Appendix F - Sediment Sampling Analylis Results.pdf

Appendix F

Sediment Sampling and Analysis Results

#=CL#

September 03, 2019

LIMS USE: FR - LEE DAY

LIMS OBJECT ID: 20118340

20118340 Project:

Pace Project No.:

RE:

Lee Day PSI InterteK 11950 Industriplex Blvd.

Baton Rouge, LA 70809

Waste Sample - C-1

Dear Lee Day:

Enclosed are the analytical results for sample(s) received by the laboratory on August 22, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely, William Shackelford william.shackelford@pacelabs.com

Project Manager (504)469-0333

Enclosures cc: Sarah Berman, Intertek PSI

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087 (504)469-0333

#=CP#

CERTIFICATIONS

Pace Project No.:

Project:

20118340 Waste Sample - C-1

New Orleans Certification IDs California Env. Lab Accreditation Program Branch:

11277CA

Florida Department of Health (NELAC): E87595 Illinois Environmental Protection Agency: 0025721 Kansas Department of Health and Environment (NELAC):

E-10266 Louisiana Dept. of Environmental Quality (NELAC/LELAP):

02006

Pennsylviania Dept. of Env Protection (NELAC): 68-04202 Texas Commission on Env. Quality (NELAC):

T104704405-09-TX

U.S. Dept. of Agriculture Foreign Soil Import: P330-10- 00119 Commonwealth of Virginia (TNI): 480246

Pace Analytical National Certification IDs 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01

EPA# TN00003

Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: AI30792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TN003 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification #: CERT0086 Nebraska Certification #: NE-OS-15-05

Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TN002 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LAO00356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: VT2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 9980939910 Wyoming UST Certification #: via A2LA 2926.01 A2LA-ISO 17025 Certification #: 1461.01 A2LA-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789

REPORT OF LABORATORY ANALYSIS

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Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

#=SS#

SAMPLE SUMMARY

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Lab ID Sample ID Matrix Date Collected Date Received

20118340001 C-1 Other 08/22/19 11:00 08/22/19 13:20

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

#=SA#

SAMPLE ANALYTE COUNT

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts

20118340001 C-1 EPA 8082 8 PASI-NSLK

EPA 8081B 9 PANRP

EPA 8151A 3 PANRP

EPA 6010B 7 PANEL

EPA 7470A 1 PANABL

EPA 8270C 18 PANJNJ

EPA 8260B 13 PANACG

SW-846 7.1.2 5 PASI-NGJE

SW-846 7.3.4.2 1 PASI-NTMO

EPA 9045 1 PASI-NGJE

SW-846 7.3.3.2 1 PASI-NMHM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

#=AR#

ANALYTICAL RESULTS

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Sample: C-1 Lab ID: 20118340001 Collected: 08/22/19 11:00 Received: 08/22/19 13:20 Matrix: Other Results reported on a "wet-weight" basis

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: EPA 8082 Preparation Method: EPA 3511 Leachate Method/Date: EPA 1311; 08/23/19 13:00

8082 GCS PCB, TCLP Low Vol

PCB-1016 (Aroclor 1016) ND ug/L 08/26/19 15:09 12674-11-208/26/19 11:510.50 1 PCB-1221 (Aroclor 1221) ND ug/L 08/26/19 15:09 11104-28-208/26/19 11:510.50 1 PCB-1232 (Aroclor 1232) ND ug/L 08/26/19 15:09 11141-16-508/26/19 11:510.50 1 PCB-1242 (Aroclor 1242) ND ug/L 08/26/19 15:09 53469-21-908/26/19 11:510.50 1 PCB-1248 (Aroclor 1248) ND ug/L 08/26/19 15:09 12672-29-608/26/19 11:510.50 1 PCB-1254 (Aroclor 1254) ND ug/L 08/26/19 15:09 11097-69-108/26/19 11:510.50 1 PCB-1260 (Aroclor 1260) ND ug/L 08/26/19 15:09 11096-82-508/26/19 11:510.50 1 Surrogates Decachlorobiphenyl (S) 44 %. 08/26/19 15:09 2051-24-308/26/19 11:5110-137 1

Analytical Method: EPA 8081B Preparation Method: 3510C Leachate Method/Date: 1311; 08/27/19 17:01 Initial pH: 8.38; Final pH: 5.08

Pesticides (GC) 8081B TCLP

Chlordane (Technical) ND mg/L 08/31/19 12:15 57-74-908/29/19 22:100.00500 1 Endrin ND mg/L 08/31/19 12:15 72-20-808/29/19 22:100.00500 1 Heptachlor ND mg/L 08/31/19 12:15 76-44-808/29/19 22:100.00500 1 Heptachlor epoxide ND mg/L 08/31/19 12:15 1024-57-308/29/19 22:100.00500 1 gamma-BHC (Lindane) ND mg/L 08/31/19 12:15 58-89-908/29/19 22:100.00500 1 Methoxychlor ND mg/L 08/31/19 12:15 72-43-508/29/19 22:100.00500 1 Toxaphene ND mg/L 08/31/19 12:15 8001-35-208/29/19 22:100.0100 1 Surrogates Decachlorobiphenyl (S) 70.8 % 08/31/19 12:15 2051-24-308/29/19 22:1010.0-128 1 Tetrachloro-m-xylene (S) 43.7 % 08/31/19 12:15 877-09-808/29/19 22:1010.0-127 1

Analytical Method: EPA 8151A Preparation Method: 8151A Leachate Method/Date: 1311; 08/27/19 17:01 Initial pH: 8.38; Final pH: 5.08

Chlorinated Herb. (GC) 8151A

2,4,5-TP (Silvex) ND mg/L 08/30/19 15:59 93-72-108/29/19 15:360.00200 1 2,4-D ND mg/L 08/30/19 15:59 94-75-7 L008/29/19 15:360.00200 1 Surrogates

2,4-DCAA (S) 97.4 % 08/30/19 15:59 19719-28-908/29/19 15:3614.0-158 1

Analytical Method: EPA 6010B Preparation Method: 3015 Leachate Method/Date: 1311; 08/27/19 17:01 Initial pH: 8.38; Final pH: 5.08

