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ATTACHMENT 3: CHEMICAL PARAMETERS, METHODOLOGIES AND QUANTITATION LIMITS
Parameter Methodology Reference Reporting Limit
| Dioxins/Furans | | HRGC/HRMS | EPA RM 23 and 0023A/8290 | see Table 1 below |
| (17 plus totals) | | | |
Metals (see table 2 below) ICP/MS EPA RM 29/6010B or C, or 6020 or A see Table 2 below
Mercury CVAA EPA RM 29/7470A or B see Table 2 below
HCl/Chlorine IC EPA RM26A see Table 3 below
Semivolatiles GC/MS EPA 0010/3542/8270C or D see Table 4 below
Semivolatiles GC/MS TO-13A
IMPORTANT!! In the event improvements or modifications are made to reference methodologies, Contractor shall incorporate these changes during the lifetime of the contract. The Contractor MUST also notify the COR of all changes.
Table 1. PCDD/PDCF1 Analyte List Reporting Limits
| ANALYTE |
| REPORTING LIMIT (pg/sample)2 |
| 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD), 1746-01-6 |
| 20 |
| 1,2,3,7,8-pentachlorodibenzo-p-dioxin (1,2,3,7,8-PeCDD), 40321-76-4 |
| 20 |
| 1,2,3,6,7,8-hexachlorodibenzo-p-dioxin (1,2,3,6,7,8-HxCDD), 57653-85-7 |
| 20 |
| 1,2,3,4,7,8-hexachlorodibenzo-p-dioxin (1,2,3,4,7,8-HxCDD), 39227-28-6 |
| 20 |
| 1,2,3,7,8,9-hexachlorodibenzo-p-dioxin (1,2,3,7,8,9-HxCDD), 19408-74-3 |
| 20 |
| 1,2,3,4,6,7,8-heptachlorodibenzo-p-dioxin (1,2,3,4,6,7,8-HpCDD), 35822-46-9 |
| 20 |
octachlorodibenzo-p-dioxin (OCDD), 3268-87-9
| 2,3,7,8-tetrachlorodibenzofuran (2,3,7,8-TCDF), 51207-31-9 |
| 20 |
| 1,2,3,7,8-pentachlorodibenzofuran (1,2,3,7,8-PeCDF), 57117-41-6 |
| 20 |
| 2,3,4,7,8-pentachlorodibenzofuran (2,3,4,7,8-PeCDF), 57117-31-4 |
| 20 |
| 1,2,3,6,7,8-hexachlorodibenzofuran (1,2,3,6,7,8-HxCDF), 57117-44-9 |
| 20 |
| 1,2,3,7,8,9-hexachlorodibenzofuran (1,2,3,7,8,9-HxCDF), 72918-21-9 |
| 20 |
| 1,2,3,4,7,8-hexachlorodibenzofuran (1,2,3,4,7,8-HxCDF), 70648-26-9 |
| 20 |
| 2,3,4,6,7,8-hexachlorodibenzofuran (2,3,4,6,7,8-HxCDF), 60851-34-5 |
| 20 |
| 1,2,3,4,6,7,8-heptachlorodibenzofuran (1,2,3,4,6,7,8-HpCDF), 67562-39-4 |
| 20 |
| 1,2,3,4,7,8,9-heptachlorodibenzofuran (1,2,3,4,7,8,9-HpCDF), 55673-89-7 |
| 20 |
| Octachlorodibenzofuran (OCDF), 39001-02-0 |
| 200 |
| Total tetrachlorodibenzo-p-dioxins (Total TCDD), 41903-57-5 |
| 20 |
| Total pentachlorodibenzo-p-dioxins (Total PeCDD), 36088-22-9 |
| 20 |
| Total hexachlorodibenzo-p-dioxins (Total HxCDD), 34465-46-8 |
| 20 |
| Total heptachlorodibenzo-p-dioxins (Total HpCDD), 37871-00-4 |
| 20 |
| Total tetrachlorodibenzofurans (Total TCDF), 55722-27-5 |
| 20 |
| Total pentachlorodibenzofurans (Total PeCDF), 30402-15-4 |
| 20 |
| Total hexachlorodibenzofurans (Total HxCDF), 55684-94-1 |
| 20 |
| Total heptachlorodibenzofurans (Total HpCDF), 38998-75-3 |
| 20 |
1Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans (PCDD/PCDF) 2Assumes a 2-way split of the extract (one being archived).
