36C26218Q9476-0001002.pdf

Thank you for the opportunity to be of service to your company. Please feel free to call if there are any questions regarding this report or if we can be of further service.

NOTE: Unless notified in writing, all samples will be discarded by appropriate disposal protocol 60 days from date received.

The reports of the Enthalpy Analytical, Inc. are confidential property of our clients and may not be reproduced or used for publication in part or in full without our written permission. This is for the mutual protection of the public, our clients, and ourselves.

Report Review performed by: Kristen Walker, Project Manager

Lab Request 388258, Page 1 of 1566535-01

Client: Marine Biochemists

Mike Langlois

Address: 2940 E. La Jolla St. #B Anaheim, CA 92806

Lab Request: 388258 Report Date: 03/12/2017 Date Received: 03/03/2017

This laboratory request covers the following listed samples which were analyzed for the parameters indicated on the attached Analytical Result Report. All analyses were conducted using the appropriate methods. Methods accredited by NELAC are indicated on the report. This cover letter is an integral part of the final report.

P.O. #4501727639Comments:

Attn:

Client ID: 9384

Enthalpy Analytical, Inc.

806 N. Batavia - Orange, CA 92868 www.associatedlabs.com info-sc@enthalpy.com

Tel: (714)771-6900 Fax: (714)538-1209

NELAP:04232CA | ELAP:1338

Formerly Associated Labs

Sample # Client Sample ID

388258-001 VA Hospital

Analyte Prepared AnalyzedDF RDL UnitsResult Notes

Sample #: 388258-001

Sampled: 03/02/2017 11:00 Site:

VA HospitalClient Sample #:

Matrix: Liquid Collector: ClientClient: Marine Biochemists

Sample Type:

