1-crackmaster-mastic-gray-cpt_SDS.pdf

SAFETY DATA SHEET

Issuing Date 30-June-2023 Revision Date Revision Number 0

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

GHS Product Identifier

Product Name: CrackMaster Mastic Gray- CPT

Other Means of Identification

Product Code(s): M1095L

Synonyms None

Recommended Use of the Chemical and Restrictions on Use

Recommended Use: Sealant

Uses Advised Against: No information Available

Supplier’s Details

Supplier Address

ThorWorks Industries, Inc 2520

S. Campbell St.

Sandusky, OH 44870

1-800-326-1994

Emergency Telephone Number

Emergency Telephone Number Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Carcinogenicity Category 1A

Hazards Not Otherwise Classified (HNOC)

Not applicable.

Label Elements

Danger

Hazard Statements

May cause cancer.

Precautionary Statements – Prevention

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood.

Wear protective gloves/clothing and eye/face protection.

Precautionary Statements – Response

IF exposed or concerned: Get medical advice/attention.

Precautionary Statements – Disposal

Dispose of contents/container to an approved waste disposal plant.

Other Information

Causes mild skin irritation.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance

Not applicable

Mixture

Chemical Name CAS Number Weight % Trade Secret

Quartz 14808-60-7 10-20 *

Limestone 1317-65-3 5-20 *

Petroleum Distillates, Hydrotreated

Heavy Paraffinic

64742-54-7 0-20 *

Titanium Dioxide 1343-67-7 0-15 *

Rubber 9006-04-6 0-6 *

Carbon Black 1333-86-4 0-6 *

Zinc Oxide 1314-13-2 0-0.75 *

Silica, Amorphous 7631-86-9 0-0.45 *

Phosphorus Pentoxide 1314-56-3 0-0.45 *

* The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

Description of First Aid Measures

General Advice IF exposed or concerned: Get medical advice/attention. Show this Safety Data Sheet to the doctor in attendance.

Inhalation Remove to fresh air.

Eye Contact Rinse thoroughly with plenty of water, also under the eyelids.

Skin Contact Wash skin with soap and water.

Ingestion Rinse mouth.

Most Important Symptoms and Effects, Both Acute and Delayed

Symptoms Prolonged contact may cause redness and irritation.

Effects of Exposure May cause cancer.

Indication of Any Immediate Medical Attention and Special Treatment Needed

Note to Physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media No information available.

Specific Hazards Arising from the

Chemical No information available.

Explosion Data

Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

Special Protective Equipment and

Precautions for Firefighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.

Use personal protection equipment.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures

Personal Precautions Ensure adequate ventilation

Other Information Refer to protective measures listed in Sections 7 and 8.

Methods and Material for Containment and Cleaning Up

Methods for Containment Prevent further leakage or spillage if safe to do so. Prevent materials or runoff from entering drains, sewers, streams, ground water or bodies of water. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.

Methods for Cleaning Up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material.

7. HANDLING AND STORAGE

Precautions for Safe Handling

Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Avoid with skin, eyes or clothing. Do not eat, drink or smoke when using this product.

Remove contaminated clothing and shoes.

Do not breathe dust/fume/gas/mist/vapors/spray. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.

Conditions for Safe Storage, Including Any Incompatibilities

Storage Conditions Store locked up. Keep container closed when not in use.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control Parameters

Exposure Limits The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this Safety Data Sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here.

Chemical Name ACGIH TLV OSHA PEL NIOSH Quartz

14808-60-7

TWA: 0.025 mg/m3 Respirable

Particulate Matter

TWA: 50 µg/m3 (Vacated)

TWA: 0.1 mg/m3 Respirable Dust

: (250) / (%SiO2 + 5) mppcf

TWA Respirable Fraction

: (10) / (%SiO2 + 2) mg/m3

TWA Respirable Fraction

IDLH: 50 mg/m3 Respirable Dust

TWA: 0.05 mg/m3 Respirable Dust

Limestone

1317-65-3

- TWA: 15 mg/m3 Total Dust

TWA: 5 mg/m3 Respirable

Fraction (Vacated)

