ATTACHMENT 3.doc

ATTACHMENT 2

PRODUCT DATA SHEET (PDS)

MATERIAL SAFETY DATA SHEETS (MSDS)

DEC 2005

BASF Foam ISO MSDS

Bayer Acrylic Coating MSDS

Neogard Coating MSDS

BaySeal 2.0 Foam MSDS

United Coatings Diathon Basecoat MSDS

_1287338635.pdf

Material Name: EVERCOAT 500 White Article Number: 6663761

Page: 1 of 10 Report Version: 1.9

MATERIAL SAFETY DATA SHEET

1. Product and Company Identification

Product Name: EVERCOAT 500 White Material Number: 6663761 Chemical Family: Water-based Acrylic Coating

2. Hazards Identification

Emergency Overview

WARNING! Color: Milky White Form: liquid Odor: Ammonia.

May cause eye, skin, and respiratory tract irritation. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture. Harmful if inhaled. Contains material which may cause cancer.

Potential Health Effects

Primary Routes of Entry: Skin Contact, Eye Contact, Ingestion, Inhalation

Medical Conditions Aggravated by Exposure:

Skin disorders, Respiratory disorders, Eye disorders

HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE

Inhalation Acute Inhalation For Component: Limestone Causes respiratory tract irritation with symptoms of coughing, sore throat and runny nose. May cause mechanical irritation.

For Component: Titanium dioxide (Rutile) May cause mechanical irritation.

For Component: Zinc Oxide May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose.

For Component: 1,3-Benzenedicarbonitrile, 2,4,5,6-tetrachloro-

Baysystems North America Product Safety & Regulatory Affairs 100 Bayer Road Pittsburgh, PA 15205-9741

USA

CALL CHEMTREC: (800) 424-9300

INTERNATIONAL: (703) 527-3887

TRANSPORTATION EMERGENCY

NON-TRANSPORTATION

Bayer Emergency Phone: (412) 923-1800 Bayer Information Phone: (800) 662-2927

Page: 2 of 10 Report Version: 1.9

Expected to be highly toxic by inhalation.

For Component: Crystalline Quartz Silica May be harmful by inhalation. May cause mechanical irritation.

Chronic Inhalation For Component: Zinc Oxide May cause pulmonary edema with symptoms of breathing difficulty and tightness of chest.

Skin Acute Skin For Component: Limestone Causes irritation with symptoms of reddening, itching, and swelling. May cause mechanical irritation.

For Component: Titanium dioxide (Rutile) Not expected to be irritating.

For Component: Zinc Oxide May cause mechanical irritation.

For Component: Crystalline Quartz Silica May cause mechanical irritation.

Eye Acute Eye For Component: Limestone Causes irritation with symptoms of reddening, tearing, stinging, and swelling. May cause mechanical irritation.

For Component: Titanium dioxide (Rutile) Not expected to be irritating.

For Component: Zinc Oxide May cause mechanical irritation.

For Component: Crystalline Quartz Silica May cause mechanical irritation.

Ingestion Acute Ingestion For Component: Limestone Slightly toxic by ingestion.

For Component: Titanium dioxide (Rutile) Not expected to be harmful if swallowed.

For Component: Zinc Oxide Not expected to be harmful if swallowed.

For Component: Crystalline Quartz Silica Not expected to be harmful if swallowed.

General Effects of Exposure Acute Effects of Exposure For Component: Crystalline Quartz Silica Exposure to Silica, Quartz can cause a very serious lung disease called Silicosis with cough, shortness of breath, and changes in chest x-ray. The earliest symptoms of silicosis may include: Shortness of breath, Page: 3 of 10 Report Version: 1.9 coughing, wheezing, fatigue, chest pain, loss of appetite and fever.

Chronic Effects of Exposure For Component: Crystalline Quartz Silica Excessive exposure to airborne crystalline silica can cause fibrotic lung damage, with scarring of the lungs with cough and shortness of breath. This is called "Silicosis". This is generally a slowly developing fibrotic disease as symptoms are usually delayed for 10 years or more. Symptoms are dyspnea, chest pain, breathlessness, and cough. The chronic lung scarring developed from the silica dust causes a progressive massive fibrosis. This may lead to increased susceptibility to tuberculosis.

Carcinogenicity:

Titanium dioxide (Rutile) IARC - Overall evaluation: 2B Possible carcinogen.

1,3-Benzenedicarbonitrile, 2,4,5,6-tetrachloro-

IARC - Overall evaluation: 2B Possible carcinogen.

Crystalline Quartz Silica NTP - Hazard Designation: Known carcinogen.

IARC - Overall evaluation: 1 Human carcinogen.

Titanium dioxide (Rutile) IARC - Overall evaluation: 2B Possible carcinogen.

1,3-Benzenedicarbonitrile, 2,4,5,6-tetrachloro-

IARC - Overall evaluation: 2B Possible carcinogen.

Crystalline Quartz Silica NTP - Hazard Designation: Known carcinogen.

IARC - Overall evaluation: 1 Human carcinogen.

3. Composition/Information on Ingredients

Hazardous Components Weight % Components CAS-No.

20 - 30% Limestone 1317-65-3 3 - 7% Titanium dioxide (Rutile) 13463-67-7 1 - 5% Zinc Oxide 1314-13-2

0.1 - 1% 1,3-Benzenedicarbonitrile, 2,4,5,6-tetrachloro- 1897-45-6

0.1 - 1% Crystalline Quartz Silica 14808-60-7

4. First Aid Measures

Eye Contact In case of contact, flush eyes with plenty of lukewarm water. Get medical attention if irritation develops.

Skin Contact In case of skin contact, wash affected areas with soap and water. Immediately remove contaminated clothing and shoes. Get medical attention if irritation develops and persists.

Inhalation If inhaled, remove to fresh air. Get medical attention if irritation develops.

Ingestion If ingested, do not induce vomiting unless directed to do so by medical personnel. Get medical attention.

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5. Fire-Fighting Measures

Suitable Extinguishing Media: All extinguishing media are suitable.

Special Fire Fighting Procedures Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture.

Unusual Fire/Explosion Hazards Toxic and irritating gases/fumes may be given off during burning or thermal decomposition.

6. Accidental release measures

Spill and Leak Procedures Cleanup personnel must use appropriate personal protective equipment. Cover spill with inert material (e.

g., dry sand or earth) and collect for proper disposal.