By Method: EPA 6010B Prep Method: EPA 3050B QCBatchID: QC1176076NELAC

Antimony ND 1 03/08/173 mg/Kg 03/07/17 JN

Arsenic ND 1 03/08/171 mg/Kg 03/07/17 JN

Barium 27.4 1 03/08/171 mg/Kg 03/07/17 JN

Beryllium ND 1 03/08/170.5 mg/Kg 03/07/17 JN

Cadmium ND 1 03/08/170.5 mg/Kg 03/07/17 JN

Chromium 9.51 1 03/08/171 mg/Kg 03/07/17 JN

Cobalt 4.45 1 03/08/170.5 mg/Kg 03/07/17 JN

Lead 2.04 1 03/08/170.5 mg/Kg 03/07/17 JN

Molybdenum ND 1 03/08/171 mg/Kg 03/07/17 JN

Nickel 5.47 1 03/08/171.5 mg/Kg 03/07/17 JN

Selenium ND 1 03/08/171 mg/Kg 03/07/17 JN

Silver ND 1 03/08/170.5 mg/Kg 03/07/17 JN

Thallium ND 1 03/08/171 mg/Kg 03/07/17 JN

Vanadium 19.0 1 03/08/170.5 mg/Kg 03/07/17 JN

Zinc 47.0 1 03/08/175 mg/Kg 03/07/17 JN

Method: EPA 7471A Prep Method: EPA 7471A QCBatchID: QC1176075NELAC

Mercury ND 1 03/07/170.14 mg/Kg 03/07/17 JP

Method: EPA 8082 Prep Method: EPA 3580A QCBatchID: QC1176061NELAC

PCB-1016 ND 2 03/08/17100 ug/Kg 03/07/17 LW

PCB-1221 ND 2 03/08/17100 ug/Kg 03/07/17 LW

PCB-1232 ND 2 03/08/17100 ug/Kg 03/07/17 LW

PCB-1242 ND 2 03/08/17100 ug/Kg 03/07/17 LW

PCB-1248 ND 2 03/08/17100 ug/Kg 03/07/17 LW

PCB-1254 ND 2 03/08/17100 ug/Kg 03/07/17 LW

PCB-1260 ND 2 03/08/17100 ug/Kg 03/07/17 LW

PCB-1262 ND 2 03/08/17100 ug/Kg 03/07/17 LW

PCB-1268 ND 2 03/08/17100 ug/Kg 03/07/17 LW

Surrogate % Recovery Limits Notes

Decachlorobiphenyl DCB (SUR) 88 50-150

Method: EPA 8260B Prep Method: EPA 5035 QCBatchID: QC1176051NELAC

1,1,1,2-Tetrachloroethane ND 1 03/07/175 ug/Kg ZZ

1,1,1-Trichloroethane ND 1 03/07/175 ug/Kg ZZ

1,1,2,2-Tetrachloroethane ND 1 03/07/175 ug/Kg ZZ

1,1,2-Trichloroethane ND 1 03/07/175 ug/Kg ZZ

1,1,2-Trichlorotrifluoroethane ND 1 03/07/175 ug/Kg ZZ

1,1-Dichloroethane ND 1 03/07/175 ug/Kg ZZ

1,1-Dichloroethene ND 1 03/07/175 ug/Kg ZZ

1,1-Dichloropropene ND 1 03/07/175 ug/Kg ZZ

1,2,3-Trichlorobenzene ND 1 03/07/175 ug/Kg ZZ

1,2,3-Trichloropropane ND 1 03/07/175 ug/Kg ZZ

1,2,4-Trichlorobenzene ND 1 03/07/175 ug/Kg ZZ

1,2,4-Trimethylbenzene ND 1 03/07/175 ug/Kg ZZ

1,2-Dibromo-3-chloropropane ND 1 03/07/175 ug/Kg ZZ

1,2-Dibromoethane ND 1 03/07/175 ug/Kg ZZ

1,2-Dichlorobenzene ND 1 03/07/175 ug/Kg ZZ

1,2-Dichloroethane ND 1 03/07/175 ug/Kg ZZ

1,2-Dichloropropane ND 1 03/07/175 ug/Kg ZZ

1,3,5-Trimethylbenzene ND 1 03/07/175 ug/Kg ZZ

1,3-Dichlorobenzene ND 1 03/07/175 ug/Kg ZZ

1,3-Dichloropropane ND 1 03/07/175 ug/Kg ZZ

1,4-Dichlorobenzene ND 1 03/07/175 ug/Kg ZZ

Lab Request 388258, Page 2 of 1566535-01 Enthalpy Analytical, Inc.

Analytical Results Report

Sampled: 03/02/2017 11:00 Site:

VA HospitalClient Sample #:

Matrix: Liquid Collector: ClientClient: Marine Biochemists

Sample Type:

By 2,2-Dichloropropane ND 1 03/07/175 ug/Kg ZZ

2-Butanone (MEK) ND 1 03/07/17100 ug/Kg ZZ

2-Chloroethyl Vinyl Ether ND 1 03/07/175 ug/Kg ZZ

2-Chlorotoluene ND 1 03/07/175 ug/Kg ZZ

4-Chlorotoluene ND 1 03/07/175 ug/Kg ZZ

4-Isopropyltoluene ND 1 03/07/175 ug/Kg ZZ

4-Methyl-2-pentanone (MIBK) ND 1 03/07/175 ug/Kg ZZ

Acetone ND 1 03/07/17100 ug/Kg ZZ

Allyl Chloride ND 1 03/07/175 ug/Kg ZZ

Benzene ND 1 03/07/175 ug/Kg ZZ

Bromobenzene ND 1 03/07/175 ug/Kg ZZ

Bromochloromethane ND 1 03/07/175 ug/Kg ZZ

Bromodichloromethane ND 1 03/07/175 ug/Kg ZZ

Bromoform ND 1 03/07/175 ug/Kg ZZ

Bromomethane ND 1 03/07/175 ug/Kg ZZ

Carbon Tetrachloride ND 1 03/07/175 ug/Kg ZZ

Chlorobenzene ND 1 03/07/175 ug/Kg ZZ

Chlorodibromomethane ND 1 03/07/175 ug/Kg ZZ

Chloroethane ND 1 03/07/175 ug/Kg ZZ

Chloroform ND 1 03/07/175 ug/Kg ZZ

Chloromethane ND 1 03/07/175 ug/Kg ZZ cis-1,2-Dichloroethene ND 1 03/07/175 ug/Kg ZZ cis-1,3-dichloropropene ND 1 03/07/175 ug/Kg ZZ cis-1,4-dichloro-2-butene ND 1 03/07/175 ug/Kg ZZ

Dibromomethane ND 1 03/07/175 ug/Kg ZZ

Dichlorodifluoromethane ND 1 03/07/175 ug/Kg ZZ

Ethylbenzene ND 1 03/07/175 ug/Kg ZZ

Hexachlorobutadiene ND 1 03/07/175 ug/Kg ZZ

Isopropylbenzene ND 1 03/07/175 ug/Kg ZZ m and p-Xylene ND 1 03/07/175 ug/Kg ZZ

Methylene chloride ND 1 03/07/175 ug/Kg ZZ

Methyl-t-butyl Ether (MTBE) ND 1 03/07/175 ug/Kg ZZ

Naphthalene ND 1 03/07/175 ug/Kg ZZ

N-butylbenzene ND 1 03/07/175 ug/Kg ZZ

N-propylbenzene ND 1 03/07/175 ug/Kg ZZ o-Xylene ND 1 03/07/175 ug/Kg ZZ

Sec-butylbenzene ND 1 03/07/175 ug/Kg ZZ

Styrene ND 1 03/07/175 ug/Kg ZZ

Tert-butylbenzene ND 1 03/07/175 ug/Kg ZZ

Tetrachloroethene ND 1 03/07/175 ug/Kg ZZ

Toluene ND 1 03/07/175 ug/Kg ZZ trans-1,2-dichloroethene ND 1 03/07/175 ug/Kg ZZ trans-1,3-dichloropropene ND 1 03/07/175 ug/Kg ZZ trans-1,4-dichloro-2-butene ND 1 03/07/175 ug/Kg ZZ

Trichloroethene ND 1 03/07/175 ug/Kg ZZ

Trichlorofluoromethane ND 1 03/07/175 ug/Kg ZZ

Vinyl Chloride ND 1 03/07/175 ug/Kg ZZ

Xylenes (Total) ND 1 03/07/175 ug/Kg ZZ

Surrogate % Recovery Limits Notes

1,2-Dichloroethane-d4 (SUR) 120 70-145

4-Bromofluorobenzene (SUR) 111 70-145

Dibromodifluoromethane (SUR) 107 70-145

Toluene-d8 (SUR) 94 70-145

Lab Request 388258, Page 3 of 1566535-01 Enthalpy

Sampled: 03/02/2017 11:00 Site:

