01_35_45.00_10_-_R0002.pdf

FY14 UH-60 Wash Apron 16027 Joint Base Lewis-McChord, WA W912DW-17-B-0013

SECTION TABLE OF CONTENTS

DIVISION 01 - GENERAL REQUIREMENTS

SECTION 01 35 45.00 10

CHEMICAL DATA QUALITY CONTROL

PART 1 GENERAL

1.1 REFERENCES

1.2 ACRONYMS

1.3 MEASUREMENT AND PAYMENT

1.4 CHEMISTRY REQUIREMENTS

1.4.1 Detergent Type and Wash Water Quality Parameters

1.4.2 Data Quality Objectives (DQO)

1.4.3 Sampling, Analysis and Measurement

1.4.3.1 Process Solid and Liquid Samples

1.5 SUBMITTALS

1.6 QUALIFICATIONS

1.6.1 Chemical Quality Control Officer

1.6.2 Project Chemist

1.6.3 Environmental Sampler

1.7 COORDINATION MEETING

PART 2 PRODUCTS

PART 3 EXECUTION

3.1 GENERAL REQUIREMENTS

3.2 QUALITY CONTROL PLAN

3.2.1 Additional Requirements

3.2.2 Chemistry Elements of the CQC Plan

3.2.2.1 Qualifications

3.2.2.2 Authority and Responsibility

3.3 SAMPLING AND ANALYSIS PLAN (SAP)

3.3.1 Field Sampling Plan (FSP)

3.3.2 Quality Assurance Project Plan (QAPP)

3.4 CHEMISTRY DATA PACKAGE

3.5 CONTROL OF CHEMICAL DATA QUALITY

3.6 ANALYTICAL TESTING LABORATORIES

3.6.1 Laboratory Analytical Requirements

3.6.2 Laboratory Performance

3.7 CHEMICAL DATA FINAL REPORT

3.8 DOCUMENTATION

3.9 NOTIFICATION OF NON-COMPLIANCE

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SECTION 01 35 45.00 10 Page 1 R0002

SECTION 01 35 45.00 10

CHEMICAL DATA QUALITY CONTROL

PART 1 GENERAL

1.1 REFERENCES

The publications listed below form a part of this specification to the extent referenced. The publications are referred to within the text by the basic designation only.

U.S. ARMY CORPS OF ENGINEERS (USACE)

EM 200-1-3 (2001) Engineering and Design -- Requirements for the Preparation of Sampling and Analysis Plans

EM 200-1-6 (1997) Environmental Quality -- Chemical Quality Assurance for HTRW Projects

ER 1110-1-263 (1998) Engineering and Design -- Chemical Data Quality Management for Hazardous, Toxic, Radioactive Waste Remedial Activities

U.S. ENVIRONMENTAL PROTECTION AGENCY (EPA)

EPA SW-846.3-3 (1999, Third Edition, Update III-A) Test Methods for Evaluating Solid Waste:

Physical/Chemical Methods

U.S. NATIONAL ARCHIVES AND RECORDS ADMINISTRATION (NARA)

WASHINGTON STATE ADMINISTRATIVE CODE (WAC)

WAC 173-340-820 Sampling and Analysis Plans

1.2 ACRONYMS

The definition of acronyms used by the Contractor that pertain to chemical data quality control shall be clearly defined for all contract related products and communications.

1.3 MEASUREMENT AND PAYMENT

Separate payment will not be made for providing and maintaining the chemical data quality requirements including the chemical data quality management, chemical data validation, minimum chemical data reporting requirements, and chemical data quality submittal requirements; these costs shall be included in the applicable unit prices or lump sum prices contained in the bidding schedule. Retesting and subsequent resampling will occur at the contractors expense.

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1.4 CHEMISTRY REQUIREMENTS

Chemical Data Quality Control (CDQC) shall be as defined in ER 1110-1-263;

this ER, which integrates USACE guidance on the subject, shall be supplemented by EM 200-1-6 for detail technical guidance on CDQC. Tables and charts defining Design Analysis (DA), ROD, and remedial technology specific chemistry shall be according to or consistent with EM 200-1-3.

1.4.1 Detergent Type and Wash Water Quality Parameters

The detergent utilized during the washing of UH-60 helicopters is MIL-PRF-85570E or Aviation NAV II. Specifications and chemical properties of the detergent are noted in the following link:

http://chemsol.com/wp-content/uploads/2013/10/MIL-PRF-85570.pdf

During washing operations of the helicopters, the mix of water to detergent is generally 2 liters in a 5 gallon bucket. This mix is applied via a long handled brush. Typically, 900 gallon of water is used during the washing of a helicopter. This results in an average mix of 2 liters of detergent with 905 gallons of water.

