05-ASI - Final Data Report - Raritan River PART 4of4 - 12 May.pdf

VOLUME IV

Public Notice Tables

Technical Report on the Sampling and Testing of Material from the Raritan River

Proposed for Dredging and HARS Ocean Disposal

Contract No. W912DS-17-D-0006 Delivery Order No. 0054

Prepared for

Army Corps of Engineers, New York District 26 Federal Plaza

New York, NY 10278

ASI Job # 38-062

ASI Job No. 38-062

TABLE 1. RESULTS OF CHEMICAL ANALYSIS OF SITE WATER AND ELUTRIATE

SITE WATER ELUTRIATE

CONSTITUENTS DETECTION LIMITS CONCENTRATION DETECTION LIMITS CONCENTRATION

Metals ppb (ug/L) ppb (ug/L) ppb (ug/L) ppb (ug/L) Ag 0.019 0.091 Cd 0.041 0.026 Cr 0.490 2.30 Cu 2.44 4.54 Hg 0.020 ND 0.290 Ni 1.50 1.89 Pb 0.964 5.05 Zn 6.06 6.04

Pesticides pptr (ng/L) pptr (ng/L) pptr (ng/L) pptr (ng/L) Aldrin 0.531 ND 0.501 ND a-Chlordane 0.442 ND 0.647 trans Nonachlor 0.436 ND 1.33 Dieldrin 0.544 ND 0.513 ND

4,4'-DDT 0.633 ND 0.597 ND

2,4'-DDT 0.795 ND 0.750 ND

4,4'-DDD 0.531 ND 1.09

2,4'-DDD 0.582 ND 0.549 ND

4,4'-DDE 0.445 ND 1.88

2,4'-DDE 0.557 ND 0.526 ND

Total DDT ND 2.97 Endosulfan I 0.531 ND 0.501 ND Endosulfan II 0.525 ND 0.495 ND Endosulfan sulfate 0.439 ND 0.414 ND Heptachlor 0.534 ND 0.504 ND Heptachlor epoxide 0.442 ND 0.417 ND

Industrial Chemicals pptr (ng/L) pptr (ng/L) pptr (ng/L) pptr (ng/L)

PCB 8 0.572 ND 0.540 ND

PCB 18 0.366 ND 0.345 ND

PCB 28 0.423 ND 0.399 ND

PCB 44 0.534 ND 0.504 ND

PCB 49 0.391 ND 10.2

PCB 52 0.499 ND 7.07

PCB 66 0.601 ND 1.33

PCB 87 0.461 ND 0.435 ND

PCB 101 0.388 ND 4.61

PCB 105 0.598 ND 1.64

PCB 118 0.576 ND 1.27

PCB 128 0.417 ND 0.128

PCB 138 0.493 ND 1.00

PCB 153 0.493 ND 1.48 ND

PCB 170 0.452 ND 0.796

PCB 180 0.458 ND 0.687

PCB 183 0.410 ND 0.298

PCB 184 0.576 ND 0.543 ND

PCB 187 0.423 ND 0.849

PCB 195 0.429 ND 0.355

PCB 206 0.464 ND 0.288

PCB 209 0.445 ND 0.561

Total PCB ND 62.2

ND = Not detected Total DDT = sum of 2,4'- and 4,4'-DDD, DDE, and DDT Total PCB = sum of congeners reported x 2

Raritan River Reach A

TABLE 1. RESULTS OF CHEMICAL ANALYSIS OF SITE WATER AND ELUTRIATE

SITE WATER ELUTRIATE

CONSTITUENTS DETECTION LIMITS CONCENTRATION DETECTION LIMITS CONCENTRATION

Metals ppb (ug/L) ppb (ug/L) ppb (ug/L) ppb (ug/L) Ag 0.013 0.094 Cd 0.041 0.046 Cr 0.440 2.46 Cu 2.39 7.08 Hg 0.020 ND 0.300 Ni 1.46 1.88 Pb 0.909 4.66 Zn 6.12 6.65

Pesticides pptr (ng/L) pptr (ng/L) pptr (ng/L) pptr (ng/L) Aldrin 0.531 ND 0.501 ND a-Chlordane 0.442 ND 0.688 trans Nonachlor 0.436 ND 1.12 Dieldrin 0.544 ND 0.513 ND

4,4'-DDT 0.633 ND 0.597 ND

2,4'-DDT 0.795 ND 0.750 ND

4,4'-DDD 0.531 ND 1.84

2,4'-DDD 0.582 ND 0.549 ND

4,4'-DDE 0.445 ND 5.04

2,4'-DDE 0.557 ND 0.526 ND

Total DDT ND 6.88 Endosulfan I 0.531 ND 0.501 ND Endosulfan II 0.525 ND 0.495 ND Endosulfan sulfate 0.439 ND 0.414 ND Heptachlor 0.534 ND 0.504 ND Heptachlor epoxide 0.442 ND 0.417 ND

Industrial Chemicals pptr (ng/L) pptr (ng/L) pptr (ng/L) pptr (ng/L)

PCB 8 0.572 ND 0.540 ND

PCB 18 0.366 ND 0.345 ND

PCB 28 0.423 ND 0.399 ND

PCB 44 0.534 ND 0.504 ND

PCB 49 0.391 ND 0.369 ND

PCB 52 0.499 ND 0.471 ND

PCB 66 0.601 ND 0.567 ND

PCB 87 0.461 ND 0.435 ND

PCB 101 0.388 ND 4.87

PCB 105 0.598 ND 3.03

PCB 118 0.576 ND 3.64

PCB 128 0.417 ND 0.465

PCB 138 0.493 ND 4.10

PCB 153 0.493 ND 3.22

PCB 170 0.452 ND 1.48

PCB 180 0.458 ND 1.54

PCB 183 0.410 ND 0.505

PCB 184 0.576 ND 0.543 ND

PCB 187 0.423 ND 1.52

PCB 195 0.429 ND 1.22

PCB 206 0.464 ND 0.499

PCB 209 0.445 ND 1.36

Total PCB ND 54.9

ND = Not detected Total DDT = sum of 2,4'- and 4,4'-DDD, DDE, and DDT Total PCB = sum of congeners reported x 2