VA HospitalClient Sample #:

Matrix: Liquid Collector: ClientClient: Marine Biochemists

Sample Type:

By Method: EPA 8270C Prep Method: Method QCBatchID: QC1176085NELAC

1,2,4-Trichlorobenzene ND 8 03/09/172000 ug/Kg 03/07/17 BB

1,2-Dichlorobenzene ND 8 03/09/172000 ug/Kg 03/07/17 BB

1,3-Dichlorobenzene ND 8 03/09/172000 ug/Kg 03/07/17 BB

1,4-Dichlorobenzene ND 8 03/09/172000 ug/Kg 03/07/17 BB

1-Methylnapthalene ND 8 03/09/172000 ug/Kg 03/07/17 BB

2,4,5-Trichlorophenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

2,4,6-Trichlorophenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

2,4-Dichlorophenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

2,4-Dimethylphenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

2,4-Dinitrophenol ND 8 03/09/179600 ug/Kg 03/07/17 BB

2,4-Dinitrotoluene ND 8 03/09/172000 ug/Kg 03/07/17 BB

2,6-Dinitrotoluene ND 8 03/09/172000 ug/Kg 03/07/17 BB

2-Chloronaphthalene ND 8 03/09/172000 ug/Kg 03/07/17 BB

2-Chlorophenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

2-Methyl-4,6-dinitrophenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

2-Methylnaphthalene ND 8 03/09/172000 ug/Kg 03/07/17 BB

2-Methylphenol (o-Cresol) ND 8 03/09/172000 ug/Kg 03/07/17 BB

2-Nitroaniline ND 8 03/09/172000 ug/Kg 03/07/17 BB

2-Nitrophenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

3 and 4-Methylphenol (m and p-Cresol) ND 8 03/09/173200 ug/Kg 03/07/17 BB

3,3'-Dichlorobenzidine ND 8 03/09/179600 ug/Kg 03/07/17 BB

3-Nitroaniline ND 8 03/09/172000 ug/Kg 03/07/17 BB

4-Bromophenyl phenyl ether ND 8 03/09/172000 ug/Kg 03/07/17 BB

4-Chloro-3-methylphenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

4-Chloroaniline ND 8 03/09/172000 ug/Kg 03/07/17 BB

4-Chlorophenyl phenyl ether ND 8 03/09/172000 ug/Kg 03/07/17 BB

4-Nitroaniline ND 8 03/09/172000 ug/Kg 03/07/17 BB

4-Nitrophenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

Acenaphthene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Acenaphthylene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Aniline ND 8 03/09/172000 ug/Kg 03/07/17 BB

Anthracene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Azobenzene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Benz(a)anthracene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Benzidine ND 8 03/09/179600 ug/Kg 03/07/17 BB

Benzo(a)pyrene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Benzo(b)fluoranthene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Benzo(g,h,i)perylene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Benzo(k)fluoranthene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Benzoic acid ND 8 03/09/179600 ug/Kg 03/07/17 BB

Benzyl alcohol ND 8 03/09/172000 ug/Kg 03/07/17 BB

Bis(2-chloroethoxy)methane ND 8 03/09/172000 ug/Kg 03/07/17 BB

Bis(2-chloroethyl) Ether ND 8 03/09/179600 ug/Kg 03/07/17 BB

Bis(2-chloroisopropyl) Ether ND 8 03/09/172000 ug/Kg 03/07/17 BB

Bis(2-ethylhexyl) phthalate ND 8 03/09/172000 ug/Kg 03/07/17 BB

Butylbenzyl Phthalate ND 8 03/09/172000 ug/Kg 03/07/17 BB

Carbazole ND 8 03/09/172000 ug/Kg 03/07/17 BB

Chrysene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Dibenz(a,h)anthracene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Dibenzofuran ND 8 03/09/172000 ug/Kg 03/07/17 BB

Diethyl phthalate ND 8 03/09/172000 ug/Kg 03/07/17 BB

Dimethyl phthalate ND 8 03/09/172000 ug/Kg 03/07/17 BB

Lab Request 388258, Page 4 of 1566535-01 Enthalpy

Sampled: 03/02/2017 11:00 Site:

VA HospitalClient Sample #:

Matrix: Liquid Collector: ClientClient: Marine Biochemists

Sample Type:

By Di-n-butyl phthalate ND 8 03/09/172000 ug/Kg 03/07/17 BB

Di-n-octyl phthalate ND 8 03/09/172000 ug/Kg 03/07/17 BB

Fluoranthene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Fluorene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Hexachlorobenzene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Hexachlorobutadiene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Hexachlorocyclopentadiene ND 8 03/09/179600 ug/Kg 03/07/17 BB

Hexachloroethane ND 8 03/09/172000 ug/Kg 03/07/17 BB

Indeno(1,2,3-cd)pyrene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Isophorone ND 8 03/09/172000 ug/Kg 03/07/17 BB

