Attachment_1_DRAFT_Analyte___Concentration_Specifications-Custom_Organic_Mix_Solutions_1.xlsx

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Request For Information (RFI) - Sources Sought Notice - Chemical Mixes
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DOIGFBO250005
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This file is a detailed technical specification document for custom organic mix solutions containing multiple chemical compounds. It outlines requirements for three separate mix packages (LS2033, LS2440, and LS2447) to be prepared in specific solvents (ethyl acetate, methanol, or acetonitrile) and delivered in 10 1mL flame-sealed ampoules per mix. Each mix contains precise concentrations of various chemical compounds measured in either µg/mL or ng/mL.

The Department of Interior US Geological Survey Office of Acquisitions and Grants issued this as part of a Request for Information (RFI)/Sources Sought Notice for market research purposes. The file includes comprehensive compound listings with CAS numbers and target values for each mix, with compounds including pesticides, pharmaceuticals, metabolites, and other organic chemicals. The specifications emphasize that while concentrations are listed with two significant figures, preparation with one significant figure is sufficient. This is not a solicitation and all costs associated with providing information are the responsibility of the contractor.

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Mix#characteristicNameCASNumberTV from vendor (ug/mL)Custom for LS2033 - This request is for 3 separate mixes (color coded), each is a multi-component mix that has specified concentrations with two significant figures. One significant figure is sufficient for your preparation. The standard should be prepared in pesticide grade ethyl acetate (carbonyl free). We will need 10 - 1 mL flame sealed ampoules. Then components and concetrations are below. Thank you.
1Atrazine1912-24-90.667
1Fipronil Desulfinyl205650-65-31.000
1Tebuconazole107534-96-31.667
1p,p'-DDE72-55-91.500
1Dieldrin60-57-11.000
1Myclobutanil88671-89-00.833
1Terbuthylazine5915-41-30.667
1.alpha.-Endosulfan959-98-80.833
1.lambda.-Cyhalothrin91465-08-61.167
1Dimethoate60-51-51.167
1Dicrotophos141-66-23.333
13,4-Dichloroaniline95-76-10.667
1Malathion121-75-53.000
1Chlorpyrifos O.A.5598-15-26.667
1Isofenphos25311-71-11.167
12-Ethyl-6-methylaniline24549-06-20.833
1Terbufos oxygen analog sulfone56070-15-613.333
1Ethion563-12-20.667
1Cyanazine21725-46-21.833
1Diazinon333-41-50.667
1Phorate298-02-21.667
1Ethoprop13194-48-41.333
1Propargite2312-35-81.667
1Azinphos-methyl oxygen analog961-22-88.333
1Malaoxon1634-78-21.833
1Phorate O.A.2600-69-32.250
1Methidathion950-37-81.000
1Disulfoton sulfone6/5/970.833
1Terbufos13071-79-91.500
1Simazine122-34-90.667
1Molinate2212-67-11.333
2Metolachlor51218-45-21.000
2Metribuzin21087-64-91.667
2Metalaxyl57837-19-11.167
2Hexazinone51235-04-22.333
2Prometryn7287-19-60.833
2Trifluralin1582-09-81.500
2Chlorpyrifos2921-88-20.833
2Cyfluthrin68359-37-51.333
2Tefluthrin79538-32-20.750
2Benfluralin1861-40-11.167
2Dichlorvos62-73-78.333
2Desulfinylfipronil amide1115248-09-37.167
22,6-Diethylaniline579-66-80.667
2Endosulfan sulfate1031-07-81.333
2Tribufos78-48-81.500
24-Chloro-2-methylphenol1570-64-51.333
2Fipronil120068-37-31.500
