SDS_UNIQUE_Concrete_Crack_Filler.pdf
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- Attached to
- Competitive Selection OH|DOT801L26-2
- Contract number
- DOT801L26-2
- Issued by
- Ohio
About this file
This document is a Safety Data Sheet (SDS) for UNIQUE® Concrete Crack Filler, published by Unique Paving Materials Corp. located in Cleveland, Ohio. The SDS is prepared according to federal regulations and provides comprehensive safety, health, and environmental information about the product. The document involves multiple regulatory bodies and inventories, including the United States Toxic Substances Control Act (TSCA), Canadian Domestic Substances List (DSL), and various international chemical substance inventories such as those in Australia, China, Japan, Korea, New Zealand, and the Philippines.
The product is a liquid concrete crack filler with a gray color and tar/asphalt odor, containing key ingredients like asphalt (≤33%), titanium dioxide (≤11%), and quartz (≤0.3%). The SDS highlights potential health hazards, including eye irritation, potential allergic skin reactions, and cancer risk, particularly from asphalt and quartz components. The product requires careful handling with protective equipment, has a pH of 8-9, and is soluble in water. While this is not a contract document, it provides critical technical and safety information for potential users of the concrete crack filler across various jurisdictions and industrial applications.
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UNIQUE® Concrete Crack Filler Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Form 205.139 (09-2019) Page 1
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
SECTION 1: Identification
1.1. Identification
Product form : Mixture Product name : UNIQUE® Concrete Crack Filler
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Crack Filler
1.3. Details of the supplier of the safety data sheet
Unique Paving Material Corp.
3993 East 93rd Street Cleveland, 44105 - United States of America T (216) 441-4880 http://www.uniquepavingmaterials.com/
1.4. Emergency telephone number
Emergency number : (800) 424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification Eye Irrit. 2B Causes eye irritation Skin Sens. 1 May cause an allergic skin reaction Carc. 1A May cause cancer
2.2. Label elements
GHS US labeling Hazard pictograms (GHS US) :
GHS07
GHS08
Signal word (GHS US) : Danger Hazard statements (GHS US) : May cause an allergic skin reaction
Causes eye irritation May cause cancer
Precautionary statements (GHS US) Prevention : Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing fumes.
Wash hands thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace Wear personal protective equipment.
Response : If on skin: Wash with plenty of water If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If exposed or concerned: Get medical advice/attention.
Specific treatment (see first aid measures on this label) If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Storage : Store locked up.
Disposal : Dispose of contents/container to meet all regulations http://www.uniquepavingmaterials.com/
Form 205.139 (09-2019) Page 2
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS US)
9% of the mixture consists of ingredient(s) of unknown acute toxicity (Oral) 9% of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal)
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS US classification
Asphalt (CAS-No.) 8052-42-4 <= 33 Carc. 2, H351
Titanium dioxide (CAS-No.) 13463-67-7 <= 11 Carc. 2, H351
Quartz (CAS-No.) 14808-60-7 <= 0.3 Acute Tox. 4 (Oral), H302 Carc. 1A, H350
1,3,5-Triazine-1,3,5(2H,4H,6H)-triethanol (CAS-No.) 4719-04-4 <= 0.158 Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see first aid measures on this label). Wash contaminated clothing before reuse.
First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after skin contact : Prolonged or repeated contact may cause skin to become dry. May cause moderate irritation.
Symptoms/effects after eye contact : redness, itching, tears. Causes eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Reactivity : Stable under normal conditions.
Form 205.139 (09-2019) Page 3
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Stop leak if safe to do so. Stable under normal conditions.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Stop leak, if possible without risk.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Avoid breathing mist fumes. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Hygiene measures : Always wash hands after handling the product. Do not eat, drink or smoke when using this product. Use good housekeeping practices during storage, transfer and handling.
. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in the original container in a cool, well ventilated place away from: children.
Keep container closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
Storage area : Store in a well-ventilated place. Store away from heat.
Form 205.139 (09-2019) Page 4
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No additional information available
8.2. Exposure controls
Appropriate engineering controls : Ensure good ventilation of the work station. General industrial hygiene practice.
Personal protective equipment : Avoid all unnecessary exposure.
Materials for protective clothing : Footwear (shoes, boots). Impervious clothing.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate mask.
