Attachment 1 FY23 Lab Sampling - SOW.pdf

Anniston Army Depot

Statement of Work

Lab Sampling and Analysis

1.0 Description of Work: The Government has a requirement to generate analytical data from laboratory analysis of samples that have been collected to comply with Anniston Army Depot

(ANAD) environmental monitoring requirements for the following:

1.0 Description of Work: The Government has a requirement to generate analytical data from laboratory analysis of samples that have been collected to comply with Anniston Army Depot

(ANAD) environmental monitoring requirements for the following:

• Testing requirements as outlined in the Anniston Army Depot (ANAD) National

Pollutant Discharge Elimination System (NPDES) Permit No. AL0002658, issued by the Alabama Department of Environmental Management (ADEM) for ANAD’s wastewater and storm water discharges.

• Hazardous waste determination samples analyzed in accordance with all current state and federal regulations.

• Other analyses required by ANAD’s environmental and quality programs for the characterization of various materials and substances.

1.1 This contract will be a base contract with four option years.

1.2 Scope Changes. The contractor shall not proceed with any verbal or written change(s) to the scope of work from sources other than the Contracting Officer, who will provide changes in writing.

2.0 Scope of Work:

2.1 The contractor laboratory shall comply with the annual Discharge Monitoring Report-

Quality Assurance (DMR-QA) Study mandated by the Environmental Protection Agency (EPA) and the Clean Water Act (Section 308) as well as relevant and applicable ADEM requirements.

The contractor laboratory may use reporting data from a Water Pollution (WP) Study. Study samples must be purchased from an accredited proficiency test provider by the contractor. A list of accredited proficiency testing providers is listed in the annual study announcement letter.

When the study opens, a copy of the study announcement will be emailed to the contractor.

2.2 The contractor shall provide all labor, equipment, and materials necessary, for the transportation and analysis of samples collected and stored at the ANAD environmental laboratory, including the required sample containers, and transport coolers, and courier service.

2.3 Disposal of any waste generated from analyses or left over from sampling shall be the sole responsibility of the contractor, after the applicable holding time. Contractor shall provide information upon request as to the final disposition of any wastes, including certificate(s) of disposal or destruction. Disposal shall be conducted by the contractor in accordance with

• Testing requirements as outlined in the Anniston Army Depot (ANAD) National

Pollutant Discharge Elimination System (NPDES) Permit No. AL0002658, issued by the Alabama Department of Environmental Management (ADEM) for ANAD’s wastewater and storm water discharges.

• Hazardous waste determination samples analyzed in accordance with all current state and federal regulations.

• Other analyses required by ANAD’s environmental and quality programs for the characterization of various materials and substances.

1.1 This contract will be a base contract with four option years.

1.2 Scope Changes. The contractor shall not proceed with any verbal or written change(s) to the scope of work from sources other than the Contracting Officer, who will provide changes in writing.

2.0 Scope of Work:

2.1 The contractor laboratory shall comply with the annual Discharge Monitoring Report-

Quality Assurance (DMR-QA) Study mandated by the Environmental Protection Agency (EPA) and the Clean Water Act (Section 308) as well as relevant and applicable ADEM requirements.

The contractor laboratory may use reporting data from a Water Pollution (WP) Study. Study samples must be purchased from an accredited proficiency test provider by the contractor. A list of accredited proficiency testing providers is listed in the annual study announcement letter.

When the study opens, a copy of the study announcement will be emailed to the contractor.

2.2 The contractor shall provide all labor, equipment, and materials necessary, for the transportation and analysis of samples collected and stored at the ANAD environmental laboratory, including the required sample containers, and transport coolers, and courier service.

2.3 Disposal of any waste generated from analyses or left over from sampling shall be the sole responsibility of the contractor, after the applicable holding time. Contractor shall provide information upon request as to the final disposition of any wastes, including certificate(s) of disposal or destruction. Disposal shall be conducted by the contractor in accordance with applicable environmental laws and regulations and in compliance with relevant safety standards.

2.4 The required work consists of analyzing samples from ANAD discharge sampling points, analyzing samples from hazardous waste and production processes, and providing timely reports on the analytical results. ANAD environmental lab personnel will prepare samples for analysis.

2.4.1 The Contractor shall pickup the government provided samples as coordinated with the

Contracting Officer Representative (COR). The COR will notify the Contractor at least 24 prior to sample pickup. The Contractor shall be responsible for providing all materials required for ensuring proper sample conditions during transport. Samples shall be picked up during normal operating times unless an alternate time and day is agreed upon by both parties. All requested pick-up samples are to be picked up at the time requested by ANAD Environmental Lab

2.4.2 Should ANAD personnel be required to ship samples via FedEx or other transportation service, Contractor shall be responsible for providing all shipping materials, including shipping labels, coolers, packing material, etc. and shall be shipped at the Contractor’s cost.