2Phosmetoxon3735-33-911.667
2Fonofos944-22-90.667
2Alachlor15972-60-80.667
2Tebuthiuron34014-18-113.333
2Propanil709-98-80.833
2Phosmet732-11-611.667
2Diazoxon962-58-31.000
2Methyl paraoxon950-35-61.167
2Iprodione36734-19-74.500
2Oxyfluorfen42874-03-31.333
2trans-Propiconazole120523-07-13.333
2Azinphos-methyl86-50-010.000
2Methyl parathion298-00-00.667
2Carbofuran1563-66-25.000
3Acetochlor34256-82-10.833
3Chlorthal-dimethyl1861-32-10.667
3Fipronil Sulfide120067-83-61.333
3Fipronil Sulfone120068-36-22.000
33,5-Dichloroaniline626-43-70.667
3Carbaryl63-25-25.000
3Pendimethalin40487-42-12.333
3Beta Cypermethrin52315-07-81.667
3Fenamiphos sulfoxide31972-43-711.667
31rs Cis-Permethrin61949-76-61.000
31-Naphthol90-15-34.167
3Prometon1610-18-01.000
3S-Ethyl dipropylthiocarbamate759-94-40.667
3Fenamiphos22224-92-62.500
32-Chloro-2',6'-diethylacetanilide6967-29-90.667
3Fenamiphos Sulfone31972-44-84.500
3cis-Propiconazole112721-87-63.333
32-Chloro-4-isopropylamino-6-amino-s-triazine6190-65-41.167
3Pronamide23950-58-50.667
3Thiobencarb28249-77-61.333
3Disulfoton298-04-43.333
3Propachlor1918-16-70.667
3Butylate2008-41-50.667
3.alpha.-Hexachlorocyclohexane319-84-60.667
3gamma-HCH (Lindane)58-89-90.667
3Parathion56-38-21.667
3Ethalfluralin55283-68-60.667
3Terbacil5902-51-22.000
3Linuron330-55-25.000
3Pebulate1114-71-21.333
3Triallate2303-17-50.667
3Napropamide15299-99-70.833
Mix#characteristicNameCASNumberTV from vendor (ng/mL)Custom for LS2440 - This request is for 3 separate mixes (color coded), each is a multi-component mix that has specified concentrations with two significant figures. One significant figure is sufficient for your preparation. The standard should be prepared in pesticide grade methanol. We will need 10 - 1 mL flame sealed ampoules. Then components and concetrations are below. Thank you.
1Metformin657-24-932.5
1Carbamazepine298-46-427.5
1Tramadol27203-92-518.5
1Atrazine1912-24-9200
1Metoprolol51384-51-125
1Bupropion34911-55-245
1Meprobamate57-53-430
1Triamterene396-01-013
1Desmethylvenlafaxine93413-62-8210
1Trimethoprim738-70-550
1Pseudoephedrine/Ephedrine mixNULL15
1Guanylurea141-83-3350
1Sitagliptin486460-32-6242.5
1Atenolol29122-68-732.5
1Thiabendazole148-79-810
1Morphinan-6-one, 4,5-epoxy-14-hydroxy-3-methoxy-17-methyl-, (5.alpha.)-76-42-662.5
1Carisoprodol78-44-450
1Warfarin81-81-215
1Quinine130-95-0200
1Diazepam439-14-510
1Morphine57-27-2200
1Diltiazem42399-41-725
1Alprazolam28981-97-752.5
1Hydroxyzine68-88-218.5
1Amphetamine300-62-911
1Hydroxy-amitriptyline, 10-1159-82-620.75
1Methotrexate59-05-2130
1Glipizide29094-61-9200
1Albuterol18559-94-916.75
1Sulfamethizole144-82-1260
1Duloxetine116539-59-492.5
1Nadolol42200-33-950
1Clonidine4205-90-7152.5
1Phenazopyridine94-78-032.5
2Acetamide, 2-(diethylamino)-N-(2,6-dimethylphenyl)-137-58-620
2Sulfamethoxazole723-46-650
2Fluconazole86386-73-475
2Cotinine486-56-616
21-(Aminomethyl)cyclohexaneacetic acid60142-96-3400
2Methocarbamol532-03-627.5
2Tolyl triazole29385-43-1200
2Venlafaxine93413-69-513
2Dextromethorphan125-71-320.5
2Propranol525-66-665
2Citalopram59729-33-816.5
2Fexofenadine83799-24-0110
2Hexamethylenetetramine100-97-0375
2Ethanamine, 2-(diphenylmethoxy)-N,N-dimethyl-58-73-1120
2Temazepam846-50-445
2Methadone76-99-319
2Metaxalone1665-48-140
2Acetaminophen103-90-2210
2Nordiazepam1088-11-550