7. Handling and Storage

Storage Temperature:

minimum: 1 °C (33.8 °F) maximum: 49 °C (120.2 °F)

Handling/Storage Precautions Avoid breathing dust, vapor, or mist. Avoid contact with skin or clothing. Avoid contact with eyes. Use only with adequate ventilation/personal protection. Wash thoroughly after handling. Keep container closed when not in use. Protect from freezing.

Further Info on Storage Conditions None known.

8. Exposure Controls / Personal Protection

Limestone (1317-65-3)

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) PEL: 5 mg/m3 (Respirable fraction.)

PEL: 15 mg/m3 (Total dust.)

Titanium dioxide (Rutile) (13463-67-7)

US. ACGIH Threshold Limit Values Time Weighted Average (TWA): 10 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) PEL: 15 mg/m3 (Total dust.)

Hazard Designation: Group A4 Not classifiable as a human carcinogen.

Zinc Oxide (1314-13-2)

Page: 5 of 10 Report Version: 1.9

Time Weighted Average (TWA): 2 mg/m3 (Respirable fraction.)

US. ACGIH Threshold Limit Values Short Term Exposure Limit (STEL): 10 mg/m3 (Respirable fraction.)

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) PEL: 5 mg/m3 (Fume.)

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) PEL: 5 mg/m3 (Respirable fraction.)

PEL: 15 mg/m3 (Total dust.)

Crystalline Quartz Silica (14808-60-7)

Time Weighted Average (TWA): 0.025 mg/m3 (Respirable fraction.)

Hazard Designation: Group A2 Suspected human carcinogen.

Industrial Hygiene/Ventilation Measures General dilution and local exhaust as necessary to control airborne vapors, mists, dusts and thermal decomposition products below appropriate airborne concentration standards/guidelines.

Respiratory Protection In case of insufficient ventilation wear suitable respiratory equipment.

Hand Protection Permeation resistant gloves.

Eye Protection splash proof goggles.

Skin and body protection Wear cloth work clothing including long pants and long-sleeved shirts.

Additional Protective Measures Employees should wash their hands and face before eating, drinking, or using tobacco products. Educate and train employees in the safe use and handling of this product. Emergency showers and eye wash stations should be available.

9. Physical and chemical properties

Form: liquid Color: Milky White Odor: Ammonia pH: 9 - 9.8 Freezing Point: 0 °C (32 °F) similar to water Boiling Point/Range: 100 °C (212 °F) similar to water Flash Point: Not applicable (water based product), however, solid material will support combustion if water has been evaporated.

Lower Explosion Limit: not applicable Upper Explosion Limit: not applicable Vapor Pressure: 17 mmHg @ 20 °C (68 °F) similar to water Viscosity, Dynamic: 10,000 cP

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10. Stability and Reactivity

Hazardous Reactions Hazardous polymerization does not occur.

Stability Stable

Materials to avoid None known.

Hazardous decomposition products By Thermal Decomposition: Acrylic monomers, other potentially toxic fumes

11. Toxicological Information

Toxicity Data for Limestone Acute Oral Toxicity LD50: 6,450 mg/kg (Rat)

Skin Irritation rabbit, Draize, Exposure Time: 24 hrs, Moderately irritating

Eye Irritation rabbit, Draize, Exposure Time: 24 hrs, Severely irritating

Toxicity Data for Aluminum hydroxide Acute Oral Toxicity LD50: > 5,000 mg/kg (Rat)

Skin Irritation rabbit, OECD Test Guideline 404, Non-irritating

Eye Irritation rabbit, OECD Test Guideline 405, No eye irritation

Repeated Dose Toxicity 28 Days, NOAEL: 14,470 ppm, (rat)

Developmental Toxicity/Teratogenicity rat, female, oral, NOAEL (teratogenicity): 1,000 mg/kg, No Teratogenic effects observed at doses tested. No fetotoxicity observed at doses tested.

Toxicity Data for Titanium dioxide (Rutile) Acute Oral Toxicity LD50: > 5,000 mg/kg (Rat)

Acute Inhalation Toxicity LC0: > 6.82 mg/l, dust/particulate, 4 hrs (Rat)

Acute dermal toxicity LD50: > 5,000 mg/kg (rabbit)

Skin Irritation rabbit, Exposure Time: 24 hrs, Non-irritating

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Eye Irritation rabbit, Draize, Non-irritating

Sensitization dermal: non-sensitizer (Guinea pig, Maximization Test) dermal: non-sensitizer (Human, Patch Test)

Repeated Dose Toxicity 28 Days, inhalation: NOAEL: 35 mg/m3, (Rat)

Mutagenicity Genetic Toxicity in Vitro:

Ames: negative (Salmonella typhimurium, Metabolic Activation: with/without) Genetic Toxicity in Vivo:

Drosophila SLRL test: negative (Drosophila melanogaster)

Carcinogenicity Rat, Male/Female, inhalation, According to IARC, several rat inhalation and intratracheal installation studies using titanium dioxide have shown increases in benign and malignant lung tumors. Reviewed human exposure data did not suggest an association between occupational exposure to titanium dioxide and risk for cancer. Additionally, the IARC working group determined that, #No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium dioxide is bound to other material, such as in paints."

Toxicity Data for Zinc Oxide Acute Oral Toxicity LD50: > 5,000 mg/kg (Rat)

Acute Inhalation Toxicity LC50: 2,500 mg/m3, (mouse)

Skin Irritation rabbit, Draize, Exposure Time: 24 hrs, Non-irritating

Eye Irritation rabbit, Draize, Slightly irritating

Mutagenicity Genetic Toxicity in Vitro:

Ames: negative (Salmonella typhimurium, Metabolic Activation: with/without) Mouse lymphoma assay: positive (Mouse lymphoma cells (L5178Y/TK), Metabolic Activation:

with/without)

Toxicity Data for Crystalline Quartz Silica Mutagenicity Genetic Toxicity in Vitro:

Ames: Negative results were reported in various in vitro studies. (Salmonella typhimurium, Metabolic Activation: with/without) Genetic Toxicity in Vivo:

Sister Chromatid Exchange: ambiguous (hamster)

Carcinogenicity rat, Male/Female, inhalation, 2 years, 6 hrs/day 5 days/week positive

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12. Ecological Information

Ecological Data for Limestone Biodegradation Not readily biodegradable.

