A02 - Purchase Desription Attachment..pdf

Department of the Army MCAAP Pamphlet 702-13 McAlester Army Ammunition Plant McAlester, Ok. 74501-9002 26 October 2022

Directorate of Quality Assurance

QUALIFIED CHEMICALS

Applicability. This document applies to the McAlester Army Ammunition Plant (MCAAP).

Suggested Improvements. The proponent of this document is the Chief of Quality Assurance Test Division. Comments and suggestions can be submitted to JMMC-QA.

Distribution. The current edition of this document will be maintained on the MCAAP SharePoint Intranet. Individual copies may be printed from that source as required.

Refer to MCAAPP 25-201 for document control requirements.

FOR THE COMMANDER:

Treaver Price Chief, Quality Assurance Laboratory

CONTENTS PARAGRAPH

Purpose Responsibility Scope Procedures Appendix A. Listing of Qualified Chemicals Appendix B. Customer Defined Shelf Life

* This pamphlet supersedes MCAAPP 702-13, 17 May 2021.

PRICE.TREAVE

R.1262935937

Digitally signed by

PRICE.TREAVER.12629359

Date: 2022.11.14 10:51:34 -06'00'

MCAAP Pamphlet 702-13

2 OCT 22

1. Purpose. To provide detailed listing and requirements of qualified chemicals used in load/assemble/pack operations.

2. Responsibility. Chief, Quality Assurance Test Division is responsible for ensuring stated purpose is accomplished.

3. Scope. All personnel requesting and/or procuring chemicals listed herein.

4. Procedures.

a. Requirements for Qualified Chemicals.

(1) Stated in the material specification and/or the ammunition load document.

(2) Contractual obligation with customer as in the First Article Acceptance of the end item.

b. Certificate of Conformance and Analysis.

(1) Required for every qualified chemical.

(2) Must state clearly which specification it conforms and include any applicable exceptions listed herein.

(3) Only stating that the material meets the purchase order is not sufficient.

(4) Information required on Certificate of Conformance and Analysis includes:

(a) Manufacturer Name (Materials are qualified by manufacturer not distributor)

(b) Product Name or Description

(c) National Stock Number (If available)

(d) Specification

(e) Lot/Batch Number

(f) Manufacture Date

(g) Expiration/Re-inspection Date

(h) Analytical Data

MCAAPP 702-13

OCT 22 3

(i) Statement of No Change in Materials or Process Quality Chemicals designated in Appendix A with “Statement of No Change in Materials or Process” must so state on the certificate.

(j) Signature of Authorized Representative.

4 OCT 22

APPENDIX A

LISTING OF QUALIFIED CHEMICALS

2,2’-Methylenebis (4-Methyl-6-Tertiarybutyl Phenol) – Commonly called AO2246 Stock #: 00X871714:4TZJ4 Specification: WS 23151

Product Manufacturer Cyanox 2246 Cytec Industries Inc.

Ralox 46 Raschig CAO-5 PMC Specialties

Citation: MIL-DTL-82886A Table VI

4,4’-Methylenebis (2,6-Di-Tert-Butylphenol) – Commonly called Ethyl 4702 Stock # ETHANOX4702:1YW43 Specification: DOD-M-82730

a. The maximum melting point requirement shall not apply.

b. The benzene insolubles requirement shall not apply.

c. The water content requirement shall be a maximum of 0.5%.

Product Manufacturer Ethanox 4702 or 4710 S.I. Group

M0214 TCI America (approved for AF)

Citation: MIL-DTL-82901E, PBXN-110

Aluminum Powder, Atomized – Commonly used with Tritonal Stock#: 1376006283382 Specification: MIL-DTL-512D, Type III, Grade C, Class 7

Product Manufacturer AMPAL 601 MIL Ampal Toyal 44 Aluminum Powder Toyal America, Inc.

420M Ecka Granules

Citation: MK-82, 83, 84 and BLU-109 Tritonal 1st Article acceptance. Any new product would require a LAP 1st Article.

Aluminum Powder, Spherical, Type I – Used for PBXN 113 Stock # 681000C110019 Specification: MIL-PRF-23950B Type I

Product Manufacturer ATA X-65 Aluminum Powder Toyal America H-5 Valimet Inc.