2.5 All samples shall be analyzed within the proper hold times and results shall be reported in accordance with Attachment B of this statement of work.

2.6 The contractor shall accomplish required testing as follows. A detailed breakdown of required testing can be found in Attachment A.

2.6.1 Resource Conservation and Recovery Act Waste Profile Sampling.

The contractor shall analyze samples, collected by the Depot, for the purpose of hazardous waste determination by the method requested. Typical analytical sampling methods requested for waste profiling include, but are not limited to, Polychlorinated Biphenyls (PCBs), Perfluorooctanoic acid and Perfluorooctane Sulfonate (PFOA/PFOS), Explosives, Toxicity

Characteristic Leaching Procedure (TCLP) metals, total metals, TCLP Volatile Organic Analysis

(VOA), TCLP Semi-Volatile Organic Analysis (SVOA), Total VOA, Total SVOA, flash point, and pH. These tests will be requested based on the process generating the waste material and chemical and/or physical properties of the material to be tested. Therefore, requested analyses may be added or excluded. Sample matrices include, but are not limited to, solids (organic and inorganic blast media, filters consisting of metals, charcoal, plastic or organic woven material, soils, rags/cloth, paint chips, absorbents), liquids (water, paints, solvents, antifreeze, petroleum fluids, detergents), and sludges (wastewater treatment filter cake, grease, wet soils, chemical plating/cleaning vat residuals, and oil and grease).

2.6.2 Asbestos and lead samples from buildings, roofing, construction projects, equipment, etc., throughout ANAD. Periodically, ANAD will require asbestos sampling from a construction or demolition project and/or other remediation type activity. The asbestos samples, which were collected by the Depot, shall be analyzed via Polarized Light Microscopy (PLM) method. The quantity of asbestos and/or lead sampling throughout the year cannot be estimated, therefore, pricing shall be based on a per sample analysis.

2.6.3 Industrial Wastewater and Sewer Treatment Plant. ANAD’s National Pollution

Discharge Elimination System (NPDES) permit requires the collection and sampling of several analytes in the water prior to discharge. The required analytes are included in Appendix A.

2.6.4 Toxicity and Biomonitoring Testing at the Sewage Treatment Plant: The Contractor shall be responsible for all sample collection and testing analysis. The sample collection and testing shall be performed in accordance with the latest edition of "EPA Short-Term Methods for

Estimating the Chronic Toxicity of Effluents and Receiving Water to Freshwater Organisms

(EPA 821-R-02-013)". Specifically, the Larval Survival and Growth Test, (Method 1000.0) shall be used for the (Pimephales promelas ) test and the Survival and Reproduction Test (Method

1002.0) shall be used for the ( Ceriodaphnia dubia) test. The sample collection and testing shall be performed on a quarterly basis as outlined in Attachment A.

4.0 Contractor Responsibilities: The contractor shall be responsible for performing the work described in this section and for providing all equipment and personnel necessary to perform this work. The Contractor shall:

4.1 Maintain a 2 month supply of sampling supplies as follows:

4.1.1 Coolers in a size and capacity necessary for transportation of all samples from each event.

4.1.2 Sampling bottles. Bottles shall be clean per the Environmental Protection Agency

(EPA) December 1992 Specifications and Guidance for Contaminant-Free Sample

Containers and Office of Solid waste and Emergency Response Directive #9240.0-

05A, EPA/R-93/051.

4.1.3 Plastic bags and bubble bags for use during shipping.

4.1.4 Shipping labels.

4.2 Arrange subcontracting of all analyses that are outside its capabilities to perform.

Subcontractors are responsible for all reporting and for complying with quality control requirements as is the primary Contractor. ANAD Environmental Lab shall be notified of any analyses submitted to a subcontractor. ANAD shall receive documentation ensuring the subcontractor is compliant with the National Environmental Laboratory Accreditation

Conference (NELAC) and other requirements set forth in this scope. This documentation shall be received before the samples are sent to the subcontractor for analysis.

4.3 Maintain a proper Chain of Custody (COC) for all samples from the time the samples are received from ANAD until the analytical results are reported to ANAD.

4.4 Upon arrival at the Environmental Lab, ensure that the COC is correct and shall resolve any discrepancies with ANAD Environmental Lab personnel before acceptance of the samples.

