1-Crafco-HP-Concrete-Cold-Patch-Safety-Data-Sheet.pdf

SAFETY DATA SHEET

1. Identification

HP Concrete Cold PatchProduct identifier

None.Other means of identification

Pavement Patching and RepairRecommended use

None known.Recommended restrictions

Manufacturer/Importer/Supplier/Distributor information

Crafco, Inc.Manufacturer:

6165 West Detroit St.Address:

Chandler, AZ 85226 USA

Crafco Materials EngineeringContact Name:

602-276-0406Telephone:

sales@crafco.comE-mail:

800-424-9300 (North America)CHEMTREC:

+ 1-703-527-3887 (International)

2. Hazard(s) identification

Not classified.Physical hazards

Not classified.Health hazards

Not classified.Environmental hazards

Not classified.OSHA defined hazards

*Hazards not stated here are "Not classified", "Not applicable" or "Classification not possible".

Label elements

None.Hazard symbol

Signal word Not applicable.

Hazard statement Not applicable.

Precautionary statement

Prevention Not applicable.

Response Not applicable.

Storage Not applicable.

Disposal Not applicable.

Hazard(s) not otherwise classified (HNOC)

None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name Common name and synonyms

219714-96-2Granite 80 - 89

471-34-1Ground Limestone 0 - 10

64742-52-5DISTILLATES (PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC

0 - 5

64742-47-8DISTILLATES (PETROLEUM),

HYDROTREATED LIGHT

0 - 3

13463-67-7TITANIUM DIOXIDE 0 - 0.5

1333-86-4CARBON BLACK 0 - 0.3

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Material name: HP Concrete Cold Patch

5597 Version #: 05 Revision date: 05-29-2020 Issue date: 04-06-2015

SDS US

4. First-aid measures

If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.

Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention, if needed.

Inhalation

Immediately flush skin with plenty of water. Wash off with soap and plenty of water. Get medical attention if irritation develops and persists. Wash clothing separately before reuse.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Continue rinsing. Get medical attention if irritation develops and persists.

Eye contact

Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If ingestion of a large amount does occur, call a poison control center immediately.

Ingestion

Not available.Most important symptoms/effects, acute and delayed

Symptoms may be delayed. Treat symptomatically.Indication of immediate medical attention and special treatment needed

Use personal protective equipment appropriate for handling. Get medical attention if symptoms occur. Wash contaminated clothing before re-use.

General information

5. Fire-fighting measures

Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media

Do not use a solid water stream as it may scatter and spread fire. Straight Streams of WaterUnsuitable extinguishing media

Fire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from the chemical

Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Structural firefighters protective clothing will only provide limited protection.

Special protective equipment and precautions for firefighters

In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. In the event of fire, cool tanks with water spray. Water runoff can cause environmental damage.

Fire fighting equipment/instructions

In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with water spray. Use water spray to cool unopened containers.

Specific methods

6. Accidental release measures

Wear appropriate protective equipment and clothing during clean-up. Ventilate closed spaces before entering them. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapor, fumes, dust and/or mist from the spilled material.

Avoid skin contact and inhalation of vapors during disposal of spills.

Personal precautions, protective equipment and emergency procedures

Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust formation.

Following product recovery, flush area with water. Prevent product from entering drains.

Methods and materials for containment and cleaning up

No special environmental precautions required.Environmental precautions

7. Handling and storage

Keep formation of airborne dusts to a minimum. Avoid breathing dust/fume/gas/mist/vapors/spray.

Avoid contact with skin. Avoid contact with eyes. Use personal protective equipment as required.

Avoid prolonged exposure. When using, do not eat, drink or smoke. Wash thoroughly after handling. Avoid release to the environment. Do not empty into drains.

Precautions for safe handling

Keep away from heat and sources of ignition. Store in a well-ventilated place. Keep container tightly closed.

Conditions for safe storage, including any incompatibilities

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Material name: HP Concrete Cold Patch

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) FormValueComponents Type

PEL 3.5 mg/m3CARBON BLACK (CAS 1333-86-4)

PEL 5 mg/m3 Mist.DISTILLATES

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

PEL 5 mg/m3 Respirable fraction.Ground Limestone (CAS 471-34-1)

15 mg/m3 Total dust.