Citation: None

OCT 22 5

Aluminum Powder, Spherical, Type IV – Commonly used for PBXN-109 and AFX-757 Stock #: 00X871709:4TZJ4 Specification: MIL-PRF-23950B Amendment 1 Type IV

Product Manufacturer ATA X-81 Aluminum Powder Toyal America H-12 Valimet Inc.

S6261 (18μ) and S6251 (16μ) Alcoa Priming Metals

Ammonium Perchlorate – Commonly called AP used in MIL-DTL-32103, AFX-757 Stock #: 00X030447:4TZJ4 Specification: WS-18485

Product Manufacturer WS-18485A AMPAC-WEECO, SMC is sole distributor

Citation: BLU-121, BLU-122, MOP, and SDB 1st article acceptance. Any new product would require a LAP 1st Article.

Blue Dye (Powder) – Used in inert filler in BLU-126 Stock #: 8010000N057975 Specification: NMD 240A

Product Code 249-2083 Cage Code 91686 Product Manufacturer 249-2083, Blue Dye Sun Chemicals Co.

Citation: NMD 240A, Bomb assembly, low collateral damage, 500 pound, BLU-126/B. Any new product would require a LAP 1st Article.

Blue Dye (Liquid) – Used in inert filler in BLU-126 Stock # L5298-NS Blue Specification: NMD 240A Product Manufacturer Novasolve Blue 298 liquid dye Nova Specialty Chemicals

Citation: RFV 15-001R1

Carnauba Wax – Used in AFX-795 Stock #: 00X04197:4TZJ4 Specification: MIL-DTL- 20065113 (AF)

Product Manufacturer Carnauba Wax NC#3 Dark SP-8 Strahl & Pitsch KTC B-1 Wax KAP TechnoChem USA Inc.

Carnauba Wax T-4 Koster Keunen

Citation: BLU-117 C/B 1st article acceptance.

6 OCT 22

Coating Compound, Thermal Insulation, Ablative – Commonly called thermal coat resin Stock #: FMA260:0TZS5 Specification: MIL-C-81904C

Product Manufacturer FAM260 Ghost Grey, Component 1 International Paint

Citation: QPL-81904, MIL-PRF-91904C is not procurable yet due to specification conflicts

Composition D-2 Stock #: 1376006283323 Specification: MIL-DTL-18164B

Product Manufacturer

Compound, Asphaltic, Hot Melt (Cavity Lining) – Commonly called tar Stock #: MIL-C-3301-47LBBBOX:81349 Specification: MIL-DTL-3301D

Product Manufacturer ZECO AA-3028 ZIEGLER CHEMICAL & MINERAL Co Pioneer 568 Pioneer Asphalt Co NGT/SA-3301D NuGenTec - Not Air Force Approved

Citation: MK-82, 83, 84, BLU-109, 110, 111, 117, and MOP 1st Article acceptance. Any new product would require a LAP 1st Article.

Compound, Polymeric Elastomer, Thermosetting – Commonly called Tuff Seal Stock #: 8030014529911 Specification: MIL-DTL-82633A (Thermal conductivity shall not apply)

Product Manufacturer EPI-Seal Bomb Sealant Abbey Color Inc.

Citation: MIL-DTL-82633A Section 6.7 Source of Supply

CXM-7, Type II – Used in PBXN-109 Stock #: 1376012805339 Specification: MIL-DTL-82907B

Product Manufacturer CXM-7, Type II BAE, Holston

Citation: MIL-DTL-82886A, Table VI

CXM-10 – Used in PBXN-110 (Type I, or blend of Type II and Type III) Stock #: 00X04920:4TZJ4 Specification: MIL-DTL-32189C

CXM-10, Type I BAE, Holston

Citation: MIL-DTL-82901D Table VIII

OCT 22 7

CXM-11 – Used in PBXN-113, AFX-1282, AFX-1209, PBXN-114 Stock #: 00X060282:4TZJ4 Specification: MIL-DTL-32230A

Product Manufacturer CXM-11 BAE, Holston

Citation: MIL-DTL-32230A Table VIII

CXM-AF-5 – Used in AFX-757 Stock #: 00X040525:4TZJ4 Specification: MIL-DTL-20084713A (AF)

Product Manufacturer CXM-AF-5 BAE, Holston

Citation: BLU-121, BLU-122, SDB, and MOP 1st article acceptance. Any new product would require a LAP 1st Article.