Metals (ICP) 6010B TCLP

Arsenic ND mg/L 08/29/19 00:16 7440-38-208/28/19 19:040.100 1 Barium 0.491 mg/L 08/29/19 00:16 7440-39-308/28/19 19:040.100 1 Cadmium ND mg/L 08/29/19 00:16 7440-43-908/28/19 19:040.100 1 Chromium ND mg/L 08/29/19 00:16 7440-47-308/28/19 19:040.100 1 Lead ND mg/L 08/29/19 00:16 7439-92-108/28/19 19:040.100 1 Selenium ND mg/L 08/29/19 00:16 7782-49-208/28/19 19:040.100 1 Silver ND mg/L 08/29/19 00:16 7440-22-408/28/19 19:040.100 1

Analytical Method: EPA 7470A Preparation Method: 7470A Leachate Method/Date: 1311; 08/27/19 17:01 Initial pH: 8.38; Final pH: 5.08

Mercury 7470A TCLP

Mercury ND mg/L 08/29/19 09:04 7439-97-608/28/19 17:330.0100 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087 (504)469-0333

EIPorras Highlight

EIPorras Highlight

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Sample: C-1 Lab ID: 20118340001 Collected: 08/22/19 11:00 Received: 08/22/19 13:20 Matrix: Other Results reported on a "wet-weight" basis

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: EPA 8270C Preparation Method: 3510C Leachate Method/Date: 1311; 08/27/19 17:01 Initial pH: 8.38; Final pH: 5.08

SVOA (GC/MS) 8270C TCLP

1,4-Dichlorobenzene ND mg/L 08/30/19 21:37 106-46-708/30/19 07:210.100 1 2,4-Dinitrotoluene ND mg/L 08/30/19 21:37 121-14-208/30/19 07:210.100 1 Hexachlorobenzene ND mg/L 08/30/19 21:37 118-74-108/30/19 07:210.100 1 Hexachloro-1,3-butadiene ND mg/L 08/30/19 21:37 87-68-308/30/19 07:210.100 1 Hexachloroethane ND mg/L 08/30/19 21:37 67-72-108/30/19 07:210.100 1 Nitrobenzene ND mg/L 08/30/19 21:37 98-95-308/30/19 07:210.100 1 Pyridine ND mg/L 08/30/19 21:37 110-86-108/30/19 07:210.100 1 3&4-Methylphenol(m&p Cresol) ND mg/L 08/30/19 21:3708/30/19 07:210.100 1 2-Methylphenol(o-Cresol) ND mg/L 08/30/19 21:37 95-48-708/30/19 07:210.100 1 Pentachlorophenol ND mg/L 08/30/19 21:37 87-86-508/30/19 07:210.100 1 2,4,5-Trichlorophenol ND mg/L 08/30/19 21:37 95-95-408/30/19 07:210.100 1 2,4,6-Trichlorophenol ND mg/L 08/30/19 21:37 88-06-208/30/19 07:210.100 1 Surrogates 2-Fluorophenol (S) 38.4 % 08/30/19 21:37 367-12-408/30/19 07:2110.0-120 1 Phenol-d5 (S) 23.2 % 08/30/19 21:37 4165-62-208/30/19 07:2110.0-120 1 Nitrobenzene-d5 (S) 50.8 % 08/30/19 21:37 4165-60-008/30/19 07:2110.0-127 1 2-Fluorobiphenyl (S) 52.1 % 08/30/19 21:37 321-60-808/30/19 07:2110.0-130 1 2,4,6-Tribromophenol (S) 60.0 % 08/30/19 21:37 118-79-608/30/19 07:2110.0-155 1 Terphenyl-d14 (S) 61.7 % 08/30/19 21:37 1718-51-008/30/19 07:2110.0-128 1

Analytical Method: EPA 8260B Preparation Method: 8260B Leachate Method/Date: 1311; 08/27/19 12:28

VOA (GC/MS) 8260B TCLP

Benzene ND mg/L 08/30/19 03:08 71-43-208/30/19 03:080.0500 1 Carbon tetrachloride ND mg/L 08/30/19 03:08 56-23-508/30/19 03:080.0500 1 Chlorobenzene ND mg/L 08/30/19 03:08 108-90-708/30/19 03:080.0500 1 Chloroform ND mg/L 08/30/19 03:08 67-66-308/30/19 03:080.250 1 1,2-Dichloroethane ND mg/L 08/30/19 03:08 107-06-208/30/19 03:080.0500 1 1,1-Dichloroethene ND mg/L 08/30/19 03:08 75-35-408/30/19 03:080.0500 1 2-Butanone (MEK) ND mg/L 08/30/19 03:08 78-93-308/30/19 03:080.500 1 Tetrachloroethene ND mg/L 08/30/19 03:08 127-18-408/30/19 03:080.0500 1 Trichloroethene ND mg/L 08/30/19 03:08 79-01-608/30/19 03:080.0500 1 Vinyl chloride ND mg/L 08/30/19 03:08 75-01-408/30/19 03:080.0500 1 Surrogates Toluene-d8 (S) 105 % 08/30/19 03:08 2037-26-508/30/19 03:0880.0-120 1 4-Bromofluorobenzene (S) 104 % 08/30/19 03:08 460-00-408/30/19 03:0877.0-126 1 1,2-Dichloroethane-d4 (S) 108 % 08/30/19 03:08 17060-07-008/30/19 03:0870.0-130 1

Analytical Method: SW-846 7.1.2Ignitability of Solids

Ignitability Not Ignitable

08/23/19 11:011

Ignites by flame N/A 08/23/19 11:011 Ignites spontaneously No 08/23/19 11:011 Ignites when agitated No 08/23/19 11:011 Ignites with moisture No 08/23/19 11:011

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Sample: C-1 Lab ID: 20118340001 Collected: 08/22/19 11:00 Received: 08/22/19 13:20 Matrix: Other Results reported on a "wet-weight" basis

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: SW-846 7.3.4.2 Preparation Method: SW-846 7.3.4.2734S Reactive Sulfide

Sulfide, Reactive ND mg/kg 08/28/19 13:2108/28/19 12:5450.0 1

Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.5 Std. Units 08/23/19 15:300.010 1