Acute and Prolonged Toxicity to Fish LC50: 56,000 mg/l (Mosquitofish (Gambusia affinis), 48 hrs)

Ecological Data for Titanium dioxide (Rutile) Acute and Prolonged Toxicity to Fish LC0: > 1,000 mg/l (Golden orfe (Leuciscus idus), 48 hrs)

Acute Toxicity to Aquatic Invertebrates EC0: > 3 mg/l (Water flea (Daphnia magna))

Toxicity to Microorganisms EC0: > 10,000 mg/l, (Pseudomonas fluorescens, 24 hrs) EC0: > 5,000 mg/l, (Escherichia coli)

Ecological Data for 1,3-Benzenedicarbonitrile, 2,4,5,6-tetrachloro- Acute and Prolonged Toxicity to Fish LC50: 0.049 mg/l (Other fish)

Acute Toxicity to Aquatic Invertebrates EC50: 0.2 mg/l (Water flea (Daphnia magna))

13. Disposal considerations

Waste Disposal Method Waste disposal should be in accordance with existing federal, state and local environmental control laws.

Empty Container Precautions Recondition or dispose of empty container in accordance with governmental regulations. Do not reuse empty container without proper cleaning.

14. Transportation information

Land transport (DOT) Non-Regulated

Sea transport (IMDG) Non-Regulated

Air transport (ICAO/IATA)

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15. Regulatory Information

United States Federal Regulations

OSHA Hazcom Standard Rating: Hazardous

US. Toxic Substances Control Act: Listed on the TSCA Inventory.

US. EPA CERCLA Hazardous Substances (40 CFR 302):

Components Zinc Oxide Included in the regulation but with no data values. See regulation for further details

SARA Section 311/312 Hazard Categories:

Acute Health Hazard, Chronic Health Hazard

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A):

None

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required:

Components Zinc Oxide 1,3-Benzenedicarbonitrile, 2,4,5,6-tetrachloro-

US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous Wastes and Appendix VIII Hazardous Constituents (40 CFR 261):

If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40 CFR 261.20-24)

State Right-To-Know Information The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state.

Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists:

Weight % Components CAS-No.

>=1% Water 7732-18-5 20 - 30% Limestone 1317-65-3 >=1% Acrylic Polymer >=1% Aluminum hydroxide 21645-51-2 3 - 7% Titanium dioxide (Rutile) 13463-67-7 1 - 5% Zinc Oxide 1314-13-2

New Jersey Environmental Hazardous Substances List and/or New Jersey RTK Special Hazardous Substances Lists:

Weight % Components CAS-No.

1 - 5% Zinc Oxide 1314-13-2

0.1 - 1% Ethylene Glycol 107-21-1

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0.1 - 1% Ammonium Hydroxide 1336-21-6

MA Right to Know Extraordinarily Hazardous Substance List:

California Prop. 65:

Warning! This product contains chemical(s) known to the State of California to be Carcinogenic. - Developmental toxin. - Female reproductive toxin. - Male reproductive toxin.

<1 ppm Lead 7439-92-1 <1 ppm Cadmium 7440-43-9

16. Other Information

NFPA 704M Rating Health 1 Flammability 1 Reactivity 0 Other 0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme

HMIS Rating Health 1* Flammability 1 Physical Hazard 0 0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe

* = Chronic Health Hazard

The method of hazard communication for Baysystems North America is comprised of Product Labels and Material Safety Data Sheets. HMIS and NFPA ratings are provided by Baysystems North America as a customer service.

Contact Person: Product Safety Department Telephone: (412) 777-2835 MSDS Number: 000000005635 Version Date: 05/31/2007 Report Version: 1.9

This information is furnished without warranty, express or implied. This information is believed to be accurate to the best knowledge of Baysystems North America. The information in this MSDS relates only to the specific material designated herein. Baysystems North America assumes no legal responsibility for use of or reliance upon the information in this MSDS.

_1287338672.pdf

Material Name: BAYSEAL 2.0 Article Number: 6725023

Page: 1 of 11 Report Version: 1.7

1. Product and Company Identification

Product Name: BAYSEAL 2.0 Material Number: 6725023 Chemical Family: Polyol System

2. Hazards Identification

Emergency Overview

WARNING! Color: Amber, Brown Form: liquid Odor: slight, Ether, Amine.

May cause eye, skin, and respiratory tract irritation. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture. Vapor reduces oxygen available for breathing. May cause a temporary fogging of the eyes. May affect nervous system. May cause irregular heartbeat. May cause kidney damage. May cause liver damage.

Primary Routes of Entry: Skin Contact, Eye Contact, Inhalation

Medical Conditions Aggravated by Exposure:

Eye disorders, Respiratory disorders, Skin disorders

HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE

Inhalation Acute Inhalation For Component: Hydrofluorocarbon May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose. May induce cardiac arrhythmia (irregular heartbeat) in some individuals. Vapor can reduce oxygen available for breathing.

For Component: Chlorinated Phosphate Ester May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose.

For Component: Ethylene Glycol Causes respiratory tract irritation with symptoms of coughing, sore throat and runny nose. Inhalation of the

Baysystems North America Product Safety & Regulatory Affairs 100 Bayer Road Pittsburgh, PA 15205-9741

USA

CALL CHEMTREC: (800) 424-9300

INTERNATIONAL: (703) 527-3887

TRANSPORTATION EMERGENCY

NON-TRANSPORTATION

Bayer Emergency Phone: (412) 923-1800 Bayer Information Phone: (800) 662-2927

Page: 2 of 11 Report Version: 1.7 glycol component is unlikely due to the low vapor pressure. If misted or handled at elevated temperatures, high concentrations can produce irritation and/or difficulty breathing. May cause nervous system effects which can include symptoms of dizziness, incoordination, headache, numbness, and/or confusion. May induce cardiac arrhythmia (irregular heartbeat) in some individuals.

For Component: Tertiary Amine May cause pulmonary edema with symptoms of breathing difficulty and tightness of chest.

Skin Acute Skin For Component: Hydrofluorocarbon Slightly toxic by skin absorption. May cause slight irritation.

For Component: Chlorinated Phosphate Ester May cause slight irritation.

For Component: Tertiary Amine Corrosive with symptoms of reddening, itching, swelling, burning and possible permanent damage.

For Component: Ethylene Glycol If sufficient amounts are absorbed, systemic toxicity may occur with symptoms similar to those described in acute inhalation. May cause slight irritation.

For Component: Tertiary Amine Toxic by skin absorption.

Chronic Skin For Component: Tertiary Amine Repeated and prolonged contact may cause an allergic skin reaction in sensitive individuals.

Eye Acute Eye For Component: Hydrofluorocarbon May cause slight irritation.

For Component: Chlorinated Phosphate Ester Not expected to be irritating.

For Component: Tertiary Amine Corrosive with symptoms of reddening, tearing, swelling, burning and possible permanent damage.