2Codeine76-57-380
2Glyburide10238-21-8145
2Loratadine79794-75-517.5
2Fluoxetine54910-89-365
2Pentoxifylline5/6/9323.5
2Dehydronifedipine67035-22-750
2Omeprazole/Esomeprazole mixNULL40
2Oseltamivir196618-13-037.5
2Norfluoxetine83891-03-6200
2Nevirapine129618-40-2115
2Sulfadimethoxine122-11-275
2Phendimetrazine634-03-750
2Antipyrine60-80-0125
2Fluticasone propionate80474-14-275
2Fadrozole102676-47-132.5
3Ractopamine97825-25-750
3Norethisterone68-22-450
3Piperonyl butoxide51-03-6150
3Caffeine58-08-2227.5
3Cimetidine51481-61-9350
31,7-Dimethylxanthine611-59-6220
3Erythromycin114-07-8200
3Ranitidine66357-35-5480
3Hydrocortisone50-23-7367.5
3Dilantin57-41-0470
3Prednisone53-03-2262.5
3Oxazepam604-75-1565
3Lorazepam846-49-1505
3Verapamil52-53-9350
3Nizatidine76963-41-2200
3Iminostilbene256-96-2362.5
3Prednisolone50-24-8375
3Acyclovir59277-89-355
3Betamethasone378-44-9285
3Ezetimibe163222-33-1512.5
3Fenofibrate49562-28-916
3Nicotine54-11-5145
3Theophylline58-55-9200
3Chlorpheniramine132-22-9135
3Hydrocodone125-29-1100
3Valacyclovir124832-26-4407.5
3Tiotropium186691-13-4125
3Loperamide53179-11-6200
3Fluvoxamine54739-18-3200
3Amitriptyline50-48-692.5
3Promethazine60-87-7285
3Paroxetine61869-08-7180
3Sertraline79617-96-240
3Raloxifene84449-90-1200
3Norsertraline87857-41-8200
3Benztropine86-13-5110
3Desmethyldiltiazem86408-45-9175
3Famotidine76824-35-685
3Norverapamil67018-85-321.5
3Propoxyphene469-62-570
3Ketoconazole65277-42-1282.5
3Tamoxifen10540-29-1675
3Lamivudine134678-17-440
3Penciclovir39809-25-1200
3Abacavir136470-78-55
MixcharacteristicNameCAS NumberTV from vendor (ng/mL)Custom for LS2447 - This request is for 3 separate mixes (color coded), each is a multi-component mix that has specified concentrations with two significant figures. One significant figure is sufficient for your preparation. The standard should be prepared in pesticide grade methanol or acetonitrile. We will need 10 - 1 mL flame sealed ampoules. Then components and concetrations are below. Thank you.
1Bromacil314-40-97.00
1Dicamba1918-00-91000.00
1Diflubenzuron35367-38-57.50
1Dimethenamid87674-68-83.75
1Diuron330-54-16.25
1Etoxazole153233-91-15.25
1Fluometuron2164-17-212.50
1Hexazinone51235-04-24.50
1Imazethapyr81335-77-510.00
1Imidacloprid138261-41-320.00
1Linuron330-55-27.00
1Metalaxyl57837-19-17.50
1Metconazole125116-23-66.25
1Methoxyfenozide161050-58-42.75
1Metolachlor51218-45-24.00
1Metribuzin21087-64-925.00
1Myclobutanil88671-89-08.75
1Oryzalin19044-88-315.00
1Prometon1610-18-05.00
1Propazine139-40-24.00
1Pyraclostrobin175013-18-03.00
1Simazine122-34-99.00
1Sulfentrazone122836-35-522.50
1Tebuconazole107534-96-318.75
1Tebuthiuron34014-18-13.75
1Tetraconazole112281-77-38.75
1Triclopyr55335-06-3110.00
22,4-D94-75-777.50
2Acephate30560-19-112.50
2Acetochlor34256-82-112.50
2Atrazine1912-24-98.50
2Azoxystrobin131860-33-83.75
2Bentazon25057-89-011.25
2Bromoxynil1689-84-575.00
2Carbaryl63-25-27.00
2Carbendazim10605-21-712.50
2Chlorimuron-ethyl90982-32-411.00
2Chlorpyrifos2921-88-23.75
2cis-Permethrin61949-76-65.25
2Diazinon333-41-58.00
2Dichlorvos62-73-765.00
2Dicrotophos141-66-25.00
2Dimethoate60-51-55.75
2Ethoprophos13194-48-46.25
2Fipronil120068-37-35.00
2Halosulfuron-methyl100784-20-115.00
2Malathion121-75-56.75
2Methomyl16752-77-53.75
2Piperonyl butoxide51-03-631.25
2Propoxur114-26-14.00
2Sulfometuron-methyl74222-97-25.00