Naphthalene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Nitrobenzene ND 8 03/09/179600 ug/Kg 03/07/17 BB

N-Nitrosodimethylamine (NDMA) ND 8 03/09/172000 ug/Kg 03/07/17 BB

N-Nitrosodi-n-propylamine (NDPA) ND 8 03/09/172000 ug/Kg 03/07/17 BB

N-Nitrosodiphenylamine ND 8 03/09/172000 ug/Kg 03/07/17 BB

Pentachlorophenol ND 8 03/09/179600 ug/Kg 03/07/17 BB

Phenanthrene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Phenol ND 8 03/09/172000 ug/Kg 03/07/17 BB

Pyrene ND 8 03/09/172000 ug/Kg 03/07/17 BB

Pyridine ND 8 03/09/172000 ug/Kg 03/07/17 BB

Total Cresol ND 8 03/09/173200 ug/Kg 03/07/17 BB

Surrogate % Recovery Limits Notes

2,4,6-Tribromophenol (SUR) 69 34-143

2-Fluorobiphenyl (SUR) 68 30-120

2-Fluorophenol (SUR) 66 13-153

Nitrobenzene-d5 (SUR) 61 27-125 p-Terphenyl (SUR) 88 33-155

Phenol-d5 (SUR) 77 24-126

Lab Request 388258, Page 5 of 1566535-01 Enthalpy

QCBatchID: QC1176051

Matrix: Liquid

Analyst: nicollez

Instrument: VOA-MS (group)Analyzed: 03/06/2017

Method: EPA 8260B

Blank Summary

Analyte Result Units NotesRDL

Blank

QC1176051MB1

1,1,1,2-Tetrachloroethane ND ug/Kg 5

1,1,1-Trichloroethane ND ug/Kg 5

1,1,2,2-Tetrachloroethane ND ug/Kg 5

1,1,2-Trichloroethane ND ug/Kg 5

1,1,2-Trichlorotrifluoroethane ND ug/Kg 5

1,1-Dichloroethane ND ug/Kg 5

1,1-Dichloroethene ND ug/Kg 5

1,1-Dichloropropene ND ug/Kg 5

1,2,3-Trichlorobenzene ND ug/Kg 5

1,2,3-Trichloropropane ND ug/Kg 5

1,2,4-Trichlorobenzene ND ug/Kg 5

1,2,4-Trimethylbenzene ND ug/Kg 5

1,2-Dibromo-3-chloropropane ND ug/Kg 5

1,2-Dibromoethane ND ug/Kg 5

1,2-Dichlorobenzene ND ug/Kg 5

1,2-Dichloroethane ND ug/Kg 5

1,2-Dichloropropane ND ug/Kg 5

1,3,5-Trimethylbenzene ND ug/Kg 5

1,3-Dichlorobenzene ND ug/Kg 5

1,3-Dichloropropane ND ug/Kg 5

1,4-Dichlorobenzene ND ug/Kg 5

2,2-Dichloropropane ND ug/Kg 5

2-Butanone (MEK) ND ug/Kg 100

2-Chloroethyl Vinyl Ether ND ug/Kg 5

2-Chlorotoluene ND ug/Kg 5

4-Chlorotoluene ND ug/Kg 5

4-Isopropyltoluene ND ug/Kg 5

4-Methyl-2-pentanone (MIBK) ND ug/Kg 5

Acetone ND ug/Kg 100

Allyl Chloride ND ug/Kg 5

Benzene ND ug/Kg 5

Bromobenzene ND ug/Kg 5

Bromochloromethane ND ug/Kg 5

Bromodichloromethane ND ug/Kg 5

Bromoform ND ug/Kg 5

Bromomethane ND ug/Kg 5

Carbon Tetrachloride ND ug/Kg 5

Chlorobenzene ND ug/Kg 5

Chlorodibromomethane ND ug/Kg 5

Chloroethane ND ug/Kg 5

Chloroform ND ug/Kg 5

Chloromethane ND ug/Kg 5 cis-1,2-Dichloroethene ND ug/Kg 5 cis-1,3-dichloropropene ND ug/Kg 5 cis-1,4-dichloro-2-butene ND ug/Kg 5