For Component: Ethylene Glycol May cause slight irritation.

For Component: Tertiary Amine Corrosive with symptoms of reddening, tearing, swelling, burning and possible permanent damage.

Chronic Eye For Component: Tertiary Amine Prolonged vapor contact may cause conjuntivitis.

Ingestion Acute Ingestion For Component: Chlorinated Phosphate Ester May be harmful if swallowed. Symptoms of ingestion may include abdominal pain, nausea, vomiting, and diarrhea. Moderately toxic by ingestion.

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For Component: Ethylene Glycol May be fatal if swallowed. Symptoms of ingestion may include abdominal pain, nausea, vomiting, and diarrhea. May cause nervous system effects which can include symptoms of dizziness, incoordination, headache, numbness, and/or confusion.

For Component: Tertiary Amine Corrosive to the digestive tract with symptoms of burning and ulceration.

Chronic Ingestion For Component: Chlorinated Phosphate Ester May cause liver damage. May cause kidney damage.

For Component: Ethylene Glycol May cause blood disorders. May cause brain damage. May cause kidney damage. May cause liver damage.

May cause lung damage.

Carcinogenicity:

No Carcinogenic substances as defined by IARC, NTP and/or OSHA

3. Composition/Information on Ingredients

Hazardous Components

10 - 20% Hydrofluorocarbon 460-73-1 7 - 13% Chlorinated Phosphate Ester CAS# is a trade secret 3 - 7% Brominated Flame Retardant CAS# is a trade secret 3 - 7% Tertiary Amine CAS# is a trade secret 1 - 5% Ethylene Glycol 107-21-1 1 - 5% Tertiary Amine CAS# is a trade secret

4. First Aid Measures

Eye Contact In case of contact, flush eyes with plenty of lukewarm water. Get medical attention if irritation develops.

Skin Contact In case of skin contact, wash affected areas with soap and water. Immediately remove contaminated clothing and shoes. Get medical attention if irritation develops.

Inhalation If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration using a pocket mask type resuscitator. Get medical attention.

Ingestion If ingested, do not induce vomiting unless directed to do so by medical personnel. Get medical attention.

5. Fire-Fighting Measures

Suitable Extinguishing Media: carbon dioxide (CO2), dry chemical, foam, water spray for large fires.

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Special Fire Fighting Procedures Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Use cold water spray to cool fire-exposed containers to minimize risk of rupture.

6. Accidental release measures

Spill and Leak Procedures Cover spill with inert material (e. g., dry sand or earth) and collect for proper disposal. Use appropriate personal protective equipment during clean up. Evacuate and keep unnecessary people out of spill area.

7. Handling and Storage

Storage Temperature:

minimum: 7 °C (44.6 °F) maximum: 29 °C (84.2 °F)

Storage Period 6 Months

Handling/Storage Precautions Handle in accordance with good industrial hygiene and safety practices. Wash thoroughly after handling.

Keep container closed when not in use. Material is hygroscopic and may absorb small amounts of atmospheric moisture. If contamination with isocyanates is suspected, do not reseal containers. Avoid contact with eyes. Avoid contact with skin or clothing. Do not breathe vapours/dust.

8. Exposure Controls / Personal Protection

Ethylene Glycol (107-21-1)

Ceiling Limit Value: 100 mg/m3 (Aerosol.)

Hazard Designation: Group A4 Not classifiable as a human carcinogen.

Industrial Hygiene/Ventilation Measures Use local and general exhaust ventilation to control levels of exposure.

Respiratory Protection In case of insufficient ventilation wear suitable respiratory equipment.

Hand Protection Permeation resistant gloves.

Eye Protection Chemical safety goggles or safety glasses with side-shields.

Skin and body protection Wear cloth work clothing including long pants and long-sleeved shirts.

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Additional Protective Measures Employees should wash their hands and face before eating, drinking, or using tobacco products. Educate and train employees in the safe use and handling of this product.

9. Physical and chemical properties

Form: liquid Color: Amber, Brown Odor: slight, Ether, Amine pH: 9.6 Freezing Point: Not Established Boiling Point/Range: Not Established Flash Point: > 93.33 °C (> 200 °F) Vapor Pressure: Not Established Specific Gravity: Not Established Solubility in Water: Partially soluble Bulk Density: Not Established

10. Stability and Reactivity

Hazardous Reactions Hazardous polymerization does not occur.

Stability Stable

Materials to avoid oxidizing agents, Isocyanates

Hazardous decomposition products By Fire: Carbon Dioxide; Carbon Monoxide; other aliphatic fragments which have not been determined

11. Toxicological Information

Toxicity Data for Hydrofluorocarbon Acute Inhalation Toxicity LC50: >200,000 ppm, 4 h (Rat)

Acute dermal toxicity LD50: > 2,000 mg/kg (Rat)

Skin Irritation rabbit, Non-irritating

Eye Irritation rabbit, Mild eye irritation

Sensitization non-sensitizer (Dog)

Repeated Dose Toxicity

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28 d, inhalation: NOAEL: 50,000 ppm, (Rat) 90 d, Inhalation: NOAEL: 2000 ppm, (Rat)

Mutagenicity Genetic Toxicity in Vitro:

Cytogenetic assay: ambiguous (human lymphocytes, Metabolic Activation: with/without) Ames: negative (Metabolic Activation: with/without) Genetic Toxicity in Vivo:

Micronucleus Assay: negative (mouse)

Developmental Toxicity/Teratogenicity No Teratogenic effects observed at doses tested.

Toxicity Data for Chlorinated Phosphate Ester Acute Oral Toxicity LD50: 632 mg/kg (Rat)

Acute Inhalation Toxicity LC50: > 17,800 mg/l, aerosol, 1 hrs (rat, Male/Female)

Acute dermal toxicity LD50: > 5,000 mg/kg (rabbit, Male/Female)

Skin Irritation Human, Patch Test, No skin irritation rabbit, No skin irritation

Eye Irritation rabbit, Draize, Exposure Time: 24 hrs, Mild eye irritation rabbit, No eye irritation

Sensitization dermal: non-sensitizer (guinea pig, Maximisation Test (GPMT)) dermal: non-sensitizer (Human, Patch Test)

Repeated Dose Toxicity 90 Days, oral: NOAEL: 36 mg/kg, (Rat, male)

Mutagenicity Genetic Toxicity in Vitro:

Ames: negative (Salmonella typhimurium, Metabolic Activation: with/without) Positive and negative results were reported.

