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ATTACHMENT 1
CHEMICAL PARAMETERS AND METHODOLOGIES
| PARAMETER^ |
| Matrix |
| METHODOLOGY |
| REFERENCE |
| Perfluorinated Alkyl Substances (PFAS)* |
| Water |
| LCMSMS |
| LCMSMS, Compliant with DoD QSM 5.1 Table B-15 (or most current DoD QSM version) |
| OC pesticides/PCBs |
| Water |
| GC/ECD |
| EPA 608 |
| OC pesticides/PCBs* |
| Water |
| GC/ECD |
| EPA 8081x/8082x (including 3000 series prep) (specify versions and prep method) |
| OC pesticides/PCBs* |
| Soil, Sediment, Sludge |
| GC/ECD |
| EPA 8081x/8082x (including 3000 series prep) (specify versions and prep method) |
| Herbicides* |
| Water |
| GC/ECD |
| EPA 8151A |
| Herbicides* |
| Soil, Sediment, Sludge |
| GC/ECD |
| EPA 8151A |
| PCBs (Aroclors)* |
| Water |
| GC/ECD |
| EPA 8082x (including 3000 series prep) (specify version and prep method) |
| PCBs (Aroclors)* |
| Soil |
| GC/ECD |
| EPA 8082x (including 3000 series prep) (specify versions and prep method) |
| Hexane Extractable Material (HEM) |
| Water |
| Gravimetric |
| EPA 1664A |
| Diesel Range Organics (DRO), C10-C28* |
| Water |
| GC/FID |
| EPA 8015x (including 3000 series prep) (specify version and prep method) |
| Diesel Range Organics (DRO), C10-C28* |
| Soil |
| GC/FID |
| EPA 8015x (including 3000 series prep) (specify version and prep method) |
| DRO + Oil Range Organics (ORO), C28-C40 |
| Water |
| GC/FID |
| See above for DRO. ORO- EPA 8015x (including 3000 series prep) (specify version and prep method) or equivalent (specify) |
| DRO + Oil Range Organics (ORO), C28-C40 |
| Soil |
| GC/FID |
| See above for DRO. ORO- EPA 8015x (including 3000 series prep) (specify version and prep method) or equivalent (specify) |
| GRO, C6-C9C10* |
| Water |
| GC/FID or GC/MS |
| EPA 8015x or 8260x (modified) (including 5000 series method) (specify methods and versions |
| GRO, C6-C10* |
| Soil |
| GC/FID or GC/MS |
| EPA 8015x or 8260x (modified) (including 5000 series method) (specify methods and versions) |
| VOC* |
| Water |
| GC/MS |
| EPA 5030B/8260x (specify method version) |
| VOC (encores, pre-preserved vials, or soil jars)* |
| Soil, Sludge, Sediment |
| GC/MS |
| EPA 5035/8260x (specify method version and supported collection type(s)) |
| VOC, BTEX only* |
| Water |
| GC/MS |
| EPA 5030B/8260x (specify method version) |
| VOC, BTEX only (ENCORES, pre-preserved vials, or jars)* |
| Soil, Sludge, Sediment |
| GC/MS |
| EPA 5035/8260x (specify method version and supported collection type(s)) |
| Volatile TICS (Top 20 TICS with a response ≥10% of the nearest internal standard) |
| n/a |
| GC/MS |
| NA, please provide procedure/SOP |
| VOC Canister Cleaning (w/ certification by lot) |
| Canister |
| GC/MS |
| EPA TO-15 |
* This analysis MUST be on the performing lab’s DoD ELAP scope ^ Please reference Attachment 3 for specific analytes and limits of quantitation (LOQs) for each parameter.