Should there be any discrepancies with a particular sample (pH, preservative, etc.), the contractor lab shall notify ANAD Environmental Laboratory immediately in order to resolve the issue and re-submit the sample.

4.5 Handle and analyze all samples in such a way as to ensure the integrity of the sample/analysis and such that all hold time/preservative requirements are met. In the event of an error concerning the sample, analysis, or hold time, the contractor shall contact the ANAD

Environmental Lab immediately to resolve the issue.

4.6 Refrigerate and store excess samples for 2 calendar weeks from receipt in case analytical results require verification or in case other issues arise. After 2 calendar weeks, the contractor will properly dispose samples in accordance with standard laboratory operating procedures and all applicable environmental laws and regulations.

4.7 Furnish all sample analytical results (that lists only specific analytes) to the ANAD Program

Manager designated on the chain of custody and to the laboratory chemist. Results shalll be submitted electronically (read-only format) no later than 7 calendar days from when the sample is received unless rush results are requested by ANAD and a time frame is agreed upon by both parties. Contractor laboratory quality control data must also be submitted with each report. The report shall include, at a minimum, analyte chemical name, Chemical Abstract Services (CAS) number, result, unit, Method Detection Limit, reporting or quantitation limit, flag, dilution factor, date/time analyzed, analyst, and batch number. A copy of each invoice and report shall also be sent to the Directorate of Risk Management’s Program Analyst for budgetary accountability.

4.8 Provide expedited analysis (ranging from same day to one week). Expedited analysis will be required by ANAD for certain sampling sets.

5.0 Activities on a Firm-Fixed Price Basis

5.1 Perform analytical testing on samples collected from the Anniston Army Depot.

The contractor shall provide all labor, equipment, and materials necessary, including the required sample containers and transport coolers, and courier service, for the transportation and analysis of samples collected and stored at the ANAD environmental laboratory. Disposal of any waste generated from analyses or left over from sampling shall be the sole responsibility of the contractor, after the applicable holding time.

Analytical results shall be presented in a Level II analytical data package. Analytical results shall only list specific analytes requested by ANAD. The report shall include, at a minimum, Chemical Abstract Services (CAS) number, result, units, Method Detection Limits (MDL), reporting or quantification limit, flags, dilution factor, date/time analyzed, analyst, and batch number. There is no limit in the scope of work as to the amount of samples that will be sent for analysis; therefore, pricing shall be based on one sample per analytical method and standard turn-around-time.

5.2 Provide expedited analysis of analytical data.

The contractor shall provide expedited analysis of the analytical samples, ranging from one day to one week, upon request of ANAD. Pricing shall be provided based on timeframes in which expedited analysis can be provided by the laboratory.

6.0 Quality Control Requirements: In the event that an error has been made in the analysis or sample results are questionable, the contractor shall perform a re-test without additional charge to the Government. If the holding time of the existing sample has not expired, that sample will be re-tested. If the holding time has expired, another sample shall be collected and transported for re-testing at the discretion of the Government. Replacement samples will be collected by

ANAD staff in the event that problems occur with shipping, testing, invalidation of results due to unacceptable QA/QC or rejection of results by ANAD. ANAD reserves the right to review data deliverables and reject any analytical result. Rejection will be based on sound technical review of the data deliverables by ANAD. ANAD also reserves the right to reject any analytical result if contractual requirements are not adhered to. Replacement samples shall be analyzed by the contractor at no additional cost to the government.

6.1 The contractor shall provide a Quality Control Statement or Case Narrative with all analytical reports.

6.2 The contractor shall provide a copy of the Laboratory Quality Control Procedures when submitting a proposal. Laboratory Quality Control Procedures must also be submitted for all subcontract labs.

6.3 ANAD may request that an ANAD sample be used for matrix spiking. The contractor shall provide sufficient information regarding number of containers and sample volume or mass required to perform this request.

7.0 Analysis: All analysis of samples/waste shall be the responsibility of the Contractor.

ANAD reserves the right to request copies of any analyses, including bench sheets, raw data, quality assurance/quality control (QA/QC) data, etc.

7.1 ANAD may occasionally require additional analyses for constituents or methods not specifically identified in this SOW. Upon request, the contractor may be asked to provide these analyses. ANAD may specify the sub-contract laboratory for such analyses during the contract period, if one is required.