Raritan River Reach B

ACOE- Raritan River Reach A

TABLE 2 TOXICITY TEST RESULTS ASI Job No. 38-062

Suspended Particulate Phase

Test Species Test Duration LPC (a)

Menidia beryllina 96 hours (b) 52.0% 0.75

Americamysis bahia 96 hours (b) 65.0% 0.69

Mytilus galloprovincialis (larval survival)

Mytilus galloprovincialis (larval normal develop.)

(a) Limiting Permissible Concentration (LPC) is the LC50 or EC50 multiplied by 0.01

(b) Median Lethal Concentration (LC50) resulting in 50% mortatlity at test termination

(c) Median Effective Concentration (EC50) based on normal development to the D-cell, prodissoconch 1 stage

Whole Sediment (10 days)

Test Species % Survival % Difference Is difference statistically

Reference Reference - Test significant? (a=0.05)

Ampelisca abdita 99% -1% No

Americamysis bahia 98% 0% No

Test

100%

98%

LC50/EC50

48 hours (b) 60.0% 0.63

48 hours (c) 22.0% 0.22

% Survival

Table 2 Tox REACH A.xls

ACOE- Raritan River Reach B

TABLE 2 TOXICITY TEST RESULTS ASI Job No. 38-062

Suspended Particulate Phase

Test Species Test Duration LPC (a)

Menidia beryllina 96 hours (b) 81.0% 0.008

Americamysis bahia 96 hours (b) >100% 0.010

Mytilus galloprovincialis (larval survival)

Mytilus galloprovincialis (larval normal develop.)

(a) Limiting Permissible Concentration (LPC) is the LC50 or EC50 multiplied by 0.01

(b) Median Lethal Concentration (LC50) resulting in 50% mortatlity at test termination

(c) Median Effective Concentration (EC50) based on normal development to the D-cell, prodissoconch 1 stage

Whole Sediment (10 days)

Test Species % Survival % Difference Is difference statistically

Reference Reference - Test significant? (a=0.05)

Ampelisca abdita 99% 3% No

Americamysis bahia 98% 2% No

0.010

48 hours (c) 22.3% 0.002

% Survival

Test

96%

96%

LC50/EC50

48 hours (b) >100%

Table 2 Tox REACH B.xls

TABLE 3. 28 DAY BIOACCUMULATION TEST RESULTS: CHEMICAL ANALYSIS OF TISSUE

Wet weight concentrations

Macoma nasuta Nereis virens

REFERENCE TEST REFERENCE TEST

CONSTITUENTS DETECTION CONCEN DETECTION CONCEN DETECTION CONCEN DETECTION CONCEN

LIMITS TRATION LIMITS TRATION LIMITS TRATION LIMITS TRATION

Metals ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) Ag 0.078 0.065 0.013 * 0.015 As 5.11 5.14 2.64 2.37 Cd 0.052 0.049 0.040 0.038 Cr 0.603 0.489 0.112 0.063 Cu 1.69 * 2.37 1.56 1.11 Hg 0.008 * 0.014 0.026 0.020 Ni 0.627 0.496 0.196 0.153 Pb 0.226 * 0.750 0.122 0.122 Zn 20.7 13.9 19.8 26.1 Pesticides ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) Aldrin 0.027 ND 0.028 ND 0.027 ND 0.027 ND a-Chlordane 0.021 ND * 0.114 0.021 ND 0.025 trans Nonachlor 0.027 ND 0.013 0.027 ND 0.018 Dieldrin 0.018 ND * 0.196 0.018 ND * 0.219

4,4'-DDT 0.024 ND 0.023 ND 0.024 ND 0.022 ND

2,4'-DDT 0.065 0.033 ND 0.033 ND 0.032 ND

4,4'-DDD 0.062 * 1.35 0.023 * 1.35

2,4'-DDD 0.033 ND * 0.423 0.033 ND * 0.466

4,4'-DDE 0.134 * 3.84 0.021 ND * 1.23

2,4'-DDE 0.018 ND * 0.446 0.018 ND 0.018 ND

Total DDT 0.299 * 6.08 0.089 * 3.08 Endosulfan I 0.030 ND 0.030 ND 0.030 ND 0.030 ND Endosulfan II 0.033 ND 0.033 ND 0.033 ND 0.033 ND Endosulfan sulfate 0.024 ND 0.023 ND 0.024 ND 0.024 ND Heptachlor 0.021 ND 0.021 ND 0.021 ND 0.021 ND Heptachlor epoxide 0.033 ND 0.033 ND 0.033 ND 0.033 ND

Industrial Chemicals ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg)

