SDS_UPM_Liquid_Blend__Above_Ambient_.pdf

UPM® Liquid Blend (Above Ambient) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Form 205.120 (11-2020) Page 1

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture Product name : UPM® Liquid Blend Other means of identification : UPM Liquid Blend (shipped above flash point)

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

UNIQUE Paving Materials Corp.

3993 East 93rd Street Cleveland, 44105 - United States of America T (216) 441-4880 http://www.uniquepavingmaterials.com/

1.4. Emergency telephone number

Emergency number : (800) 424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (GHS-US)

Skin Irrit. 2 H315 Skin Sens. 1 H317 Carc. 1B H350

STOT RE 2 H373

Full text of H-phrases: see section 16

2.2. Label elements

GHS-US labeling

Hazard pictograms (GHS-US) :

GHS07

GHS08

Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H315 - Causes skin irritation

H317 - May cause an allergic skin reaction H350 - May cause cancer H373 - May cause damage to organs through prolonged or repeated exposure

Precautionary statements (GHS-US)

: P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe fumes or vapours P261 - Avoid breathing fumes P264 - Wash hands thoroughly after handling P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear personal protective equipment P302+P352 - If on skin: Wash with plenty of water for at least 15 minutes P308+P313 - If exposed or concerned: Get medical advice/attention P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment (see first aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P362+P364 - Take off contaminated clothing and wash it before reuse http://www.uniquepavingmaterials.com/

Form 205.120 (11-2020) Page 2

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

P405 - Store locked up P501 - Dispose of contents/container to meet all regulations

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity (GHS-US)

1.12 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Oral)

1.12 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal)

SECTION 3: Composition/information on ingredients

3.1. Substance

Not applicable

3.2. Mixture

Name Product identifier % Classification (GHS-US)

Petroleum Asphalt Base (CAS No) 8052-42-4 75 - 95 Carc. 1B, H350

Petroleum Solvent (CAS No) 68476-34-6 3 - 25 Flam. Liq. 3, H226 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Carc. 2, H351

STOT RE 2, H373

Asp. Tox. 1, H304 Aquatic Chronic 2, H411

Polyamines 0 - 3 Skin Sens. 1, H317 Carc. 1B, H350

Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.

First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see first aid measures on this label).

First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist.

First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after inhalation : Inhaling this product can result in respiratory tract irritation, leading to mild to severe irritation of the nose, throat and lungs. Dizziness, headaches, nausea.

Symptoms/injuries after skin contact : Causes skin irritation.

Symptoms/injuries after eye contact : Severe irritation including redness, teraing and blurred vision.

Symptoms/injuries after ingestion : May cause a light irritation of the linings of the mouth, throat, and gastrointestinal tract.

Ingestion may cause nausea, vomiting and diarrhea.

4.3. Indication of any immediate medical attention and special treatment needed

Form 205.120 (11-2020) Page 3

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Flammable liquid and vapor.

Explosion hazard : Never use a welding or cutting torch on or near drums of this material (even empty drums) because the material can ignite explosively. May form flammable/explosive vapour-air mixture.

Reactivity : Stable under normal conditions.

5.3. Advice for firefighters

Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Water or foam may cause frothing which can be violent and may present a life-threatening situation. Frothing is most likely to occur when streams of water or foam are sprayed into hot or burning containers. . Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.

6.1.1. For non-emergency personnel

Protective equipment : Wear personal protective equipment.

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.

Emergency procedures : Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

For containment : Dike the product for recovery.

Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.

Collect spillage. Store away from other materials.

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.

Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing fumes.

Hygiene measures : Wash hands thoroughly after handling.

Form 205.120 (11-2020) Page 4

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

7.2. Conditions for safe storage, including any incompatibilities

Technical measures : Container remains hazardous when empty. Continue to observe all precautions. Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical equipment.

Storage conditions : Keep container tightly closed. Keep only in the original container in a cool, well ventilated place away from high temperature or ignition sources. Keep container closed when not in use.

Incompatible products : Strong bases. Strong acids.

Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.

Storage temperature : Short term store near 200F; Pump at 170F and above; Long term may be stored at ambient temperature to minimize the volatilization of petroleum solvent.

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

UPM Liquid Blend/ SC cutback Asphalt

ACGIH Not applicable

OSHA Not applicable

Petroleum Asphalt Base (8052-42-4)

ACGIH ACGIH TWA (mg/m³) 5

OSHA OSHA PEL (Ceiling) (ppm) 5 ppm as fumes

Petroleum Solvent (68476-34-6)

ACGIH ACGIH TWA (mg/m³) 100 mg/m³

Polyamines

ACGIH Not applicable

8.2. Exposure controls

Personal protective equipment : Avoid all unnecessary exposure.

Materials for protective clothing : Impervious clothing. Footwear (shoes, boots).

Hand protection : Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.

Skin and body protection : Wear suitable protective clothing.

Respiratory protection : Wear appropriate mask.

Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Appearance : Dark, Viscous Liquid.

Color : Black;Dark

Odor : ammonia odor;Tar, Petroleum

Form 205.120 (11-2020) Page 5

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

Odor threshold : No data available pH : No data available

Relative evaporation rate (butyl acetate=1) : Slower than Ether

Melting point : No data available

Freezing point : No data available

Boiling point : 400 °F

Flash point : 200 - 230 °F Cleveland Tag Open Cup Method

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : No data available

Relative vapor density at 20 °C : Heavier than air.

Relative density : Lower than water.

Specific gravity / density : lower than water

Solubility : Negligible.

Water: Solubility in water of component(s) of the mixture :

• : 0.4 % • .epsilon.-Caprolactam: 4560 g/l (at 20 °C)

Log Pow : No data available

Log Kow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity

Stable under normal conditions.

10.2. Chemical stability

Flammable liquid and vapor. May form flammable/explosive vapor-air mixture.

Form 205.120 (11-2020) Page 6

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

10.3. Possibility of hazardous reactions

Not established.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.

10.5. Incompatible materials

Strong acids. Strong bases.

10.6. Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide. May release flammable gases.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

LD50 oral rat > 5000 mg/kg

LD50 dermal rabbit > 2000 mg/kg

LC50 inhalation rat (mg/l) > 94.4 ml/m³

LD50 oral rat 5000 mg/kg

LD50 dermal rabbit 2000 mg/kg

ATE US (oral) 5000.000 mg/kg body weight

ATE US (dermal) 2000.000 mg/kg body weight

ATE US (gases) 4500.000 ppmV/4h

ATE US (dust, mist) 1.500 mg/l/4h

Skin corrosion/irritation : Causes skin irritation.

Serious eye damage/irritation : Not classified Respiratory or skin sensitization : May cause an allergic skin reaction.

Germ cell mutagenicity : Not classified Carcinogenicity : May cause cancer.

IARC group 2A - Probably carcinogenic to humans, 2B - Possibly carcinogenic to humans

Reproductive toxicity : Not classified Specific target organ toxicity (single exposure)

: Not classified

Specific target organ toxicity (repeated exposure)

: May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard : Not classified Potential Adverse human health effects and symptoms

: Based on available data, the classification criteria are not met.

Symptoms/injuries after inhalation : Inhaling this product can result in respiratory tract irritation, leading to mild to severe irritation of the nose, throat and lungs. Dizziness, headaches, nausea.

Symptoms/injuries after skin contact : Causes skin irritation.

Symptoms/injuries after eye contact : Severe irritation including redness, tearing and blurred vision.

Symptoms/injuries after ingestion : May cause a light irritation of the linings of the mouth, throat, and gastrointestinal tract.

Ingestion may cause nausea, vomiting and diarrhea.

Form 205.120 (11-2020) Page 7

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : Avoid release to the environment.

12.2. Persistence and degradability

UPM Liquid Blend/ SC cutback Asphalt

Persistence and degradability Not established.

Persistence and degradability Not established.

Persistence and degradability May cause long-term adverse effects in the environment.

