4,7,8,9-HpCDF 2000 pg/L 13C-OCDD 4000 pg/L 13C-OCDF 4000 pg/L

Sediment - PFAS Perfluorooctanoic acid (PFOA) 0.2 ug/Kg Perfluorobutanoic acid (PFBA) 0.2 ug/Kg Perfluorooctanesulfonic acid (PFOS) 0.2 ug/Kg Perfluoropentanoic acid (PFPeA) 0.2 ug/Kg Perfluorohexanoic acid (PFHxA) 0.2 ug/Kg

13C4 PFOS

Perfluoroheptanoic acid (PFHpA) 0.2 ug/Kg

13C4 PFOA

Perfluorononanoic acid (PFNA) 0.2 ug/Kg Perfluorodecanoic acid (PFDA) 0.2 ug/Kg Perfluorobutanesulfonic acid (PFBS) 0.2 ug/Kg Perfluoropentanesulfonic acid (PFPeS) 0.2 ug/Kg Perfluorohexanesulfonic acid (PFHxS) 0.2 ug/Kg Perfluoroheptanesulfonic acid (PFHpS) 0.2 ug/Kg Perfluorodecanesulfonic acid (PFDS) 0.2 ug/Kg Perfluorooctanesulfonamide (FOSA) 0.2 ug/Kg

13C8 FOSA

13C4 PFBA

13C5 PFPeA 13C2 PFHxA 13C4 PFHpA

13C5 PFNA

13C2 PFDA

13C3 PFBS

18O2 PFHxS

1H,1H,2H,2H-Perfluorooctane sulfonic acid (6:2 FTS) 0.2 ug/Kg

13C2 6:2 FTS

Hexafluoropropylene Oxide Dimer Acid (HFPO- DA/GenX) 0.2 ug/Kg

13C3 HFPO-DA

PFPrS 0.2 ug/Kg Water - Nutrients Total Kjeldahl Nitrogen 1 mg/L Phosphorus, Total 0.1 mg/L Water - TOC/DOC Total Organic Carbon 0.5 mg/L Dissolved Organic Carbon 0.5 mg/L Water - Metals Antimony 2 ug/L Arsenic 1 ug/L Barium 1 ug/L Beryllium 0.5 ug/L

Cadmium 1 ug/L Chromium 2 ug/L Cobalt 1 ug/L Copper 2 ug/L Lead 1 ug/L Molybdenum 2 ug/L Nickel 2 ug/L Selenium 2 ug/L Silver 1 ug/L Thallium 1 ug/L Vanadium 2 ug/L Zinc 20 ug/L Mercury 0.0002 mg/L Water - Perchlorate Perchlorate 2 ug/L Water - PAHs 1-Methylnaphthalene 0.2 ug/L 2-Methylnaphthalene 0.2 ug/L Acenaphthene 0.2 ug/L Acenaphthylene 0.2 ug/L Anthracene 0.2 ug/L Benzo[g,h,i]perylene 0.2 ug/L Benzo[k]fluoranthene 0.2 ug/L Benzo[a]anthracene 0.2 ug/L Benzo[a]pyrene 0.2 ug/L Benzo[b]fluoranthene 0.2 ug/L Chrysene 0.2 ug/L Dibenz(a,h)anthracene 0.2 ug/L Fluoranthene 0.2 ug/L Fluorene 0.2 ug/L Indeno[1,2,3-cd]pyrene 0.2 ug/L Naphthalene 0.2 ug/L Phenanthrene 0.2 ug/L Pyrene 0.2 ug/L 2-Fluorobiphenyl Nitrobenzene-d5 p-Terphenyl-d14 Water - SOCs 1,2,4-Trichlorobenzene 10 ug/L 1,2-Dichlorobenzene 10 ug/L 1,3-Dichlorobenzene 10 ug/L 1,4-Dichlorobenzene 10 ug/L 1-Methylnaphthalene 10 ug/L

