1-Crafco-Mastic-Polypatch-and-Matrix-Safety-Data-Sheet.pdf

SAFETY DATA SHEET

1. Identification

Crafco Mastic and Matrix ProductsProduct identifier

None.Other means of identification

Pavement Patching and RepairRecommended use

None known.Recommended restrictions

Manufacturer/Importer/Supplier/Distributor information

Crafco, Inc.Manufacturer:

6165 West Detroit St.Address:

Chandler, AZ 85226 USA

Crafco Materials EngineeringContact Name:

602-276-0406Telephone:

sales@crafco.comE-mail:

800-424-9300 (North America)CHEMTREC:

+ 1-703-527-3887 (International)

2. Hazard(s) identification

Not classified.Physical hazards

Not classified.Health hazards

Not classified.Environmental hazards

Not classified.OSHA defined hazards

*Hazards not stated here are "Not classified", "Not applicable" or "Classification not possible".

Label elements

None.Hazard symbol

Signal word Not applicable.

Hazard statement Not applicable.

Precautionary statement

Prevention Not applicable.

Response Not applicable.

Storage Not applicable.

Disposal Not applicable.

Hazard(s) not otherwise classified (HNOC)

None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name Common name and synonyms

64742-52-5DISTILLATES (PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC

0 - 75

14808-60-7QUARTZ 0 - 75

8052-42-4ASPHALT 10 - 40

26.06Other components below reportable levels

471-34-1CALCIUM CARBONATE 0 - 10

4. First-aid measures

If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.

Call a physician if symptoms develop or persist. Get medical attention, if needed.

Inhalation

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Material name: Crafco Mastic and Matrix Products

5013 Version #: 01 Issue date: 05-11-2020

SDS US

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Thoroughly wash (or discard) clothing and shoes before reuse.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Get medical attention if irritation develops and persists.

Eye contact

Rinse mouth. Do not induce vomiting. Do not use mouth-to-mouth method if victim ingested the substance. Call a POISON CENTER or doctor/physician if you feel unwell.

Ingestion

Not available.Most important symptoms/effects, acute and delayed

In case of ingestion, the decision of whether or not to induce vomiting should be made by the attending physician. Certain pre-existing conditions may make workers particularly susceptible to the effects of this chemical: asthma, allergies, impaired pulmonary function.

Indication of immediate medical attention and special treatment needed

If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Discard any shoes or clothing items that cannot be decontaminated.

General information

5. Fire-fighting measures

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Addition of water or foam to the fire may cause frothing.

Suitable extinguishing media

Do not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing media

Fire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from the chemical

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters should wear full protective clothing including self contained breathing apparatus. Structural firefighters protective clothing will only provide limited protection.

Special protective equipment and precautions for firefighters

In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. ALWAYS stay away from tanks engulfed in flame. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. In the event of fire, cool tanks with water spray. By fire, toxic gases may be formed (COx, NOx). Keep run-off water out of sewers and water sources. Dike for water control.

Fire fighting equipment/instructions

In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with water spray. Use water spray to cool unopened containers.

Specific methods

6. Accidental release measures

Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during clean-up. Ventilate closed spaces before entering them. Do not touch or walk through spilled material.

Personal precautions, protective equipment and emergency procedures

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Dike far ahead of spill for later disposal. Following product recovery, flush area with water.

Never return spills in original containers for re-use.

Methods and materials for containment and cleaning up

Prevent further leakage or spillage if safe to do so. Runoff or release to sewer, waterway or ground is forbidden.

Environmental precautions

7. Handling and storage

The product is non-combustible. If heated, irritating vapors may be formed. Do not use in areas without adequate ventilation. Wash hands thoroughly after handling. Wash hands after handling.

Observe good industrial hygiene practices.

Precautions for safe handling

Store in a well-ventilated place. Keep the container tightly closed and dry. Store in a closed container away from incompatible materials. Keep out of the reach of children.

Conditions for safe storage, including any incompatibilities

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Material name: Crafco Mastic and Matrix Products

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) FormValueComponents Type

PEL 5 mg/m3 Respirable fraction.CALCIUM CARBONATE (CAS 471-34-1)

15 mg/m3 Total dust.