Analytical Method: SW-846 7.3.3.2 Preparation Method: SW-846 7.3.3.2733C S Reactive Cyanide

Cyanide, Reactive ND mg/kg 08/28/19 13:5508/28/19 12:5425.0 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

#=QC#

QUALITY CONTROL DATA

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1338346 3510C

EPA 8081B

Pesticides (GC) 8081B TCLP

Associated Lab Samples: 20118340001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: R3446273-1

Associated Lab Samples: 20118340001

Matrix: Solid

Analyzed gamma-BHC (Lindane) mg/L ND 0.00500 08/30/19 11:45 Endrin mg/L ND 0.00500 08/30/19 11:45 Heptachlor mg/L ND 0.00500 08/30/19 11:45 Heptachlor epoxide mg/L ND 0.00500 08/30/19 11:45 Methoxychlor mg/L ND 0.00500 08/30/19 11:45 Chlordane (Technical) mg/L ND 0.00500 08/30/19 11:45 Toxaphene mg/L ND 0.0100 08/30/19 11:45 Decachlorobiphenyl (S) % 79.2 10.0-128 08/30/19 11:45 Tetrachloro-m-xylene (S) % 37.3 10.0-127 08/30/19 11:45

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

R3446273-2LABORATORY CONTROL SAMPLE:

LCSSpike gamma-BHC (Lindane) mg/L 0.007660.0100 76.6 55.0-129 Endrin mg/L 0.007400.0100 74.0 57.0-134 Heptachlor mg/L 0.007420.0100 74.2 27.0-132 Heptachlor epoxide mg/L 0.007170.0100 71.7 57.0-130 Methoxychlor mg/L 0.007480.0100 74.8 54.0-155 Decachlorobiphenyl (S) % 67.1 10.0-128 Tetrachloro-m-xylene (S) % 48.2 10.0-127

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1337215 8151A

EPA 8151A

Chlorinated Herb. (GC) 8151A

Associated Lab Samples: 20118340001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: R3446034-2

Associated Lab Samples: 20118340001

Matrix: Solid

Analyzed

2,4-D mg/L ND 0.00200 08/30/19 12:33 2,4,5-TP (Silvex) mg/L ND 0.00200 08/30/19 12:33

2,4-DCAA (S) % 101 14.0-158 08/30/19 12:33

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

R3446034-1LABORATORY CONTROL SAMPLE:

LCSSpike

2,4-D mg/L 0.0625 L0,P90.0500 125 50.0-120 2,4,5-TP (Silvex) mg/L 0.0581 P90.0500 116 50.0-125

2,4-DCAA (S) % 97.4 14.0-158

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R3446034-3MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1132106-01

R3446034-4

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

2,4-D mg/L MH,P90.0500 121 50.0-120135 11.1 200.0500ND 0.0603 0.0674 2,4,5-TP (Silvex) mg/L MH,P90.0500 113 50.0-125128 12.4 200.0500ND 0.0565 0.0640

2,4-DCAA (S) % 103 14.0-158114

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1336266

EPA 6010B

Metals (ICP) 6010B TCLP

Associated Lab Samples: 20118340001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: R3445292-1

Associated Lab Samples: 20118340001

Matrix: Solid

Analyzed

Arsenic mg/L ND 0.100 08/28/19 23:12 Barium mg/L ND 0.100 08/28/19 23:12 Cadmium mg/L ND 0.100 08/28/19 23:12 Chromium mg/L ND 0.100 08/28/19 23:12 Lead mg/L ND 0.100 08/28/19 23:12 Selenium mg/L ND 0.100 08/28/19 23:12 Silver mg/L ND 0.100 08/28/19 23:12

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

R3445292-2LABORATORY CONTROL SAMPLE & LCSD:

LCSSpike LCSD

% Rec RPD Max

RPD

LCSD

Result

R3445292-3

Arsenic mg/L 9.8610.0 98.6 80.0-12097.49.74 1.19 20 Barium mg/L 10.310.0 103 80.0-12010110.1 1.26 20 Cadmium mg/L 9.9110.0 99.1 80.0-12097.79.77 1.40 20 Chromium mg/L 10.110.0 101 80.0-12099.99.99 1.35 20 Lead mg/L 10.110.0 101 80.0-12099.89.98 0.794 20 Selenium mg/L 9.9410.0 99.4 80.0-12098.29.82 1.20 20 Silver mg/L 1.912.00 95.6 80.0-12094.21.88 1.57 20

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R3445292-5MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1132875-01

R3445292-6

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Arsenic mg/L 10.0 95.7 75.0-12596.8 1.15 2010.0ND 9.57 9.68 Barium mg/L 10.0 102 75.0-125103 0.828 2010.0ND 10.2 10.3 Cadmium mg/L 10.0 96.8 75.0-12597.5 0.721 2010.0ND 9.68 9.75 Chromium mg/L 10.0 100 75.0-125101 0.854 2010.0ND 10.0 10.1 Lead mg/L 10.0 99.2 75.0-125100 0.841 2010.0ND 9.92 10.0 Selenium mg/L 10.0 94.7 75.0-12594.5 0.193 2010.0ND 9.54 9.52 Silver mg/L 2.00 93.6 75.0-12594.1 0.463 202.00ND 1.87 1.88

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R3445292-7MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1132394-02

R3445292-8

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Arsenic mg/L 10.0 101 75.0-12598.8 1.78 2010.0ND 10.1 9.88 Barium mg/L 10.0 102 75.0-125100 1.52 2010.00.455 10.6 10.5

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087 (504)469-0333

EIPorras Highlight

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R3445292-7MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1132394-02

R3445292-8

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Cadmium mg/L 10.0 99.6 75.0-12598.1 1.56 2010.0ND 9.96 9.81 Chromium mg/L 10.0 100 75.0-125100 0.140 2010.0ND 10.0 10.0 Lead mg/L 10.0 101 75.0-12599.9 1.04 2010.0ND 10.1 9.99 Selenium mg/L 10.0 101 75.0-12598.2 2.53 2010.0ND 10.1 9.82 Silver mg/L 2.00 95.6 75.0-12595.2 0.390 202.00ND 1.91 1.90