Mammalian cell - gene mutation assay: positive (Mouse lymphoma cells (L5178Y/TK), Metabolic Activation: with) Positive and negative results were reported.

Toxicity to Reproduction/Fertility Other method, inhalation, daily, (rat, male) Reproductive effects have been observed in animal studies.

Developmental Toxicity/Teratogenicity rat, female, oral, gestation, daily, NOAEL (teratogenicity): > 1%, NOAEL (maternal): > 1% No Teratogenic effects observed at doses tested. No fetotoxicity observed at doses tested.

Toxicity Data for Tertiary Amine Acute Oral Toxicity LD50: 2,000 - 5,000 mg/kg (rat)

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Acute dermal toxicity LD50: 1,000 - 2,000 mg/kg (rabbit)

Skin Irritation rabbit, Corrosive

Eye Irritation rabbit, Corrosive

Toxicity Data for Ethylene Glycol Acute Oral Toxicity LD50: 4,700 mg/kg (Rat)

Acute Inhalation Toxicity LC50: > 200 mg/m3, 2 hrs (rat)

Acute dermal toxicity LD50: 10,600 mg/kg (rabbit)

Skin Irritation rabbit, Draize Test, Slightly irritating

Eye Irritation rabbit, Draize Test, Slightly irritating

Repeated Dose Toxicity 16 Weeks, Inhalation: NOAEL: 3.49 mg/l, (Rat, Male/Female, daily)

Mutagenicity Genetic Toxicity in Vitro:

Ames: Negative results were reported in various in vitro studies. (Salmonella typhimurium, Metabolic Activation: with/without) Genetic Toxicity in Vivo:

Dominant Lethal Assay: negative (rat, male, oral) Drosophila SLRL test: positive (Drosophila melanogaster, ) Micronucleus Assay: negative (mouse, )

Carcinogenicity rat, oral, 2 years, daily Did not show carcinogenic effects in animal experiments.

mouse, dermal, lifetime, daily negative

Toxicity to Reproduction/Fertility Fertility Screening, oral, (mouse, Male/Female) NOAEL (parental): 2,500 mg/kg, NOAEL (F1): > 750 mg/kg, No effects on Reproductive parameters observed at doses tested.

Three generation study, oral, daily, (rat) NOAEL (parental): > 1,000 mg/kg, NOAEL (F1): > 1,000 mg/kg, NOAEL (F2): > 1,000 mg/kg, Developmental Toxicity/Teratogenicity rabbit, female, dermal, NOAEL (teratogenicity): approximately 2,000 mg/kg, NOAEL (maternal): > 1,000 mg/kg, Fetotoxicity has been observed in animal studies. Teratogenic effects have been observed in animal studies.

Rat, female, oral, NOAEL (teratogenicity): < 500 mg/kg, NOAEL (maternal): 1,000 mg/kg, Page: 8 of 11 Report Version: 1.7

Fetotoxicity has been observed in animal studies. Teratogenic effects have been observed in animal studies.

Toxicity Data for Tertiary Amine Acute Oral Toxicity LD50: 3,250 uL/kg (Rat) LD50: 2,800 mg/kg (Rat)

Acute dermal toxicity LD50: > 1,000 mg/kg (rabbit)

Skin Irritation rabbit, Corrosive

12. Ecological Information

Ecological Data for Hydrofluorocarbon Acute and Prolonged Toxicity to Fish LC50: > 97.9 mg/l (Rainbow trout (Salmo gairdneri), 48 h)

Acute Toxicity to Aquatic Invertebrates EC50: 81.8 mg/l (Water flea (Daphnia magna), 96 h)

Ecological Data for Chlorinated Phosphate Ester Biodegradation Aerobic, 0 %, Exposure time: 28 Days, Not readily biodegradable.

Bioaccumulation Carp, Exposure time: 42 Days, approximately 0.8 - 2.8 BCF

Acute and Prolonged Toxicity to Fish LC50: approximately 84 mg/l (Bluegill (Lepomis macrochirus), 96 hrs) LC50: 51 mg/l (Fathead minnow (Pimephales promelas), 96 hrs) LC50: 30 mg/l (Guppy (Poecilia reticulata), 96 hrs)

Acute Toxicity to Aquatic Invertebrates EC50: approximately 131 mg/l (Water flea (Daphnia magna), 48 hrs)

Toxicity to Aquatic Plants EC50: 45 mg/l, End Point: biomass (Green algae (Scenedesmus subspicatus), 72 hrs) EC50: 41 - 55 mg/l, End Point: biomass (Green algae (Selenastrum capricornutum), 96 h)

Toxicity to Microorganisms EC50: 295 mg/l, (Photobacterium phosphoreum, 30 min) EC50: 784 mg/l, (Activated sludge microorganisms, 3 hrs)

Ecological Data for Ethylene Glycol Biodegradation Aerobic, > 40 %, Exposure time: 20 Days

Biological Oxygen Demand (BOD) 5 Days, 0.78 - 1.81 g/g

Chemical Oxygen Demand (COD)

1.19 - 1.29 g/g

Page: 9 of 11 Report Version: 1.7

Theoretical Biological Oxygen Demand (ThBOD)

1.26 - 1.29 g/g

Bioaccumulation Golden orfe, Exposure time: 3 Days, 10 BCF

Acute and Prolonged Toxicity to Fish 41,000 mg/l (Coho salmon, silver salmon (Oncorhynchus kisutch), 96 hrs) LC50: 49,000 - 57,000 mg/l (Fathead minnow (Pimephales promelas), 96 hrs) LC50: 18,500 mg/l (Rainbow trout (Salmo gairdneri), 96 hrs)

Acute Toxicity to Aquatic Invertebrates EC50: 46,300 - 57,600 mg/l (Water flea (Daphnia magna), 48 hrs) EC50: 13,900 - 29,700 mg/l (Ceriodaphnia sp, 48 hrs)

Toxicity to Aquatic Plants EC50: 6,500 - 13,000 mg/l, End Point: growth (Green algae (Selenastrum capricornutum), 96 hrs)

Toxicity to Microorganisms EC50: 10,000 mg/l, (Pseudomonas putida, 16 hrs) EC50: 621 mg/l, (Photobacterium phosphoreum, 30 min)

13. Disposal considerations

Waste Disposal Method Waste disposal should be in accordance with existing federal, state and local environmental control laws.

Empty Container Precautions Recondition or dispose of empty container in accordance with governmental regulations.