PCB 8 0.060 ND * 0.523 0.060 ND 0.060 ND

PCB 18 0.027 ND * 0.755 0.027 ND * 0.975

PCB 28 0.074 * 2.17 0.016 * 1.40

PCB 44 0.012 * 0.720 0.064 * 1.13

PCB 49 0.051 * 2.24 0.010 * 1.73

PCB 52 0.016 * 2.38 0.083 * 2.59

PCB 66 0.155 * 1.99 0.042 ND * 1.22

PCB 87 0.027 ND * 0.305 0.027 ND * 0.061

PCB 101 0.108 * 2.37 0.276 * 1.69

PCB 105 0.024 ND * 0.445 0.024 ND * 0.204

PCB 118 0.022 * 1.45 0.064 * 0.925

PCB 128 0.0300 ND * 0.124 0.044 * 0.170

PCB 138 0.144 * 1.48 1.09 * 1.89

PCB 153 0.818 * 2.74 1.73 * 2.92

PCB 170 0.018 * 0.214 0.134 * 0.296

PCB 180 0.054 * 0.519 0.460 * 0.764

PCB 183 0.021 ND * 0.150 0.173 * 0.260

PCB 184 0.048 ND 0.049 ND 0.048 ND * 0.597

PCB 187 0.023 * 0.594 0.666 * 0.984

PCB 195 0.018 ND 0.036 0.021 * 0.143

PCB 206 0.018 ND 0.018 ND 0.068 0.165

PCB 209 0.033 ND 0.033 ND 0.136 0.141

Total PCB 3.30 * 42.5 10.3 * 40.6 1,4-Dichlorobenzene 0.118 * 0.236 0.108 0.083

TABLE 3. (Continued)

Macoma nasuta Nereis virens

REFERENCE TEST REFERENCE TEST

CONSTITUENTS DETECTION CONCEN DETECTION CONCEN DETECTION CONCEN DETECTION CONCEN

LIMITS TRATION LIMITS TRATION LIMITS TRATION LIMITS TRATION

PAH's ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) Naphthalene 0.652 * 1.09 0.468 0.491 Acenaphthylene 0.153 * 0.604 0.087 * 0.190 Acenaphthene 0.194 * 0.541 0.185 * 0.441 Fluorene 0.207 * 0.786 0.095 * 0.228 Phenanthrene 1.31 * 5.01 0.465 * 0.936 Anthracene 0.304 * 2.03 0.053 * 0.184 Fluoranthene 2.82 * 25.8 0.397 * 7.77 Pyrene 3.05 * 30.8 0.403 * 9.58 Benzo(a)anthracene 0.909 * 8.73 0.126 * 0.459 Chrysene 1.58 * 14.5 0.047 * 0.453 Benzo(b)fluoranthene 1.38 * 13.5 0.089 * 0.756 Benzo(k)fluoranthene 1.26 * 9.56 0.114 * 0.847 Benzo(a)pyrene 0.916 * 7.80 0.081 * 0.496 Indeno(1,2,3-cd)pyrene 0.574 * 5.31 0.048 * 0.169 Dibenzo(a,h)antracene 0.133 * 1.25 0.093 ND * 0.068 Benzo(g,h,i)perylene 0.542 * 5.67 0.089 * 0.454 Total PAH's 16.0 * 133 2.79 * 23.5

Dioxins pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg)

2378 TCDD 0.010 ND 0.044 0.057 * 0.282

12378 PeCDD 0.014 ND 0.014 ND 0.256 ND 0.114 123478 HxCDD 0.011 ND 0.012 ND 0.014 0.029 123678 HxCDD 0.054 0.132 0.092 * 0.267 123789 HxCDD 0.011 ND 0.012 ND 0.010 ND * 0.127 1234678 HpCDD 0.060 * 1.76 1.49 1.08

1234789 OCDD 7.52 23.7 9.75 10.2

2378 TCDF 0.010 ND * 0.526 0.904 * 1.81

12378 PeCDF 0.010 ND 0.011 ND 0.149 0.200 23478 PeCDF 0.010 ND * 0.054 0.280 0.351 123478 HxCDF 0.008 ND 0.095 0.005 ND * 0.139 123678 HxCDF 0.008 ND 0.017 0.026 0.027 234678 HxCDF 0.009 ND 0.009 ND 0.020 0.022 123789 HxCDF 0.009 ND 0.030 0.005 ND 0.006 ND 1234678 HpCDF 0.243 * 0.704 0.573 0.562 1234789 HpCDF 0.052 0.066 0.005 ND 0.048

12346789 OCDF 0.508 * 0.966 0.646 0.476

ND = Not detected Total PAH = Sum of all PAH's.

Total DDT = sum of 2,4'- and 4,4'-DDD, DDE, and DDT Total PCB = 2(x), where x = sum of PCB congeners Concentrations shown are the mean of 5 replicate analyses in wet weight.

Means were determined using conservative estimates of concentrations of constituents that were at concentrations below the detection limit.

* = Statistically significant at the 95% confidence level.

TABLE 3. 28 DAY BIOACCUMULATION TEST RESULTS: CHEMICAL ANALYSIS OF TISSUE

Wet weight concentrations

Macoma nasuta Nereis virens

REFERENCE TEST REFERENCE TEST

CONSTITUENTS DETECTION CONCEN DETECTION CONCEN DETECTION CONCEN DETECTION CONCEN

LIMITS TRATION LIMITS TRATION LIMITS TRATION LIMITS TRATION

Metals ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) ppm (mg/kg) Ag 0.078 * 0.097 0.013 0.013 As 5.11 * 5.83 2.64 2.36 Cd 0.052 0.067 0.040 0.042 Cr 0.603 0.540 0.112 0.112 Cu 1.69 * 3.12 1.56 1.19 Hg 0.008 * 0.016 0.026 0.017 Ni 0.627 0.549 0.196 0.188 Pb 0.226 * 0.785 0.122 0.138 Zn 20.7 21.5 19.8 32.5 Pesticides ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) Aldrin 0.027 ND 0.028 ND 0.027 ND 0.027 ND a-Chlordane 0.021 ND * 0.238 0.021 ND * 0.162 trans Nonachlor 0.027 ND 0.029 0.027 ND * 0.136 Dieldrin 0.018 ND * 0.280 0.018 ND * 0.382