PEL 15 mg/m3 Total dust.TITANIUM DIOXIDE (CAS 13463-67-7)

US. OSHA Table Z-3 (29 CFR 1910.1000) FormValueComponents Type

TWA 5 mg/m3 Respirable fraction.TITANIUM DIOXIDE (CAS 13463-67-7)

15 mg/m3 Total dust.

50 mppcf Total dust.

15 mppcf Respirable fraction.

US. ACGIH Threshold Limit Values FormValueComponents Type

TWA 3 mg/m3 Inhalable fraction.CARBON BLACK (CAS 1333-86-4)

TWA 5 mg/m3 Inhalable fraction.DISTILLATES

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

TWA 10 mg/m3TITANIUM DIOXIDE (CAS 13463-67-7)

US. NIOSH: Pocket Guide to Chemical Hazards FormValueComponents Type

TWA 0.1 mg/m3CARBON BLACK (CAS 1333-86-4)

Ceiling 1800 mg/m3DISTILLATES

(PETROLEUM),

HYDROTREATED HEAVY

NAPHTHENIC (CAS

64742-52-5)

STEL 10 mg/m3 Mist.

TWA 350 mg/m3

TWA 100 mg/m3DISTILLATES

(PETROLEUM),

HYDROTREATED LIGHT

(CAS 64742-47-8)

TWA 5 mg/m3 Respirable.Ground Limestone (CAS 471-34-1)

10 mg/m3 Total

No biological exposure limits noted for the ingredient(s).Biological limit values

Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica should be monitored and controlled.

Exposure guidelines

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Material name: HP Concrete Cold Patch

Ensure adequate ventilation, especially in confined areas.Appropriate engineering controls

Individual protection measures, such as personal protective equipment

Avoid contact with eyes. Wear safety glasses with side shields (or goggles).Eye/face protection

Skin protection

Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style gloves.

Hand protection

Wear chemical protective equipment that is specifically recommended by the manufacturer. Apron and long sleeves are recommended.

Other

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Respiratory protection

Not available.Thermal hazards

When using do not smoke. Do not breathe dust. Avoid contact with eyes. Avoid contact with skin.

Avoid contact with clothing. Wash hands before breaks and immediately after handling the product.

Keep away from food and drink. Handle in accordance with good industrial hygiene and safety practice.

General hygiene considerations

9. Physical and chemical properties

Pellets.Appearance

Solid.Physical state

Solid.Form

Grey.Color

Hydrocarbon-like.Odor

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling range

Unknown

Flash point > 200.0 °F (> 93.3 °C) Cleveland Open Cup

Evaporation rate Not available.

Not available.Flammability (solid, gas)

Upper/lower flammability or explosive limits

Flammability limit - lower

0.7 % estimated

Flammability limit -upper (%)

5 % estimated

Explosive limit - lower

Not available.

Explosive limit - upper

Not available.

Vapor pressure 0.15 hPa estimated

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature Unknown

Decomposition temperature Not available.

Viscosity Not available.

Other information

Density 16.00 - 17.00 lb/gal

Percent volatile < 2 %

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Material name: HP Concrete Cold Patch

Specific gravity 2.00

10. Stability and reactivity

The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity

Stable under normal temperature conditions.Chemical stability

Hazardous polymerization does not occur.Possibility of hazardous reactions

Not known.Conditions to avoid

Oxidizing materials.Incompatible materials

Irritants. Upon decomposition, product emits acrid dense smoke with carbon dioxide, carbon monoxide, trace oxides of nitrogen and sulfur, and water.

Hazardous decomposition products

11. Toxicological information

Information on likely routes of exposure

Inhalation Inhalation of vapors/fumes generated by heating this product may cause respiratory irritation with throat discomfort, coughing or difficulty breathing.

Skin contact Causes mild skin irritation.

Eye contact Irritating to eyes.

Ingestion May cause discomfort if swallowed.

Symptoms related to the physical, chemical and toxicological characteristics

Not available.

Information on toxicological effects

Acute toxicity

Test ResultsComponents Species

CARBON BLACK (CAS 1333-86-4)

Oral

Acute

LD50 Rat > 8000 mg/kg

Ground Limestone (CAS 471-34-1)

Oral

Acute

* Estimates for product may be based on additional component data not shown.

