1-2022-01-04_SDS_US_-_C-23.pdf

SAFETY DATA SHEET

1. Identification Product identifier C-23®

Other means of identification

Product code 1955

Recommended use Asphalt Restorative Seal/Recycling Emulsion/Asphalt Cold Pour Crack Filler

Recommended restrictions None known

Manufacturer/Importer/Supplier/Distributor information

Manufacturer

Manufacturer: D & D Emulsions, Inc.

Address: 270 Park Avenue East

P.O. Box 1706

Mansfield, OH 44901

24- Hour Telephone Number:

CHEMTREC: 1-800-424-9300 (USA and Canada)

CCN794154

2. Hazard(s) identification Physical hazards Not classified

Health hazards Not classified

Environmental hazards Not classified

OSHA defined hazards Not classified

Label elements

Hazard symbol None

Signal word Not applicable

Hazard statement Not applicable

Precautionary statement

Prevention Not applicable

Response Not applicable

Storage Not applicable

Disposal Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at the time of disposal.

Other hazards None known

Supplemental information Not applicable

3. Composition/information on ingredients Mixtures

Chemical name Common name and synonyms CAS number %

ASPHALT 8052-42-4 <40

DISTILLATES (PETROLEUM), 64742-52-5 <35

HYDROTREATED HEAVY

NAPHTHENIC

4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact Rinse with water. Get medical attention if irritation develops and persists.

Ingestion Rinse mouth. Do not induce vomiting without the advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.

Most important Direct contact with eyes may cause temporary irritation.

symptoms/effects, acute and delayed

Indication of immediate Treat symptomatically medical attention and special treatment needed

General information Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.

Material name: C-23® SDS US

1955 Version #: 01 Issue date: 08-23-2021 1 / 7

Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Dry chemicals. Carbon dioxide (CO2).

Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from During fire, gases hazardous to health may be formed.

the chemical

Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

and precautions for firefighters

Fire-fighting Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray equipment / instructions and remove container if no risk is involved.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low protective equipment and areas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For emergency procedures personal protection, see section 8 of the SDS.

Methods and materials for Extinguish all flames in the vicinity.

Containment and cleanup Large Spills: Stop the flow of material if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand, or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements, or confined areas.

Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use.

Environmental precautions Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do

so. Do not contaminate water. Avoid discharge into drains, water sources or onto the ground.

7. Handling and storage

Precautions for safe handling Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use only in well- ventilated areas.

Conditions for safe storage, Keep out of reach of children. Store in original tightly closed container.

including any incompatibilities

8. Exposure controls/personal protection Occupational exposure limits

US. ACGIH Threshold Limit Values

Components Type Value Form

ASPHALT (CAS 8052-42-4) TWA 0.5 mg/m 3 Inhalable fraction.

DISTILLATES PEL 5mg/m3

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

Canada, Alberta OELs (Occupational Health & Safety Code, Schedule 1 Table 2)

Components Type Value Form

ASPHALT (CAS 8052-42-4) TWA 5mg/m3 Fume

DISTILLATES STEL 10mg/m3 Mist.

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

TWA 5mg/m3 Mist

1955 Version #: 01 Issue date: 08-23-2021 2 / 7

Canada. British Columbia OELs. (Occupational Exposure Limits of Chemical Substances, Occupational Health and Safety

Regulations 296/97, as amended.

Components Type Value Form

ASPHALT (CAS 8052-42-4) TWA 0.5mg/m3 Aerosol, inhalable.

DISTILLATES TWA 1mg/m3 Mist.

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS 64742-52-5)

Canada. Manitoba OELs. (Reg. 217/2006, The Workplace Safety and Health Act)

ASPHALT (CAS 8052-42-4) TWA 0.5mg/m3 Inhalable Fume

DISTILLATES TWA 1mg/m3 Inhalable fraction

(PETROLEUM),

Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)

ASPHALT (CAS 8052-42-4) TWA 0.5mg/m3 Inhalable fraction

DISTILLATES TWA 1mg/m3 Inhalable fraction

(PETROLEUM),

Canada. Quebec OELs. (Ministry of Labor – Regulation respecting occupational health and safety)

ASPHALT (CAS 8052-42-4) TWA 5mg/m3 Fume.

DISTILLATES STEL 10mg/m3 Mist.

(PETROLEUM),

HYDROTREATED HEAVY

TWA 5mg/m3 Mist.

Canada. Saskatchewan OELs (Occupational Health and Safety Regulations, 1996, Table 21)

ASPHALT (CAS 8052-42-4) 15 minute 1.5mg/m3 Inhalable fraction

8 hour 0.5mg/m3 Inhalable fraction

DISTILLATES 15 minute 10mg/m3

(PETROLEUM),

HYDROTREATED HEAVY

8 hour 5mg/m3

Biological limit values No biological exposure limits noted for the ingredient(s).

Appropriate engineering Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure controls limit is not exceeded.