Dibromomethane ND ug/Kg 5

Dichlorodifluoromethane ND ug/Kg 5

Di-isopropyl ether (DIPE) ND ug/Kg 5

Ethylbenzene ND ug/Kg 5

Ethyl-tertbutylether (ETBE) ND ug/Kg 5

Hexachlorobutadiene ND ug/Kg 5

Lab Request 388258, Page 6 of 1566535-01 Enthalpy

QCBatchID: QC1176051

Analyst: nicollez

Instrument: VOA-MS (group)Analyzed: 03/06/2017

Method: EPA 8260B

Matrix Spike/Matrix Spike Duplicate Summary

Analyte Amount

Spike Amount

MS MSD Units MS RPD %Rec RPD

Spike Result

MSD MSDMS

Recoveries LimitsSample

Notes

QC1176051MS1, QC1176051MSD1 Source: 388307-001

1,1-Dichloroethene 9.7 2259-172984950 54ND 50 108ug/Kg

Benzene 8.3 2462-137924650 50ND 50 100ug/Kg

Chlorobenzene 4.3 2460-133924650 48ND 50 96ug/Kg

Methyl-t-butyl Ether (MTBE) 16.3 2162-137904550 53ND 50 106ug/Kg

Toluene 4.3 2159-139924650 48ND 50 96ug/Kg

Trichloroethene 5.8 2166-1421005050 53ND 50 106ug/Kg

Analyte Result Units NotesRDL

Blank

QC1176051MB1

Isopropylbenzene ND ug/Kg 5 m and p-Xylene ND ug/Kg 5

Methylene chloride ND ug/Kg 5

Methyl-t-butyl Ether (MTBE) ND ug/Kg 5

Naphthalene ND ug/Kg 5

N-butylbenzene ND ug/Kg 5

N-propylbenzene ND ug/Kg 5 o-Xylene ND ug/Kg 5

Sec-butylbenzene ND ug/Kg 5

Styrene ND ug/Kg 5 t-Butyl alcohol (TBA) ND ug/Kg 10

Tert-amylmethylether (TAME) ND ug/Kg 5

Tert-butylbenzene ND ug/Kg 5

Tetrachloroethene ND ug/Kg 5

Toluene ND ug/Kg 5 trans-1,2-dichloroethene ND ug/Kg 5 trans-1,3-dichloropropene ND ug/Kg 5 trans-1,4-dichloro-2-butene ND ug/Kg 5