| PARAMETER ^ |
| Matrix |
| METHODOLOGY |
| REFERENCE |
| SVOC* |
| Water |
| GC/MS |
| EPA 8270x (including 3000 series prep) (specify version and prep method) |
| SVOC* |
| Soil, Sludge, Sediment |
| GC/MS |
| EPA 8270x (including 3000 series prep) (specify version and prep method) |
| Semivolatile TICS (Top 20 TICS with a response ≥10% of the nearest internal standard) |
| n/a |
| GC/MS |
| NA (provide procedure/SOP) |
| SVOC, PAHs only* |
| Water |
| GC/MS |
| EPA 8270x (including 3000 series prep) (specify version and prep method) |
| SVOC, PAHs only, low level by SIM* |
| Water |
| GC/MS SIM |
| EPA 8270x mod (including 3000 series prep) (specify version and prep method) |
| SVOC, PAHs only* |
| Soil, Sludge, Sediment |
| GC/MS |
| EPA 8270x (including 3000 series prep) (specify version and prep method) |
| SVOC, PAHs only, low level by SIM* |
| Soil, Sludge, Sediment |
| GC/MS |
| EPA 8270x mod (including 3000 series prep) (specify version and prep method) |
| Explosives* |
| Water |
| HPLC |
| EPA 8330x (specify method version) |
| Explosives (analysis only)* |
| Soil, Sludge, Sediment |
| HPLC |
| EPA 8330B |
| Explosives (drying, seiving, grinding only)* |
| Soil, Sludge, Sediment |
| Puck mill or equivlaent |
| EPA 8330B and DoD Quality Systems Manual (QSM), latest version |
| TCLP extraction only (extraction to cover pesticides, herbicides, SVOC, metals (one parameter or all))* |
| Water |
| As per EPA 1311 |
| EPA 1311 |
| TCLP extraction only (extraction to cover pesticides, herbicides, SVOC, metals (one parameter or all))* |
| Solid/Waste |
| As per EPA 1311 |
| EPA 1311 |
| TCLP extraction only for VOCs (zero headspace)* |
| Water |
| As per EPA 1311 |
| EPA 1311 zero headspace extraction |
| TCLP extraction only for VOCs (zero headspace)* |
| Solid/Waste |
| As per EPA 1311 |
| EPA 1311 Zero headspace extraction |
| Metals (analysis only (RCRA 8) of TCLP extract)* |
| TCLP Extract |
| CVAA and ICP (or ICP-MS) |
| EPA 7470x, 6010x (or 6020x) (specify methods and versions) |
| SVOC (analysis only of TCLP extract)* |
| TCLP Extract |
| GC/MS |
| EPA 8270x (Analysis of TCLP extract only) (specify method version) |
| Pesticides/Herbicides (analysis only of TCLP extract)* |
| TCLP extract |
| GC/ECD |
| EPA 8081x/8151A (specify method version) |
| VOC (analysis only of TCLP extract)* |
| TCLP Extract |
| GC/MS |
| EPA 8260x (specify version) |
| TCLP extraction and analysis for the 8 RCRA metals only* |
| Water |
| As per EPA 1311 |
| EPA 1311, 7470x, 6010x (or 6020x) (specify methods and versions) |
| TCLP extraction and analysis for the 8 RCRA metals only* |
| Solid/Waste |
| As per EPA 1311 |
| EPA 1311, 7470x, 6010x (or 6020x) (specify methods and versions) |
^ Please reference Attachment 3 for specific analytes and limits of quantitation (LOQs) for each parameter.
| PARAMETER^ |
| MATRIX |
| METHODOLOGY |
| REFERENCE |
| TCLP extraction and analysis for the full TCLP suite (VOC, pesticides, herbicides, SVOC, 8 RCRA metals) * |
| Water |
| As per EPA 1311 |
| EPA 1311, 7470x, 6010x (or 6020x), 8081x, 8151A, 8270x, 8260x (specify methods and versions) |
| TCLP extraction and analysis for the full TCLP suite (VOC, pesticides, herbicides, SVOC, 8 RCRA metals) * |
| Solid/Waste |
| As per EPA 1311 |
| EPA 1311, 7470x, 6010x (or 6020x), 8081x, 8151A, 8270x, 8260x (specify methods and versions) |
^ Please reference Appendix 6’Attachment 3 for specific analytes and limits of quantitation (LOQs) for each parameter.