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1336583 7470A

EPA 7470A

Mercury 7470A TCLP

Associated Lab Samples: 20118340001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: R3445371-1

Associated Lab Samples: 20118340001

Matrix: Solid

Analyzed

Mercury mg/L ND 0.0100 08/29/19 08:31

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

R3445371-2LABORATORY CONTROL SAMPLE & LCSD:

LCSSpike LCSD

% Rec RPD Max

RPD

LCSD

Result

R3445371-3

Mercury mg/L 0.03250.0300 108 80.0-12095.70.0287 12.4 20

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R3445371-4MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1132394-02

R3445371-5

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Mercury mg/L R10.0300 97.3 75.0-12577.0 23.3 200.0300ND 0.0292 0.0231

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R3445371-6MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1132421-01

R3445371-7

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Mercury mg/L 0.0300 101 75.0-125111 8.81 200.0300ND 0.0304 0.0332

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087 (504)469-0333

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1337449 3510C

EPA 8270C

SVOA (GC/MS) 8270C TCLP

Associated Lab Samples: 20118340001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: R3446212-2

Associated Lab Samples: 20118340001

Matrix: Solid

Analyzed

1,4-Dichlorobenzene mg/L ND 0.100 08/30/19 15:21 2,4-Dinitrotoluene mg/L ND 0.100 08/30/19 15:21 Hexachlorobenzene mg/L ND 0.100 08/30/19 15:21 Hexachloro-1,3-butadiene mg/L ND 0.100 08/30/19 15:21 Hexachloroethane mg/L ND 0.100 08/30/19 15:21 Nitrobenzene mg/L ND 0.100 08/30/19 15:21 Pyridine mg/L ND 0.100 08/30/19 15:21 2-Methylphenol(o-Cresol) mg/L ND 0.100 08/30/19 15:21 3&4-Methylphenol(m&p Cresol) mg/L ND 0.100 08/30/19 15:21 Pentachlorophenol mg/L ND 0.100 08/30/19 15:21 2,4,5-Trichlorophenol mg/L ND 0.100 08/30/19 15:21 2,4,6-Trichlorophenol mg/L ND 0.100 08/30/19 15:21 Nitrobenzene-d5 (S) % 64 10.0-127 08/30/19 15:21 2-Fluorobiphenyl (S) % 69.3 10.0-130 08/30/19 15:21 Terphenyl-d14 (S) % 83.8 10.0-128 08/30/19 15:21 Phenol-d5 (S) % 26.6 10.0-120 08/30/19 15:21 2-Fluorophenol (S) % 45.7 10.0-120 08/30/19 15:21 2,4,6-Tribromophenol (S) % 74.5 10.0-155 08/30/19 15:21

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

R3446212-1LABORATORY CONTROL SAMPLE:

LCSSpike

1,4-Dichlorobenzene mg/L 0.3750.500 75.0 18.0-120 2,4-Dinitrotoluene mg/L 0.3930.500 78.6 49.0-124 Hexachlorobenzene mg/L 0.4310.500 86.2 44.0-120 Hexachloro-1,3-butadiene mg/L 0.3900.500 78.0 19.0-120 Hexachloroethane mg/L 0.3550.500 71.0 15.0-120 Nitrobenzene mg/L 0.3170.500 63.4 27.0-120 Pyridine mg/L 0.2140.500 42.8 10.0-120 2-Methylphenol(o-Cresol) mg/L 0.2960.500 59.2 28.0-120 3&4-Methylphenol(m&p Cresol) mg/L 0.3140.500 62.8 31.0-120 Pentachlorophenol mg/L 0.3260.500 65.2 23.0-120 2,4,5-Trichlorophenol mg/L 0.4510.500 90.2 44.0-120 2,4,6-Trichlorophenol mg/L 0.4170.500 83.4 42.0-120 Nitrobenzene-d5 (S) % 51.6 10.0-127 2-Fluorobiphenyl (S) % 74.0 10.0-130 Terphenyl-d14 (S) % 82.3 10.0-128 Phenol-d5 (S) % 27.4 10.0-120 2-Fluorophenol (S) % 46.6 10.0-120 2,4,6-Tribromophenol (S) % 81.0 10.0-155

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R3446212-3MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1131335-01

R3446212-4

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

1,4-Dichlorobenzene mg/L 0.500 36.6 17.0-12024.8 38.4 400.500ND 0.183 0.124 2,4-Dinitrotoluene mg/L ML,R10.500 47.2 39.0-12531.6 39.6 250.500ND 0.236 0.158 Hexachlorobenzene mg/L ML,R10.500 50.6 35.0-12231.4 46.8 240.500ND 0.253 0.157 Hexachloro-1,3-butadiene mg/L R10.500 40.2 12.0-12025.8 43.6 340.500ND 0.201 0.129 Hexachloroethane mg/L 0.500 33.6 10.0-12022.6 39.1 400.500ND 0.168 0.113 Nitrobenzene mg/L R10.500 39.8 12.0-12026.8 39.0 300.500ND 0.199 0.134 Pyridine mg/L ML,R10.500 9.74 10.0-1200.00 200 370.500ND 0.0487 ND 2-Methylphenol(o-Cresol) mg/L R10.500 33.0 10.0-12022.8 36.6 300.500ND 0.165 0.114 3&4-Methylphenol(m&p Cresol) mg/L 0.500 35.8 10.0-12025.2 34.8 360.500ND 0.179 0.126

Pentachlorophenol mg/L R10.500 37.4 10.0-12824.4 42.1 370.500ND 0.187 0.122 2,4,5-Trichlorophenol mg/L R10.500 51.4 33.0-12034.4 39.6 310.500ND 0.257 0.172 2,4,6-Trichlorophenol mg/L R10.500 49.4 26.0-12032.2 42.2 310.500ND 0.247 0.161 Nitrobenzene-d5 (S) % 29.3 10.0-12723.9 2-Fluorobiphenyl (S) % 40.7 10.0-13026.9 Terphenyl-d14 (S) % 48.2 10.0-12830.8 Phenol-d5 (S) % 18.5 10.0-12012.6 2-Fluorophenol (S) % 26.8 10.0-12018.2 2,4,6-Tribromophenol (S) % 48.7 10.0-15531.8