2Tebupirimphos96182-53-52.50
2Terbufos13071-79-98.50
2Thiobencarb28249-77-65.25
2trans-Permethrin61949-77-74.75
2Trifloxystrobin141517-21-73.50
31H-1,2,4-Triazole288-88-027.50
33-Phenoxybenzoic acid3739-38-676.25
34-Hydroxychlorothalonil28343-61-552.50
3cis-Bifenthrin acid/cis-Cyhalothrin acid/cis-Tefluthrin acid68127-59-3131.25
3Dechlorometolachlor126605-22-92.50
3Fipronil amide205650-69-711.50
3Hydroxymetolachlor131068-72-93.00
3Hydroxysimazine(2599-11-3)150.00
3Metolachlor oxanilic acid152019-73-3186.25
3Metolachlor sulfonic acid171118-09-585.00
3N-(3,4-Dichlorophenyl)-N'-methylurea3567-62-26.25
3Propiconazole60207-90-17.50
42-Chloro-6-ethylamino-4-amino-s-triazine {CEAT} (deisopropylatrazine)1007-28-925.00
42-Hydroxy-4-isopropylamino-6-ethylamino-s-triazine (2-hydroxyatrazine) {OIET}2163-68-010.00
42-Hydroxy-4-isopropylamino-6-amino-s-triazine {IOIAT} (deethylhydroxyatrazine)19988-24-05.00
42-Chloro-4,6-diamino-s-triazine {CAAT} (Didealkylatrazine)3397-62-430.00
42-Chloro-4-isopropylamino-6-amino-s-triazine {CIAT} (deethylatrazine)6190-65-413.75
4Acetochlor oxanilic acid194992-44-481.25
4Acetochlor sulfonic acid187022-11-3400.00
4Desulfinylfipronil205650-65-34.75
4Diketonitrile-isoxaflutole143701-75-112.50
4Fipronil sulfide120067-83-65.25
4Fipronil sulfone120068-36-27.00
4Methamidophos10265-92-612.50
4Terbufos sulfone56070-16-740.00
4Terbufos sulfoxide10548-10-43.75
Mix#characteristicNameCASNumberTV from vendor (ug/mL)Custom for LS4437 - This request is for 3 separate mixes (color coded), each is a multi-component mix that has specified concentrations with two significant figures. One significant figure is sufficient for your preparation. The standard should be prepared in Purge & Trap Methanol. We will need 9 - 1 mL flame sealed ampoules. Then components and concetrations are below. Thank you.
1Methyl tert-butyl ether1634-04-40.3
1Pentanal110-62-31.35
11,4-Dioxane123-91-15
1Butyraldehyde123-72-89.5
11,2-Dichloropropane78-87-50.1
1Acetonitrile75-05-820
1tert-Butanol75-65-06
11,2,3-Trichloropropane96-18-40.15
11,2-Dibromo-3-chloropropane96-12-80.5
11,1-Dichloropropanone513-88-26
1Ethylene dibromide106-93-40.1
1Dimethoxymethane109-87-51.1
1Cyclohexanone108-94-130
1Isopropanol67-63-045
12-Ethylhexanol104-76-7110
12-Nitropropane79-46-93
22-Propen-1-ol107-18-6195
24-Methyl-2-pentanol108-11-25
2Hexachlorocyclopentadiene77-47-4250
2Nitrobenzene98-95-335
2trans-Crotonaldehyde123-73-965
2Methyl isoamyl ketone110-12-30.55
21-Octanol111-87-545
2Chloropicrin76-06-23.5
21,3-Dioxolane646-06-09.5
2Isophorone78-59-160
21-Methoxy-4-(2-propenyl)benzene140-67-010
2.alpha.-Terpineol98-55-5125
21-Butanol71-36-320
22,6-Dimethyl-4-heptanone108-83-80.8
2N-Nitrosodiethylamine55-18-5130
3Ethyl acetate141-78-61.5
3Methyl acetate79-20-93.5
3Propyl acetate109-60-40.8
3Isopropyl acetate108-21-40.25
32-ethoxyethyl acetate111-15-9525
3Isobutyl acetate110-19-02.075
Mix#characteristicNameCASNumberTV from vendor (ug/mL)Custom for LS4440 - This request is for 3 separate mixes (color coded), each is a multi-component mix that has specified concentrations with two significant figures. One significant figure is sufficient for your preparation. The standard should be prepared in Purge & Trap Methanol. We will need 10 - 1 mL flame sealed ampoules. Then components and concetrations are below. Thank you.