2,4,5-Trichlorophenol 10 ug/L 2,4,6-Trichlorophenol 10 ug/L 2,4-Dichlorophenol 10 ug/L 2,4-Dimethylphenol 10 ug/L 2,4-Dinitrophenol 50 ug/L 2,4-Dinitrotoluene 10 ug/L 2,6-Dichlorophenol 10 ug/L 2,6-Dinitrotoluene 10 ug/L 2-Chloronaphthalene 10 ug/L 2-Chlorophenol 10 ug/L 2-Methylnaphthalene 10 ug/L 2-Methylphenol 10 ug/L 2-Nitroaniline 10 ug/L 2-Nitrophenol 10 ug/L 3,3'-Dichlorobenzidine 10 ug/L 3 & 4 Methylphenol 10 ug/L 3-Nitroaniline 10 ug/L 4,6-Dinitro-2-methylphenol 50 ug/L 4-Bromophenyl phenyl ether 10 ug/L 4-Chloro-3-methylphenol 10 ug/L 4-Chloroaniline 10 ug/L 4-Chlorophenyl phenyl ether 10 ug/L 4-Nitroaniline 10 ug/L 4-Nitrophenol 10 ug/L Acenaphthene 10 ug/L Acenaphthylene 10 ug/L Aniline 10 ug/L Anthracene 10 ug/L Azobenzene 10 ug/L Benzidine 50 ug/L Benzo[a]anthracene 10 ug/L Benzo[a]pyrene 10 ug/L Benzo[b]fluoranthene 10 ug/L Benzo[g,h,i]perylene 10 ug/L Benzo[k]fluoranthene 10 ug/L Benzoic acid 50 ug/L Benzyl alcohol 10 ug/L Bis(2-chloroethoxy)methane 10 ug/L Bis(2-chloroethyl)ether 25 ug/L bis (2-Chloroisopropyl) ether 10 ug/L

Bis(2-ethylhexyl) phthalate 10 ug/L Butyl benzyl phthalate 10 ug/L Chrysene 10 ug/L Dibenz(a,h)anthracene 10 ug/L Dibenzofuran 10 ug/L Diethyl phthalate 10 ug/L Dimethyl phthalate 10 ug/L Di-n-butyl phthalate 10 ug/L Di-n-octyl phthalate 10 ug/L Fluoranthene 10 ug/L Fluorene 10 ug/L Hexachloro-1,3-butadiene 10 ug/L Hexachlorobenzene 10 ug/L Hexachlorocyclopentadiene 25 ug/L Hexachloroethane 10 ug/L Indeno[1,2,3-cd]pyrene 10 ug/L Isophorone 10 ug/L Naphthalene 10 ug/L Nitrobenzene 25 ug/L N-Nitrosodimethylamine 10 ug/L N-Nitrosodi-n-propylamine 10 ug/L n-Nitrosodiphenylamine(as diphenylamine) 10 ug/L Pentachlorophenol 10 ug/L Phenanthrene 10 ug/L Phenol 10 ug/L Pyrene 10 ug/L Pyridine 10 ug/L 2,4,6-Tribromophenol 2-Fluorobiphenyl 2-Fluorophenol Nitrobenzene-d5 p-Terphenyl-d14 Phenol-d6 Water - Pesticides 4,4'-DDD 0.04 ug/L 4,4'-DDE 0.02 ug/L 4,4'-DDT 0.02 ug/L Aldrin 0.02 ug/L alpha-BHC 0.008 ug/L alpha-Chlordane 0.02 ug/L beta-BHC 0.03 ug/L

Chlordane 0.2 ug/L delta-BHC 0.02 ug/L Dieldrin 0.02 ug/L Endosulfan I 0.008 ug/L Endosulfan II 0.04 ug/L Endosulfan sulfate 0.02 ug/L Endrin 0.02 ug/L Endrin aldehyde 0.2 ug/L Endrin ketone 0.02 ug/L gamma-Chlordane 0.06 ug/L gamma-BHC 0.008 ug/L Heptachlor 0.008 ug/L Heptachlor epoxide 0.04 ug/L Methoxychlor 0.04 ug/L Toxaphene 0.4 ug/L Tetrachloro-m-xylene DCB Decachlorobiphenyl Water - PCBs Aroclor-1016 0.4 ug/L Aroclor-1221 0.4 ug/L Aroclor-1232 0.4 ug/L Aroclor-1242 0.4 ug/L Aroclor-1248 0.4 ug/L Aroclor-1254 0.4 ug/L Aroclor-1260 0.4 ug/L Tetrachloro-m-xylene DCB Decachlorobiphenyl Water - Dioxins and Furans 2,3,7,8-TCDD 10 pg/L 2,3,7,8-TCDF 10 pg/L 1,2,3,7,8-PeCDD 50 pg/L 1,2,3,7,8-PeCDF 50 pg/L 2,3,4,7,8-PeCDF 50 pg/L 1,2,3,4,7,8-HxCDD 50 pg/L 1,2,3,6,7,8-HxCDD 50 pg/L 1,2,3,7,8,9-HxCDD 50 pg/L 1,2,3,4,7,8-HxCDF 50 pg/L 1,2,3,6,7,8-HxCDF 50 pg/L 1,2,3,7,8,9-HxCDF 50 pg/L 2,3,4,6,7,8-HxCDF 50 pg/L 1,2,3,4,6,7,8-HpCDD 50 pg/L

