146-269-msds_hyd_food_grade_oil_0003.pdf

GHS product identifier

Other means of identification

Product type

Section 1. Identification

Relevant identified uses of the substance or mixture and uses advised against

Identified uses Food grade hydraulic and compressor oil.:

Conforms to HCS 2012 - United States and Canada WHMIS 2015

Emergency telephone number (with hours of operation)

SAFETY DATA SHEET

269 Hydraulic Oil H1 ISO 22, 32, 46, 68, 100, 150 and 220

269 Hydraulic Oil H1 ISO 22, 32, 46, 68, 100, 150 and 220 Not available.

Liquid.

Schaeffer Mfg. Company 102 Barton Street Saint Louis, Missouri 63104 Tel: 314-865-4100 Fax: 314-865-4107 Toll Free: 1-800-325-9962 E-Mail: safety@schaefferoil.com Web: http://www.schaefferoil.com

+1 314 865-4105 (24-hour response number)

:Supplier's details

Section 2. Hazards identification

AQUATIC HAZARD (LONG-TERM) - Category 3Classification of the substance or mixture

Signal word : No signal word.

Hazard statements : H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements

Prevention : P273 - Avoid release to the environment.

Response : Not applicable.

Storage : Not applicable.

Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

GHS label elements

Hazards not otherwise classified

: None known.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

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269 Hydraulic Oil H1 ISO 22, 32, 46, 68, 100, 150 and 220

Section 3. Composition/information on ingredients

Other means of identification

: Not available.

Substance/mixture : Mixture

Ingredient name

Dec-1-ene, homopolymer, hydrogenated Dec-1-ene, oligomers, hydrogenated 80 - 100 68037-01-4 2,6-Di-tert-Butyl-p-cresol 0.1 - 1 128-37-0

CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

United States: The exact percentage (concentration) in the composition has been withheld as a trade secret in accordance with paragraph (i) of §1910.1200.

Canada: The exact percentage (concentration) in the composition has been withheld as a trade secret in accordance with the amended HPR as of April 2018.

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person.

If unconscious, place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water. Get medical attention if symptoms occur.

Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No known significant effects or critical hazards.

No known significant effects or critical hazards.

No known significant effects or critical hazards.

Eye contact : No known significant effects or critical hazards.

Potential acute health effects

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Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

No specific data.

This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

None known.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.

Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Small spill Stop leak if without risk. Move containers from spill area. Absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

U.S.A. regulations may require reporting spills of this material that could reach any surface waters. Report spills to all applicable Federal, State, Provincial and local authorities and/or the United States National Response Center at (800) 424-8802 as appropriate or required.

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Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas.

Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Contaminated absorbent material may pose the same hazard as the spilled product.

Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill :

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

Dec-1-ene, homopolymer, hydrogenated Dec-1-ene, oligomers, hydrogenated

None.

2,6-Di-tert-Butyl-p-cresol NIOSH REL (United States, 10/2016).

TWA: 10 mg/m³ 10 hours.

ACGIH TLV (United States, 3/2018).

TWA: 2 mg/m³ 8 hours. Form: Inhalable fraction and vapor

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits

Canada

Occupational exposure limits

Ingredient name

2,6-Di-tert-Butyl-p-cresol CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 4 mg/m³ 15 minutes. Form: Inhalable fraction and vapor TWA: 2 mg/m³ 8 hours. Form: Inhalable fraction and vapor CA Ontario Provincial (Canada, 1/2018).

TWA: 2 mg/m³ 8 hours. Form: Inhalable fraction and vapor.

CA British Columbia Provincial (Canada, 7/2018).

TWA: 2 mg/m³ 8 hours. Form: Inhalable vapor and aerosol CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 10 mg/m³ 8 hours.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 10 mg/m³ 8 hours.

Exposure limits

United States

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Section 8. Exposure controls/personal protection

Hand protection

Eye/face protection

Respiratory protection :

Body protection :

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Appropriate engineering controls

: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection :

Wear eye protection such as safety glasses, chemical goggles, or face shields if engineering controls or work practices are not adequate to prevent eye contact.

Use nitrile or oil resistant gloves.

Personal protective clothing such as gloves, aprons, boots and complete facial protection should be selected based on the task being performed and the risks involved.

Users should determine acceptable performance characteristics of protective clothing.

Consider physical requirements and other substances present when selecting protective clothing.

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved.

If a risk assessment indicates that respiratory protection is required, use a properly fitted, air-purifying or supplied air respirator that complies with an approved standard.

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid. [Clear.]

Not available.

0.83 to 0.86

>10 [Air = 1]

Not available.

Insoluble in water.

Mild.Odor pH

Colorless.Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Open cup: 235 to 277°C (455 to 530.6°F)

Not available.

Not available.