7.2 Reporting Limits for the analytical results reported in accordance with the contract will generally be determined by regulatory action levels (i.e RCRA/ TCLP). If the reporting limits are not met, action shall be taken by the contractor to identify what issues are preventing the desired goal, and communication shall be provided between ANAD and the contractor and/or subcontractor to address actions that may be taken to achieve the required data (i.e., adjustment to injection volume, dilution factors/multiple sample dilutions, sample prep alternatives or cleanup, use of screening detectors or alternate detectors). Reporting Limits are listed under

Attachment B of this document.

7.3 Method 1311- Toxicity Characteristic Leaching Procedure – Results shall be reported using the regulatory unit (mg/l). The contractor shall determine and report the appropriate single value result for a sample where multiple analyses are required in accordance with the method for direct comparison to the regulatory threshold.

8.0 Accreditation: As outlined in the DOD Quality Systems Manual (QSM), the Contractor and all subcontractors must be compliant with the National Environmental Laboratory Accreditation

Conference (NELAC).

9.0 Applicable Publications and Regulations: The following laws and regulations with the latest amendments in effect on the date of this action form a part of these specifications, as well as those referred to in paragraph 5 above.

a. Alabama Water Pollution Control Act, Sections 22-22-1 et seq., Code of Alabama (1975) as amended.

b. Alabama Environmental Management Act, Sections 22-22A-1 et seq., Code of Alabama

(1975) as amended.

c. Alabama Air Pollution Control Act, Sections 22-28-1 et seq., Code of Alabama (1975) as amended.

d. Hazardous Waste Management and Minimization Act, Sections 22-30-1 et seq., Code of

Alabama (1975) as amended.

e. Alabama Department of Environmental Management Administrative Code:

(1) ADEM Admin. Code R. 335-1-.01 et seq.-General Administration

(2) ADEM Admin. Code R. 335-3-.01 et seq.-Air Division Rules

(3) ADEM Admin. Code R. 335-6-.01 et seq.-Water Division Rules

(4) ADEM Admin. Code R. 335-14-.01 et seq.-Hazardous Waste Program

f. Resource Conservation and Recovery Act as amended (1978, 1980, 1984), 42 USC 6901 et seq.

g. Clean Water Act as amended (1973-1985), 33 USC 1251 et seq.

h. Clean Air Act as amended (1973, 1974, 1977, 1978, 1980, 1981, 1983), 42 USC 7401 et seq.

i. Comprehensive Environmental Response, Compensation, and Liability Act as amended (1982, 1986), 42 USC 9601 et seq.

j. Code of Federal Regulations, Title 40, Protection of the Environment, with emphasis upon

Parts 260-268, 270-272, 300, 302.

k. ANAD National Pollutant Discharge Elimination System (NPDES) Permit No. AL0002658, issued by ADEM.

ATTACHMENT A

Parameter Sample Type Month Cost

Asbestos Waste Profile

Cyanide (Free) IWTP

Total Toxic Organics IWTP

TKN STP Apr-Oct

Nitrate + Nitrite STP Apr-Oct

Phosphate STP Apr-Oct

Mercury STP Jan & Jul

Toxicity and Biomonitoring (Pimephales promelas) STP Quarterly

Toxicity and Biomonitoring (Ceriodaphnia dubia) STP Quarterly

BETX/Naphthalene Storm Water

Cyanide (Total and Amenable) Storm Water

Fluorene Storm Water

Perchlorates Storm Water Annual

TKN Storm Water

Nitrate + Nitrite Storm Water

Flashpoint Waste Sample pH Waste Sample

PAH Waste Sample

Semi-Volatiles Waste Sample

Volatiles Waste Sample

RCRA Metals and Additional Metals (Sb, Be, Ni, TI, V, Zn) Waste Sample

TCLP/RCRA Volatiles Waste Sample

TCLP/RCRA Semi-Volatiles Waste Sample

Total Metals Waste Sample

Total Volatiles Waste Sample

Total Semi-Volatiles Waste Sample

Explosives Varies

Halogens & Water Content Used Oil

NDMA Well Water

Dissolved Metals Well Water

TOX/TOC/Phenols/Chloride Well Water

Total Mercury Waste Sample

PFOA and PFAS Waste Sample

Polychlorinated Biphenyls (PCBs) Waste Sample

*Includes but not limited to all RCRA regulated characteristic hazardous constituents for waste codes D004-D043, constituents listed under F001-F006 and hazardous constituents listed at 40 CFR 268.48 if requested.

