In this 5-year research program, the principal goals of the TC-COE and the proposed synthetic, physical, and spectroscopic studies are: (1) to define the structure, bonding, and reactivity of…

Active Cooperative Agreement Awarded Last action

Award ID
DENA0004151
Recipient
Awarding agency
Obligated
$9,301,090

Award facts

Assistance listing
81.112 Stewardship Science Grant Program
Completion date 63% complete
Place of performance
Atlanta, GA, USA

Award details come from USAspending.gov.

Description

In this 5-year research program, the principal goals of the TC-COE and the proposed synthetic, physical, and spectroscopic studies are: (1) to define the structure, bonding, and reactivity of plutonium hydride complexes, and (2) to disentangle the effects of media, autoradiolytic processes, and coordination chemistry in controlling the kinetics and thermochemistry of americium redox reactions supported by the development of novel detector and spectroscopic instrumentation. These goals seek to define the fundamental criteria necessary to address long-standing challenges in understanding and predicting the behavior of puhx and in preparing pure americium from a variety of feedstocks. These two research goals are highly synergistic (FIG. 1): the requisite infrastructure as well as methodologies are related and can only be addressed by the proposed, tightly-knit multidisciplinary team.

Transactions

Action Obligated Date
Amendment $2,282,277
Amendment $2,206,025
Amendment $0
Amendment $2,195,933
Amendment $0
Original award $2,616,855

Subawards

Subrecipient Amount Awarded
Purdue University As newcomers into the center, who will be joining in years 4 and 5, we are proposing chemistry that fits well with the above previously existing project… $171,282
University Of California, Santa Barbara We will prepare a library of complexes containing discrete An-H bonds to serve as models for comparative spectroscopic, structural, and computational… $1,093,266
Washington State University A fundamental principle of the electronic structure of d-block and f- block coordination compounds is the observation that a half filled or fully filled valence… $1,601,195
The University Of Akron Prof. Popov will employ quantum-mechanical calculations to support/interpret experimental results to map out a complete picture (i) of plutonium hydride bonding… $159,156
The University Of Iowa We will prepare a library of borohydride complexes containing discrete An-H bonds (An = actinide) to serve as molecular PuH3 models for comparative… $1,508,069

Quick answers

Who received award DENA0004151?

DENA0004151 was awarded to Georgia TECH Research Corp by National Nuclear Security Administration (Department of Energy) on September 22, 2023.

How much is award DENA0004151 worth?

$9,301,090 has been obligated on DENA0004151.

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