CXM-AF-7 – Used in AFX-795 Stock #: 1376015628442 Specification: MIL-DTL-20065102A (AF)

Product Manufacturer CXM-AF-7 BAE, Holston

Citation: BLU-117 C/B 1st article acceptance. Any new product would require a LAP 1st Article.

Di (2-ethylhexyl) Adipate – Commonly called DOA Stock #: 00X871713:4TZJ4 Specification: MIL-DTL-23443C, (previously DOD-D-23443B with Amendment 2) MIL-DTL- 23443C).

Product Manufacturer Plastomoll DOA BASF Corporation Eastman DOA Plasticizer Eastman Chemical Company Hatcol 2908 Hatco Corportation

Citation: MIL-DTL-82886A Table VI

Dibutyltin Dilaurate – Commonly called Dbtdl Stock #: 681000N014265 Specification: DOD-D-82727, the specific gravity for dibutyltin dilaurate is not required

Product Manufacturer COTIN 200 Catalyst Vertelius Performance Materials, Inc.

DBT Momentive Performance Materials, Inc.

DABCO T-12 Air Products and Chemicals, Inc.

Fascat 4202 Catalyst Arkema, Inc.

Citation: MIL-DTL-82901D Table IV

8 OCT 22

Glyceryl ester of 12-hydroxy Stearic Acid – Commonly called castor wax Stock #: 00X860191:4TZJ4 Specification: MIL-G-48246

a. The alkalinity requirement shall not apply

b. The melting point requirement shall be 83⁰ to 90⁰C

c. The viscosity requirement shall be 40 cP maximum at 93⁰C and 10 cP minimum at

121⁰C

d. The reactivity requirement shall not apply

Citation: NMD 191, Bomb, Penetrator, 2000 Pound, BLU-109A (D-1)/B, Inert Loaded

Gypsum, Dead Burned – Commonly called Snow White Stock #: 00X891277:4TZJ4 Specification: MIL-G-48344 Amendment 1

a. The purity requirement shall not apply

b. The combined water content requirement shall be 1.0% max.

Citation: NMD 191, Bomb, Penetrator, 2000 Pound, BLU-109A (D-1)/B, Inert Loaded

Hollow Glass Spheres – Used in inert filler for BLU-126 Stock#:

Specification: NMD 240A

Attribute Requirement Density (g/cm3) 1.10 ± 0.05 Composition Fused borosilicate glass Shape Hollow nonporous microspheres Particle Size, Average Size (µm) 9 - 13 Particle Size Distribution (µm) 90% finer than 19 - 21 50% finer than 9 - 11 10% finer than 4 - 5 Strength (min.) psi 10,000 Hardness (Mohs scale) 6 Alkalinity (max.) 0.5 meg/gr Loss on Drying (max.) 0.5 weight % (10 min @ 250 ⁰F)

Sphericel 110P8 Potters Industries, Inc.

OCT 22 9

Impact Beads – Used in inert filler for BLU-126 Stock #: 00X061100:4TZJ4 Specification: NMD 240A

Attribute Requirement Nominal Diameter (in) 0.0021 – 0.0041 % Round (min.) 85.0 Specific Gravity (g/cm3) 2.45 – 2.55 Silica Content (% min.) 67 Free Iron Content (% max.) 0.1, by weight Hardness Rockwell 48 – 50C

AG Ballotini Impact Beads Potters Industries, Inc.

Isodecyl Pelargonate – Commonly called IDP Stock #: 2911:0ZNZ1 Specification: AS 2328

Product Manufacturer Synative ES 2911 Cognis Corporation

Citation: MIL-DTL-82901D Table IV

Isophorone Diisocyanate – Commonly called IPDI Stock #: 00X871711:4TZJ4 Specification: WS 16305

Product Manufacturer Vestant IPDI Evonik Degussa Desmodur I Convestro formerly Bayer Corporation

Lecithin – Used in AFX-757, Destex, PBXN-110, and PBXN-113 Stock #: 00X930726:4TZJ4 Specification: MIL-L-3061B Amendment 1

a. The acid number requirement for lecithin shall be a maximum of 32

b. The acetone insoluble requirement for lecithin shall be a minimum of 62%

c. The lecithin percent requirement shall be a minimum of 13%

Solec F Solec (Require MCAAP Test) B60 W.A. Cleary Products, Inc.

