7._MSDS.pdf

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Safety Data Sheet

Product code BEN0020 Product name BENZALDEHYDE SYN DEA - PRAKASH

Issue date 01-Jan-2015 Revision date 07-Apr-2017 Version 2

1. Identification of the Substance/Preparation and of the Company/Undertaking

Product identifier Product name BENZALDEHYDE SYN DEA - PRAKASH

Other means of identification Product code BEN0020 UN/ID no 1990 Synonyms None Registration number(s) CAS: 100-52-7

Recommended use of the chemical and restrictions on use Recommended Use Industry Use.

Uses advised against No information available

Details of the supplier of the safety data sheet

Emergency telephone number Company Phone Number Use CHEMTREC instead of Emergency Phone Number 24 Hour Emergency Phone Number (800) 424-9300 Emergency telephone Contract# CCN17256

2. Hazards Identification

Classification

Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Serious eye damage/eye irritation Category 2A Specific target organ toxicity (single exposure) Category 3

Label Elements

EMERGENCY OVERVIEW

Supplier Address Phoenix Aromas and Essential Oils, LLC.

355 Chestnut Street Norwood, NJ 07648 Phone: (201) 784-6100 Fax: (201) 784-8566

Flammable liquids Category 4

Warning

Hazard statements Harmful if swallowed Harmful if inhaled Causes serious eye irritation May cause respiratory irritation Combustible liquid

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BEN0020 BENZALDEHYDE SYN DEA - PRAKASH Revision date 07-Apr-2017

Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from flames and hot surfaces. - No smoking Wear protective gloves/eye protection/face protection Keep cool Precautionary Statements - Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF INHALED: Remove person to fresh air and keep comfortable for breathing Call a POISON CENTER or doctor if you feel unwell IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell Rinse mouth In case of fire: Use CO2, dry chemical, or foam to extinguish Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store locked up

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Other Information

• Causes mild skin irritation

• Toxic to aquatic life 100 % of the mixture consists of ingredient(s) of unknown toxicity

3. Composition/information on Ingredients

Chemical Family Aromatic aldehyde.

Formula C7H6O

Botanical Species CAS No. Weight-% Benzaldehyde 100-52-7 100

4. First Aid Measures

Description of first aid measures

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists:

Get medical advice/attention.

Skin contact Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water. Wash contaminated clothing before reuse. Consult a physician if necessary.

Appearance Clear Physical state Liquid

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Odor Characteristic Odor

Inhalation Move to fresh air in case of accidental inhalation of vapors. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.

Ingestion Do not induce vomiting without medical advice. Clean mouth with water. Never give anything by mouth to an unconscious person. Get medical attention.

Most important symptoms and effects, both acute and delayed

Symptoms No information available.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. Fire-Fighting Measures

Suitable Extinguishing Media Use CO2, dry chemical, or foam.

Unsuitable extinguishing media .

Specific hazards arising from the chemical No information available.

Hazardous combustion productsIrritating or toxic substances may be emitted upon burning, combustion, or decomposition.

Explosion data Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

Special protective actions for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and inhalation of vapors. Wear protective gloves/protective clothing and eye/face protection.

Wash thoroughly after handling.

Environmental precautions

Environmental precautions See Section 12 for additional Ecological Information.

Methods and material for containment and cleaning up

Methods for Containment Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13).

Methods for cleaning up Cover liquid spill with sand, earth or other non-combustible absorbent material. Sweep up and shovel into suitable containers for disposal.

7. Handling and Storage

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Avoid breathing vapors or mists. Ensure adequate ventilation, especially in confined areas. Wash thoroughly after handling. When using do not eat, drink

Page 3 / 7 or smoke.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from sunlight.

Keep locked up and out of reach of children.

Incompatible materials None known based on information supplied.

8. Exposure Controls/Personal Protection

Control parameters

Exposure guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.

Appropriate engineering controls

Engineering controls Showers Eyewash stations Ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles).

Skin and Body Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Ensure adequate ventilation, especially in confined areas.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. When using do not eat, drink or smoke. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. Avoid breathing (dust, vapor, mist, gas).

9. Physical and Chemical Properties

Information on basic physical and chemical properties

Physical state Liquid Appearance Clear Odor Characteristic Odor Color Colorless to Pale Yellow Odor threshold Not applicable

Property Values Remarks • Method pH Not applicable Melting point / freezing point -19.5 °C Boiling point / boiling range 230 °C Flash Point 62 °C / 144 °F Evaporation Rate Not applicable Flammability (solid, gas) Not applicable Flammability Limit in Air

Upper flammability limit: Not applicable Lower flammability limit: Not applicable

Vapor pressure 0.06 Vapor Density Not applicable Specific gravity 1.041

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Explosive properties Not applicable Oxidizing properties Not applicable

Other Information

Softening point not applicable Molecular weight 106.12 VOC content (%) Not applicable Density Not applicable Bulk Density Not applicable

10. Stability and Reactivity

Reactivity

Chemical stability Stable under recommended storage conditions.

Possibility of Hazardous Reactions None under normal processing.

Conditions to avoid Extremes of temperature and direct sunlight.

Incompatible materials None known based on information supplied.

Hazardous Decomposition Products None known based on information supplied.

11. Toxicological Information

Information on likely routes of exposure

Product Information

Inhalation Avoid breathing vapors or mists. Harmful by inhalation.

Eye Contact Avoid contact with eyes. Severely irritating to eyes.

Skin contact Avoid contact with skin. Causes mild skin irritation.

Ingestion Harmful if swallowed.

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes mild skin irritation.

Serious eye damage/eye irritation Causes severe eye irritation.

Water solubility Not applicable Solubility in other solvents Not applicable Partition coefficient Not applicable Autoignition Temperature Not applicable Decomposition temperature Not applicable Kinematic viscosity No data available Dynamic viscosity Not applicable

No data available

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Sensitization Not expected to cause skin sensitization.

Germ cell mutagenicity Not classified.

Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.

Reproductive toxicity No information available.

STOT - single exposure Not classified.

STOT - repeated exposure Not classified.

Aspiration hazard Not classified.

Numerical measures of toxicity - Product Information

Unknown acute toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document .

ATEmix (oral) 1430 mg/kg ATEmix (inhalation-dust/mist) 1.5 mg/l

12. Ecological Information

Ecotoxicity

Harmful to aquatic life

0 % of the mixture consists of components(s) of unknown hazards to the aquatic environment

Persistence and degradability No information available.

Bioaccumulation No information available.

Other adverse effects No information available

13. Disposal Considerations

Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated packaging Do not reuse container.

14. Transport Information

DOT

UN/ID no 1990 Proper Shipping Name Benzaldehyde Hazard Class 9 Packing group III

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15. Regulatory Information

US Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden release of pressure hazard No Reactive Hazard No

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42)

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

US State Regulations

U.S. State Right-to-Know Regulations

This product contains substances regulated by state right-to-know regulations

U.S. EPA Label information EPA Pesticide registration number Not applicable

16. Other Information

Issue date 01-Jan-2015 Revision date 07-Apr-2017 Revision note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Classification and labeling according to the IFRA/IOFI Labeling Manual 2016.

End of Safety Data Sheet

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