TWA: 15 mg/m3 Total Dust

(Vacated)

TWA: 5 mg/m3 Respirable

Fraction

TWA: 10 mg/m3 Total Dust

TWA: 5 mg/m3 Respirable Dust

Titanium Dioxide

13463-67-7

TWA: 0.2 mg/m3 Nanoscale

Respirable Particulate Matter

TWA: 2.5 mg/m3 Finescale

Respirable Particulate Matter

TWA: 15 mg/m3 Total Dust

(Vacated)

TWA: 10 mg/m3 Total Dust

IDLH: 5,000 mg/m3

TWA: 2.4 mg/m3 CIB 63 Fine

TWA: 0.3 mg/m3 CIB 63 Ultrafine, Including Engineered Nanoscale

Rubber

9006-04-6

Dermal Sensitizer; Respiratory

Sensitizer

TWA: 0.0001 mg/m3 Inhalable

Allergenic Proteins Inhalable

Particulate Matter S*

Carbon Black

1333-86-4

TWA: 3 mg/m3 Inhalable

Particulate Matter

TWA: 3.5 mg/m3 (Vacated)

TWA: 10 mg/m3

IDLH: 1750 mg/m3

TWA: 3.5 mg/m3

TWA: 0.1 mg/m3 Carbon Black in

Presence of Polycyclic Aromatic

Hydrocarbons PAH

Zinc Oxide

1314-13-2

STEL: 10 mg/m3 Respirable

Particulate Matter

TWA: 2 mg/m3 Respirable

Particulate Matter

TWA: 5 mg/m3 Dust

TWA: 15 mg/m3 Total Dust

TWA: 5 mg/m3 Respirable

Fraction (Vacated)

TWA: 10 mg/m3 Total Dust

(Vacated)

TWA: 5 mg/m3 Respirable

Fraction (Vacated)

STEL: 10 mg/m3 Fume

IDLH: 500 mg/m3

Ceiling: 15 mg/m3 Dust

TWA: 5 mg/m3 Dust and Fume

STEL: 10 mg/m3 Fume

Silica, Amorphous

7631-86-9

- TWA: 50 µg/m3 Excludes

Construction Work, Agricultural

Operations, and Exposures That

Result from the Processing of

Sorptive Clays (Vacated)

TWA: 6 mg/m3 < 1% Crystalline

Silica

TWA: 20 mppcf

: (80) / (%SiO2) mg/m3 TWA

IDLH: 3,000 mg/m3

TWA: 6 mg/m3

Appropriate Engineering Controls

Engineering Controls Showers

Eyewash Stations

Ventilations Systems

Individual Protection Measures, Such as Personal Protective Equipment

Eye/Face Protection Wear safety glasses with side shields (or goggles).

Hand Protection Wear suitable gloves.

Skin and Body Protection Wear suitable protective clothing.

Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.

General Hygiene Considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and immediately after handling the product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties

Appearance: Gray Solid

Physical State Solid

Odor Bland

Odor Threshold No data available pH No data available pH (as Aqueous Solution) No data available

Melting Point / Freezing Point 65 – 122 °C / 149.0 – 251.6 °F

Initial Boiling Point and Boiling Point Range No data available

Flash Point > 210 °C / > 410.0 °F

Evaporation Rate No data available

Flammability No data available

Flammability Limit in Air

Upper Flammability or Explosive Limits

Lower Flammability or Explosive Limits No date available

Vapor Pressure No data available

Relative Vapor Density No data available

Relative Density No data available

Water Solubility No data available

Solubility(ies) No data available

Partition Coefficient No data available

Autoignition Temperature > 260 °C / > 500.0 °F

Decomposition Temperature No data available

Kinematic Viscosity

Dynamic Viscosity

No data available

No data available

Other Information

Explosive Properties No information available

Oxidizing Properties No information available

Softening Point No information available

Molecular Weight No information available

Liquid Density No information available

Bulk Density No information available

VOC Content No information available

10. STABILITY AND REACTIVITY

Reactivity None under normal use conditions.