Two samples have indicated the following effluent wash water concentrations:

Analyte Sample 1 Sample 2 COD 1190mg/L 1150mg/L Cyanide 0.006mg/L ND Oil and Grease ND ND Gasoline Range Organics ND ND CLP TAL Metals Cr 20.5ug/L 16.8ug/L Cu 17.8ug/L 9.93ug/L Pb 1.49ug/L 1.32ug/L Zn 33.5ug/L 19.4ug/L Ag 0.154ug/L 0.188ug/L Ba 7.75ug/L 9.27ug/L Be ND 0.031ug/L Ca 11.700ug/L 11,500ug/L Co 1.08ug/L 0.517ug/L Fe 140ug/L 147ug/L Mn 1.49ug/L 6.35ug/L Mg 4,630ug/L 4,270ug/L Ni 7.93ug/L 3.85ug/L K 1,930ug/L 1,660ug/L Na 10,900ug/L 9,440ug/L V 1.45ug/L 1.35ug/L Ar 0.636ug/L 0.724ug/L Cd 249ug/L 87.2ug/L Hg ND ND Sb 1.5ug/L 1.32ug/L Al 112ug/L 111ug/L Ti 0.033ug/L 0.045ug/L Se ND ND

Where: ND = Non-detect, ug/L = micrograms per liter, mg/L = milligrams per liter

No further analysis on wash water has been conducted.

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Results indicate elevated Cadmium, Nickel, Sodium, Potassium, Chromium, and Zinc (0.5-10 times higher) in effluent wash water when evaluating results to runoff water. COD was ND in runoff water and 1,150 to 1,190 mg/L in the effluent wash water.

1.4.2 Data Quality Objectives (DQO)

Sample acquisition, chemical analysis and chemical parameter measurements shall be performed so that the resulting data meet and support data use requirements. The chemical data shall be acquired, documented within the contractor's sampling and analysis plan (SAP), verified and reported to ensure that the specified precision, accuracy, representativeness, comparability, completeness and sensitivity requirements are achieved.

1.4.3 Sampling, Analysis and Measurement

Influent (helicopter wash water) and effluent water (collected at nearby manhole) from the water treatment system shall be analyzed with three grab samples each for the following analytes: Total Suspended Solids (TSS), Oil and Grease, Arsenic, Cadmium, Chromium, Copper, Lead, Mercury, Nickel, Silver, and Zinc. These samples shall be analyzed using the following methods: EPA 160.2 for TSS, EPA 1664 for Oil and Grease, and EPA 200 for metals. The results shall be measured in micrograms per liter. Any exceedances of the effluent as noted in Section 22 00 00.01 PACKAGED AIRCRAFT WASH SYSTEM AND GENERAL PLUMBING, section 2.1.2Paragraph WATER TREATMENT SYSTEM shall require modification of the system and another water treatment test shall occur as described herein. This additional sampling and testing shall result in sampling and analysis at the expense to the contractor.

1.4.3.1 Process Solid and Liquid Samples

Process liquid samples shall be collected and analyzed and/or shipped to a primary laboratory according to the the Contractor's Sampling Analysis Plan.

1.5 SUBMITTALS

Government approval is required for submittals with a "G" designation;

submittals not having a "G" designation are for information only. When used, a designation following the "G" designation identifies the office that will review the submittal for the Government. Submit the following in accordance with Section 01 33 00 SUBMITTAL PROCEDURES:

SD-03 Product Data

Sampling and Analysis Plan; G

Submit no later than 30 days after receipt of notice to proceed.

SD-06 Test Reports

Chemistry Data Package

Chemical Data Final Report; G

Label each report with the contract number, project name, and location. Submit no later than 60 days after sample collection.

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1.6 QUALIFICATIONS

1.6.1 Chemical Quality Control Officer

As a minimum, the Contractor's Chemical Quality Control Officer shall have: a degree in Chemistry;with 2 years of field experience in standard analytical chemistry methods common for analyzing soil, water, air and other materials for chemical contamination assessment. The Chemical Quality Control Officer shall ensure that all chemistry related objectives including responsibilities for DQO definitions, sampling and analysis, project requirements for data documentation and validation, and final project reports are attained. The Chemical Quality Control officer need not be present onsite during routine sampling, but shall be available for consultation with Government and Contractor personnel.

1.6.2 Project Chemist

As a minimum, the Contractor's Senior Chemist shall have: a degree in Chemistry; 2 years of field experience in calibrating and operating various field monitoring devices; and 2 years of experience in the operation of an commercial laboratory with standard analytical chemistry methods common for analyzing soil, water, air and other materials for chemical contamination assessment, including data for hazardous waste manifesting. The project chemist shall ensure that all chemistry related goals of the program are attained. The project chemist shall be onsite during all sampling events and shall also be available for consultation with Government personnel.