4,4'-DDT 0.024 ND 0.023 ND 0.024 ND 0.022 ND

2,4'-DDT 0.065 0.032 ND 0.033 ND 0.032 ND

4,4'-DDD 0.062 * 1.58 0.023 * 2.44

2,4'-DDD 0.033 ND * 0.369 0.033 ND * 0.564

4,4'-DDE 0.134 * 6.46 0.021 ND * 3.40

2,4'-DDE 0.018 ND * 0.967 0.018 ND 0.378

Total DDT 0.299 * 9.40 0.089 * 6.80 Endosulfan I 0.030 ND 0.030 ND 0.030 ND 0.030 ND Endosulfan II 0.033 ND 0.032 ND 0.033 ND 0.033 ND Endosulfan sulfate 0.024 ND 0.023 ND 0.024 ND 0.024 ND Heptachlor 0.021 ND 0.021 ND 0.021 ND 0.021 ND Heptachlor epoxide 0.033 ND 0.033 ND 0.033 ND 0.033 ND

Industrial Chemicals ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg)

PCB 8 0.060 ND * 0.628 0.060 ND * 0.254

PCB 18 0.027 ND * 2.93 0.027 ND * 4.62

PCB 28 0.074 * 5.75 0.016 * 5.40

PCB 44 0.012 * 2.52 0.064 * 4.37

PCB 49 0.051 * 5.42 0.010 * 5.29

PCB 52 0.016 * 7.00 0.083 * 8.85

PCB 66 0.155 * 4.91 0.042 ND * 4.62

PCB 87 0.027 ND * 1.23 0.027 ND * 0.859

PCB 101 0.108 * 4.52 0.276 * 4.36

PCB 105 0.024 ND * 1.20 0.024 ND * 0.958

PCB 118 0.022 * 3.00 0.064 * 2.60

PCB 128 0.030 ND * 0.275 0.044 * 0.427

PCB 138 0.144 * 2.48 1.09 * 3.09

PCB 153 0.818 * 3.19 1.73 * 4.27

PCB 170 0.018 * 0.359 0.134 * 0.627

PCB 180 0.054 * 0.826 0.460 * 1.28

PCB 183 0.021 ND * 0.258 0.173 0.411

PCB 184 0.048 ND 0.049 ND 0.048 ND 0.049 ND

PCB 187 0.023 * 0.728 0.666 * 1.34

PCB 195 0.018 ND 0.018 ND 0.021 * 0.418

PCB 206 0.018 ND 0.018 ND 0.068 0.146

PCB 209 0.033 ND 0.033 ND 0.136 0.159

Total PCB 3.30 * 94.5 10.3 * 109 1,4-Dichlorobenzene 0.118 * 0.287 0.108 0.083

TABLE 3. (Continued)

Macoma nasuta Nereis virens

REFERENCE TEST REFERENCE TEST

CONSTITUENTS DETECTION CONCEN DETECTION CONCEN DETECTION CONCEN DETECTION CONCEN

LIMITS TRATION LIMITS TRATION LIMITS TRATION LIMITS TRATION

PAH's ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) ppb (ug/kg) Naphthalene 0.652 * 1.21 0.468 0.555 Acenaphthylene 0.153 * 0.682 0.087 * 0.345 Acenaphthene 0.194 * 9.92 0.185 * 9.52 Fluorene 0.207 * 6.34 0.095 * 1.55 Phenanthrene 1.31 * 38.4 0.465 * 5.15 Anthracene 0.304 * 12.9 0.053 * 1.03 Fluoranthene 2.82 * 140 0.397 * 54.8 Pyrene 3.05 * 154 0.403 * 63.4 Benzo(a)anthracene 0.91 * 29.6 0.126 * 1.98 Chrysene 1.58 * 38.1 0.047 * 2.10 Benzo(b)fluoranthene 1.38 * 25.2 0.089 * 2.07 Benzo(k)fluoranthene 1.26 * 16.6 0.114 * 2.14 Benzo(a)pyrene 0.916 * 14.4 0.081 * 1.28 Indeno(1,2,3-cd)pyrene 0.574 * 6.55 0.048 * 0.370 Dibenzo(a,h)antracene 0.133 * 1.37 0.093 ND * 0.132 Benzo(g,h,i)perylene 0.542 * 7.24 0.089 * 0.974 Total PAH's 16.0 * 503 2.79 * 147

Dioxins pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg) pptr(ng/kg)

2378 TCDD 0.010 ND * 0.221 0.057 * 0.588

12378 PeCDD 0.014 ND 0.018 ND 0.256 ND 0.120 123478 HxCDD 0.011 ND * 0.027 0.014 0.017 123678 HxCDD 0.054 * 0.468 0.092 * 0.476 123789 HxCDD 0.011 ND * 0.069 0.010 ND 0.110 1234678 HpCDD 0.060 * 2.15 1.49 * 1.68

1234789 OCDD 7.52 * 32.4 9.75 * 15.4

2378 TCDF 0.010 ND * 0.704 0.90 * 2.14

12378 PeCDF 0.010 ND 0.093 0.149 0.339 23478 PeCDF 0.010 ND 0.105 0.280 * 0.606 123478 HxCDF 0.008 ND 0.125 0.005 ND * 0.416 123678 HxCDF 0.008 ND 0.057 0.026 0.039 234678 HxCDF 0.009 ND 0.022 0.020 0.087 123789 HxCDF 0.009 ND 0.009 ND 0.005 ND 0.007 * ND 1234678 HpCDF 0.243 * 0.747 0.573 0.730 1234789 HpCDF 0.052 0.009 ND 0.005 ND 0.014

12346789 OCDF 0.508 0.706 0.646 0.578

ND = Not detected Total PAH = Sum of all PAH's.