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1336904 8260B

EPA 8260B

VOA (GC/MS) 8260B TCLP

Associated Lab Samples: 20118340001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: R3445912-3

Associated Lab Samples: 20118340001

Matrix: Solid

Analyzed

Benzene mg/L ND 0.0500 08/30/19 00:43 Carbon tetrachloride mg/L ND 0.0500 08/30/19 00:43 Chlorobenzene mg/L ND 0.0500 08/30/19 00:43 Chloroform mg/L ND 0.250 08/30/19 00:43 1,2-Dichloroethane mg/L ND 0.0500 08/30/19 00:43 1,1-Dichloroethene mg/L ND 0.0500 08/30/19 00:43 2-Butanone (MEK) mg/L ND 0.500 08/30/19 00:43 Tetrachloroethene mg/L ND 0.0500 08/30/19 00:43 Trichloroethene mg/L ND 0.0500 08/30/19 00:43 Vinyl chloride mg/L ND 0.0500 08/30/19 00:43 Toluene-d8 (S) % 103 80.0-120 08/30/19 00:43 4-Bromofluorobenzene (S) % 104 77.0-126 08/30/19 00:43 1,2-Dichloroethane-d4 (S) % 109 70.0-130 08/30/19 00:43

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

R3445912-1LABORATORY CONTROL SAMPLE & LCSD:

LCSSpike LCSD

% Rec RPD Max

RPD

LCSD

Result

R3445912-2

Benzene mg/L 0.02400.0250 95.8 70.0-12393.70.0234 2.26 20 Carbon tetrachloride mg/L 0.02430.0250 97.1 68.0-12692.00.0230 5.42 20 Chlorobenzene mg/L 0.02450.0250 98.0 80.0-12197.60.0244 0.427 20 Chloroform mg/L 0.02460.0250 98.3 73.0-12095.90.0240 2.48 20 1,2-Dichloroethane mg/L 0.02650.0250 106 70.0-1281070.0267 0.814 20 1,1-Dichloroethene mg/L 0.02310.0250 92.5 71.0-12485.90.0215 7.40 20 2-Butanone (MEK) mg/L 0.1720.125 137 44.0-1601440.179 4.47 20 Tetrachloroethene mg/L 0.02280.0250 91.1 72.0-13289.20.0223 2.08 20 Trichloroethene mg/L 0.02270.0250 90.7 78.0-12488.80.0222 2.16 20 Vinyl chloride mg/L 0.02220.0250 88.8 67.0-13185.20.0213 4.12 20 Toluene-d8 (S) % 103 80.0-120102 4-Bromofluorobenzene (S) % 107 77.0-126106 1,2-Dichloroethane-d4 (S) % 118 70.0-130116

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R3445912-4MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1132666-04

R3445912-5

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Benzene mg/L 1.25 112 17.0-158103 8.87 271.25ND 1.41 1.29 Carbon tetrachloride mg/L 1.25 121 23.0-159114 6.33 281.25ND 1.51 1.42 Chlorobenzene mg/L 1.25 109 33.0-152104 5.12 271.25ND 1.36 1.29

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R3445912-4MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1132666-04

R3445912-5

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Chloroform mg/L 1.25 112 29.0-154106 5.69 281.25ND 1.40 1.33 1,2-Dichloroethane mg/L 1.25 114 29.0-151109 3.98 271.250.00238 1.42 1.37 1,1-Dichloroethene mg/L 1.25 113 11.0-160106 6.88 291.25ND 1.42 1.32 2-Butanone (MEK) mg/L 6.25 134 10.0-160136 2.00 326.25ND 8.36 8.53 Tetrachloroethene mg/L 1.25 107 10.0-160102 5.43 271.25ND 1.34 1.27 Trichloroethene mg/L 1.25 108 10.0-160101 6.65 251.25ND 1.35 1.27 Vinyl chloride mg/L 1.25 112 10.0-160106 5.28 271.25ND 1.40 1.33 Toluene-d8 (S) % 101 80.0-120102 4-Bromofluorobenzene (S) % 107 77.0-126108 1,2-Dichloroethane-d4 (S) % 119 70.0-130119

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

154846

EPA 3511

EPA 8082

8082 GCS TCLP PCB

Associated Lab Samples: 20118340001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 689582

Associated Lab Samples: 20118340001

Matrix: Water

Analyzed

PCB-1016 (Aroclor 1016) ug/L ND 0.50 08/26/19 14:39 PCB-1221 (Aroclor 1221) ug/L ND 0.50 08/26/19 14:39 PCB-1232 (Aroclor 1232) ug/L ND 0.50 08/26/19 14:39 PCB-1242 (Aroclor 1242) ug/L ND 0.50 08/26/19 14:39 PCB-1248 (Aroclor 1248) ug/L ND 0.50 08/26/19 14:39 PCB-1254 (Aroclor 1254) ug/L ND 0.50 08/26/19 14:39 PCB-1260 (Aroclor 1260) ug/L ND 0.50 08/26/19 14:39 Decachlorobiphenyl (S) %. 108 10-137 08/26/19 14:39

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

690629LABORATORY CONTROL SAMPLE:

LCSSpike

PCB-1016 (Aroclor 1016) ug/L 46.454.5 85 14-115 PCB-1260 (Aroclor 1260) ug/L 47.754.5 87 16-115 Decachlorobiphenyl (S) %. 51 10-137

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

155097

SW-846 7.3.4.2

SW-846 7.3.4.2

734S Reactive Sulfide

Associated Lab Samples: 20118340001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 691957

Associated Lab Samples: 20118340001

Matrix: Solid

Analyzed

Sulfide, Reactive mg/kg ND 50.0 08/28/19 13:21

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

691958LABORATORY CONTROL SAMPLE:

LCSSpike

Sulfide, Reactive mg/kg 441500 88 1-110

Parameter Units

MS

Result % Rec Limits Qualifiers% RecConc.