LD50 Rat 6450 mg/kg

Not classified.Skin corrosion/irritation

Moderately irritating to the eyes. Not classified.Serious eye damage/eye irritation

Respiratory or skin sensitization

Respiratory sensitization Not classified.

Not classified.Skin sensitization

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Germ cell mutagenicity

Carcinogenicity This product contains components that may cause cancer, however, after formation this product is encapsulated and the normal routes of exposure are unavailable.

IARC Monographs. Overall Evaluation of Carcinogenicity

CARBON BLACK (CAS 1333-86-4) 2B Possibly carcinogenic to humans.

DISTILLATES (PETROLEUM), HYDROTREATED HEAVY

NAPHTHENIC (CAS 64742-52-5)

3 Not classifiable as to carcinogenicity to humans.

TITANIUM DIOXIDE (CAS 13463-67-7) 2B Possibly carcinogenic to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)

Not regulated.

US. National Toxicology Program (NTP) Report on Carcinogens

Not listed.

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Material name: HP Concrete Cold Patch

Not classified.Reproductive toxicity

Specific target organ toxicity

- single exposure

Not available.

Specific target organ toxicity

- repeated exposure

Not available.

Aspiration hazard Not available.

12. Ecological information

Not expected to be harmful to aquatic organisms.Ecotoxicity

Product Test ResultsSpecies

HP Concrete Cold Patch

Aquatic

LC50Fish 193.2066 mg/l, 96 hours estimatedFish

Components Test ResultsSpecies

DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8)

Aquatic

LC50Fish 2.9 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss)

* Estimates for product may be based on additional component data not shown.

Ground Limestone (CAS 471-34-1)

Aquatic

LC50Fish > 56000 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis)

Not available.Persistence and degradability

Not available.Bioaccumulative potential

Not available.Mobility in soil

Other adverse effects Not available.

13. Disposal considerations

Dispose of contents/container in accordance with local/regional/national/international regulations.

When this product as supplied is to be discarded as waste, it does not meet the definition of a RCRA waste under 40 CFR 261.

Disposal instructions

Not available.Waste from residues / unused products

Offer rinsed packaging material to local recycling facilities.Contaminated packaging

14. Transport information

DOT

Not regulated as dangerous goods.

IATA

Not regulated as dangerous goods.

IMDG

Not regulated as dangerous goods.

Not available.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

15. Regulatory information

This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

US federal regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

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Material name: HP Concrete Cold Patch

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)

Not regulated.

SARA 302 Extremely hazardous substance

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Not listed.

YesSARA 311/312 Hazardous chemical

Serious eye damage or eye irritationClassified hazard categories

SARA 313 (TRI reporting)

Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Not regulated.Safe Drinking Water Act

(SDWA)

WARNING: This product contains a chemical known to the State of California to cause cancer.US state regulations

California Proposition 65

California Proposition 65 - CRT: Listed date/Carcinogenic substance

CARBON BLACK (CAS 1333-86-4) Listed: February 21, 2003

TITANIUM DIOXIDE (CAS 13463-67-7) Listed: September 2, 2011

US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))

CARBON BLACK (CAS 1333-86-4)

DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC (CAS 64742-52-5)

DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8)

TITANIUM DIOXIDE (CAS 13463-67-7)

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

YesAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)

YesEurope European Inventory of Existing Commercial Chemical Substances

(EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

YesJapan Inventory of Existing and New Chemical Substances (ENCS)

YesKorea Existing Chemicals List (ECL)

YesNew Zealand New Zealand Inventory

YesPhilippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS)

YesTaiwan Taiwan Chemical Substance Inventory (TCSI)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

04-06-2015Issue date

05-29-2020Revision date

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Material name: HP Concrete Cold Patch

Version # 05

HMIS® is a registered trade and service mark of the NPCA.Further information

Health: 1 Flammability: 0 Instability: 0

NFPA ratings

ACGIH

EPA: AQUIRE database NLM: Hazardous Substances Data Base US. IARC Monographs on Occupational Exposures to Chemical Agents IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices

References

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Disclaimer

Physical & Chemical Properties: Multiple Properties GHS: Classification

Revision information

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Material name: HP Concrete Cold Patch