ATTACHMENT B

Metals Analysis Reporting Limits

TOTAL METALS – Group A: RCRA Metals

Analyte CAS Number Aqueous Non-Aqueous

RL units RL units

Arsenic 7440-38-2 10.0 µg/L 1.0 mg/kg

Barium 7440-39-3 50. µg/L 5.0 mg/kg

Cadmium 7440-43-9 05.0 µg/L 0.50 mg/kg

Chromium (all forms) 7440-47-3 10. µg/L 5.0 mg/kg

Lead1 7439-92-1 15. µg/L 5.0 mg/kg

Mercury 7439-97-6 0.20 µg/L 0.20 mg/kg

Selenium1 7782-49-2 50. µg/L 1.0 mg/kg

Silver 7440-22-4 10. µg/L 3.0 mg/kg

TOTAL METALS – Group B: Additional CERCLA Metals and non-RCRA Metals with Primary

MCLs

Analyte

CAS Number Aqueous Non-Aqueous

RL units RL units

Antimony 7440-36-0 6.0 µg/L 3.0 mg/kg

Beryllium 7440-41-7 4.0 µg/L 5.0 mg/kg

Cobalt 7440-48-4 5.0 µg/L 5.0 mg/kg

Copper 7440-50-8 5.0 µg/L 2.5 mg/kg

Nickel 7440-02-0 10. µg/L 5.0 mg/kg

Thallium 7440-28-0 2.0 µg/L 1.0 mg/kg

Vanadium 7440-62-2 10. µg/L 5.0 mg/kg

Zinc 7440-66-6 20. µg/L 2.0 mg/kg

TOTAL METALS – Group C: Indicator and Water Quality Metals

Analyte

CAS Number Aqueous Non-Aqueous

RL units RL units

Aluminum 7429-90-5 200. µg/L 100. mg/kg

Calcium 7440-70-2 500. µg/L 100. mg/kg

Iron 7439-89-6 100. µg/L 100. mg/kg

Magnesium 7439-95-4 100. µg/L 10. mg/kg

Manganese 7439-96-5 5.0 µg/L 2.0 mg/kg

Potassium 7440-09-7 100. µg/L 100. mg/kg

Sodium 7440-23-5 500. µg/L 100. mg/kg

TOTAL METALS - Group D: Hexavalent Chromium

Analyte

CAS Number Aqueous Non-Aqueous

Cr6+Aqueous samples 18540-29-9 0.3 µg/L N/A N/A

Cr6+-Non-aqueous1 18540-29-9 N/A N/A 20. mg/kg

TOTAL METALS - Group E: Metals, other

Analyte

CAS Number Aqueous Non-Aqueous

RL units RL units

Boron 7440-42-8 50. µg/L 100. mg/kg

Lithium 7439-93-2 50. µg/L 1.0 mg/kg

Molybdenum 7439-98-7 50. µg/L 1.0 mg/kg

Strontium 7440-24-6 50. µg/L 5.0 mg/kg

Tin 7440-31-5 200. µg/L 2.0 mg/kg

Titanium 7440-32-6 50. µg/L 2.0 mg/kg

ATTACHMENT C

General Chemistry Reporting Limits

GENERAL CHEMISTRY – Group A: Cyanide and Sulfide

Analyte Aqueous Non-Aqueous

CAS

Number RL units RL units

Total Cyanide 57-12-5 0.0050 mg/L 1.0 mg/kg

Free Cyanide 57-12-5 0.2 mg/L 1.0 mg/kg

Amenable Cyanide 57-12-5 0.0050 mg/L 1.0 mg/kg

Total Sulfide 18496-25-8 1.0 mg/L 25. mg/kg

GENERAL CHEMISTRY – Group B: Solid Waste Standard List

Analyte

CAS Number Aqueous Non-Aqueous

Ammonia-N 14798-03-9 0.10 mg/L N/A N/A

Chloride 16887-00-6 2.0 mg/L 20. mg/kg

Nitrate-Nitrite 14797-558/

1479765-0 0.010 mg/L 1.