1Chloroform67-66-325
1Methyl tert-butyl ether1634-04-425
1Trichloroethylene79-01-625
1Acetone67-64-1625
1Dichlorobromomethane75-27-425
11,1-Dichloroethane75-34-325
1HCFC-2275-45-61
11,2,4-Trimethylbenzene95-63-60.8
11,2,3-Trichloropropane96-18-43
11,1-Dichloroethene75-35-425
11,2,3,4-Tetramethylbenzene488-23-32.5
1Toluene108-88-325
1m,p-Xylene179601-23-130
1Isopropyl ether108-20-31.5
1Methyl ethyl ketone78-93-3125
1Chlorodibromomethane124-48-125
1Pentane109-66-01.65
1HFC-152a75-37-61.5
1tert-Butylbenzene98-06-61.5
1Carbon tetrachloride56-23-525
11,2,3,5-Tetramethylbenzene527-53-72
1Vinyl chloride75-01-425
1n-Butylbenzene104-51-82
1n-Propylbenzene103-65-10.9
1sec-Butylbenzene135-98-80.85
11,2-Dibromo-3-chloropropane96-12-8125
1HCFC-2175-43-41.25
1Methylene chloride75-09-2125
1Bromobenzene108-86-10.625
11,1,2-Trichloroethane79-00-525
1Ethylene dibromide106-93-450
2Tetrachloroethylene127-18-425
2Benzene71-43-225
21,2-Dichloropropane78-87-525
2cis-1,2-Dichloroethylene156-59-225
2Tetrahydrofuran109-99-960
2Ethyl ether60-29-72.5
21,2,3-Trimethylbenzene526-73-81.5
2CFC-11376-13-125
2o-Ethyltoluene611-14-30.8
2Cumene98-82-825
2p-Cymene99-87-61.5
2CFC-1175-69-450
2o-Xylene95-47-625
21,3-Dichlorobenzene541-73-1125
2Ethylbenzene100-41-425
21,1,1-Trichloroethane71-55-625
2trans-1,2-Dichloroethylene156-60-525
2Tribromomethane75-25-225
2p-Dichlorobenzene106-46-7125
21,2-Dichloroethane107-06-225
2o-Dichlorobenzene95-50-1125
2o-Chlorotoluene95-49-80.7
2Chlorobenzene108-90-725
2Methyl isobutyl ketone108-10-1125
2Naphthalene91-20-36.5
2Butane106-97-82
21,3,5-Trimethylbenzene108-67-80.8
2Ethyl tert-butyl ether637-92-30.8
2Chloroethane75-00-350
2p-Chlorotoluene106-43-41.05
2Styrene100-42-525
31,2,3,4-Tetrahydronaphthalene119-64-22
3HCFC-123306-83-20.625
3Ethane, 1-chloro-1,1-difluoro-75-68-32
31,2,4-Trichlorobenzene120-82-1125
3Bromochloromethane74-97-525
31,1,1,2-Tetrachloroethane630-20-61
3Carbon disulfide75-15-050
3Dibromomethane74-95-30.85
3Acrylonitrile107-13-112
3Hexachloroethane67-72-12.5
3Methyl bromide74-83-9125
3Chloromethane74-87-350
31,1,2,2-Tetrachloroethane79-34-525
3CFC-1275-71-850
3trans-1,3-Dichloropropene10061-02-625
3cis-1,3-Dichloropropene10061-01-525
3Hexachlorobutadiene87-68-3127.5
3Methyl Acrylate96-33-325
3Vinyl bromide593-60-21
3tert-Amyl methyl ether994-05-81.5
3CFC-11476-14-20.75
31,3-Butadiene106-99-02
3trans-1,4-Dichloro-2-butene110-57-650
3Ethyl methacrylate97-63-210
32-Hexanone591-78-6250
31,1-Dichloropropene563-58-61
32,2-Dichloropropane594-20-71.5
31,3-Dichloropropane142-28-91.5
3Methyl iodide74-88-48.5
31,2,3-Trichlorobenzene87-61-61.5
3Allyl chloride107-05-12
3Hexane110-54-31.7
3Methacrylonitrile126-98-78
3Methyl methacrylate80-62-69

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