B70 W.A. Cleary Products, Inc.

B70L W.A. Cleary Products, Inc.

Citation: MIL-DTL-32259B Table VII

10 OCT 22

Methyl Ethyl Ketone Peroxide, Solution – Commonly called MEKP Stock # 6810011200408 Specification: A-A-59304A

Product Manufacturer Cadox M-50A AkzoNobel Corp.

Citation: BLU-109, 110, 111, and 117 1st article acceptance. Any new product would require a LAP 1st Article.

N, N 2-hydroxyethyl Dimethyl Hydantoin – Commonly called DHE Stock #: 00X871712:4TZJ4 Specification: WS 23149

a. Refractive Index shall not apply

b. Conductivity, and Phosphate content shall replace Refractive index

Product Manufacturer Dantocol DHE Lonza Inc.

Citation: MIL-DTL-82886A Table VI, confirmation from Navy.

Polybutadiene, Liquid, Hydroxyl-terminated – Commonly called PolyBd or R-45 Stock #: 00X871710:4TZJ4 Specification: WS 23148D Type II

Product Manufacturer R-45HTLO Petrochemicals & Refining USA (formerly Cray

Valley formerly Sartomer) HYPRO 2800X95 CVC Thermoset Specialties

Rosin, Wood – Used in Filler-E Stock #: 00X841247:4TZJ4 Specification: LLL-R-626D Class B or A-A-59142 Class B Type I

a. The insoluble matter in toluene requirement shall not apply

b. The saponification number requirement shall not apply

c. The acid number requirement shall be 140 minimum

Product Manufacturer

Citation: NMD 191A, ECP# IHDPT-720, Bomb, Penetrator, 2000 Pound, BLU-109A (D-1)/B, Inert Loaded

Solid Glass Spheres – Used in inert filler for BLU-126 Stock #: 00X061102:4TZJ4 Specification: NMD 240A

Attribute Requirement Specific Gravity (g/cm3) 2.5

OCT 22 11

Particle Size Distribution (µm)

90% finer than 60 50% finer than 35 10% finer than 18 Silica Content (%) 72.5 Free Iron Content (% max.) 0.1 Hardness (Mohs scale) 6.0 Softening Point (⁰C) 704

Spheriglass 3000A Potters Industries, Inc.

Citation: NMD 240A, Bomb assembly, low collateral damage, 500 pound, BLU-126/B, loaded 1st article for BLU-126. Any new product would require a LAP 1st Article.

Trinitrotoluene – Commonly called TNT Stock #: 1376006283333 Specification: MIL-DTL-248D Amendment 2, Type I or III (Type III produced by MCAAP).

Citation

Triphenylbismuth – Commonly called TPB Stock #: 00X871709:4TZJ$ Specification: MIL-T-82825 (OS)

Product Manufacturer BSC-152 Boulder Scientific Company WS 20883 Island Pyrochemical Industries

Penta Manufacturing Co. (require MCAAP test mix)

12 OCT 22

APPENDIX B

CUSTOMER DEFINED SHELF LIFE

The materials listed have a shelf life designated by the customer in addition to any shelf life stated by the manufacturer. The most restrictive shelf life must apply.

MATERIAL SHELF LIFE STORAGE CONDITION REFERENCE

Polybutadiene (PolyBd) 12 months 60⁰ to 90⁰F ADL923AS683

NMS000107

Triphenylbismuth (TPB) 12 months Ambient, no UV light ADL923AS683

N, N2-Hydroxyl-Ethyl Dimethyl Hydantoin (DHE)

12 months Ambient ADL923AS683

Isophorone Diisocyanate

(IPDI)

Open 6 months, Unopened 12 months

50⁰ to 120⁰F NMS000107

Ammonium Perchlorate 12 months 60⁰ to 90⁰F NMS000107

CXM-AF-5 12 months Ambient NMS000107

ADL Number: ADL923AS683 Body Assembly, Bomb General Purpose, 1000 Pound, BLU- 110/B, PBXN-109 Loaded, NTP

Drawing Number: NMS000107, Load Specification, BLU-122/B, AFX-757