Total DDT = sum of 2,4'- and 4,4'-DDD, DDE, and DDT Total PCB = 2(x), where x = sum of PCB congeners Concentrations shown are the mean of 5 replicate analyses in wet weight.

Means were determined using conservative estimates of concentrations of constituents that were at concentrations below the detection limit.

* = Statistically significant at the 95% confidence level.

TABLE 1 Template Version: 12/27/00 Bioaccumulation Table for NY/NJ Harbor Projects, ALL VALUES ARE IN WET WEIGHT Project Name: ACOE, 38-062 Sample Area/Location: Raritan River Reach A

COMPARISON DATA

Col. 1 Col. 2 [11] Col. 3 [11] Col. 4 [11] 5 Col. 6 [11] 7 Col. 8 Col. 9 Col. 10 Col. 11 Col. 12 Col. 13 Col. 14 Col. 15 Col. 16 Col. 17 Col. 18 Col. 19 Col. 20

Sample I.D. Reference Reference Test Sed. [1] Test Sed. [1] Conv.Fac. Test Sed. Test Sed. Test Sed. Test Sed. Human Health Human Health Ecological clam/worm SS SS Carcinogenic BaP Tox. Equiv. BaP Tox. Equiv. Cancer (10E-4) Non-Cancer Background Background FDA Non-Specific Regional

(clam) (worm) (clam) (worm) [2] (clam) (worm) TEF [3] Conc.(clam)[4] Conc.(worm)[4] Level[5] Level (HQ=1) (clam) (worm) Limits [7] Effects Level Matrix [12] Compound (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg)[10] (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) PAHs Acenaphthene 0.194 0.185 0.541 * 0.441 * 1/1 0.541 0.441 8,775,000 8.1 0.5 [15] Acenapthylene 0.153 0.087 0.604 * 0.190 * 1/1 0.604 0.190 [6] 4.6 1.3 [15] Anthracene 0.304 0.053 2.03 * 0.184 * 1/1 2.03 0.184 43,605,000 10.0 1.6 3,750 Fluorene 0.207 0.095 0.786 * 0.228 * 1/1 0.786 0.228 5,805,000 7.4 0.3 [15] Naphthalene 0.652 0.468 1.09 * 0.491 1/1 1.09 0.491 [6] 26.4 4.5 [15] Phenanthrene 1.31 0.465 5.01 * 0.936 * 1/1 5.01 0.936 43,605,000 32.7 4.7 [15] Benzo(a)anthracene* 0.909 0.126 8.73 * 0.459 * 2/2 17.5 0.918 0.1 1.75 0.092 [6] 25.1 4.8 [15] Benzo(a)pyrene* 0.916 0.081 7.80 * 0.496 * 2/2 15.6 0.992 1 15.6 0.992 [6] 24.2 7.6 8,000 [8] Benzo(g,h,i)perylene 0.542 0.089 5.67 * 0.454 * 3/3 17.0 1.36 [6] 22.2 7.6 [15] Benzo(b)fluoranthene* 1.38 0.089 13.5 * 0.756 * 2/2 27.0 1.51 0.1 2.70 0.151 [6] 40.6 16.5 [15] Benzo(k)fluoranthene* 1.26 0.114 9.56 * 0.847 * 2/2 19.1 1.69 0.01 0.191 0.017 [6] 81.6 5.6 [15] Chrysene* 1.58 0.047 14.5 * 0.453 * 2/2 29.0 0.906 0.001 0.0290 0.0009 [6] 29.4 6.7 [15] Dibenzo(a,h)anthracene* 0.133 0.093U 1.25 * 0.068 * 2/2 2.50 0.136 1 2.50 0.14 [6] 8.5 1.1 [15] Fluoranthene 2.82 0.397 25.8 * 7.77 * 1/1 25.8 7.77 1 5,805,000 43.8 10.6 [15] Indeno(1,2,3-cd)pyrene* 0.574 0.048 5.31 * 0.169 * 3/3 15.9 0.507 0.1 1.590 0.051 [6] 16.6 4.4 [15] Pyrene 3.05 0.403 30.8 * 9.58 * 1/1 30.8 9.6 4,387,000 51.3 26.6 [15]

TOTAL PAHs 210 28 25.4 1.4 2,000 (BaP eqv.) 432.7 104.60 40,000 [9]

PESTICIDES

Aldrin 0.027U 0.027U 0.028U 0.027U 2/2 0.056 0.054 33 167 0.9 0.1 300 299 [10] Dieldrin 0.018U 0.018U 0.196 * 0.219 * 2/2 0.392 0.438 65 518 0.1 300 4.37 [10] a-Chlordane 0.021U 0.021U 0.114 * 0.025 2/2 0.228 0.050 0.7 300 Trans nonachlor 0.027U 0.027U 0.013 0.018 2/2 0.026 0.036 0.5 Heptachlor 0.021U 0.021U 0.021U 0.021U 2/2 0.042 0.042 0.05 300 Heptachlor epoxide 0.033U 0.033U 0.033U 0.033U 1/1 0.033 0.033 0.2 300

Total Residual Chlordane/Heptachlor 0.329 0.161 114 135 1.7 64# [10]

Endosulfan I 0.03U 0.03U 0.03U 0.03U 1/1 0.030 0.030 [6] 0.2 Endosulfan II 0.033U 0.033U 0.033U 0.033U 1/1 0.033 0.033 [6] 0.1 Endosulfan sulfate 0.024U 0.024U 0.023U 0.024U 1/1 0.023 0.024 [6] 0.1 Total Endosulfans 0.086 0.087 87,000 0.4 2.86# [10]