14. Transportation information

Land transport (DOT)

Sea transport (IMDG) Non-Regulated

Air transport (ICAO/IATA) Proper Shipping Name: Aviation regulated liquid, n.o.s. (contains Hydrofluorocarbon) Hazard Class or Division: 9 UN-No: UN3334 Packaging Group:

Hazard Label(s): Miscellaneous

15. Regulatory Information

Page: 10 of 11 Report Version: 1.7

United States Federal Regulations

OSHA Hazcom Standard Rating: Hazardous

US. Toxic Substances Control Act: Listed on the TSCA Inventory.

US. EPA CERCLA Hazardous Substances (40 CFR 302):

Components Ethylene Glycol Reportable quantity: 5,000 lbs

SARA Section 311/312 Hazard Categories:

Acute Health Hazard, Chronic Health Hazard

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A):

None

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required:

Components Ethylene Glycol

US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous Wastes and Appendix VIII Hazardous Constituents (40 CFR 261):

If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40 CFR 261.20-24)

State Right-To-Know Information The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state.

Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists:

Weight % Components CAS-No.

>=1% Polyester Polyol 10 - 20% Hydrofluorocarbon 460-73-1 7 - 13% Chlorinated Phosphate Ester CAS# is a trade secret 3 - 7% Brominated Flame Retardant CAS# is a trade secret 3 - 7% Tertiary Amine CAS# is a trade secret 1 - 5% Ethylene Glycol 107-21-1

New Jersey Environmental Hazardous Substances List and/or New Jersey RTK Special Hazardous Substances Lists:

Weight % Components CAS-No.

1 - 5% Ethylene Glycol 107-21-1

Pennsylvania Right to Know Special Hazard Substance List:

Weight % Components CAS-No.

<0.075% 1,4-Dioxane 123-91-1

MA Right to Know Extraordinarily Hazardous Substance List:

<0.075% 1,4-Dioxane 123-91-1

Page: 11 of 11 Report Version: 1.7

California Prop. 65:

Warning! This product contains chemical(s) known to the State of California to be Carcinogenic.

Weight % Components CAS-No.

<0.075% 1,4-Dioxane 123-91-1 <15 ppb Formaldehyde 50-00-0

16. Other Information

NFPA 704M Rating Health 2 Flammability 1 Reactivity 0 Other 0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme

HMIS Rating Health 2* Flammability 1 Physical Hazard 0 0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe

* = Chronic Health Hazard

The method of hazard communication for Baysystems North America is comprised of Product Labels and Material Safety Data Sheets. HMIS and NFPA ratings are provided by Baysystems North America as a customer service.

Contact Person: Product Safety Department Telephone: (412) 777-2835 MSDS Number: 000000006390 Version Date: 02/06/2007 Report Version: 1.7

This information is furnished without warranty, express or implied. This information is believed to be accurate to the best knowledge of Baysystems North America. The information in this MSDS relates only to the specific material designated herein. Baysystems North America assumes no legal responsibility for use of or reliance upon the information in this MSDS.

_1287338929.pdf

M A T E R I A L S A F E T Y D A T A S H E E T

DIATHON BASECOAT 5'S

PRODUCT NAME: DIATHON BASECOAT 5'S

PRODUCT CODE: DI-BC-05

~~~~ SECTION 1 ~~~~ MANUFACTURER IDENTIFICATION ~ ~~~

Manufacturer's Name : UNITED COATINGS MANUFAC TURING CO Address : 19011 EAST CATALDO AVE.

: SPOKANE VALLEY, WASHING TON 99016-9423

: INITIAL(FIRST CALL)CHEM TREC(800)424-9300

INFORMATION PHONE : (509) 926-7143

TOLL FREE : BACK-UP(800)541-4383

DATE PRINTED : 10/28/2004

DATE REVISED : August 2004

~~~~ SECTION 2 ~~~~ HAZARDOUS INGREDIENTS/SARA III INFORMATION ~~~~

Reportable Components CAS Number MM HG @ Temp Weight %

CALCIUM CARBONATE 1317-65-3 N/A N/A 45

OSHA PEL-15MG/M3, TOTAL DUST, 5MG/M3, RESPIRAB LE DUST.

ACGIH TLV-10 MG/M3, TOTAL DUST CONTAINING NO A SBESTOS AND <1% FREE SILICA.

IF SILICA LEVELS ABOVE 1.0% ARE PRESENT, THE T LV VALUE IS O.1 MG OF

RESPIRABLE SILICA PER CU. METER FOR BOTH OSHA PEL AND ACGIH TLV.

Water 7732-18-5 UNK UNK 18 No OEL's Established

DI(HEPTYL, NONYL, UNDECYL) PHTHALATE68515-42-4 .300 356F180C 2

OSHA PEL: NOT EST., ACGIH TLV: NOT EST., STEL: NOT EST.

Titanium Dioxide 13463-67-7 N/A N/A 2 ACGIH total dust TLV-10mg/m3 OSHA Total Dust, 8 HR TWA, PEL-15 mg/m3, 5mg/m3 Respirable dust # Hydrous Magnesium Aluminum Silicate12174-11- 7 N/A N/A .3 OSHA PEL: 15 mg/m3 total dust, 5 mg/m3 respira ble dust, ACGIH TLV: 10 mg/m3 total dust

No toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372 are present in the product base.

NOTE: If tinted may contain Carbon Black CAS#1 333-86-4 AND/OR Crystalline Silica CAS#14808-60-7. If tinted D ARK GRAY or BLACK consider these levels to be reportable

This MSDS may be used for other colors and con tainer sizes of this product

~~~~ SECTION 3 ~~~~ HAZARDS IDENTIFICATION ~~~~

Eyes:

May result in irritation.

Skin:

Liquid material in contact with the skin may c ause irritation

Ingestion:

May cause abdominal pain, nausea and vomiting.

Inhalation:

It is possible to breathe this material under certain conditions of handling and use (for example, d uring heating, spraying, or stirring). Breathing small amoun ts of this material during normal handling is not likely to cause harmful effects.

Breathing large amounts may be harmful.Symptom s usually occur at air concentrations higher than the recommended exp osure limits.

Symptoms indicating over exposure include, but are not limited to, headache, nausea and irritation of the nose, t hroat and lungs.

~~~~ SECTION 4 ~~~~ FIRST AID MEASURES ~~~~

Eyes:

Immediately flush with copious amounts of wat er for at least 15 minutes. If redness, itching, or a bu rning sensation persist consult a physician or ophthalmologist immedia tely

Skin:

Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get medical attention if i rritation or other ill effects develop or persist.