Reporting/quantitation limits listed apply to each train fraction.
Table 2. Metals Analyte List and Reporting Limits
| ANALYTE |
| REPORTING LIMIT (ug/sample)1 |
| REPORTING LIMIT (ug/sample)2 |
| Aluminum (Al), 7429-90-5 |
| 10 |
| 5 |
| Antimony (Sb), 7440-36-0 |
| 0.4 |
| 0.2 |
| Arsenic (As), 7440-38-2 |
| 0.4 |
| 0.2 |
| Barium (Ba), 7440-39-3 |
| 1 |
| 0.5 |
| Beryllium (Be), 7440-41-7 |
| 0.1 |
| 0.1 |
| Cadmium (Cd), 7440-43-9 |
| 0.1 |
| 0.1 |
| Chromium (Cr), 7440-47-3 |
| 0.3 |
| 0.2 |
| Cobalt (Co), 7440-48-4 |
| 0.1 |
| 0.1 |
| Copper (Cu), 7440-50-8 |
| 0.5 |
| 0.3 |
| Lead (Pb), 7439-92-1 |
| 0.2 |
| 0.1 |
| Manganese (Mn), 7439-96-5 |
| 0.8 |
| 0.3 |
| Mercury (Hg), 7439-97-6 (FRONT HALF) |
| 0.03 |
| N/A |
| Mercury (Hg), 7439-97-6 (BACK HALF) |
| N/A |
0.01
| Mercury (Hg), 7439-97-6 (EMPTY IMPINGER) |
| N/A |
0.05
| Mercury (Hg), 7439-97-6 (KMnO4/H2SO4 IMPINGER) |
| N/A |
0.1
| Mercury (Hg), 7439-97-6 (HCl IMPINGER) |
| N/A |
0.05
| Nickel (Ni), 7440-02-0 |
| 0.5 |
| 0.3 |
| Phosphorus (P), 7723-14-0 |
| 18 |
| 9 |
| Selenium (Se), 7782-49-2 |
| 1 |
| 0.5 |
| Silver (Ag), 7440-22-4 |
| 0.2 |
| 0.1 |
| Thallium (Tl), 7440-28-0 |
| 0.5 |
| 0.3 |
| Uranium (U), 7440-61-1 |
| Not established |
| Not established |
| Vanadium (V), 7440-62-2 |
| 0.2 |
| 0.1 |
1Front half reporting limits.
2Back half reporting limits (four mercury fractions are listed individually). The back half mercury reporting limit assumes a 300 mL sample volume, and the empty impinger reporting limit assumes a 100 mL sample volume.
Reporting limits are not dependent upon submitted volume except those specified in footnote 2.
Table 3. Hydrogen Chloride and Chlorine Reporting Limits
| ANALYTE |
| REPORTING LIMIT (ug/sample) 1 |
| Hydrogen Chloride, 7647-01-0 |
| 200 |
1Reporting limits assume a dilution factor of 1 and a submitted impinger volume (total impinger volume per fraction) of 200 mL.