Not available.Odor threshold

Partition coefficient: n-octanol/water

Appearance

>300°C (>572°F)

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Boiling point/boiling range :

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Section 9. Physical and chemical properties Viscosity Kinematic (100oC (212oF)): 4.6 to 31.5 cSt

Kinematic (40°C (104°F)): 22.2 to 242 cSt

Flow time (ISO 2431) : Not available.

VOC content : Not available.

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Reactive or incompatible with the following materials: Strong acids, bases and oxidizers.

Incompatible materials :

Possibility of hazardous reactions

: May react with oxygen and strong oxidizing agents, such as chlorates, nitrates, peroxides, etc.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Specific target organ toxicity (single exposure)

Information on toxicological effects

Acute toxicity

Product/ingredient name Result Species Dose Exposure

Irritation/Corrosion

Product/ingredient name Result Score Exposure Observation

Sensitization

Species

2,6-Di-tert-Butyl-p-cresol LD50 Oral Rat 890 mg/kg -

2,6-Di-tert-Butyl-p-cresol Eyes - Moderate irritant Rabbit - 24 hours 100 mg - Skin - Moderate irritant Rabbit - 48 hours 500 mg -

There is no data available.

Mutagenicity

Carcinogenicity

Teratogenicity

Reproductive toxicity

Classification

Product/ingredient name NTPIARCOSHA

There is no data available.

2,6-Di-tert-Butyl-p-cresol - 3 -

There is no data available.

There is no data available.

Specific target organ toxicity (repeated exposure)

There is no data available.

There is no data available.

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Section 11. Toxicological information

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: Dermal contact. Eye contact. Inhalation. Ingestion.

: No known significant effects or critical hazards.

: No known significant effects or critical hazards.

: No known significant effects or critical hazards.

: No known significant effects or critical hazards.

Eye contact

Inhalation

Skin contact

Ingestion

General

Carcinogenicity

Mutagenicity

Teratogenicity

Developmental effects

Fertility effects

: No known significant effects or critical hazards.

: No known significant effects or critical hazards.

: No known significant effects or critical hazards.

: No known significant effects or critical hazards.

: No known significant effects or critical hazards.

: No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact

Inhalation

Skin contact

Ingestion

No known significant effects or critical hazards.

No known significant effects or critical hazards.

No known significant effects or critical hazards.

: No known significant effects or critical hazards.

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Acute toxicity estimates

There is no data available.

Information on the likely routes of exposure

Potential acute health effects

Potential immediate effects

: No known significant effects or critical hazards.

Short term exposure

: No known significant effects or critical hazards.

Potential immediate effects

: No known significant effects or critical hazards.

Potential delayed effects

Long term exposure

Potential delayed effects : No known significant effects or critical hazards.

There is no data available.

Section 12. Ecological information Toxicity

2,6-Di-tert-Butyl-p-cresol Acute EC50 1440 µg/L Fresh water Daphnia - Daphnia pulex - Neonate 48 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

There is no data available.

Aspiration hazard

Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

Dec-1-ene, homopolymer, hydrogenated Dec-1-ene, oligomers, hydrogenated

>6.5 - high

2,6-Di-tert-Butyl-p-cresol 5.1 330 to 1800 high

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Section 14. Transport information

Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

AERG : Not applicable

Not regulated.

Not regulated. Not regulated.

DOT Classification IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Environmental hazards

No. No. No.

No.

Not regulated.

TDG Classification

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Section 15. Regulatory information U.S. Federal regulations

None of the components are listed.

WARNING: This product can expose you to Ethyl acrylate, which is known to the State of California to cause cancer.

For more information go to www.P65Warnings.ca.gov.

Massachusetts

SARA 313

California Prop. 65

Clean Air Act Section 112

(b) Hazardous Air Pollutants (HAPs)

: Listed

Clean Air Act Section 602 Class I Substances

: Not listed

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

DEA List II Chemicals (Essential Chemicals)

: Not listed

New York : None of the components are listed.

New Jersey : None of the components are listed.

Pennsylvania : None of the components are listed.

State regulations

SARA 302/304

SARA 304 RQ : Not applicable.

SARA 311/312

Classification Not applicable.

United States inventory (TSCA 8b): All components are listed or exempted.

No products were found.

There is no data available.

Canadian lists

None of the components are listed.Canadian NPRI :

CEPA Toxic substances : None of the components are listed.

Canada inventory (DSL

NDSL)

: All components are listed or exempted.

Section 16. Other information

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

/0 Flammability : 1 Physical hazards : 0

010 Instability :Flammability :

Health :

Health :

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Section 16. Other information

History

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

Procedure used to derive the classification

Classification Justification

AQUATIC HAZARD (LONG-TERM) - Category 3 Calculation method

Date of issue mm/dd/yyyy

Date of previous issue

Version :

12/15/2019

06/15/2015

Prepared by : KMK Regulatory Services Inc.

US Tariff Heading Number : 3403.19.0000

3403.19.0000:Schedule B Code

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

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