Trichloroethene ND ug/Kg 5

Trichlorofluoromethane ND ug/Kg 5

Vinyl Chloride ND ug/Kg 5

Xylenes (Total) ND ug/Kg 5

Lab Control Spike/ Lab Control Spike Duplicate Summary

Analyte

Spike Amount

LCS LCSD Units LCS RPD %Rec RPD

Spike Result

LCSD LCSDLCS

Recoveries Limits

Notes

QC1176051LCS1

1,1-Dichloroethene 59-1721105550 ug/Kg

Benzene 62-137964850 ug/Kg

Chlorobenzene 60-133984950 ug/Kg

Methyl-t-butyl Ether (MTBE) 62-137984950 ug/Kg

Toluene 59-1391065350 ug/Kg

Trichloroethene 66-1421105550 ug/Kg

Lab Request 388258, Page 7 of 1566535-01 Enthalpy

QCBatchID: QC1176061

Analyst: nhernandez

Instrument: SVOA-GC (group)Analyzed: 03/07/2017

Method: EPA 8082

Matrix Spike/Matrix Spike Duplicate Summary

Analyte Amount

Spike Amount

MS MSD Units MS RPD %Rec RPD

Spike Result

MSD MSDMS

Recoveries LimitsSample

Notes

QC1176061MS1, QC1176061MSD1 Source: 388258-001

PCB-1016 5.4 70-1301085.45 5.7ND 5 mg/Kg

PCB-1260 1.7 2070-1301206.05 5.9ND 5 mg/Kg

Blank Summary

Analyte Result Units NotesRDL

Blank

QC1176061MB1

PCB-1016 ND ug/Kg 50

PCB-1221 ND ug/Kg 50

PCB-1232 ND ug/Kg 50

PCB-1242 ND ug/Kg 50

PCB-1248 ND ug/Kg 50

PCB-1254 ND ug/Kg 50

PCB-1260 ND ug/Kg 50

PCB-1262 ND ug/Kg 50

PCB-1268 ND ug/Kg 50

Lab Control Spike/ Lab Control Spike Duplicate Summary

Analyte

Spike Amount

LCS LCSD Units LCS RPD %Rec RPD

Spike Result

LCSD LCSDLCS

Recoveries Limits

Notes

QC1176061LCS1

PCB-1016 70-1301226.15 mg/Kg

PCB-1260 70-1301226.15 mg/Kg

Lab Request 388258, Page 8 of 1566535-01 Enthalpy

QCBatchID: QC1176075

Analyst: dswafford

Instrument: AAICP-HG1Analyzed: 03/07/2017

Method: EPA 7471A

Matrix Spike/Matrix Spike Duplicate Summary

Analyte Amount

Spike Amount

MS MSD Units MS RPD %Rec RPD

Spike Result

MSD MSDMS

Recoveries LimitsSample

Notes

QC1176075MS1, QC1176075MSD1 Source: 388307-001

Mercury 2.7 2075-125830.750.83 0.730.06 0.83 81mg/Kg

Blank Summary

Analyte Result Units NotesRDL

Blank

QC1176075MB1

Mercury ND mg/Kg 0.14

Lab Control Spike/ Lab Control Spike Duplicate Summary

Analyte

Spike Amount

LCS LCSD Units LCS RPD %Rec RPD

Spike Result

LCSD LCSDLCS

Recoveries Limits

Notes

QC1176075LCS1

Mercury 80-1201010.840.83 mg/Kg

Lab Request 388258, Page 9 of 1566535-01 Enthalpy

QCBatchID: QC1176076

Analyst: dswafford

Instrument: AAICP (group)Analyzed: 03/07/2017

Method: EPA 6010B

Matrix Spike/Matrix Spike Duplicate Summary

Analyte Amount

Spike Amount

MS MSD Units MS RPD %Rec RPD

Spike Result

MSD MSDMS

Recoveries LimitsSample

Notes

QC1176076MS1, QC1176076MSD1 Source: 388307-001

Antimony 3.3 2075-1255656.1100 58.0ND 100 58mg/Kg M

Arsenic 6.9 2075-1258992.8100 99.43.77 100 96mg/Kg

Barium 3.7 2075-125100132100 13732.1 100 105mg/Kg

Beryllium 5.3 2075-1259796.7100 102ND 100 102mg/Kg

Cadmium 8.7 2075-1259494.4100 103ND 100 103mg/Kg

Chromium 8.4 2075-12595103100 1127.69 100 104mg/Kg

Cobalt 8.1 2075-1259497.7100 1064.02 100 102mg/Kg

Copper 7.5 2075-12593102100 1108.98 100 101mg/Kg

Lead 0.0 2075-1250110100 110112 100 0mg/Kg M

Blank Summary

Analyte Result Units NotesRDL

Blank

QC1176076MB1

Antimony ND mg/Kg 3

Arsenic ND mg/Kg 1

Barium ND mg/Kg 1

Beryllium ND mg/Kg 0.5

Cadmium ND mg/Kg 0.5

Chromium ND mg/Kg 1

Cobalt ND mg/Kg 0.5

Copper ND mg/Kg 1

Lead ND mg/Kg 0.5

Molybdenum ND mg/Kg 1

Nickel ND mg/Kg 1.5

Selenium ND mg/Kg 1

Silver ND mg/Kg 0.5

Thallium ND mg/Kg 1

Vanadium ND mg/Kg 0.5

Zinc ND mg/Kg 5

Lab Control Spike/ Lab Control Spike Duplicate Summary

Analyte

Spike Amount

LCS LCSD Units LCS RPD %Rec RPD

Spike Result

LCSD LCSDLCS

Recoveries Limits

Notes

QC1176076LCS1

Antimony 80-120100100100 mg/Kg

Arsenic 80-1209392.6100 mg/Kg

Barium 80-120102102100 mg/Kg

Beryllium 80-12010099.6100 mg/Kg

Cadmium 80-120101101100 mg/Kg

Chromium 80-120100100100 mg/Kg

Cobalt 80-120101101100 mg/Kg

Copper 80-120104104100 mg/Kg

Lead 80-1209898.1100 mg/Kg

Molybdenum 80-1209998.5100 mg/Kg

Nickel 80-120104104100 mg/Kg

Selenium 80-1208685.6100 mg/Kg

Silver 80-1208988.8100 mg/Kg

Thallium 80-1209695.8100 mg/Kg

Vanadium 80-120101101100 mg/Kg

Zinc 80-120102102100 mg/Kg

Lab Request 388258, Page 10 of 1566535-01 Enthalpy

QCBatchID: QC1176076

Analyst: dswafford

Instrument: AAICP (group)Analyzed: 03/07/2017

Method: EPA 6010B

Analyte Amount

Spike Amount

MS MSD Units MS RPD %Rec RPD

Spike Result

MSD MSDMS

Recoveries LimitsSample

Notes

QC1176076MS1, QC1176076MSD1 Source: 388307-001

Molybdenum 4.5 2075-1259393.2100 97.50.28 100 97mg/Kg

Nickel 5.8 2075-12596101100 1074.59 100 102mg/Kg

Selenium 4.6 2075-1257877.9100 81.6ND 100 82mg/Kg

Silver 7.4 2075-1258282.0100 88.3ND 100 88mg/Kg

Thallium 3.0 2075-1258887.9100 90.6ND 100 91mg/Kg