PEL 5 mg/m3 Mist.DISTILLATES

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

PEL 0.05 mg/m3 Respirable dust.QUARTZ (CAS 14808-60-7)

US. OSHA Table Z-3 (29 CFR 1910.1000) FormValueComponents Type

TWA 0.1 mg/m3 Respirable.QUARTZ (CAS 14808-60-7)

2.4 mppcf Respirable.

US. ACGIH Threshold Limit Values FormValueComponents Type

TWA 0.5 mg/m3 Inhalable fume.ASPHALT (CAS 8052-42-4)

TWA 5 mg/m3 Inhalable fraction.DISTILLATES

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

TWA 0.025 mg/m3 Respirable fraction.QUARTZ (CAS 14808-60-7)

US. NIOSH: Pocket Guide to Chemical Hazards FormValueComponents Type

Ceiling 5 mg/m3 Fume.ASPHALT (CAS 8052-42-4)

TWA 5 mg/m3 Respirable.CALCIUM CARBONATE (CAS 471-34-1)

10 mg/m3 Total

Ceiling 1800 mg/m3DISTILLATES

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

STEL 10 mg/m3 Mist.

TWA 350 mg/m3

TWA 0.05 mg/m3 Respirable dust.QUARTZ (CAS 14808-60-7)

No biological exposure limits noted for the ingredient(s).Biological limit values

Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded.

Appropriate engineering controls

Individual protection measures, such as personal protective equipment

Wear safety glasses; chemical goggles (if splashing is possible). Wear chemical goggles; face shield (if handling molten material).

Eye/face protection

Skin protection

Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style gloves.

Hand protection

Wear suitable protective clothing and eye/face protection. Use of an impervious apron is recommended.

Other

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Respiratory protection

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Material name: Crafco Mastic and Matrix Products

During product use, there is a risk of thermal burns.Thermal hazards

When using do not smoke. Avoid contact with eyes. Avoid contact with skin. Keep away from food and drink. Handle in accordance with good industrial hygiene and safety practice.

General hygiene considerations

9. Physical and chemical properties

Solid.Appearance

Solid.Physical state

Solid.Form

Black. Dark brownColor

Product is a black, semi-solid with a burnt tar odor.Odor

Odor threshold Not available.

pH Not available.

Melting point/freezing point 150 - 250 °F (65.56 - 121.11 °C) ASTM D36 Softening Point

Initial boiling point and boiling range

> 800 °F (> 426.67 °C)

Flash point > 400.0 °F (> 204.4 °C)

Evaporation rate Not available.

Not available.Flammability (solid, gas)

Upper/lower flammability or explosive limits

Flammability limit - lower

Not available.

Flammability limit -upper (%)

Not available.

Explosive limit - lower

Not available.

Explosive limit - upper

Not available.

Vapor pressure 4.07 hPa estimated

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature > 700 °F (> 371.11 °C)

Decomposition temperature Not available.

Viscosity Not available.

Other information

Density Not Available

Percent volatile 0 %

Specific gravity 1 - 2.2

10. Stability and reactivity

Not ReactiveReactivity

Material is stable under normal conditions.Chemical stability

Hazardous polymerization does not occur.Possibility of hazardous reactions

Strong oxidizing agents.Conditions to avoid

Incompatible with oxidizing agents.Incompatible materials

Upon decomposition, product emits acrid dense smoke with carbon dioxide, carbon monoxide, trace oxides of nitrogen and sulfur, and water.

Hazardous decomposition products

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Material name: Crafco Mastic and Matrix Products

11. Toxicological information

Information on likely routes of exposure

Inhalation May cause irritation to the respiratory system.

Skin contact Irritating to skin.

Eye contact Causes eye irritation. Molten material will produce thermal burns.

Ingestion May cause discomfort if swallowed. However, ingestion is not likely to be a primary route of occupational exposure.

Symptoms related to the physical, chemical and toxicological characteristics

Not available.

Information on toxicological effects

Acute toxicity

Test ResultsComponents Species

CALCIUM CARBONATE (CAS 471-34-1)

Oral

Acute

* Estimates for product may be based on additional component data not shown.

LD50 Rat 6450 mg/kg

Defats the skin. Causes irritation.Skin corrosion/irritation

Irritating to eyes.Serious eye damage/eye irritation

Respiratory or skin sensitization

Respiratory sensitization Not available.