1.6.3 Environmental Sampler

As a minimum, the Contractor's Environmental Sampler shall have: a degree in Chemistry, Environmental Science, Engineering, Geology, Hydrology, or a related field; 2 years of experience in the development and preparation of SAP and work plans; 2 years of experience in and knowledge of EPA methods for collecting environmental and hazardous waste samples. The Environmental Sampler shall collect all onsite samples. The Environmental Sampler shall review the sampling results, and provide recommendations for the Contractor's sampling program.

1.7 COORDINATION MEETING

After the preconstruction conference, before any sampling or testing, the Contractor and the Contracting Officer will meet at the construction site to discuss the CQC Plan and the SAP. The coordination meeting will be simultaneous to any CQC coordination meeting required in Section 01 45 00.00 10 QUALITY CONTROL unless otherwise indicated or directed. A list of definable features that involve chemical measurements shall be agreed upon. Management of the chemical data quality system including project DQO, project submittals, chemical data documentation, chemical data assessment, required sampling and analysis protocols, and minimum data reporting requirements shall be agreed upon. The meeting will serve to establish an interrelationship between the Contractor's chemical data quality management and Government chemical quality assurance requirements.

Minutes of the meeting will be documented by the Government and shall be signed by both the Contractor and the Contracting Officer. The minutes will include any or all unresolved chemical issues along with the conditions for resolution and will become a part of the contract file.

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PART 2 PRODUCTS

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PART 3 EXECUTION

3.1 GENERAL REQUIREMENTS

Provide chemical sample acquisition, sample analysis, instrumental measurements of chemical parameters for chemical data quality control. An effective chemical data quality control system shall be established that meets the requirements for the chemical measurement DQO applicable to the project. The system shall cover chemical measurements pertaining to and required for Contractor and subcontractor produced chemical data.

3.2 QUALITY CONTROL PLAN

3.2.1 Additional Requirements

In addition to the quality control requirements specified in Section 01 45 00.00 10 QUALITY CONTROL, the CQC Plan shall incorporate the qualifications, authority and responsibilities of all chemical quality management and support personnel. Chemical measurements including sampling and/or chemical parameter measurement will not be permitted to begin until after production and acceptance of the CQC Plan, and Government approval of the SAP.

3.2.2 Chemistry Elements of the CQC Plan

To cover contract related chemical measurements by the Contractor and all subContractors, the CQC Plan shall include the following as a minimum.

3.2.2.1 Qualifications

Names, education, experience qualifications, authorities, and decision-making responsibilities of all chemical quality management and support personnel. The CQC Plan shall contain a copy of a letter from the project QC manager designating and authorizing a Chemical Quality Control Officer and chemical quality control organization staff.

3.2.2.2 Authority and Responsibility

A diagram, flow chart, or figure clearly depicting the chemical data quality management and support staff and the authority and responsibility of each for chemical sampling and analysis, procedures for corrective actions, deliverables and submittals, deviations and changes, chemical quality documentation, data validation, minimum data reporting requirements, and DQO for chemical parameter measurement by the Contractor and subContractors. The contents of this section of the CQC Plan shall be included in the applicable "Project Organization" elements of the FSP and the QAPP.

3.3 SAMPLING AND ANALYSIS PLAN (SAP)

Prepare the SAP in accordance with CDQC requirements EM 200-1-3 and WAC 173-340-820. The SAP is a single document that contains two distinct elements: FSP and QAPP. The SAP confirms the Contractor's understanding of the contract requirements for chemical data quality control, and describes procedures for sample submittal for analysis, field chemical parameter

SECTION 01 35 45.00 10 Page 6 measurement, data documentation, data assessment and data reporting requirements. In the SAP, delineate the methods to be used to accomplish the chemical quality control items to assure accurate, precise, representative, complete, legally defensible and comparable data. Describe all chemical parameter measurements for all matrices for all phases of the remediation contract. As a single interrelated document, provide the SAP to field and laboratory personnel. Original/innovative approaches to chemical parameter measurements may be proposed for cost reduction and remediation efficiency by abbreviated sampling, contingency sampling and/or contingency analysis, onsite analytical services, equivalency or screening methods. Clearly identify the Contractor obtained laboratories. Address all levels of the investigation with enough detail to become a document which may be used as an audit guide for field and laboratory work. Furnish copies of the Government approved SAP to all laboratories and the Contractor's field sampling crew.