Chemical Stability Stable under normal conditions.

Possibility of Hazardous Reactions None under normal processing.

Conditions to Avoid None known based on information supplied.

Incompatible Materials Strong oxidizing agents.

Hazardous Decomposition Products Aldehydes, polycyclic aromatic hydrocarbons, carbon monoxide, hydrogen sulfide, burning produces obnoxious and toxic fumes, carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke).

11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure

Product Information

Inhalation Specific test data for the substance or mixture is not available.

Eye Contact Specific test data for the substance or mixture is not available.

Skin Contact Causes mild skin irritation.

Ingestion Specific test data for the substance or mixture is not available.

Symptoms Related to the Physical and Toxicological Characteristics

Symptoms Prolonged contact may cause redness and irritation.

Acute Toxicity

Numerical Measures of Toxicity

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

Petroleum Distillates, Hydrotreated Heavy Paraffinic

64742-54-7

> 15 g/kg (Rat) > 5,000 mg/kg (Rabbit) -

Titanium Dioxide

13463-67-7

> 10,000 mg/kg (Rat) - = 5.09 mg/L (Rat) 4h

Carbon Black

1333-86-4

> 15,400 mg/kg (Rat) - > 4.6 mg/m3 (Rat) 4h

Zinc Oxide

1314-13-2

> 5,000 mg/kg (Rat) > 2,000 mg/kg (Rat) > 5,700 mg/m3 (Rat) 4h

Silica, Amorphous

7631-86-9

= 7,900 mg/kg (Rat) > 5,000 mg/kg (Rabbit) > 58.8 mg/L (Rat) 4h

Phosphorus Pentoxide

1314-56-3

- - = 1,217 mg/m3 (Rat) 1h

Delayed and Immediate Effects As Well As Chronic Effects From Short and Long-Term Exposure

Skin Corrosion/Irritation Classification based on data available for ingredients. Causes mild skin irritation.

Serious Eye Damage/Eye Irritation No information available.

Respiratory or Skin Sensitization No information available.

Germ Cell Mutagenicity No information available.

Carcinogenicity Contains a known or suspected carcinogen. Classification based on data available for ingredients. May cause cancer. This product contains titanium dioxide in a non-respirable form. Inhalation of titanium dioxide is unlikely to occur from exposure to this product. This product contains carbon black in a non-respirable form. Inhalation of carbon black is unlikely occur from exposure to this product. This product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to this product.

The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical Name ACGIH IARC NTP OSHA

Quartz

14808-60-7

A2 Group 1 Known X

Petroleum Distillates, Hydrotreated Heavy

Paraffinic

64742-54-7

A2 Group 1 Known X

Titanium Dioxide

13463-67-7

A3 Group 2B - X

Carbon Black

1333-86-4

A3 Group 2B - X

Silica, Amorphous

7631-86-9

- Group 3 Known X

Legend

ACGIH (American Conference of Governmental Industrial Hygienists)

A2 – Suspected Human Carcinogen

A3 – Animal Carcinogen

IARC (International Agency for Research on Cancer)

Group 1 – Carcinogenic to Humans

Group 2B – Possibly Carcinogenic to Humans

Group 3 – Not Classifiable as to Carcinogenicity in Humans

NTP (National Toxicology Program)

Known – Known Carcinogen

OSHA (Occupational Safety and Health Administration of the U.S. Department of Labor)

X – Present

Reproductive Toxicity Contains a known or suspected reproductive toxin. Classification based on data available for ingredients.

STOT – Single Exposure No information available.

STOT – Repeated Exposure No information available.

Target Organ Effects Respiratory system. Eyes. Skin. Lungs. Lymphatic System.

Aspiration Hazard No information available.

Other Adverse Effects No information available.