Ingestion:

Do no induce vomiting. Never give anything by mouth to an unconscious person. Treat for shock. If uncons cious and vomiting, turn the person on their side to avoid choking

Inhalation:

Remove to fresh air. Get medical attention if ill effects persist

Note to Physician:

Treat according to person's condition and spec ifics of exposure

~~~~ SECTION 5 ~~~~ FIRE FIGHTING MEASURES ~~~~

Flammable Properties Flash Point: 440F/226.7C Lower Flammable Limits: N/A Upper Flammable Limit: N/A Auto Ignition Temperature:

Not determined Extinguishing Media:

Use extinguishing media appropriate for surrou nding fire Special Fire Fighting Procedures:

As in any fire, NIOSH approved (SCBA)self-cont ained breathing apparatus and protective clothing sh ould be worn.

Respiratory and eye protection required for fi re fighting personnel.

Full protective equipment should be used for a ll indoor fires and any significant outdoor fires. For small outdoor f ires, use of an SCBA may not be required.

Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool

~~~~ SECTION 6 ~~~~ ACCIDENTAL RELEASE MEASURES ~ ~~~

Small Spill:

Determine whether to evacuate or isolate the a rea according to your local emergency plan. Dike and absorb with inert material such as sand.

Large Spill:

Remove all liquid with the use of a vacuum sys tem. If unable to remove as a liquid, then begin to absorb wi th sand, saw dust or commercial absorbent, and scoop up and place i n containers for proper disposal.

~~~~ SECTION 7 ~~~~ HANDLING AND STORAGE ~~~~

Handling & Storage:

Use with adequate ventilation. Provide ventila tion during use to control exposure within Section 8 guide lines. If TLV's are exceeded use appropriate respiratory protectio n. Avoid eye contact.

Avoid skin contact. Do not breathe vapor. Keep container closed. Do not take internally.

Other Precautions:

Always obey hazard warnings and handle empty c ontainers as if they contained material. Follow all MSDS/la bel precautions even after container is emptied because it may reta in product residues.

Avoid prolonged or repeated breathing of vapor or spray mist. Use only in a well ventilated area. Keep out of th e reach of children.

Wash thoroughly after handling.

~~~~ SECTION 8 ~~~~ EXPOSURE CONTROLS/PERSONAL PR OTECTION ~~~~

Engineering Controls:

General and local exhaust ventilation is recom mended to maintain vapor exposures below recommended lim its. Where concentrations are above recommended limits as determined by air sampling or are unknown, appropriate respirato ry protection should be worn. Follow OSHA Respirator Regulations (29 C FR 1910.134) and use

NIOSH/MSHA

approved respirators.

In outside mixing and application operations, situate workers upwind of operation & provide airflow in a downwind d irection so as to carry fumes and residual spray away from workers. If there is a lack of air movement monitor for maximum exposure limits a s indicated in section 2 and if exceeded don appropriate Respiratory Equipment.

Respiratory Protection:

None required if area is adequately ventilated . Where overspray is present, if concentration of prod uct is not known or is above the exposure guidelines use NIOSH approv ed air-purifying respirator equipped with an ammonia/methylamin e cartridge(s). Follow OSHA regulation 29 CFR 1910.134 for respirator use.

Skin Protection:

Chemical protective gloves are recommended.

Eye Protection:

Safety glasses with side-shields Eye protecti on worn must be compatible with respiratory protection syst em employed.

~~~~ SECTION 9 ~~~~ PHYSICAL AND CHEMICAL PROPERT IES ~~~~

Boiling Range: 212F/100C - 2500-3000C Specific Gravity(H2O=1): 1.4594 Vapor Density(Air=1): Lighter than air.

Evaporation Rate(N-Butyl Acetate=1) : Slower t han ether.

Coating V.O.C.: 0.09 lb/gl Coating V.O .C.: 11 g/l Material V.O.C.: 0.05 lb/gl Material V. O.C.: 5 g/l Solubility in Water: Soluble.

Appearance: Highly thixotropic liquid. Various colors and textures Odor: Ammonia

~~~~ SECTION 10 ~~~~ STABILITY & REACTIVITY DATA ~~~~

Stability:

Stable.

Conditions To Avoid:

Extremely hot or cold temperatures and mixing/ applying in inadequately vented areas.

Incompatible Materials:

Avoid strong oxidizing agents such as liquid c hlorine, concentrated oxygen, sodium hypochlorite or ca lcium hypochlorite.

Hazardous Decomposition Products Thermal decomposition may yield carbon monoxid e and carbon dioxide. Unidentified organic compounds in fum es and smoke may be formed during combustion.

Hazardous Polymerization:

Will not occur.

~~~~ SECTION 11 ~~~~ TOXICOLOGICAL INFORMATION ~~ ~~

*Data is for individual components of preparat ion.

Materials having a known chronic/accute effect s on eyes:

Ammonia CAS# 1336-21-6: Draize test, rabbit, eye: 250 ug Severe

Materials having a known dermal toxicity.

Titanium Dioxide CAS#13463-67-7 Dermal LD50 ( rabbit) >10 g/kg

Materials having a known oral toxicity.TITANIU M DIOXIDE CAS#13463- 67-7 Oral LD50 (rat) >25 g/kg

DI(HEPTYL, NONYL, UNDECYL) PHTHALATE

CAS#68515-42-4 Oral LD50 (rat): > 6,400 mg/kg AMMONIA CAS#1336-21-6 Oral, rat: LD 50 = 350 mg/kg

Materials having a known Inhalation hazard:

TITANIUM DIOXIDE CAS#13463-67-7 LC50 (rat)>6.8 2 mg/l(4 hr) AMMONIA CAS# 1336-21-6: rat LC50: 2000 ppm/4- hr

2500-6500PPM: DANGEROUS FOR AS LITTLE AS 30 MI NUTES. 5000-10,000PPM:

RAPIDLY FATAL FOR SHORT EXPOSURES.

Identified Carcinogens/Longterm Effects:

NO ANIMAL DATA AVAILABLE

Identified Teratogens:

NO ANIMAL DATA AVAILABLE

Identified Reproductive toxins :

NO ANIMAL DATA AVAILABLE

Identified Mutagens:

NO ANIMAL DATA AVAILABLE

~~~~ SECTION 12 ~~~~ ECOLOGICAL INFORMATION ~~~~

Ecotoxicological effects on plants and animals :

AMMONIA CAS# 1336-21-6:This material is expec ted to be very toxic to aquatic life. The LC50/96-hour values for fish are less than 1 mg/l. The EC50/48-hour values for daphn ia are less than 1 mg/l.