mg/kg pH N/A 0.1 units 0.1 units

Specific Conductance N/A 5.0 µS/cm N/A N/A

Sulfate 14808-79-8 5.0 mg/L 100. mg/kg

Residue, Filterable (TDS) N/A 20. mg/L N/A N/A

Residue, Total (TS) N/A 20. mg/L N/A N/A

GENERAL CHEMISTRY – Group C: Additional Ground Water Indicator Parameters

CAS Number Aqueous

Non- Aqueous

RL units RL units

Alkalinity7,8a (as CaCO3) N/A 5.0 mg/L N/A N/A

Bicarbonate8a (as CaCO3) 71-52-3 10. mg/L N/A N/A

Carbonate8a (as CaCO3) 3812-32-6 10. mg/L N/A N/A

Eh8a (Oxidation-Reduction Potential) N/A 0 Volts N/A N/A

Fluoride7 16984-48-8 0.10 mg/L N/A N/A

Hardness7 (as CaCO3) N/A 1.0 mg/L N/A N/A

Oxygen, Total Dissolved 7782-44-7 1.0 mg/L N/A N/A

Phosphorus, Total7 (as PO4 3-) 14265-44-2 0.5 mg/L 130 mg/kg

Turbidity7 N/A 0.5 NTU N/A N/A

ATTACHMENT D

Volatile Organic Analysis (VOA) Reporting Limits

VOA – Group A: Standard Volatiles List

Number

Aqueous 25 mL purge Soil/Sediment (low concentration)

RL units RL units

Acetone 67-64-1 20. µg/L 50. µg/kg Acrolein 107-02-6 20 µg/L 40 µg/kg

Benzene 71-43-2 1. µg/L 5. µg/kg

Bromodichloromethane 75-27-4 1. µg/L 5. µg/kg

Bromoform 75-25-2 1. µg/L 5. µg/kg

Bromomethane 74-83-9 2. µg/L 10. µg/kg n-Butanol 71-36-3 1000 µg/L 1000 µg/kg

2-Butanone (MEK) 78-93-3 20. µg/L 50. µg/kg n-Butylbenzene 104-51-8 1. µg/L 5. µg/kg sec-Butylbenzene 135-98-8 1. µg/L 5. µg/kg tert-Butylbenzene 98-06-6 1. µg/L 5. µg/kg

Carbon disulfide 75-15-0 20. µg/L 50. µg/kg

Carbon tetrachloride 56-23-5 1. µg/L 5. µg/kg

Chlorobenzene 108-90-7 1. µg/L 5. µg/kg

Chloroethane 75-00-3 2. µg/L 10. µg/kg

Chloroform 67-66-3 1. µg/L 5. µg/kg

Chloromethane 74-87-3 2. µg/L 10. µg/kg

1,2-Dibromoethane (EDB) 106-93-4 1. µg/L 5. µg/kg

Dibromomethane 74-95-3 1. µg/L 5. µg/kg

1,2-Dichlorobenzene 95-50-1 1. µg/L 5. µg/kg

1,3-Dichlorobenzene 541-73-1 1. µg/L 5. µg/kg

1,4-Dichlorobenzene 106-46-7 1. µg/L 5. µg/kg

Dichlorodifluoromethane 75-71-8 2 µg/L 10. µg/kg

1,1-Dichloroethane 75-34-3 1. µg/L 5. µg/kg

1,2-Dichloroethane 107-06-2 1. µg/L 5. µg/kg

1,1-Dichloroethene 75-35-4 1. µg/L 5. µg/kg cis-1,2-Dichloroethene 156-59-2 1. µg/L 5. µg/kg trans-1,2-Dichloroethene 156-60-5 1. µg/L 5. µg/kg

VOA – Group A: Standard Volatiles List, continued

CAS

Number Aqueous 25 mL purge Soil/Sediment (low concentration)

1,2-Dichloropropane 78-87-5 1. µg/L 5. µg/kg cis-1,3-Dichloropropene 10061-01-5 1. µg/L 5. µg/kg trans-1,3-Dichloropropene 10061-02-6 1. µg/L 5. µg/kg

Ethylbenzene 100-41-4 1. µg/L 5. µg/kg

2-Hexanone (MBK) 591-78-6 20. µg/L 50. µg/kg

Isopropylbenzene 98-82-8 1. µg/L 5. µg/kg p-Isopropylbenzene 99-87-6 1. µg/L 5. µg/kg