Irritating to skin.Skin sensitization

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Germ cell mutagenicity

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. This product contains crystalline silica. Silica is a known carcinogen; however in this encapsulated form the normal routes of exposure are unavailable.

IARC Monographs. Overall Evaluation of Carcinogenicity

Not listed.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)

Not regulated.

US. National Toxicology Program (NTP) Report on Carcinogens

Not listed.

Contains no ingredient listed as toxic to reproductionReproductive toxicity

Specific target organ toxicity

- single exposure

Not available.

Specific target organ toxicity

- repeated exposure

Not available.

Aspiration hazard Not available.

Chronic effects Prolonged inhalation may be harmful. May cause eczema-like skin disorders (dermatitis).

12. Ecological information

This product has no known eco-toxicological effects. Not expected to be harmful to aquatic organisms.

Ecotoxicity

Components Test ResultsSpecies

* Estimates for product may be based on additional component data not shown.

CALCIUM CARBONATE (CAS 471-34-1)

Aquatic

LC50Fish > 56000 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis)

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Material name: Crafco Mastic and Matrix Products

Not available.Persistence and degradability

Not available.Bioaccumulative potential

Not available.Mobility in soil

Other adverse effects Not available.

13. Disposal considerations

Dispose of contents/container in accordance with local/regional/national/international regulations.

When this product as supplied is to be discarded as waste, it does not meet the definition of a RCRA waste under 40 CFR 261.

Disposal instructions

Not applicable.Hazardous waste code

Dispose of in accordance with local regulations.Waste from residues / unused products

Offer rinsed packaging material to local recycling facilities.Contaminated packaging

14. Transport information

DOT

Not regulated as dangerous goods.

IATA

Not regulated as dangerous goods.

IMDG

Not regulated as dangerous goods.

Not available.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not regulated as dangerous goods.General information

If the product is shipped at temperatures below 212°F (100°C), it is not regulated for transport by ground, air or vessel. If shipped above 212 deg F: "UN3257, Elevated Temperature Liquid, n.o.s.

(Asphalt mixture), 9, PG III"

Further information

15. Regulatory information

All components are on the U.S. EPA TSCA Inventory List.US federal regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)

QUARTZ (CAS 14808-60-7) Cancer lung effects immune system effects kidney effects

SARA 302 Extremely hazardous substance

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Not listed.

Specific target organ toxicity (single or repeated exposure)Classified hazard categories

SARA 313 (TRI reporting)

Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Not regulated.Safe Drinking Water Act

(SDWA)

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Material name: Crafco Mastic and Matrix Products

WARNING: This product contains a chemical known to the State of California to cause cancer.US state regulations

California Proposition 65

California Proposition 65 - CRT: Listed date/Carcinogenic substance

ASPHALT (CAS 8052-42-4) Listed: January 1, 1990

QUARTZ (CAS 14808-60-7) Listed: October 1, 1988

US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))

ASPHALT (CAS 8052-42-4)

DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC (CAS 64742-52-5)

QUARTZ (CAS 14808-60-7)

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

YesAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)

YesEurope European Inventory of Existing Commercial Chemical Substances

(EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

YesJapan Inventory of Existing and New Chemical Substances (ENCS)

YesKorea Existing Chemicals List (ECL)

YesNew Zealand New Zealand Inventory

YesPhilippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS)

YesTaiwan Taiwan Chemical Substance Inventory (TCSI)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

05-11-2020Issue date

Version # 01

HMIS® is a registered trade and service mark of the NPCA.Further information

Health: 0 Flammability: 0 Instability: 0

NFPA ratings

ACGIH

EPA: AQUIRE database US. IARC Monographs on Occupational Exposures to Chemical Agents HSDB® - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices

References

The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Disclaimer

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Material name: Crafco Mastic and Matrix Products

Product and Company Identification: Alternate Trade Names First-aid measures: Skin contact Fire-fighting measures: Specific hazards arising from the chemical Handling and storage: Conditions for safe storage, including any incompatibilities Exposure controls/personal protection: Appropriate engineering controls Physical & Chemical Properties: Multiple Properties Stability and reactivity: Reactivity Toxicological information: Carcinogenicity Transport information: Further information HazReg Data: International Inventories GHS: Classification

Revision information

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Material name: Crafco Mastic and Matrix Products