1,2,3,4,6,7,8-HpCDF 50 pg/L 1,2,3,4,7,8,9-HpCDF 50 pg/L OCDD 100 pg/L OCDF 100 pg/L Total TCDD 10 pg/L Total TCDF 10 pg/L Total PeCDD 50 pg/L Total PeCDF 50 pg/L Total HxCDD 50 pg/L Total HxCDF 50 pg/L Total HpCDD 50 pg/L Total HpCDF 50 pg/L 13C-2,3,7,8-TCDD 2000 pg/L 13C-2,3,7,8-TCDF 2000 pg/L 13C-1,2,3,7,8-PeCDD 2000 pg/L 13C-1,2,3,7,8-PeCDF 2000 pg/L 13C-2,3,4,7,8-PeCDF 2000 pg/L 13C-1,2,3,4,7,8-HxCDD 2000 pg/L 13C-1,2,3,6,7,8-HxCDD 2000 pg/L 13C-1,2,3,4,7,8-HxCDF 2000 pg/L 13C-1,2,3,6,7,8-HxCDF 2000 pg/L 13C-2,3,4,6,7,8-HxCDF 2000 pg/L 13C-1,2,3,7,8,9-HxCDF 2000 pg/L 13C-1,2,3,4,6,7,8-HpCDD 2000 pg/L 13C-1,2,3,4,6,7,8-HpCDF 2000 pg/L 13C-1,2,3,4,7,8,9-HpCDF 2000 pg/L 13C-OCDD 4000 pg/L 13C-OCDF 4000 pg/L Water - PFAS Perfluorobutanoic acid (PFBA) 5 ng/L Perfluoropentanoic acid (PFPeA) 2 ng/L Perfluorohexanoic acid (PFHxA) 2 ng/L Perfluoroheptanoic acid (PFHpA) 2 ng/L Perfluorooctanoic acid (PFOA) 2 ng/L Perfluorononanoic acid (PFNA) 2 ng/L Perfluorodecanoic acid (PFDA) 2 ng/L Perfluorobutanesulfonic acid (PFBS) 2 ng/L Perfluoropentanesulfonic acid (PFPeS) 2 ng/L Perfluorohexanesulfonic acid (PFHxS) 2 ng/L Perfluoroheptanesulfonic acid (PFHpS) 2 ng/L Perfluorooctanesulfonic acid (PFOS) 2 ng/L

Perfluorodecanesulfonic acid (PFDS) 2 ng/L Perfluorooctanesulfonamide (FOSA) 2 ng/L

13C8 FOSA

13C4 PFBA

13C5 PFPeA 13C2 PFHxA 13C4 PFHpA

13C4 PFOA

13C5 PFNA

13C2 PFDA

13C3 PFBS

18O2 PFHxS

13C4 PFOS

1H,1H,2H,2H-Perfluorooctane sulfonic acid (6:2 FTS) 5 ng/L

13C2 6:2 FTS

Hexafluoropropylene Oxide Dimer Acid (HFPO- DA/GenX) 4 ng/L

13C3 HFPO-DA ng/L PFPrS 2 ng/L

4. Delivery Location Contractor shall deliver the sample bottles to the following address:

Bureau of Reclamation Lower Colorado Basin Regional Office Attention: Thomas Ashley (LCB-2629) 500 Date Street, Bldg. 900 Boulder City, NV 89005

5. Performance Period The ordering period will be five years under an Indefinite Delivery/Indefinite Quantity (IDIQ) contract; Task Orders will be issued on an as needed basis.