SDS_INTEGRA-SEAL_Asphalt_Sealer.pdf

INTEGRA-SEAL® Asphalt Sealer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Form 205.133 (05-2017) Page 1

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture Trade name : INTEGRA-SEAL® ASPHALT SEALER, INTEGRA-SEAL® ASPHALT SEALER PLUS

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

UNIQUE Paving Materials Corp.

3993 East 93rd Street Cleveland, 44105 - United States of America T (216) 441-4880 http://www.uniquepavingmaterials.com/

1.4. Emergency telephone number

Emergency number : (800) 424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (GHS-US)

Skin Irrit. 2 H315 Eye Irrit. 2A H319 Skin Sens. 1 H317 Carc. 1A H350

Full text of H-phrases: see section 16

2.2. Label elements

GHS-US labeling

Hazard pictograms (GHS-US) :

GHS07

GHS08

Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H315 - Causes skin irritation

H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H350 - May cause cancer

Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P261 - Avoid breathing fumes mist or vapours.

P264 - Wash hands thoroughly after handling P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear gloves, goggles and protective clothing.

P302+P352 - If on skin: Wash with plenty of water for at least 15 minutes P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention P321 - Specific treatment (see first aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P362+P364 - Take off contaminated clothing and wash it before reuse P405 - Store locked up http://www.uniquepavingmaterials.com/

Form 205.133 (05-2017) Page 2

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

P501 - Dispose of contents/container to meet all regulations.

2.3. Other hazards

Other hazards not contributing to the classification

: This product does not contain any constituents that, based on information currently available, are considered a reproductive toxin.

2.4. Unknown acute toxicity (GHS-US)

21.5 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Oral)

21.5 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal) 13 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Dust/Mist))

SECTION 3: Composition/information on ingredients

3.1. Substance

Not applicable

3.2. Mixture

Name Product identifier % Classification (GHS-US)

Petroleum Asphalt Base (CAS No) 8052-42-4 24.875 - 39.96

Carc. 1B, H350

Filler Clay (CAS No) Trade Secret 2 - 25 Skin Irrit. 2, H315 Eye Irrit. 2A, H319

Coloring Agent (CAS No) Trade Secret 0 - 3 Carc. 2, H351

Trade Secret* 0 - 2 Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317

Trade Secret* 0 - 1.5 Carc. 1B, H350

Trade Secret* 0 - 1 Carc. 1A, H350

Trade Secret A* 0 - 1 Carc. 2, H351

*Chemical name, CAS number and/or exact concentration have been withheld as a trade secret

Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Artificial respiration and/or oxygen if necessary. Get medical advice/attention if you feel unwell. Allow victim to breathe fresh air. Allow the victim to rest.

First-aid measures after skin contact : Take off immediately all contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. Never use solvents or thinner to remove product from the skin. Wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention. Specific treatment (see first aid measures on this label). If skin irritation or rash occurs:

First-aid measures after eye contact : Rinse cautiously with water for several minutes. Immediately rinse with water for a prolonged period while holding the eyelids wide open. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

First-aid measures after ingestion : Immediately call a poison center or doctor/physician. Keep victim warm and rested. Keep respiratory tract clear. Never give anything by mouth to unconscious person. If symptoms persist, call a physician and take victim immediately to hospital. . Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

Form 205.133 (05-2017) Page 3

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after skin contact : severe skin irritation, redness, dermatitis. Causes skin irritation.

Symptoms/injuries after eye contact : Causes eye irritation. Causes serious eye irritation.

Symptoms/injuries after ingestion : Vomiting. Swallowing a small quantity of this material will result in serious health hazard.

4.3. Indication of any immediate medical attention and special treatment needed

No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Fire hazard : This material may burn after prolonged heating at elevated temperatures.

Explosion hazard : Be cautious of potentially volatile vapors that may evolve from the material at elevated temperatures. Under the proper conditions these vapours can travel to an ignition source and ignite. At elevated temperatures this material can potentially evolve flammable vapours which, especially when contained in a confined space, can create a potential explosion hazard.

Reactivity : Stable under normal conditions.

5.3. Advice for firefighters

Firefighting instructions : Be cautious of potentially volatile vapors that may evolve from the material at elevated temperatures. Under the proper conditions these vapours can travel to an ignition source and ignite. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

Special protective equipment for fire fighters

: Wear self-contained breathing apparatus and protective suit (see item 8).

Specific methods : At elevated temperatures this material can potentially evolve flammable vapours which, especially when contained in a confined space, can create a potential explosion hazard.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Should the product undergo thermal decomposition, general products of combustion could result. Hydrogen sulfide, sulfur compounds, oxides of carbon (i.e. carbon monoxide, carbon dioxide) and other poisonous gases would likely be included in the products of combustion.