Table 4. Semivolatile Organic Compound (SVOC) (Method 0010 Train) Analyte List and Reporting Limits
ANALYTE
REPORTING LIMIT (ug/sample)1
| Acenaphthylene, 208-96-8 |
| 1 |
| Benz(a)anthracene, 56-55-3 |
| 1 |
| Benzo(b)fluoranthene, 205-99-2 |
| 1 |
| Benzo(k)fluoranthene, 207-08-9 |
| 1 |
| Benzo(ghi)perylene, 191-24-2 |
| 1 |
| Benzo(a)pyrene, 50-32-8 |
| 1 |
| Benzyl alcohol, 100-51-6 |
| 2 |
bis(2-Chloroethoxy)methane, 111-91-1
| bis(2-Chloroethyl) ether, 111-44-4 |
| 2 |
bis(2-Chloroisopropyl) ether [also/better bis(2-chloro-1-methylethyl)ether or 2,2’-oxybis(1-chloropropane)], 108-60-1 bis(2-Ethylhexyl) phthalate, 117-81-7
| 4-Bromophenyl phenyl ether, 101-55-3 |
| 1 |
| Butyl benzyl phthalate, 85-68-7 |
| 1 |
| 4-Chloroaniline, 106-47-8 |
| 5 |
4-Chloro-3-methylphenol, 59-50-7
| 1-Chloronaphthalene, 90-13-1 |
| 2 |
| 2-Chloronaphthalene, 91-58-7 |
| 1 |
| 2-Chlorophenol, 95-57-8 |
| 3 |
4-Chlorophenyl phenyl ether, 7005-72-3
| Dibenz(a,h)anthracene, 53-70-3 |
| 1 |
| Di-n-butyl phthalate, 84-74-2 |
| 2 |
| 1,2-Dichlorobenzene, 95-50-1 |
| 2 |
| 1,3-Dichlorobenzene, 541-73-1 |
| 2 |
| 1,4-Dichlorobenzene, 106-46-7 |
| 2 |
| 3,3'-Dichlorobenzidine, 91-94-1 |
| 3 |
| 2,4-Dichlorophenol, 120-83-2 |
| 2 |
| Diethyl phthalate, 84-66-2 |
| 2 |
| 2,4-Dimethylphenol, 105-67-9 |
| 2 |
| Dimethyl phthalate, 131-11-3 |
| 2 |
4,6-Dinitro-2-methylphenol, 534-52-1
| 2,4-Dinitrophenol, 51-28-5 |
| 5 |
| 2,4-Dinitrotoluene, 121-14-2 |
| 1 |
| 2,6-Dinitrotoluene, 606-20-2 |
| 3 |
| Di-n-octyl phthalate, 117-84-0 |
| 2 |
| Diphenylamine, 122-39-4 |
| 2 |
| Hexachlorobenzene, 118-74-1 |
| 2 |
| Hexachlorobutadiene, 87-68-3 |
| 2 |
Hexachlorocyclopentadiene, 77-47-4
| Hexachloroethane, 67-72-1 |
| 2 |
Indeno(1,2,3-cd)pyrene, 193-39-5
| 1-Methylnaphthalene, 90-12-0 |
| 3 |
| 2-Methylnaphthalene, 91-57-6 |
| 2 |
| 2-Methylphenol, 95-48-7 |
| 3 |
| 3-Methylphenol, 108-39-4; and 4-Methylphenol, 106-44-5 |
| 4 |
| 2-Nitroaniline, 88-74-4 |
| 5 |
| 3-Nitroaniline, 99-09-2 |
| 5 |
| 4-Nitroaniline, 100-01-6 |
| 5 |
| 4-Nitrophenol, 100-02-7 |
| 4 |
N-Nitrosodimethylamine, 62-75-9
N-Nitrosodiphenylamine, 86-30-6
N-Nitrosodi-n-propylamine, 621-64-7
| Pentachlorophenol, 87-86-5 |
| 3 |
1,2,4-Trichlorobenzene, 120-82-1
| 2,4,5-Trichlorophenol, 95-95-4 |
| 2 |
| 2,4,6-Trichlorophenol, 88-06-2 |
| 2 |
1Reporting limit applies to all 3 method 3542 fractions.
Assumes a 2-way split of the extract (one being archived). If PCBs are being determined, a 3-way split of the extract (one being archived) would result. Reporting limits in the above table would be multiplied by 1.5 in that case.
Department of the Army Medical Command