Methyl-t-butyl ether (MTBE) 1634-04-4 20. µg/L 50. µg/kg

Methylene chloride 75-09-2 5. µg/L 50. µg/kg

4-Methyl-2-pentanone (MIBK) 108-10-1 20. µg/L 50. µg/kg

Naphthalene 91-20-3 1. µg/L 5. µg/kg n-Propylbenzene 103-65-1 1. µg/L 5. µg/kg

Styrene 100-42-5 1. µg/L 5. µg/kg

1,1,1,2-Tetrachloroethane 630-20-6 1. µg/L 5. µg/kg

1,1,2,2-Tetrachloroethane 79-34-5 1. µg/L 5. µg/kg

Tetrachloroethene 127-18-4 1. µg/L 5. µg/kg

Toluene 108-88-3 1. µg/L 5. µg/kg

1,2,4-Trichlorobenzene 120-82-1 1. µg/L 5. µg/kg

1,1,1-Trichloroethane 71-55-6 1. µg/L 5. µg/kg

1,1,2-Trichloroethane 79-00-5 1. µg/L 5. µg/kg

Trichloroethene 79-01-6 1. µg/L 5. µg/kg

Trichlorofluoromethane 75-69-4 2 µg/L 10 µg/kg

1,2,4 Trimethylbenzene 95-63-6 1. µg/L 5. µg/kg

1,3,5 Trimethylbenzene 108-67-8 1. µg/L 5. µg/kg

Vinyl acetate 108-05-4 20. µg/L 50. µg/kg

Vinyl chloride 75-01-4 1. µg/L 5. µg/kg o-Xylene 95-47-6 1. µg/L 5. µg/kg m-Xylene 108-38-3 1. µg/L 5. µg/kg p-Xylene 106-42-3 1. µg/L 5. µg/kg

VOA – Group B: BTEX and MTBE

Number Aqueous 25 mL purge Soil/Sediment (low

Benzene 71-43-2 1. µg/L 5. µg/kg

Ethylbenzene 100-41-4 1. µg/L 5. µg/kg

Toluene 108-88-3 1. µg/L 5. µg/kg

Xylenes (total o-, m-, and p-) 1330-20-7 1. µg/L 5. µg/kg

Methyl-t-butyl-ether (MTBE) 1634-04-4 10. µg/L 50. µg/kg

VOA – Group C: Antifreeze/Coolant

Analyte

CAS

Number

Aqueous Soil/Sediment

RL units RL units

Ethylene glycol 107-21-1 500. µg/L 500. µg/kg

Propylene glycol 107-21-1 500. µg/L 500. µg/kg

ATTACHMENT E

Semivolatile Organic Analysis (SVOA) and Nonvolatile Organic Analysis (NVOA)

Reporting Limits

SVOA – Group A: Standard Semivolatiles List

CAS

Number

Aqueous Soil/Sediment (low concentration)

RL units RL units

Acenaphthene 83-32-9 10 µg/L 660 µg/kg

Acenaphthylene 208-96-8 10 µg/L 660 µg/kg

Anthracene 120-12-7 10 µg/L 660 µg/kg

Benzo[a]anthracene12a 56-55-3 10 µg/L 660 µg/kg

Benzo[b]fluoranthene12a 205-99-2 10 µg/L 660 µg/kg

Benzo[k]fluoranthene12a 207-08-9 10 µg/L 660 µg/kg

Benzoic acid 65-85-0 50 µg/L 3300 µg/kg

Benzo[g,h,i]perylene 191-24-2 10 µg/L 660 µg/kg

Benzo[a]pyrene12a 50-32-8 10 µg/L 660 µg/kg

Benzyl alcohol 100-54-6 20 µg/L 1300 µg/kg

Bis(2-chloroethoxy)methane 111-91-1 10 µg/L 660 µg/kg

SVOA – Group A: GC/MS Standard Semivolatiles List, continued

Analyte CAS Number Aqueous

Soil/Sediment (low concentration)