6.1.1. For non-emergency personnel

Protective equipment : Wear personal protective equipment.

Emergency procedures : Avoid contact with skin, eyes and clothing. Ventilate spillage area. Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. Equip clean-up crew with proper protection.

Emergency procedures : Stop leak if safe to do so. Ventilate area.

Form 205.133 (05-2017) Page 4

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

6.2. Environmental precautions

Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.

Methods for cleaning up : Dike for recovery or absorb with appropriate material. Pump or shovel any salvageable material into clean containers for reuse. Absorb any remaining liquid with sand, vermiculite or other absorbent material and shovel the mixture into containers for disposal. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid contact with skin, eyes and clothing. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing vapours. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.

Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures : Comply with applicable regulations.

Storage conditions : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Store in a well-ventilated place. Store away from freezing (avoid freezing during storage). Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.

Incompatible products : Oxidizing agent. Strong bases. Strong acids.

Incompatible materials : Sources of ignition. Direct sunlight.

Maximum storage period : 12 months in unopened containers Heat-ignition : Keep away from heat, sparks and flame.

Storage area : Store away from heat. Store in a well-ventilated place.

Special rules on packaging : Store in a closed container.

Packaging materials : Store in a well-ventilated place. Keep container tightly closed.

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

INTEGRA-SEAL ASPHALT SEALER

ACGIH Not applicable

OSHA Not applicable

Petroleum Asphalt Base (8052-42-4)

ACGIH ACGIH TWA (mg/m³) 5

OSHA OSHA PEL (Ceiling) (ppm) 5 ppm as fumes

Form 205.133 (05-2017) Page 5

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

Filler Clay (Trade Secret)

OSHA Remark (OSHA) 15 mg/m3 total dust, 5mg/m3 Respirable Dust

Trade Secret

ACGIH ACGIH TWA (mg/m³) 0.025 respirable fraction

OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³ respirable dust

OSHA Remark (OSHA) (3) See Table Z-3.

Trade Secret A

ACGIH ACGIH TWA (mg/m³) 1 mg/m³

ACGIH Remark (ACGIH) LRT irr; A3

OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³

Coloring Agent (Trade Secret)

ACGIH ACGIH TWA (mg/m³) 3.5 mg/m³

8.2. Exposure controls

Personal protective equipment : apron. Boots. Gloves. Splash goggles. Avoid all unnecessary exposure.

Materials for protective clothing : Boots. Lab coat.

Hand protection : protective gloves. Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.

Skin and body protection : Chemical resistant apron. Lab coat. Boots. Wear suitable protective clothing.

Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate mask.

Environmental exposure controls : Avoid release to the environment.

Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Appearance : Dark, Viscous Liquid.

Color : Dark

Odor : No data available

Odor threshold : No data available pH : 9 - 10.5

Relative evaporation rate (butyl acetate=1) : slower than Ether

Form 205.133 (05-2017) Page 6

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

Melting point : No data available

Freezing point : No data available

Boiling point : 212 °F

Flash point : > 600 °F

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : No data available

Relative vapor density at 20 °C : ≤ 1

Relative density : No data available

Specific gravity / density : 1.07 Solubility : insoluble in water

Log Pow : No data available

Log Kow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available.

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity

Stable under normal conditions.

10.2. Chemical stability

Not established.

10.3. Possibility of hazardous reactions

Not established.

10.4. Conditions to avoid

Freezing. Sparks. Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials

Oxidizing agent. Strong acids. Strong bases.

Form 205.133 (05-2017) Page 7

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

10.6. Hazardous decomposition products

Mainly water vapor. Other potentially hazardous toxic vapors and organic compounds may be formed once water is fully evaporated, including hydrogen sulfide fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

LD50 oral rat > 5000 mg/kg

LD50 dermal rabbit > 2000 mg/kg

LC50 inhalation rat (mg/l) > 94.4 ml/m³

Filler Clay (Trade Secret)

LD50 oral rat > 5000 mg/kg

LD50 dermal rat > 5000 mg/kg

LD50 oral rat > 10000 mg/kg

LC50 inhalation rat (mg/l) > 6.8 mg/l/4h

LD50 oral rat 8000 (≥ 8000) mg/kg

LD50 dermal rabbit > 3000 mg/kg

ATE US (oral) 8000.000 mg/kg body weight

LD50 oral rat 580 g/kg

LD50 dermal rat 2 g/kg

LD50 dermal rabbit 3.5 g/kg

ATE US (oral) 500.000 mg/kg body weight

Skin corrosion/irritation : Causes skin irritation.

pH: 9 - 10.5 Serious eye damage/irritation : Causes serious eye irritation.

pH: 9 - 10.5 Respiratory or skin sensitization : May cause an allergic skin reaction.