3.3.1 Field Sampling Plan (FSP)

The FSP contains necessary technical detail and direction for the field personnel to understand sampling and field measurement requirements. In the FSP provide a comprehensive description and full detail for personnel to perform all onsite activities required to attain project DQO, including:

locations of samples, sampling procedures for onsite and offsite chemical analysis, summaries of analyses to be performed on samples, shipment of samples for offsite analyses, data documentation and reporting requirements.

3.3.2 Quality Assurance Project Plan (QAPP)

The QAPP contains necessary technical detail and direction for field and laboratory personnel to understand project sample analysis, quality control and data reporting requirements, analytical methods, required detection limits, QC requirements, and data validation and reporting requirements.

3.4 CHEMISTRY DATA PACKAGE

Provide the chemistry data package through USACE Contracting Officer at when the analysis of the samples have been finalized.

The chemistry data package contains information to demonstrate that the project's DQO have been fulfilled. The QA function will assess the Contractor's compliance with the SAP, and will recommend corrective action as necessary.

3.5 CONTROL OF CHEMICAL DATA QUALITY

Contractor chemical data quality control ensures that a quality control program is in place that assures sampling and analytical activities and the resulting chemical parameter measurement data comply with the DQO and the requirements of the SAP. Utilize the three-phase control system that includes a preparatory, initial and follow-up phase for each definable feature of work. The three-phase chemical data control process must ensure that data reporting requirements are achieved and shall be implemented according to Section 01 45 00.00 10 QUALITY CONTROL. Combine the three-phase chemical data control process with that under Section

01 45 00.00 10 QUALITY CONTROL.

3.6 ANALYTICAL TESTING LABORATORIES

Propose the analytical laboratories to be used for the primary samples

SECTION 01 35 45.00 10 Page 7 analyses. Laboratory validation requirements shall be in accordance with paragraph Laboratory Validation Requirements. The Contractor may utilize its own laboratory or utilize subcontract laboratories to achieve the primary required sample analyses.

3.6.1 Laboratory Analytical Requirements

Provide the specified chemical analyses by the Contractor's laboratory.

Provide chemical analyses to achieve the project DQO for all parameters specified by the methods. To give the USACE programs the greatest flexibility in the execution of its projects, the EPA SW-846.3-3 methods are generally the methods employed for the analytical testing of environmental samples. These methods are flexible and shall be adapted to individual project-specific requirements.

3.6.2 Laboratory Performance

Provide continued acceptable analytical performance and shall establish a procedure to address data deficiencies noted by review and/or quality assurance sample results. Provide and implement a mechanism for providing analytical labs with the SAP or QAPP portion of the SAP, for monitoring the lab's performance and for performing corrective action procedures.

3.7 CHEMICAL DATA FINAL REPORT

The CDFR shall be produced including a summary of quality control practices employed and all chemical parameter measurement activities after project completion. As a minimum, the CDFR shall contain the following:

a. Summary of project scope and description.

b. Summary of any deviations from the design chemical parameter measurement specifications.

c. Summary of chemical parameter measurements performed as contingent measurements.

d. Summary discussion of resulting data including achieving data reporting requirements.

e. Summary of achieving project specific DQO.

f. Presentation and evaluation of the data to include an overall assessment on the quality of the data for each method and matrix.

g. Internal QC data generated during the project, including tabular summaries correlating sample identifiers with all blank, matrix spikes, surrogates, duplicates, laboratory control samples, and batch identifiers.

h. A list of the affected sample results for each analyte (indexed by method and matrix) including the appropriate data qualifier flag (J, B, R, etc.), where sample results are negatively impacted by adverse quality control criteria.

i. Summary of field and laboratory oversight activities, providing a discussion of the reliability of the data, QC problems encountered, and a summary of the evaluation of data quality for each analysis and matrix as indicated by the laboratory QC data and any other relevant

SECTION 01 35 45.00 10 Page 8 findings.

j. Conclusions and recommendations. This section of the CDFR shall determine whether the water treatment system (WTS) has met the required water quality standards. If the WTS was unable to do so recommendations on how to met these requirements shall be provided.

k. The appendix will contain: (1) Chemistry data package from the contractor's labrotory.

3.8 DOCUMENTATION

Documentation records shall be provided as factual evidence that required chemical data has been produced and chemical data quality has been achieved. The documentation shall comply with the requirements specified in paragraphs SAMPLING AND ANALYSIS PLAN, CHEMISTRY DATA PACKAGE, and

CHEMICAL DATA FINAL REPORT.

3.9 NOTIFICATION OF NON-COMPLIANCE

The Contracting Officer will notify the Contractor of any detected noncompliance with the foregoing requirements. Take immediate corrective action after receipt of such notice.

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