Interactive Effects No information available.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Chemical Name Algae/Aquatic Plants Fish Toxicity to

Mircoorganisms

Crustacea

Petroleum Distillates, Hydrotreated Heavy

Paraffinic

64742-54-7

- LC50: > 5,000 mg/L

(96h, Oncorhynchus

Mykiss)

- EC50: > 1,000 mg/L

(48h, Daphnia Magna)

Zinc Oxide

1314-13-2

- LC50: = 1.55 mg/L

(96h, Danio Rerio)

Silica, Amorphous

7631-86-9

EC50: = 440 mg/L

(72h, Pseudokirchneriella

Subcapitata)

LC50: = 5,000 mg/L

(96h, Brachydanio

Rerio)

- EC50: = 7,600 mg/L

(48h, Ceriodaphnia

Dubia)

Persistence and Degradability No information available.

Bioaccumulation No information available.

Other Adverse Effects No information available.

13. DISPOSAL CONSIDERATIONS

Disposal Methods

Waste From Residues/Unused Products Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.

Contaminated Packaging Do not reuse empty containers.

California Hazardous Waste Status This product contains one or more substances that are listed with the State of

California as a hazardous waste.

14. TRANSPORTATION INFORMATION

DOT Not regulated

IATA Not regulated

IMDG Not regulated

15. REGULATORY INFORMATION

International Inventories

Contact supplier for inventory compliance status.

U.S. Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical of chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

Chemical Name SARA 313 – Threshold Values %

Zinc Oxide – 1314-13-2 1.0%

SARA 311/312 Hazard Categories

Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate classifications.

CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and

40 CFR 122.42).

Chemical Name CWA – Reportable

Quantities

CWA – Toxic Pollutants CWA – Priority

Pollutants

CWA – Hazardous

Substances

Zinc Oxide 1314-13-2 - X - -

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive

Environmental Response Compensation and Liability ACT (CERCLA) (40 CFR 302) or the Superfund Amendments and

Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional or state level pertaining to releases of this material.

U.S. State Regulations

California Proposition 65

Chemical Name California Proposition 65

Silica, Amorphous – 7631-86-9 Carcinogen

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

Silica, Amorphous 7631-86-9 - X X

U.S. EPA Label Information

EPA Pesticide Registration Number Not applicable

16. OTHER INFORMATION

NFPA Health Hazards 0 Flammability 1 Instability 0 Special Hazards -

HMIS Health Hazards 1* Flammability 1 Physical Hazards 0 Personal Protection X

Chronic Hazard Star Legend * = Chronic Health Hazard

Key or Legend to Abbreviations and Acronyms Used in the Safety Data Sheet

Legend Section 8: Exposure Controls/Personal Protection

TWA TWA (Time-Weighted Average) STEL STEL(Short-Term Exposure Limit)

Ceiling Maximum Limit Value * Skin Designation

Key Literature References and Sources for Data Used to Compile the SDS

Agency for Toxic Substances and Disease Registry (ATSDR)

U.S. Environmental Protection Agency ChemView Database

European Food Safety Authority (EFSA)

Environmental Protection Agency (EPA)

Acute Exposure Guideline Level(s) (AGEL(s))

U.S. Environmental Protection Agency Federal Insecticide, Fungicide and Rodenticide Act

U.S. Environmental Protection Agency High Production Volume Chemicals

Food Research Journal

Hazardous Substance Database

International Uniform Chemical Information Database (IUCLID)

Jaan GHS Classification

Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS)

National Institute for Occupational Safety and Health (NIOSH)

National Library of Medicine’s ChemID Plus (NLM CIP)

National Library of Medicine’s PubMed Database (NLM PUBMED)

National Toxicology Program (NTP)

New Zealand’s Chemical Classification and Information Database (CCID)

Organization for Economic Cooperation and Development Environment, Health and Safety Publications

Organization for Economic Cooperation and Development High Production Volume Chemicals Program

Organization for Economic Cooperation and Development Screening Information Data Set.

World Health Organization (WHO)

Revision Date: 30-June-2023

Revision Note: No information available.

General Disclaimer

The information provided on this SDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.