Vanadium 8.3 2075-12598115100 12516.7 100 108mg/Kg

Zinc 6.1 2075-12589127100 13537.9 100 97mg/Kg

Lab Request 388258, Page 11 of 1566535-01 Enthalpy

QCBatchID: QC1176085

Analyst: nhernandez

Instrument: SVOA-MS (group)Analyzed: 03/07/2017

Method: EPA 8270C

Blank Summary

Analyte Result Units NotesRDL

Blank

QC1176085MB1

1,2,4-Trichlorobenzene ND ug/Kg 250

1,2-Dichlorobenzene ND ug/Kg 250

1,3-Dichlorobenzene ND ug/Kg 250

1,4-Dichlorobenzene ND ug/Kg 250

1-Methylnapthalene ND ug/Kg 250

2,4,5-Trichlorophenol ND ug/Kg 250

2,4,6-Trichlorophenol ND ug/Kg 250

2,4-Dichlorophenol ND ug/Kg 250

2,4-Dimethylphenol ND ug/Kg 250

2,4-Dinitrophenol ND ug/Kg 1200

2,4-Dinitrotoluene ND ug/Kg 250

2,6-Dinitrotoluene ND ug/Kg 250

2-Chloronaphthalene ND ug/Kg 250

2-Chlorophenol ND ug/Kg 250

2-Methyl-4,6-dinitrophenol ND ug/Kg 250

2-Methylnaphthalene ND ug/Kg 250

2-Methylphenol (o-Cresol) ND ug/Kg 250

2-Nitroaniline ND ug/Kg 250

2-Nitrophenol ND ug/Kg 250

3 and 4-Methylphenol (m and p-Cresol) ND ug/Kg 400

3,3'-Dichlorobenzidine ND ug/Kg 1200

3-Nitroaniline ND ug/Kg 250

4-Bromophenyl phenyl ether ND ug/Kg 250

4-Chloro-3-methylphenol ND ug/Kg 250

4-Chloroaniline ND ug/Kg 250

4-Chlorophenyl phenyl ether ND ug/Kg 250

4-Methylphenol (p-Cresol) ND ug/Kg 400

4-Nitroaniline ND ug/Kg 250

4-Nitrophenol ND ug/Kg 250

Acenaphthene ND ug/Kg 250

Acenaphthylene ND ug/Kg 250

Aniline ND ug/Kg 250

Anthracene ND ug/Kg 250

Azobenzene ND ug/Kg 250

Benz(a)anthracene ND ug/Kg 250

Benzidine ND ug/Kg 1200

Benzo(a)pyrene ND ug/Kg 250

Benzo(b)fluoranthene ND ug/Kg 250

Benzo(g,h,i)perylene ND ug/Kg 250

Benzo(k)fluoranthene ND ug/Kg 250

Benzoic acid ND ug/Kg 1200

Benzyl alcohol ND ug/Kg 250

Bis(2-chloroethoxy)methane ND ug/Kg 250

Bis(2-chloroethyl) Ether ND ug/Kg 1200

Bis(2-chloroisopropyl) Ether ND ug/Kg 250

Bis(2-ethylhexyl) phthalate ND ug/Kg 250

Butylbenzyl Phthalate ND ug/Kg 250

Carbazole ND ug/Kg 250

Chrysene ND ug/Kg 250

Dibenz(a,h)anthracene ND ug/Kg 250

Dibenzofuran ND ug/Kg 250

Lab Request 388258, Page 12 of 1566535-01 Enthalpy

Analyst: nhernandez

Instrument: SVOA-MS (group)Analyzed: 03/07/2017

Method: EPA 8270C

Matrix Spike/Matrix Spike Duplicate Summary

Analyte Amount

Spike Amount

MS MSD Units MS RPD %Rec RPD

Spike Result

MSD MSDMS

Recoveries LimitsSample

Notes

QC1176085MS1, QC1176085MSD1 Source: 388258-001

1,2,4-Trichlorobenzene 13.3 3545-1226024004000 2100ND 4000 53ug/Kg

1,4-Dichlorobenzene 14.6 3532-1215522004000 1900ND 4000 48ug/Kg

2,4,5-Trichlorophenol 12.9 3542-1328333004000 2900ND 4000 73ug/Kg

Analyte Result Units NotesRDL

Blank

QC1176085MB1

Diethyl phthalate ND ug/Kg 250

Dimethyl phthalate ND ug/Kg 250

Di-n-butyl phthalate ND ug/Kg 250

Di-n-octyl phthalate ND ug/Kg 250

Fluoranthene ND ug/Kg 250

Fluorene ND ug/Kg 250

Hexachlorobenzene ND ug/Kg 250

Hexachlorobutadiene ND ug/Kg 250

Hexachlorocyclopentadiene ND ug/Kg 1200

Hexachloroethane ND ug/Kg 250

Indeno(1,2,3-cd)pyrene ND ug/Kg 250

Isophorone ND ug/Kg 250

Naphthalene ND ug/Kg 250

Nitrobenzene ND ug/Kg 1200

N-Nitrosodimethylamine (NDMA) ND ug/Kg 250

N-Nitrosodi-n-propylamine (NDPA) ND ug/Kg 250

N-Nitrosodiphenylamine ND ug/Kg 250

Pentachlorophenol ND ug/Kg 1200

Phenanthrene ND ug/Kg 250

Phenol ND ug/Kg 250

Pyrene ND ug/Kg 250

Pyridine ND ug/Kg 250

Total Cresol ND ug/Kg 400

Lab Control Spike/ Lab Control Spike Duplicate Summary

Analyte

Spike Amount

LCS LCSD Units LCS RPD %Rec RPD

Spike Result

LCSD LCSDLCS

Recoveries Limits

Notes

QC1176085LCS1

1,2,4-Trichlorobenzene 45-1227028004000 ug/Kg

1,4-Dichlorobenzene 32-1216526004000 ug/Kg

2,4,5-Trichlorophenol 42-1328835004000 ug/Kg

2,4-Dimethylphenol 17-1088032004000 ug/Kg

2,4-Dinitrotoluene 33-1519337004000 ug/Kg

2-Chlorophenol 57-1167530004000 ug/Kg

3 and 4-Methylphenol (m and p-Cresol) 30-1438835004000 ug/Kg

4-Chloro-3-methylphenol 30-1419036004000 ug/Kg

4-Nitrophenol 21-1388835004000 ug/Kg

Acenaphthene 68-1348333004000 ug/Kg

Benzo(b)fluoranthene 65-16210542004000 ug/Kg

Chrysene 70-1509337004000 ug/Kg

N-Nitrosodi-n-propylamine (NDPA) 19-1637329004000 ug/Kg

Pentachlorophenol 25-11310040004000 ug/Kg

Phenol 27-1247028004000 ug/Kg

Pyrene 55-1399538004000 ug/Kg

Lab Request 388258, Page 13 of 1566535-01 Enthalpy

Analyst: nhernandez

Instrument: SVOA-MS (group)Analyzed: 03/07/2017

Method: EPA 8270C

Analyte Amount

Spike Amount

MS MSD Units MS RPD %Rec RPD

Spike Result

MSD MSDMS

Recoveries LimitsSample

Notes

QC1176085MS1, QC1176085MSD1 Source: 388258-001

2,4-Dimethylphenol 3.4 3517-1087530004000 2900ND 4000 73ug/Kg

2,4-Dinitrotoluene 12.8 3533-1516325004000 2200ND 4000 55ug/Kg