691960MATRIX SPIKE SAMPLE:

MSSpike

Result 60312808006

Sulfide, Reactive mg/kg 441500 84 1-110ND

Parameter Units Dup

Result Max RPD QualifiersRPDResult

60312808006

691959SAMPLE DUPLICATE:

Sulfide, Reactive mg/kg ND 20ND

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

154577

EPA 9045

EPA 9045

9045 pH

Associated Lab Samples: 20118340001

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

689440LABORATORY CONTROL SAMPLE:

LCSSpike pH at 25 Degrees C Std. Units 6.06 100 97-103

Parameter Units Dup

Result Max RPD QualifiersRPDResult

20118285001

689441SAMPLE DUPLICATE:

pH at 25 Degrees C Std. Units 8.3 0 208.3

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

155100

SW-846 7.3.3.2

SW-846 7.3.3.2

733C Reactive Cyanide

Associated Lab Samples: 20118340001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 691969

Associated Lab Samples: 20118340001

Matrix: Solid

Analyzed

Cyanide, Reactive mg/kg ND 25.0 08/28/19 13:43

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

691970LABORATORY CONTROL SAMPLE:

LCSSpike

Cyanide, Reactive mg/kg ND100 7 1-110

Parameter Units

MS

Result % Rec Limits Qualifiers% RecConc.

691972MATRIX SPIKE SAMPLE:

MSSpike

Result 60312808006

Cyanide, Reactive mg/kg ND100 5 1-110ND

Parameter Units Dup

Result Max RPD QualifiersRPDResult

60312808006

691971SAMPLE DUPLICATE:

Cyanide, Reactive mg/kg ND 20ND

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

#=QL#

QUALIFIERS

Pace Project No.:

Project:

20118340 Waste Sample - C-1

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.

ND - Not Detected at or above adjusted reporting limit.

TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.

MDL - Adjusted Method Detection Limit.

PQL - Practical Quantitation Limit.

RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix.

S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable.

SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

TNI - The Nelac Institute

LABORATORIES

Pace Analytical NationalPAN Pace Analytical Services - New OrleansPASI-N

BATCH QUALIFIERS

Batch: 154875 A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume.[M5]

ANALYTE QUALIFIERS

Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0 Matrix spike recovery and/or matrix spike duplicate recovery was above laboratory control limits. Result may be biased high.

MH

Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits. Result may be biased low.

ML

RPD between the primary and confirmatory analysis exceeded 40%.P9 RPD value was outside control limits.R1

REPORT OF LABORATORY ANALYSIS

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Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.:

Project:

20118340 Waste Sample - C-1

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch

20118340001 154846 154875C-1 EPA 3511 EPA 8082

20118340001 1338346 1338346C-1 3510C EPA 8081B

20118340001 1337215 1337215C-1 8151A EPA 8151A

20118340001 1336266 1336266C-1 3015 EPA 6010B

20118340001 1336583 1336583C-1 7470A EPA 7470A

20118340001 1337449 1337449C-1 3510C EPA 8270C

20118340001 1336904 1336904C-1 8260B EPA 8260B

20118340001 154636C-1 SW-846 7.1.2

20118340001 155097 155240C-1 SW-846 7.3.4.2 SW-846 7.3.4.2

20118340001 154577C-1 EPA 9045

20118340001 155100 155238C-1 SW-846 7.3.3.2 SW-846 7.3.3.2

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/03/2019 03:05 PM

Pace Analytical Services, LLC 1000 Riverbend Blvd - Suite F

St. Rose, LA 70087

ANALYTICAL REPORT

September 03, 2019

Pace Analytical - St. Rose, LA

Sample Delivery Group: L1132205

Samples Received: 08/23/2019

Project Number: 20118340

Description: Waste

Site: 001

Report To: William Shackelford

1000 Riverbend Blvd

Suite F

St. Rose, LA 70087

Entire Report Reviewed By:

September 03, 2019

[Preliminary Report]

Nancy McLain Pro ject Manager

Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received.

12065 Lebanon Rd Mount Jul iet , TN 37122 615-758-5858 800-767-5859 www.pacenational .com

Cp

Tc

Ss

Cn

Sr

Qc

Gl

Al

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Pace Analytical - St. Rose, LA 20118340 L1132205 09/03/19 10:45 1 of 19

September 03, 2019

Nancy McLain Pro ject Manager

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Pace Analytical - St. Rose, LA 20118340 L1132205 09/03/19 11:08 1 of 19 https://www.pacenational.com mailto:william.shackelford@pacelabs.com?subject=Pace National SDG: L1132205 - PN: 20118340&body=Email regarding SDG: L1132205 - Project Number: 20118340 mailto:nmclain@pacenational.com?subject=Pace National SDG: L1132205&body=Email regarding SDG: L1132205 https://www.pacenational.com mailto:nmclain@pacenational.com?subject=Pace National SDG: L1132205&body=Email regarding SDG: L1132205

ONE LAB. NATIONWIDE.TABLE OF CONTENTS

Cp: Cover Page 1

Tc: Table of Contents 2

Ss: Sample Summary 3

Cn: Case Narrative 4

Sr: Sample Results 5

C-1 L1132205-01 5

Qc: Quality Control Summary 7

Mercury by Method 7470A 7

Metals (ICP) by Method 6010B 8

Volatile Organic Compounds (GC/MS) by Method 8260B 10

Chlorinated Acid Herbicides (GC) by Method 8151A 12

Pesticides (GC) by Method 8081B 13

Semi Volatile Organic Compounds (GC/MS) by Method 8270C 14

Gl: Glossary of Terms 16

Al: Accreditations & Locations 17

Sc: Sample Chain of Custody 18

Cp

Tc

Ss

Cn

Sr

Qc

Gl

Al

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Pace Analytical - St. Rose, LA 20118340 L1132205 09/03/19 10:45 2 of 19

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Pace Analytical - St. Rose, LA 20118340 L1132205 09/03/19 11:08 2 of 19

ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

C-1 L1132205-01 Waste 08/22/19 11:00 08/23/19 08:45

Method Batch Dilution Preparation Analysis Analyst Location date/time date/time

Preparation by Method 1311 WG1335478 1 08/27/19 12:28 08/27/19 12:28 CGD Mt. Juliet, TN

Preparation by Method 1311 WG1335772 1 08/27/19 17:01 08/27/19 17:01 CGD Mt. Juliet, TN