Titanium Dioxide CAS#13463-67-7 96 Hr LC50 (Fa thead minnows)>1,000 mg/l

Chemical Fate :

NO DATA.

~~~~ SECTION 13 ~~~~ DISPOSAL CONSIDERATIONS ~~~~

Instructions:

Whatever cannot be saved for reuse should be t ransferred to an appropriate and approved waste disposal fac ility. Consult appropriate national, state and local regulato ry agencies to ascertain proper disposal procedures.

~~~~ SECTION 14 ~~~~ TRANSPORT INFORMATION ~~~~

Shipping Information:

DOT INFORMATION: 49 CFR 172.101

DOT DESCRIPTION: NOT HAZARDOUS

~~~~ SECTION 15 ~~~~ REGULATORY INFORMATION ~~~~

(Not meant to be all inclusive-selected regula tions represented) US Regulations:

Status Of Substances Lists:

The Concentrations Shown In Section II Are Max imum Ceiling Levels (Weight %) to be used for calculations for reg ulations.

A reportable quantity is a quantity of a hazar dous substance that triggers reporting requirements under the Comp rehensive Environmental Response Compensation And Liability Act (CERCL A).

If a spill of a substance exceeds it's reporta ble quantity (RQ) in CFR 302.3,Table 40 302.4 Appendix A & 302.4 Ap pendix B, the release must be reported to The National R esponse Center At (800) 424-8802, The State Emergency Respons e Commission (SERC), And community emergency coordinators l ikely to be affected.

Components present that could require reportin g under the statute are:

See sectionII for percentages *Toxic:Not reportable in quantities less than1 % Ammonia CAS#1336-21-6 RQ 1000 #

Superfund Amendments And Reauthorization Act O f 1986 (SARA) Title III Requires emergency planning based on the Thres hold Quantities(TPQ'S)and release reporting based on Reportable Quantiti es (RQ'S) In 40 CFR 355 Appendix A&B Extremely Hazardous Substances. T he emergency planning and release requirements of 40 CFR 355 apply to an y facility at which there is present any amount of any extremely hazardous substance(EHS) equal to or in excess of it's Threshold Planni ng Quantity(TPQ).

Components present that could require reportin g under the statute are:

None known.

EPCRA 40 CFR 372(Section 313) Requires EPA and the States to anually collect data on releases of certain to xic materials from industrial facilities, and make the data avail able to the public in the Toxics Release Inventory(TRI). This informatio n must be included in all MSDS'S that are copied and distributed or comp iled for this material.

Reporting Threshold: Standard: A facility must report if it manufactures (including imports) or processes 25,000 pounds or more or otherwise uses 10,000 pounds or more of a listed toxic chemic al during the calendar year.

Components present that could require reportin g under the statute are:

See Section II The components of this product are listed or e xcluded from listing on the US Toxic Substance Control Act (TSCA) chemical substance inventory.

Mixtures shall be assumed to present the same health hazards as do the Components Which Comprise One Percent(By Weigh t Or Volume) or greater of the Mixture,except that the mixture shall be assumed to present carcinogenic hazard if it has a component in c oncentrations of 0.1 percent greater.For a list of hazardous ingredients:

See Section II the remaining percentage of unspecified ingred ients, if any, are not contained in above DeMinimis concentrations an d/or are believed to be non-hazardous under the OSHA Hazard Communi cation Standard (29 CFR 1910.1200), and may consist of pigmen ts, fillers, defoamers, wetting agents, resins, dryers,anti-bacterial agents, water and/or solvents in varying concentrations.

International Regulations:

Canadian WHMIS:

This product is not a 'controlled product' und er the Canadian workplace hazardous materials informa tion system (WHMIS).

Canadian Environmental Protection Act (CEPA):

All of the components of this product are exem pt or listed on the DSL.See Section II For Composition/Info rmation on Ingredients

EINECS:

Calcium Carbonate CAS#1317-65-3 E INECS#:215- 665-4 Titanium Dioxide CAS#13463-67-7 E INECS#:236-675-5 Di(Heptyl,Nonyl,Undecyl)Phthalate CAS#68515-42 -4 EINECS#:Not listed Ammonia CAS#1336-21-6 EINECS#:215-647-6

State Regulations:

California:

California Proposition 65: The following State ment is made in order to comply with The California Safe Drinking Wa ter and Toxic Enforcement Act of 1986 "WARNING:This product contains the chemical(s) appearing below known to the State of California to:

A: Cause Cancer None known.

*If tinted contains Carbon Black:CAS#1333-86-4 and may also contain trace amounts of Crystalline Silica:CAS#14808-60-7 B: Cause Birth Defects or other Reproductive Harm :

None known.

In addition to the above named chemical(s)(if any),this product may contain trace amounts of chemicals, known to the State of California, to cause Cancer or Birth Defects and other Reproductive Harm Delaware:

Listed on the Delaware Air Quality Management List:

Ammonia CAS#7664-41-7 DR Q 100#

Florida:

None known.

Massachusetts:

Titanium Dioxide CAS#13463-67-7 Substance Cod es:4 Ammonia CAS#1336-21-6 Substance Co des: F8

Michigan:

None known Minnesota:

Titanium Dioxide CAS#13463-67-7 Listed In The Minnesota Hazardous Substances L ist:

Codes: A Hazards: -- Carcinogen? NO

New Jersey:

New Jersey Extraordinarily Hazardous Substance Ammonia CAS#1336-21-6 RTK Substance numbe r: 0084 NJ Threshold:19,000

New York:

Ammonia CAS#1336-21-6 RQ--Air 1000, RQ --Land 100 Pennsylvania:

Ammonia CAS#1336-21-6 Co de:E Titanium Dioxide CAS#13463-67-7 Co de:--

Washington:

Titanium Dioxide(Total Dust) CAS#13463-67-7 Washington Air Contaminant: ppm mg /Cubic Meter

TWA UNK 10

STEL UNK UN K

CEILING UNK UN K

SKIN:UNK

~~~~ SECTION 16 ~~~~ OTHER INFORMATION ~~~~

HMIS® III

Health : 2 Flammability : 0 Physical Hazard : 0 *Following Health rating Indicates Chronic/Car cinogenic Effects HMIS® III Personal Protection : I This rating is for the product as it is packag ed. This rating will need to be adjusted by the user based on conditions of use.

The information contained herein is furnished without warranty of any kind. Users should consider th ese data only as a supplement to other information gathered by th em & determine the suitability & completeness of information from all sources to assure proper use & disposal of these materials & the safety & health of employees & customersThe information contained herein relates only to the specific material identified.