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Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Skin protection

Hand protection Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style glove

Other Wear appropriate chemical resistant clothing.

Respiratory protection When workers are facing concentrations above the exposure limit, they must use appropriate certified respirators.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene Keep away from food or drink. Always observe good personal hygiene measures, such as washing after handling the material and considerations before eating, drinking, and or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance Brown Liquid

Physical state Liquid

Form Not available

Color Brown

Odor Mild Petroleum Odor

Odor threshold Not available pH Not available

Melting point/freezing point Not available

Initial boiling point and 212 °F (100°C) boiling range

Flash point >=449.6°F (>=232.0° C)

Evaporation rate Not available

Flammability (solid, gas) Not available

Upper/lower flammability or explosive limits

Flammability limit – lower Not available

Flammability limit - Not available upper (%)

Explosive limit – lower Not available

Explosive limit – upper Not available

Vapor pressure Not available

Vapor density Not available

Relative density Not available

Solubility (ies)

Solubility (water) Readily Dispersible

Partition coefficient Not available

(n-octanol/water)

Auto-ignition temperature Not available

Decomposition temperature Not available

Viscosity Not available

Other information

Specific gravity 0.92 – 1.04

10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage, and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid Heat, flames, and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials Strong oxidizing agents.

Hazardous decomposition No hazardous decomposition products are known.

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11. Toxicological information Information on likely routes of exposure

Inhalation Prolonged inhalation may be harmful.

Skin contact Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.

Eye contact Direct contact with eyes may cause temporary irritation.

Ingestion Expected to be a low ingestion hazard.

Symptoms related to the physical, Direct contact with eyes may cause temporary irritation.

chemical and toxicological characteristics

Information on toxicological effects

Acute toxicity Not available

Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye irritation Not classified

Respiratory or skin sensitization

Respiratory sensitization Not available

Skin sensitization Not classified

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity Contains a substance/a group of substances which may cause cancer.

ACGIH Carcinogens

DISTILLATES (PETROLEUM), HYDROTREATED HEAVY A4 Not classifiable as a human carcinogen

Naphthenic (CAS 64742-52-5)

Canada – Manitoba OELs: Carcinogenicity

DISTILLATES (PETROLEUM), HYDROTREATED HEAVY Not classifiable as a human carcinogen.

NAPHTHENIC (CAS 64742-52-5)

IARC Monographs. Overall Evaluation of Carcinogenicity

DISTILLATES (PETROLEUM), HYDROTREATED HEAVY 3 Not classifiable as to carcinogenicity to humans.

NAPHTHENIC (CAS 64742-52-5)

Reproductive toxicity This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity Not classified

- single exposure

Specific target organ toxicity Not classified

- repeated exposure

Aspiration hazard Not available

Chronic effects Prolonged inhalation may be harmful.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available

Mobility in soil No data available

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Contract with a disposal operator licensed by the Law on Disposal and cleaning. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not discharge into drains, water sources or onto the ground. Dispose of in accordance with all applicable regulations.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

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Waste from residues/unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions)

Avoid discharge into water sources or onto the ground.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.

Since emptied containers may retain product residue, follow label warnings even after container is emptied.

14. Transport information

TDG

Not regulated as dangerous goods.

IATA

Not regulated as dangerous goods.

IMDG

Not regulated as dangerous goods.

Transport in bulk according to Not available

Annex II of MARPOL 73/78 and the IBC Code

15. Regulatory information

Canadian regulations This product is classified in accordance with WHMIS 2015 Regulations.

Controlled Drug and Substances Act

Not regulated.

Export Control List (CEPA 1999, Schedule 3)

Not listed.

Greenhouse Gases

Not listed.

Precursor Control Regulations

Not regulated.

International regulations

Stockholm Convention

Not applicable.

Rotterdam Convention

Not applicable.

Kyoto Protocol

Not applicable.

Montreal Protocol

Not applicable.

Basel Convention

Not applicable.

International Inventories

Country (s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS) Yes

Canada Domestic Substances List (DSL) Yes

Canada Non-Domestic Substances List (NDSL) No

China Inventory of Existing Chemical Substances in China (IECSC) Yes

Europe European Inventory of Existing Commercial Chemical Substances Yes

(EINECS)

Europe European List of Notified Chemical Substances (ELINCS) No

Japan Inventory of Existing and New Chemical Substances (ENCS) No

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Korea Existing Chemicals List (ECL) Yes

New Zealand New Zealand Inventory Yes

Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes

*A “Yes” indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

A “No” indicates that one or more components of the product are not listed or exempt from this listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision Issue date 08-23-2021

Version # 01

References ACGIH

EPA: AQUIRE database

NLM: Hazardous Substance Data Base

US. IARC Monographs on Occupational Exposures to Chemical Agents

IARC Monographs: Overall Evaluation of Carcinogenicity

National Toxicology Program (NTP) Report of Carcinogens

ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Revision Information This document has undergone significant changes and should be reviewed in its entirety.

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