Mercury by Method 7470A WG1336583 1 08/28/19 17:33 08/29/19 09:04 ABL Mt. Juliet, TN

Metals (ICP) by Method 6010B WG1336266 1 08/28/19 19:04 08/29/19 00:16 EL Mt. Juliet, TN

Volatile Organic Compounds (GC/MS) by Method 8260B WG1336904 1 08/30/19 03:08 08/30/19 03:08 ACG Mt. Juliet, TN

Chlorinated Acid Herbicides (GC) by Method 8151A WG1337215 1 08/29/19 15:36 08/30/19 15:59 RP Mt. Juliet, TN

Pesticides (GC) by Method 8081B WG1338346 1 08/29/19 22:10 08/31/19 12:15 RP Mt. Juliet, TN

Semi Volatile Organic Compounds (GC/MS) by Method 8270C WG1337449 1 08/30/19 07:21 08/30/19 21:37 JNJ Mt. Juliet, TN

Cp

Tc

Ss

Cn

Sr

Qc

Gl

Al

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Pace Analytical - St. Rose, LA 20118340 L1132205 09/03/19 10:45 3 of 19

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Pace Analytical - St. Rose, LA 20118340 L1132205 09/03/19 11:08 3 of 19

ONE LAB. NATIONWIDE.CASE NARRATIVE

All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data.

[Preliminary Report]

Nancy McLain Pro jec t Manager

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Pace Analytical - St. Rose, LA 20118340 L1132205 09/03/19 10:45 4 of 19

Nancy McLain Pro jec t Manager

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Pace Analytical - St. Rose, LA 20118340 L1132205 09/03/19 11:08 4 of 19 mailto:nmclain@pacenational.com?subject=Pace National SDG: L1132205&body=Email regarding SDG: L1132205 mailto:nmclain@pacenational.com?subject=Pace National SDG: L1132205&body=Email regarding SDG: L1132205

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01

L 1 1 3 2 2 0 5

C-1 C o l l e c t e d d a t e / t i m e : 0 8 / 2 2 / 1 9 1 1 : 0 0

Preparation by Method 1311

Result Qualifier Prep Batch

Analyte date / time

TCLP Extraction - 8/27/2019 5:01:43 PM WG1335772

TCLP ZHE Extraction - 8/27/2019 12:28:44 PM WG1335478

Fluid 1 8/27/2019 5:01:43 PM WG1335772

Initial pH 8.38 8/27/2019 5:01:43 PM WG1335772

Final pH 5.08 8/27/2019 5:01:43 PM WG1335772

Mercury by Method 7470A

Result Qualifier RDL Limit Dilution Analysis Batch

Analyte mg/l mg/l mg/l date / time

Mercury ND 0.0100 0.20 1 08/29/2019 09:04 WG1336583

Metals (ICP) by Method 6010B

Result Qualifier RDL Limit Dilution Analysis Batch

Analyte mg/l mg/l mg/l date / time

Arsenic ND 0.100 5 1 08/29/2019 00:16 WG1336266

Barium 0.491 0.100 100 1 08/29/2019 00:16 WG1336266

Cadmium ND 0.100 1 1 08/29/2019 00:16 WG1336266

Chromium ND 0.100 5 1 08/29/2019 00:16 WG1336266

Lead ND 0.100 5 1 08/29/2019 00:16 WG1336266

Selenium ND 0.100 1 1 08/29/2019 00:16 WG1336266

Silver ND 0.100 5 1 08/29/2019 00:16 WG1336266

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier RDL Limit Dilution Analysis Batch

Analyte mg/l mg/l mg/l date / time

Benzene ND 0.0500 0.50 1 08/30/2019 03:08 WG1336904

Carbon tetrachloride ND 0.0500 0.50 1 08/30/2019 03:08 WG1336904

Chlorobenzene ND 0.0500 100 1 08/30/2019 03:08 WG1336904

Chloroform ND 0.250 6 1 08/30/2019 03:08 WG1336904

1,2-Dichloroethane ND 0.0500 0.50 1 08/30/2019 03:08 WG1336904

1,1-Dichloroethene ND 0.0500 0.70 1 08/30/2019 03:08 WG1336904

2-Butanone (MEK) ND 0.500 200 1 08/30/2019 03:08 WG1336904

Tetrachloroethene ND 0.0500 0.70 1 08/30/2019 03:08 WG1336904

Trichloroethene ND 0.0500 0.50 1 08/30/2019 03:08 WG1336904

Vinyl chloride ND 0.0500 0.20 1 08/30/2019 03:08 WG1336904

(S) Toluene-d8 105 80.0-120 08/30/2019 03:08 WG1336904

(S) 4-Bromofluorobenzene 104 77.0-126 08/30/2019 03:08 WG1336904

(S) 1,2-Dichloroethane-d4 108 70.0-130 08/30/2019 03:08 WG1336904

Chlorinated Acid Herbicides (GC) by Method 8151A

Result Qualifier RDL Limit Dilution Analysis Batch

Analyte mg/l mg/l mg/l date / time

2,4,5-TP (Silvex) ND 0.00200 1 1 08/30/2019 15:59 WG1337215

2,4-D ND J4 0.00200 10 1 08/30/2019 15:59 WG1337215

(S) 2,4-Dichlorophenyl Acetic Acid 97.4 14.0-158 08/30/2019 15:59 WG1337215

Pesticides (GC) by Method 8081B

Result Qualifier RDL Limit Dilution Analysis Batch

Analyte mg/l mg/l mg/l date / time

Chlordane ND 0.00500 0.03 1 08/31/2019 12:15 WG1338346

Endrin ND 0.00500 0.02 1 08/31/2019 12:15 WG1338346

Heptachlor ND 0.00500 0.0080 1 08/31/2019 12:15 WG1338346

Heptachlor epoxide ND 0.00500 0.0080 1 08/31/2019 12:15 WG1338346

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ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01