Environmental exposure controls : Avoid release to the environment.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Gray
Odor : Tar, asphalt
Odor threshold : No data available pH : 8 – 9
Freezing point : 0°C / 32°F
Boiling point : 100°C / 212°F
Flash point : Not applicable – water-based
Relative evaporation rate (butyl acetate=1) : No data available
Oxidizing properties : No data available
Vapor pressure : No data available
Relative density : 1.042 Relative vapor density at 20 °C : No data available
Solubility : Soluble in water.
Log Pow : No data available
Viscosity : 1000 – 1500 cP
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Form 205.139 (09-2019) Page 5
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
9.2. Other information
SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under normal conditions.
10.2. Chemical stability
Not established.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous fumes. Carbon monoxide. Carbon dioxide.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
Asphalt (8052-42-4)
LD50 oral rat > 5000 mg/kg
LD50 dermal rabbit > 2000 mg/kg
Quartz (14808-60-7)
ATE US (oral) 500 mg/kg body weight
1,3,5-Triazine-1,3,5(2H,4H,6H)-triethanol (4719-04-4)
LD50 oral rat 763 mg/kg
ATE US (oral) 763 mg/kg body weight
Titanium dioxide (13463-67-7)
LD50 oral rat > 10000 mg/kg
Skin corrosion/irritation : Not classified.
Serious eye damage/irritation : Causes eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified Carcinogenicity : May cause cancer.
IARC group 2B - Possibly carcinogenic to humans
In OSHA Hazard Communication Carcinogen list
Yes
Form 205.139 (09-2019) Page 6
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
IARC group 1 - Carcinogenic to humans
National Toxicology Program (NTP) Status 2 - Known Human Carcinogens
In OSHA Hazard Communication
IARC group 2B - Possibly carcinogenic to humans
In OSHA Hazard Communication
Reproductive toxicity : Not classified Specific target organ toxicity – single exposure
: Not classified
Specific target organ toxicity – repeated exposure
: Not classified
Aspiration hazard : Not classified
Potential Adverse human health effects and symptoms
: Based on available data, the classification criteria are not met.
Symptoms/effects after skin contact : Prolonged or repeated contact may cause skin to become dry. May cause moderate irritation.
Symptoms/effects after eye contact : redness, itching, tears. Causes eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
Persistence and degradability Not established.
12.3. Bioaccumulative potential
Bioaccumulative potential Not established.
Form 205.139 (09-2019) Page 7
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
BCF fish 1 (no bioaccumulation expected)
Log Pow > 6
12.4. Mobility in soil
12.5. Other adverse effects
Effect on the global warming : No known effects from this product.
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Product/Packaging disposal recommendations
: Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to meet all regulations.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Not evaluated
Transportation of Dangerous Goods
Not evaluated
Transport by sea
Not evaluated
Air transport
Not evaluated
Form 205.139 (09-2019) Page 8
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
SECTION 15: Regulatory information
15.1. US Federal regulations
Listed on the United States TSCA (Toxic Substances Control Act) inventory
EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a final TSCA section 4 test rule.
15.2. International regulations
CANADA
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
EU-Regulations
National regulations
Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Japanese ISHL (Industrial Safety and Health Law) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on INSQ (Mexican National Inventory of Chemical Substances) Listed on CICR (Turkish Inventory and Control of Chemicals) Listed on the TCSI (Taiwan Chemical Substance Inventory)
Form 205.139 (09-2019) Page 9
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
Listed on IARC (International Agency for Research on Cancer) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Japanese ISHL (Industrial Safety and Health Law) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed as carcinogen on NTP (National Toxicology Program) Listed on the Canadian IDL (Ingredient Disclosure List) Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Japanese ISHL (Industrial Safety and Health Law) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Japanese ISHL (Industrial Safety and Health Law) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on INSQ (Mexican National Inventory of Chemical Substances)
15.3. US State regulations
U.S. - California - Proposition 65 - Carcinogens List
U.S. - California - Proposition 65 - Developmental Toxicity
U.S. - California - Proposition 65 - Reproductive Toxicity - Female
U.S. - California - Proposition 65 - Reproductive Toxicity - Male
No significant risk level (NSRL)
Yes No No No
U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List
Form 205.139 (09-2019) Page 10
3993 E. 93rd Street ι Cleveland, OH 44105 ι Phone 800.441.4880 ι Fax 216.341.8514 ι UniquePavingMaterials.com
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product
“Providing valuable products from valuable people to valuable customers.”
This document contains confidential proprietary and trade secret information of UNIQUE Paving Materials Corp., and copying, dissemination, or use by anyone other than UNIQUE'S intended recipient is strictly prohibited by law.
File details come from the government source that posted it. Updated .