12.3. Bioaccumulative potential

UPM Liquid Blend/ SC cutback Asphalt

BCF fish 1 <=

Bioaccumulative potential Not established.

12.4. Mobility in soil

12.5. Other adverse effects

Effect on ozone layer :

Effect on the global warming : No known ecological damage caused by this product.

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : Dispose in accordance with all applicable Federal, State and Local regulations.

Sewage disposal recommendations : Do not dispose of waste into sewer.

Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to meet all regulations.

Additional information : Handle empty containers with care because residual vapors are flammable.

Ecology - waste materials : Avoid release to the environment.

Form 205.120 (11-2020) Page 8

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

SECTION 14: Transport information

Department of Transportation (DOT)

In accordance with DOT

Transport document description : UN3256 Elevated temperature liquid, flammable, n.o.s., 3, III

UN-No.(DOT) : UN3256

Proper Shipping Name (DOT) : Elevated temperature liquid, flammable, n.o.s.

Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120

Hazard labels (DOT) : 3 - Flammable liquid

Packing group (DOT) : III - Minor Danger

DOT Packaging Non Bulk (49 CFR 173.xxx)

: None

DOT Packaging Bulk (49 CFR 173.xxx) : 247

DOT Symbols : G - Identifies PSN requiring a technical name

DOT Special Provisions (49 CFR 172.102) : IB1 - Authorized IBCs: Metal (31A, 31B and 31N). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.

T3 - 2.65 178.274(d)(2) Normal............. 178.275(d)(2) TP3 - The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following: Degree of filling = 95 * dr / df Where: df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively.

TP29 - A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in 178.275 of this subchapter, where the test pressure is

1.5 times the MAWP.

DOT Packaging Exceptions (49 CFR 173.xxx)

: None

DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27)

: Forbidden

DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75)

: Forbidden

DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel.

Emergency Response Guide (ERG) Number

: 128

Other information : No supplementary information available.

Transportation of Dangerous Goods

Transport by sea

Proper Shipping Name (IMDG) : ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S.

Air transport

Form 205.120 (11-2020) Page 9

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

SECTION 15: Regulatory information

15.1. US Federal regulations

UPM Liquid Blend/ SC cutback Asphalt

Not listed on the United States TSCA (Toxic Substances Control Act) inventory

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for:

Hydrogen Sulfide CAS No 7783-06-4 C<=0.095%

Polyamines CAS No C<=1.12%

Tall Oil CAS No Trade secret C<=5.32%

Distilled Tall Oil CAS No 8002-26-4 C<=2.80%

This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

15.2. International regulations

CANADA

No additional information available

EU-Regulations

No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Not classified

15.2.2. National regulations

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer and/or reproductive harm

U.S. - New Jersey - Right to Know Hazardous Substance List

Form 205.120 (11-2020) Page 10

3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com

SECTION 16: Other information

Other information : None.

Full text of H-phrases:

------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4

------ Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4

------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2

------ Asp. Tox. 1 Aspiration hazard Category 1

------ Carc. 1B Carcinogenicity Category 1B

------ Carc. 2 Carcinogenicity Category 2

------ Flam. Liq. 3 Flammable liquids Category 3

------ Skin Irrit. 2 Skin corrosion/irritation Category 2

------ Skin Sens. 1 Skin sensitization Category 1

------ STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2

------ H226 Flammable liquid and vapour

------ H304 May be fatal if swallowed and enters airways

------ H312 Harmful in contact with skin

------ H315 Causes skin irritation

------ H317 May cause an allergic skin reaction

------ H332 Harmful if inhaled

------ H350 May cause cancer

------ H351 Suspected of causing cancer

------ H373 May cause damage to organs through prolonged or repeated exposure

------ H411 Toxic to aquatic life with long lasting effects

GHS US SDS

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

“Providing valuable products from valuable people to valuable customers.”

This document contains confidential proprietary and trade secret information of UNIQUE Paving Materials Corp., and copying, dissemination, or use by anyone other than UNIQUE'S intended recipient is strictly prohibited by law.