4,4-DDT 0.024U 0.024U 0.023U 0.022U 11/11 0.253 0.242 0.6 1.0

2,4-DDT 0.065 0.033U 0.033U 0.032U 2/2 0.066 0.064 0.4

4,4-DDD 0.062 0.023 1.35 * 1.35 * 3/3 4.05 4.05 3.9

2,4-DDD 0.033U 0.033U 0.423 * 0.466 * 2/2 0.846 0.932 1.4

4,4-DDE 0.134 0.021U 3.84 * 1.23 * 2/2 7.68 2.46 3.5 4.3

2,4-DDE 0.018U 0.018U 0.446 * 0.018U 2/2 0.892 0.036 0.1

Total DDT 13.8 7.78 11.1 40

TOTAL PCBs 3.30 10.3 42.5 * 40.6 * 1/2 42.5 81.2 106.6 88.1 2,000 100(clam) 113(worm) [18] 1,4-Dichlorobenzene 0.118 0.108 0.236 * 0.083 1/1 0.236 0.083 60,000 [6] 11,820 [10]

METALS (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) Arsenic 5.11 2.64 5.14 2.37 1/1 5.14 2.37 [17] [17] 4.89 12.6 [10] Cadmium 0.052 0.040 0.049 0.038 [16] 0.049 0.038 1.21 0.11 0.3 Chromium (total) 0.603 0.112 0.489 0.063 1/1 0.489 0.063 [6] 73 1.28 1.31 11.8 [10] Copper 1.69 1.56 2.37 * 1.11 1/1 2.37 1.11 [6] 540 5.58 2.78 9.6 [10] Lead 0.226 0.122 0.750 * 0.122 1/1 0.750 0.122 [6] 1.3 1.41 1.64 11.9 [10] Mercury 0.008 0.026 0.014 * 0.020 [16] 0.014 0.020 0.04 0.03 1 0.2 Nickel 0.627 0.196 0.496 0.153 1/1 0.496 0.153 [6] 290 1.10 0.77 3.8 [10] Silver 0.078 0.013 0.065 0.015 * 1/1 0.065 0.015 [6] 73 0.15 1.4 [10] Zinc 20.7 19.8 13.9 26.1 1/1 13.9 26.1 [6] 4,400 11.50 20.61 1,517 [10]

TABLE 1 (continued) Bioaccumulation Table for NY/NJ Harbor Projects, ALL VALUES ARE IN WET WEIGHT

COMPARISON DATA

Col. 1 Col. 2 Col. 3 Col. 4 [11] 5.00 Col. 6 [11] 7.00 Col. 8 Col. 9 Col. 10 Col. 11 Col. 12 Col. 13 Col. 14 Col. 15 Col. 16 Col. 17 Col. 18 Col. 19 Col. 20

Sample I.D. Reference Reference Test Sed. [1] Test Sed. [1] Conv.Fac. Test Sed. Test Sed. Test Sed. Test Sed. Human Health Human Health Ecological Regional clam/worm SS SS TEQ TEQ Cancer (10E-4) Non-Cancer Background Background FDA Non specific Dioxin

(clam) (worm) (clam) (worm) [2] (clam) (worm) TEF [3] (clam) (worm) Level Level (HQ=1) (clam) (worm) Limits [7] Effects Level Value Compound (pptr) (pptr) (pptr) (pptr) (pptr) (pptr) (pptr) (pptr) (pptr) (pptr)[10] TEQ (pptr) TEQ (pptr) (pptr) (pptr) (pptr)

DIOXINS

2,3,7,8,-TCDD 0.01U 0.057 0.044 0.282 * 1 0.044 0.282 1.73 2.50 1 [13]

1,2,3,7,8-PeCDD 0.014U 0.256U 0.014U 0.114 0.5 0.007 0.057 0.41 1,2,3,4,7,8-HxCDD 0.011U 0.014 0.012U 0.029 0.1 0.001 0.0029 0.10 1,2,3,6,7,8-HxCDD 0.054 0.092 0.132 0.267 * 0.1 0.0132 0.0267 0.17 1,2,3,7,8,9-HxCDD 0.011U 0.01U 0.012U 0.127 * 0.1 0.0012 0.0127 0.08 1,2,3,4,6,7,8-HpCDD 0.060 1.490 1.76 * 1.08 0.01 0.0176 0.0108 0.13

OCDD 7.52 9.75 23.7 10.2 0.001 0.0237 0.0102 0.11

2,3,7,8-TCDF 0.01U 0.90 0.526 * 1.81 * 0.1 0.0526 0.181 0.27

1,2,3,7,8-PeCDF 0.01U 0.149 0.011U 0.200 0.05 0.00055 0.01 0.05 2,3,4,7,8-PeCDF 0.01U 0.280 0.054 * 0.351 0.5 0.027 0.1755 0.39 1,2,3,4,7,8-HxCDF 0.008U 0.005U 0.095 0.139 * 0.1 0.0095 0.0139 0.08 1,2,3,6,7,8-HxCDF 0.008U 0.026 0.017 0.027 0.1 0.0017 0.0027 0.09 1,2,3,7,8,9-HxCDF 0.009U 0.005U 0.030 0.006U 0.1 0.003 0.0006 0.11 2,3,4,6,7,8-HxCDF 0.009U 0.020 0.009U 0.022 0.1 0.0009 0.0022 0.08 1,2,3,4,6,7,8-HpCDF 0.243 0.573 0.704 * 0.562 0.01 0.00704 0.00562 0.04 1,2,3,4,7,8,9-HpCDF 0.052 0.005U 0.066 0.048 0.01 0.00066 0.00048 0.02

OCDF 0.508 0.646 0.966 * 0.476 0.001 0.000966 0.000476 0.01

TEQs - non 2,3,7,8-TCDD 0.167616 0.512776 2.14 4.5 [14] TEQs (all) 0.211616 0.794776 1.73 4.64 10 [13]