RL units RL units

Bis(2-chloroethyl)ether 111-44-4 10 µg/L 660 µg/kg

Bis(2-chloroisopropyl)ether 108-60-1 10 µg/L 660 µg/kg

Bis(2-ethylhexyl)phthalate 117-81-7 10 µg/L 660 µg/kg

4-Bromophenyl phenyl ether 101-55-3 10 µg/L 660 µg/kg

Butyl benzyl phthalate 85-68-7 10 µg/L 660 µg/kg

Carbazole 86-74-8 10 µg/L 660 µg/kg

4-Chloroaniline 106-47-8 20 µg/L 1300 µg/kg

4-Chloro-3-methylphenol 59-50-7 20 µg/L 1300 µg/kg

2-Chloronaphthalene 91-58-7 10 µg/L 660 µg/kg

2-Chlorophenol 95-57-8 10 µg/L 660 µg/kg

4-Chlorophenyl phenyl ether 7005-72-3 10 µg/L 660 µg/kg

Chrysene12b 218-01-9 10 µg/L 660 µg/kg

Dibenzo[a,h]anthracene 53-70-3 10 µg/L 660 µg/kg

Dibenzofuran 132-64-9 10 µg/L 660 µg/kg

Di-n-butylphthalate 84-74-2 10 µg/L 660 µg/kg

3,3’-Dichlorobenzidine 91-94-1 20 µg/L 1300 µg/kg

2,4-Dichlorophenol 120-83-2 10 µg/L 660 µg/kg

Diethyl phthalate 84-66-2 10 µg/L 660 µg/kg

2,4-Dimethylphenol 105-67-9 10 µg/L 660 µg/kg

Dimethyl phthalate 131-11-3 10 µg/L 660 µg/kg

4,6-Dinitro-2-methylphenol 534-52-1 50 µg/L 3300 µg/kg

2,4-Dinitrophenol 51-25-5 50 µg/L 3300 µg/kg

2,4-Dinitrotoluene 121-14-2 10 µg/L 660 µg/kg

2,6-Dinitrotoluene 606-20-2 10 µg/L 660 µg/kg

Di-n-octyl phthalate 117-84-0 10 µg/L 660 µg/kg

Fluoranthene 206-44-0 10 µg/L 660 µg/kg

Fluorene 86-73-7 10 µg/L 660 µg/kg

Hexachlorobenzene 118-74-1 10 µg/L 660 µg/kg

Hexachlorobutadiene 87-68-3 10 µg/L 660 µg/kg

1-Methylnaphthalene 90-12-0 10 µg/L 660 µg/kg

2-Methylnaphthalene 91-57-6 10 µg/L 660 µg/kg

SVOA – Group A: GC/MS Standard Semivolatiles List, continued

CAS

Number

Aqueous Soil/Sediment (low concentration)

RL units RL units

Hexachlorocyclopentadiene 77-47-4 10. µg/L 660 µg/kg

Hexachloroethane 67-72-1 10. µg/L 660 µg/kg

Indeno[1,2,3-cd]pyrene12c 193-39-5 10. µg/L 660 µg/kg

Isophorone 78-59-1 10. µg/L 660 µg/kg

2-Methylnaphthalene 91-57-6 10. µg/L 660 µg/kg

2-Methylphenol (o-cresol) 95-48-7 10. µg/L 660 µg/kg

3-Methylphenol (m-cresol) 108-39-4 10. µg/L 660 µg/kg

4-Methylphenol (p-cresol) 106-44-5 10. µg/L 660 µg/kg

Naphthalene 91-20-3 18. µg/L 18000. µg/kg

2-Nitroaniline18 88-74-4 50. µg/L 3300 µg/kg

3-Nitroaniline 99-09-2 50. µg/L 3300 µg/kg

4-Nitroaniline 100-01-6 20. µg/L 1300 µg/kg

Nitrobenzene16b 98-95-3 10. µg/L 660 µg/kg

2-Nitrophenol 88-75-5 10. µg/L 660 µg/kg

4-Nitrophenol 100-02-7 50. µg/L 3300 µg/kg

N-Nitrosodiphenylamine 86-30-6 10. µg/L 660 µg/kg

N-Nitroso-di-n-propylamine19 621-64-7 10. µg/L 660 µg/kg

Pentachlorophenol20 87-86-5 50. µg/L 3300 µg/kg

Phenanthrene 85-01-8 10. µg/L 660 µg/kg

Phenol 108-95-2 10. µg/L 660 µg/kg

Pyrene 129-00-0 10. µg/L 660 µg/kg

1,2,4-Trichlorobenzene 120-82-1 10. µg/L 660 µg/kg

2,4,5-Trichlorophenol 95-95-4 10. µg/L 660 µg/kg

2,4,6-Trichlorophenol 88-06-2 10. µg/L 660 µg/kg

SVOA – Group B: Polychlorinated Biphenyl Compounds (PCBs) as Aroclors

Analyte

CAS

Number

Aqueous Soil/Sediment

(low

Wipes

RL units RL units RL units

Aroclor 1016 12674-11-2 0.5 µg/L 1800 µg/kg 10. µg/100 cm2

Aroclor 1221 11104-28-2 0.5 µg/L 1800 µg/kg 10. µg/100 cm2

Aroclor 1232 11141-16-5 0.5 µg/L 1800 µg/kg 10. µg/100 cm2

Aroclor 1242 53469-21-9 0.5 µg/L 1800 µg/kg 10. µg/100 cm2

Aroclor 1248 12672-29-6 0.5 µg/L 1800. µg/kg 10. µg/100 cm2

Aroclor 1254 11097-69-1 0.5 µg/L 1800. µg/kg 10. µg/100 cm2

Aroclor 1260 11096-82-5 0.5 µg/L 1800. µg/kg 10. µg/100 cm2

Aroclor 1262 37324-23-5 0.5 µg/L 1800. µg/kg 10. µg/100 cm2