Germ cell mutagenicity : Not classified Carcinogenicity : May cause cancer.

IARC group 2A - Probably carcinogenic to humans, 2B - Possibly carcinogenic to humans

IARC group 1 - Carcinogenic to humans

Trade Secret A

Additional information Trade Secret A dust, when inhaled, has been classified by the International Agency for Research on Cancer (IARC) as an IARC Group 2B carcinogen, meaning it is possibly carcinogenic to humans. The findings of the IARC are based on the discovery that high concentrations of pigment-grade (powdered) and ultrafine titanium dioxide dust caused respiratory tract cancer in rats exposed by inhalation and intratracheal instillation.

Form 205.133 (05-2017) Page 8

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

IARC group 2B - Possibly carcinogenic to humans

IARC group 2B - Possibly carcinogenic to humans

Reproductive toxicity : Not classified Specific target organ toxicity (single exposure)

: Not classified

Additional information Target organs :Eyes,skin and respiratory system.

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard : Not classified Potential Adverse human health effects and symptoms

: Based on available data, the classification criteria are not met.

Symptoms/injuries after skin contact : severe skin irritation, redness, dermatitis. Causes skin irritation.

Symptoms/injuries after eye contact : Causes eye irritation. Causes serious eye irritation.

Symptoms/injuries after ingestion : Vomiting. Swallowing a small quantity of this material will result in serious health hazard.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - water : Bioaccumulation of this product or its components is not a known environmental fate.

Although this product is not considered an ecological toxin, the release of this product into surface waters should be avoided.

LC50 fish 1 > 1 ml/l 96h

EC50 Daphnia 1 > 1 mg/l 48h

12.2. Persistence and degradability

INTEGRA-SEAL ASPHALT SEALER

Persistence and degradability Not established.

Form 205.133 (05-2017) Page 9

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

12.3. Bioaccumulative potential

INTEGRA-SEAL ASPHALT SEALER

Bioaccumulative potential Not established.

Bioaccumulative potential The product is practically insoluble in water and not biodegradable.

12.4. Mobility in soil

Ecology - soil No specific data.

12.5. Other adverse effects

Effect on ozone layer :

Effect on the global warming : No known ecological damage caused by this product.

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : Dispose in accordance with all applicable Federal, State and Local regulations.

Sewage disposal recommendations : Do not dispose of waste into sewer.

Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to meet all regulations.

Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with DOT Not Evaluated

Additional information

Other information : No supplementary information available.

ADR

No additional information available

Transport by sea

Form 205.133 (05-2017) Page 10

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

Air transport

SECTION 15: Regulatory information

15.1. US Federal regulations

Listed on the United States TSCA (Toxic Substances Control Act) inventory

SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Immediate (acute) health hazard

15.2. International regulations

CANADA

No additional information available

EU-Regulations

No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Not classified

15.2.2. National regulations

Listed on IARC (International Agency for Research on Cancer)

15.3. US State regulations

U.S. - California - Proposition 65 - Carcinogens List

U.S. - California - Proposition 65 - Developmental Toxicity

U.S. - California - Proposition 65 - Reproductive Toxicity - Female

U.S. - California - Proposition 65 - Reproductive Toxicity - Male

No significance risk level

(NSRL)

Yes No No No

U.S. - New Jersey - Right to Know Hazardous Substance List

Form 205.133 (05-2017) Page 11

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

SECTION 16: Other information

Other information : None.

Full text of H-phrases:

------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4

------ Carc. 1A Carcinogenicity Category 1A

------ Carc. 1B Carcinogenicity Category 1B

------ Carc. 2 Carcinogenicity Category 2

------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A

------ Skin Irrit. 2 Skin corrosion/irritation Category 2

------ Skin Sens. 1 Skin sensitization Category 1

------ H302 Harmful if swallowed

------ H315 Causes skin irritation

------ H317 May cause an allergic skin reaction

------ H319 Causes serious eye irritation

------ H350 May cause cancer

------ H351 Suspected of causing cancer

GHS US SDS

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

“Providing valuable products from valuable people to valuable customers.”

This document contains confidential proprietary and trade secret information of UNIQUE Paving Materials Corp., and copying, dissemination, or use by anyone other than UNIQUE'S intended recipient is strictly prohibited by law.