PROJECT DATA

Project Data

TABLE 1 Template Version: 12/27/00 Bioaccumulation Table for NY/NJ Harbor Projects, ALL VALUES ARE IN WET WEIGHT Project Name: ACOE, 38-062 Sample Area/Location: Raritan River Reach B

COMPARISON DATA

Col. 1 Col. 2 [11] Col. 3 [11] Col. 4 [11] 5 Col. 6 [11] 7 Col. 8 Col. 9 Col. 10 Col. 11 Col. 12 Col. 13 Col. 14 Col. 15 Col. 16 Col. 17 Col. 18 Col. 19 Col. 20

Sample I.D. Reference Reference Test Sed. [1] Test Sed. [1] Conv.Fac. Test Sed. Test Sed. Test Sed. Test Sed. Human Health Human Health Ecological clam/worm SS SS Carcinogenic BaP Tox. Equiv. BaP Tox. Equiv. Cancer (10E-4) Non-Cancer Background Background FDA Non-Specific Regional

(clam) (worm) (clam) (worm) [2] (clam) (worm) TEF [3] Conc.(clam)[4] Conc.(worm)[4] Level[5] Level (HQ=1) (clam) (worm) Limits [7] Effects Level Matrix [12] Compound (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg)[10] (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) (ug/Kg) PAHs Acenaphthene 0.194 0.185 9.92 * 9.52 * 1/1 9.92 9.52 8,775,000 8.1 0.5 [15] Acenapthylene 0.153 0.087 0.682 * 0.345 * 1/1 0.682 0.345 [6] 4.6 1.3 [15] Anthracene 0.304 0.053 12.9 * 1.03 * 1/1 12.9 1.03 43,605,000 10.0 1.6 3,750 Fluorene 0.207 0.095 6.34 * 1.55 * 1/1 6.34 1.55 5,805,000 7.4 0.3 [15] Naphthalene 0.652 0.468 1.21 * 0.555 1/1 1.21 0.555 [6] 26.4 4.5 [15] Phenanthrene 1.31 0.465 38.4 * 5.15 * 1/1 38.4 5.15 43,605,000 32.7 4.7 [15] Benzo(a)anthracene* 0.909 0.126 29.6 * 1.98 * 2/2 59.2 3.96 0.1 5.92 0.396 [6] 25.1 4.8 [15] Benzo(a)pyrene* 0.916 0.081 14.4 * 1.28 * 2/2 28.8 2.56 1 28.8 2.560 [6] 24.2 7.6 8,000 [8] Benzo(g,h,i)perylene 0.542 0.089 7.24 * 0.974 * 3/3 21.7 2.92 [6] 22.2 7.6 [15] Benzo(b)fluoranthene* 1.38 0.089 25.2 * 2.07 * 2/2 50.4 4.14 0.1 5.04 0.414 [6] 40.6 16.5 [15] Benzo(k)fluoranthene* 1.26 0.114 16.6 * 2.14 * 2/2 33.2 4.28 0.01 0.332 0.043 [6] 81.6 5.6 [15] Chrysene* 1.58 0.047 38.1 * 2.10 * 2/2 76.2 4.20 0.001 0.0762 0.0042 [6] 29.4 6.7 [15] Dibenzo(a,h)anthracene* 0.133 0.093U 1.37 * 0.132 * 2/2 2.74 0.264 1 2.74 0.26 [6] 8.5 1.1 [15] Fluoranthene 2.82 0.40 140 * 54.8 * 1/1 140 54.8 1 5,805,000 43.8 10.6 [15] Indeno(1,2,3-cd)pyrene* 0.574 0.048 6.55 * 0.370 * 3/3 19.7 1.11 0.1 1.970 0.111 [6] 16.6 4.4 [15] Pyrene 3.05 0.403 154 * 63.4 * 1/1 154 63.4 4,387,000 51.3 26.6 [15]

TOTAL PAHs 655 160 45.9 3.8 2,000 (BaP eqv.) 432.7 104.60 40,000 [9]

PESTICIDES

Aldrin 0.027U 0.027U 0.028U 0.027U 2/2 0.056 0.054 33 167 0.9 0.1 300 299 [10] Dieldrin 0.018U 0.018U 0.280 * 0.38 * 2/2 0.560 0.760 65 518 0.1 300 4.37 [10] a-Chlordane 0.021U 0.021U 0.238 * 0.162 * 2/2 0.476 0.324 0.7 300 Trans nonachlor 0.027U 0.027U 0.029 0.136 * 2/2 0.058 0.272 0.5 Heptachlor 0.021U 0.021U 0.021U 0.021U 2/2 0.042 0.042 0.05 300 Heptachlor epoxide 0.033U 0.033U 0.033U 0.033U 1/1 0.033 0.033 0.2 300

Total Residual Chlordane/Heptachlor 0.609 0.671 114 135 1.7 64# [10]

Endosulfan I 0.03U 0.03U 0.03U 0.03U 1/1 0.030 0.030 [6] 0.2 Endosulfan II 0.033U 0.033U 0.032U 0.033U 1/1 0.032 0.033 [6] 0.1 Endosulfan sulfate 0.024U 0.024U 0.023U 0.024U 1/1 0.023 0.024 [6] 0.1 Total Endosulfans 0.085 0.087 87,000 0.4 2.86# [10]