L 1 1 3 2 2 0 5

C-1 C o l l e c t e d d a t e / t i m e : 0 8 / 2 2 / 1 9 1 1 : 0 0

Pesticides (GC) by Method 8081B

Result Qualifier RDL Limit Dilution Analysis Batch

Analyte mg/l mg/l mg/l date / time

Lindane ND 0.00500 0.40 1 08/31/2019 12:15 WG1338346

Methoxychlor ND 0.00500 10 1 08/31/2019 12:15 WG1338346

Toxaphene ND 0.0100 0.50 1 08/31/2019 12:15 WG1338346

(S) Decachlorobiphenyl 70.8 10.0-128 08/31/2019 12:15 WG1338346

(S) Tetrachloro-m-xylene 43.7 10.0-127 08/31/2019 12:15 WG1338346

Semi Volatile Organic Compounds (GC/MS) by Method 8270C

Result Qualifier RDL Limit Dilution Analysis Batch

Analyte mg/l mg/l mg/l date / time

1,4-Dichlorobenzene ND 0.100 7.50 1 08/30/2019 21:37 WG1337449

2,4-Dinitrotoluene ND 0.100 0.13 1 08/30/2019 21:37 WG1337449

Hexachlorobenzene ND 0.100 0.13 1 08/30/2019 21:37 WG1337449

Hexachloro-1,3-butadiene ND 0.100 0.50 1 08/30/2019 21:37 WG1337449

Hexachloroethane ND 0.100 3 1 08/30/2019 21:37 WG1337449

Nitrobenzene ND 0.100 2 1 08/30/2019 21:37 WG1337449

Pyridine ND 0.100 5 1 08/30/2019 21:37 WG1337449

3&4-Methyl Phenol ND 0.100 400 1 08/30/2019 21:37 WG1337449

2-Methylphenol ND 0.100 200 1 08/30/2019 21:37 WG1337449

Pentachlorophenol ND 0.100 100 1 08/30/2019 21:37 WG1337449

2,4,5-Trichlorophenol ND 0.100 400 1 08/30/2019 21:37 WG1337449

2,4,6-Trichlorophenol ND 0.100 2 1 08/30/2019 21:37 WG1337449

(S) 2-Fluorophenol 38.4 10.0-120 08/30/2019 21:37 WG1337449

(S) Phenol-d5 23.2 10.0-120 08/30/2019 21:37 WG1337449

(S) Nitrobenzene-d5 50.8 10.0-127 08/30/2019 21:37 WG1337449

(S) 2-Fluorobiphenyl 52.1 10.0-130 08/30/2019 21:37 WG1337449

(S) 2,4,6-Tribromophenol 60.0 10.0-155 08/30/2019 21:37 WG1337449

(S) p-Terphenyl-d14 61.7 10.0-128 08/30/2019 21:37 WG1337449

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ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1336583

M e r c u r y b y M e t h o d 7 4 7 0 A L 1 1 3 2 2 0 5 - 0 1

Method Blank (MB)

(MB) R3445371-1 08/29/19 08:31

MB Result MB Qualifier MB MDL MB RDL

Analyte mg/l mg/l mg/l

Mercury U 0.00330 0.0100

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3445371-2 08/29/19 08:33 • (LCSD) R3445371-3 08/29/19 08:35

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte mg/l mg/l mg/l % % % % %

Mercury 0.0300 0.0325 0.0287 108 95.7 80.0-120 12.4 20

L1132394-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1132394-02 08/29/19 08:37 • (MS) R3445371-4 08/29/19 08:44 • (MSD) R3445371-5 08/29/19 08:46

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte mg/l mg/l mg/l mg/l % % % % %

Mercury 0.0300 ND 0.0292 0.0231 97.3 77.0 1 75.0-125 J3 23.3 20

L1132421-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1132421-01 08/29/19 08:48 • (MS) R3445371-6 08/29/19 08:50 • (MSD) R3445371-7 08/29/19 08:53

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte mg/l mg/l mg/l mg/l % % % % %

Mercury 0.0300 ND 0.0304 0.0332 101 111 1 75.0-125 8.81 20

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ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1336266

M e t a l s ( I C P ) b y M e t h o d 6 0 1 0 B L 1 1 3 2 2 0 5 - 0 1

Method Blank (MB)

(MB) R3445292-1 08/28/19 23:12

MB Result MB Qualifier MB MDL MB RDL

Analyte mg/l mg/l mg/l

Arsenic U 0.0333 0.100

Barium U 0.0333 0.100

Cadmium U 0.0333 0.100

Chromium U 0.0333 0.100

Lead U 0.0333 0.100

Selenium U 0.0333 0.100

Silver U 0.0333 0.100

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3445292-2 08/28/19 23:14 • (LCSD) R3445292-3 08/28/19 23:17

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte mg/l mg/l mg/l % % % % %

Arsenic 10.0 9.86 9.74 98.6 97.4 80.0-120 1.19 20

Barium 10.0 10.3 10.1 103 101 80.0-120 1.26 20

Cadmium 10.0 9.91 9.77 99.1 97.7 80.0-120 1.40 20

Chromium 10.0 10.1 9.99 101 99.9 80.0-120 1.35 20

Lead 10.0 10.1 9.98 101 99.8 80.0-120 0.794 20

Selenium 10.0 9.94 9.82 99.4 98.2 80.0-120 1.20 20

Silver 2.00 1.91 1.88 95.6 94.2 80.0-120 1.57 20

L1132875-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1132875-01 08/28/19 23:19 • (MS) R3445292-5 08/28/19 23:25 • (MSD) R3445292-6 08/28/19 23:27

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte mg/l mg/l mg/l mg/l % % % % %

Arsenic 10.0 ND 9.57 9.68 95.7 96.8 1 75.0-125 1.15 20

Barium 10.0 ND 10.2 10.3 102 103 1 75.0-125 0.828 20

Cadmium 10.0 ND 9.68 9.75 96.8 97.5 1 75.0-125 0.721 20

Chromium 10.0 ND 10.0 10.1 100 101 1 75.0-125 0.854 20

Lead 10.0 ND 9.92 10.0 99.2 100 1 75.0-125 0.841 20

Selenium 10.0 ND 9.54 9.52 94.7 94.5 1 75.0-125 0.193 20

Silver 2.00 ND 1.87 1.88 93.6 94.1 1 75.0-125 0.463 20

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ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1336266

M e t a l s ( I C P ) b y M e t h o d 6 0 1 0 B L 1 1 3 2 2 0 5 - 0 1

L1132394-02…