2-Chlorophenol 12.8 3557-1166325004000 2200ND 4000 55ug/Kg M

4-Chloro-3-methylphenol 9.5 3530-1418333004000 3000ND 4000 75ug/Kg

4-Nitrophenol 17.5 3521-1387831004000 2600ND 4000 65ug/Kg

Acenaphthene 10.2 3568-1347831004000 2800ND 4000 70ug/Kg

Benzo(b)fluoranthene 14.5 3565-1629337004000 3200ND 4000 80ug/Kg

Chrysene 12.1 3570-1508835004000 3100ND 4000 78ug/Kg

N-Nitrosodi-n-propylamine (NDPA) 18.2 3519-1636024004000 2000ND 4000 50ug/Kg

Pentachlorophenol 10.9 3525-1137329004000 2600ND 4000 65ug/Kg

Phenol 16.7 3527-1246526004000 2200ND 4000 55ug/Kg

Pyrene 11.8 3555-1399036004000 3200ND 4000 80ug/Kg

Lab Request 388258, Page 14 of 1566535-01 Enthalpy

Data Qualifiers and Definitions

Qualifiers A See Report Comments.

B Analyte was present in an associated method blank.

B1 Analyte was present in a sample and associated method blank greater than MDL but less than RDL.

BQ1 No valid test replicates. Sample Toxicity is possible. Best result was reported.

BQ2 No valid test replicates.

BQ3 No valid test replicates. Final DO is less than 1.0 mg/L. Result may be greater.

C Possible laboratory contamination.

D RPD was not within control limits. The sample data was reported without further clarification.

D1 Lesser amount of sample was used due to insufficient amount of sample supplied.

D2 Reporting limit is elevated due to sample matrix. Target analyte was not detected above the elevated reporting limit.

DW Sample result is calculated on a dry weigh basis.

E Concentration is estimated because it exceeds the quantification limits of the method.

I The sample was read outside of the method required incubation period.

J Reported value is estimated

L The laboratory control sample (LCS) or laboratory control sample duplicate (LCSD) was out of control limits.

Associated sample data was reported with qualifier.

M The matrix spike (MS) or matrix spike duplicate (MSD) was not within control limits due to matrix interference. The associated LCS and/or LCSD was within control limits and the sample data was reported without further clarification.

M1 The matrix spike (MS) or matrix spike duplicate (MSD) is not within control limits due to matrix interference.

M2 The matrix spike (MS) or matrix spike duplicate (MSD) was not within control limits. The associated LCS and/or LCSD was not within control limits. Sample result is estimated.

N1 Sample chromatography does not match the specified TPH standard pattern.

NC The analyte concentration in the sample exceeded the spike level by a factor of four or greater, spike recovery and limits do not apply.

P Sample was received without proper preservation according to EPA guidelines.

P1 Temperature of sample storage refrigerator was out of acceptance limits.

P2 The sample was preserved within 24 hours of collection in accordance with EPA 218.6.

Q1 Analyte Calibration Verification exceeds criteria. The result is estimated.

Q2 Analyte calibration was not verified and the result was estimated.

Q3 Analyte initial calibration was not available or exceeds criteria. The result was estimated.

S The surrogate recovery was out of control limits due to matrix interference. The associated method blank surrogate recovery was within control limits and the sample data was reported without further clarification.

S1 The associated surrogate recovery was out of control limits; result is estimated.

S2 The surrogate was diluted out due to the presence of high concentrations of target and/or non-target compounds.

Surrogate recoveries in the associated batch QC met recovery criteria.

S3 Internal Standard did not meet recovery limits. Analyte concentration is estimated.

T Sample was extracted/analyzed past the holding time.

T1 Reanalysis was reported past hold time due to failing replicates in the original analysis (BOD only).

T2 Sample was analyzed ASAP but received and analyzed past the 15 minute holding time.

T3 Sample received and analyzed out of hold time per client’s request.

T4 Sample was analyzed out of hold time per client’s request.

T5 Reanalysis was reported past hold time. The original analysis was within hold time, but not reportable.

T6 Hold time is indeterminable due to unspecified sampling time.

T7 Sample was analyzed past hold time due to insufficient time remaining at time of receipt.

Definitions DF Dilution Factor

MDL Method Detection Limit. Result is reported ND when it is less than or equal to MDL.

ND Analyte was not detected or was less than the detection limit.

NR Not Reported. See Report Comments.

RDL Reporting Detection Limit

TIC Tentatively Identified Compounds

Lab Request 388258, Page 15 of 1566535-01 Enthalpy