4,4-DDT 0.024U 0.024U 0.023U 0.022U 11/11 0.253 0.242 0.6 1.0

2,4-DDT 0.07 0.033U 0.032U 0.032U 2/2 0.064 0.064 0.4

4,4-DDD 0.062 0.023 1.58 * 2.44 * 3/3 4.74 7.32 3.9

2,4-DDD 0.033U 0.033U 0.369 * 0.564 * 2/2 0.738 1.128 1.4

4,4-DDE 0.134 0.021U 6.46 * 3.40 * 2/2 12.9 6.80 3.5 4.3

2,4-DDE 0.018U 0.018U 0.967 * 0.378 2/2 1.93 0.756 0.1

Total DDT 20.6 16.3 11.1 40

TOTAL PCBs 3.30 10.3 94.5 * 109 * 1/2 94.5 218 106.6 88.1 2,000 100(clam) 113(worm) [18] 1,4-Dichlorobenzene 0.118 0.108 0.287 * 0.083 1/1 0.287 0.083 60,000 [6] 11,820 [10]

METALS (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) (mg/Kg) Arsenic 5.11 2.64 5.83 * 2.36 1/1 5.83 2.36 [17] [17] 4.89 12.6 [10] Cadmium 0.052 0.040 0.067 0.042 [16] 0.067 0.042 1.21 0.11 0.3 Chromium (total) 0.603 0.112 0.540 0.112 1/1 0.540 0.112 [6] 73 1.28 1.31 11.8 [10] Copper 1.69 1.56 3.12 * 1.19 1/1 3.12 1.19 [6] 540 5.58 2.78 9.6 [10] Lead 0.226 0.122 0.785 * 0.138 1/1 0.785 0.138 [6] 1.3 1.41 1.64 11.9 [10] Mercury 0.008 0.026 0.016 * 0.017 [16] 0.016 0.017 0.04 0.03 1 0.2 Nickel 0.627 0.196 0.549 0.188 1/1 0.549 0.188 [6] 290 1.10 0.77 3.8 [10] Silver 0.078 0.013 0.097 * 0.013 1/1 0.097 0.013 [6] 73 0.15 1.4 [10] Zinc 20.7 19.8 21.5 32.5 1/1 21.5 32.5 [6] 4,400 11.50 20.61 1,517 [10]

TABLE 1 (continued) Bioaccumulation Table for NY/NJ Harbor Projects, ALL VALUES ARE IN WET WEIGHT

COMPARISON DATA

Col. 1 Col. 2 Col. 3 Col. 4 [11] 5.00 Col. 6 [11] 7.00 Col. 8 Col. 9 Col. 10 Col. 11 Col. 12 Col. 13 Col. 14 Col. 15 Col. 16 Col. 17 Col. 18 Col. 19 Col. 20

Sample I.D. Reference Reference Test Sed. [1] Test Sed. [1] Conv.Fac. Test Sed. Test Sed. Test Sed. Test Sed. Human Health Human Health Ecological Regional clam/worm SS SS TEQ TEQ Cancer (10E-4) Non-Cancer Background Background FDA Non specific Dioxin

(clam) (worm) (clam) (worm) [2] (clam) (worm) TEF [3] (clam) (worm) Level Level (HQ=1) (clam) (worm) Limits [7] Effects Level Value Compound (pptr) (pptr) (pptr) (pptr) (pptr) (pptr) (pptr) (pptr) (pptr) (pptr)[10] TEQ (pptr) TEQ (pptr) (pptr) (pptr) (pptr)

DIOXINS

2,3,7,8,-TCDD 0.01U 0.057 0.221 * 0.588 * 1 0.221 0.588 1.73 2.50 1 [13]

1,2,3,7,8-PeCDD 0.014U 0.256U 0.018U 0.120 0.5 0.009 0.06 0.41 1,2,3,4,7,8-HxCDD 0.011U 0.014 0.027 * 0.017 0.1 0.003 0.0017 0.10 1,2,3,6,7,8-HxCDD 0.05 0.092 0.468 * 0.476 * 0.1 0.0468 0.0476 0.17 1,2,3,7,8,9-HxCDD 0.011U 0.01U 0.069 * 0.110 0.1 0.0069 0.011 0.08 1,2,3,4,6,7,8-HpCDD 0.060 1.49 2.15 * 1.68 * 0.01 0.0215 0.0168 0.13

OCDD 7.52 9.75 32.4 * 15.4 * 0.001 0.0324 0.0154 0.11

2,3,7,8-TCDF 0.01U 0.90 0.704 * 2.14 * 0.1 0.0704 0.214 0.27

1,2,3,7,8-PeCDF 0.01U 0.149 0.093 0.339 0.05 0.00465 0.01695 0.05 2,3,4,7,8-PeCDF 0.01U 0.280 0.105 0.606 * 0.5 0.0525 0.303 0.39 1,2,3,4,7,8-HxCDF 0.008U 0.005U 0.125 0.416 * 0.1 0.0125 0.0416 0.08 1,2,3,6,7,8-HxCDF 0.008U 0.026 0.057 0.039 0.1 0.0057 0.0039 0.09 1,2,3,7,8,9-HxCDF 0.009U 0.005U 0.009U 0.007U * 0.1 0.0009 0.0007 0.11 2,3,4,6,7,8-HxCDF 0.009U 0.020 0.022 0.087 0.1 0.0022 0.0087 0.08 1,2,3,4,6,7,8-HpCDF 0.243 0.573 0.747 * 0.730 0.01 0.00747 0.0073 0.04 1,2,3,4,7,8,9-HpCDF 0.052 0.005U 0.009U 0.014 0.01 0.00009 0.00014 0.02

OCDF 0.508 0.646 0.706 0.578 0.001 0.000706 0.000578 0.01

TEQs - non 2,3,7,8-TCDD 0.276716 0.749368 2.14 4.5 [14] TEQs (all) 0.497716 1.337368 1.73 4.64 10 [13]

PROJECT DATA

Project Data

VOLUME V

Statistical Analysis of Tissue Samples

M. nasuta

VOLUME VI

Statistical Analysis of Tissue Samples

N. virens