| PARAMETER |
| MATRIX |
| METHODOLOGY |
Alkalinity, Total
| Water |
| SM 2320B or other 40CFR136 approved method |
| Alkalinity, Bicarbonate |
| Water |
| SM 2320B or other applicable 40CFR136 approved method for total alkalinity |
Ammonia
| Water |
| EPA 350.1 (rev 2.0), or SM 4500-NH3 F, G, or H |
BOD
Bromide
| Water |
| EPA 300.0 (rev 2.1), EPA 300.1 (rev 1.0), or other 40CFR136 approved ion chromatography method |
Chloride
| Water |
| EPA 300.0 (rev 2.1) or EPA 300.1 (rev 1.0), or other 40CFR136 approved ion chromatography method |
| Chromium VI |
| Water |
| EPA 218.6 or SM 3500 B or C |
| Chromium VI |
| Soil |
| EPA 7000 series (modified) or other (specify method) |
COD
| Water |
| EPA 410.4, SM 5220D, or other 40CFR136 approved method |
Color
| Conductivity (Specific Conductance) |
| Water |
| EPA 120.1 or SM 2510B |
Cyanide, Total
| Water |
| EPA 335.4 or other 40CFR136 approved SM 4500-CN method combination |
Cyanide, Amenable to Chlorination
Cyanide, Available
| Water |
| OIA-1677 or other 40CFR 136 approved method |
Dissolved Organic Carbon (DOC)
| Water |
| Any 40CFR136 approved method for total organic carbon |
| Flashpoint |
| Liquids |
| EPA 1010A (ASTM D93) |
Fluoride
| Water |
| EPA 300.0 (rev 2.1), EPA 300.1 (rev 1.0), or other 40CFR136 approved method |
| Hardness |
| Water |
| SM 2340B (by calculation, using Ca and Mg concentrations determined by ICP) |
| Ignitability/burn rate test |
| Solids |
| EPA 1030 |
| PARAMETER |
| MATRIX |
| METHODOLOGY |
Moisture/Solids (percent)
| Soil, Sludge, Sediment |
| Laboratory SOP, gravimetric |
Nitrate-Nitrite
| Water |
| EPA 353.2 or other 40CFR13640CFR136 approved method |
Nitrate only
| Water |
| EPA 300.0 (rev 2.1), EPA 300.1 (rev 1.0), or other 40CFR136 approved method |
Nitrite only
| Water |
| EPA 300.0 (rev 2.1), EPA 300.1 (rev 1.0), or other 40CFR136 approved method |
ortho-Phosphate
| Water |
| EPA 300.0 (rev 2.1), EPA 300.1 (rev 1.0), or other 40CFR136 approved method |
| Paint Filter Liquids Test |
| Solids, Semisolids |
| EPA 9095B |
| Perchlorate* |
| Water |
| EPA 6850 or 6860 |
| Perchlorate* |
| Soil, Sludge, Sediment |
| EPA 6850 or 6860 |
pH
| Water |
| EPA SW846 9040x (specifiy version) |
pH
| Soil, Sludge, Sediment |
| EPA SW846 9045x (specify version) |
pH
| Water |
| EPA 150.2 or SM 4500-H+ B |
Phosphorus, Total
| Water |
| Any 40CFR136 approved method or method combination that includes digestion |
| Silica |
| Water |
| Any 40CFR136 approved method |
Sulfate
| Water |
| EPA 300.0 (rev 2.1) or EPA 300.1 (rev 1.0), or other 40CFR136 approved ion chromatography method |
Surfactants (MBAS)
Total Kjeldahl nitrogen (TKN)
| Water |
| SM 4500-Norg B combined with any 40CFR136 approved method |
Total Dissolved Solids (TDS)
Total Organic Carbon (TOC)
| Water |
| Any 40CFR136 approved method |
Total Organic Carbon (TOC)
| Soil, Sludge, Sediment |
| Methods of Soil Analysis 29-3.5.2 or equivalent (submit method for APHC approval) |
Total Suspended Solids (TSS)
Turbidity
| Water |
| EPA 180.1 or SM 2130B |
Sample Preparation Procedures:
| Sample Preparation/Digestion, EPA SW-846 3000 series* |
| Soil, Sediment, Sludge and Bulk (specify method and version) |
| Sample Preparation/Digestion, EPA SW-846 3000 series (for ICP analysis); specify method and version* |
| Water |
| Sample Preparation/Digestion, EPA SW-846 3000 series (for ICP-MS analysis- if different from above); specify method and version* |
| Water |
| Sample Preparation, EPA 200.2* |
| Water |
ICPMS 6020 for Waters and Solids*
WATER*
| METAL (to be requested and priced by individual metal) |
| METHOD |
| METAL (to be requested and priced by individual metal) |
| METHOD |
| Antimony (Sb) |
| 6020x |
| Lead (Pb) |
| 6020x |
| Arsenic (As) |
| 6020x |
| Manganese (Mn) |
| 6020x |
| Barium (Ba) |
| 6020x |
| Molybdenum (Mo) |
| 6020x |
| Beryllium (Be) |
| 6020x |
| Nickel (Ni) |
| 6020x |
| Cadmium (Cd) |
| 6020x |
| Selenium (Se) |
| 6020x |
| Chromium (Cr) |
| 6020x |
| Silver (Ag) |
| 6020x |
| Cobalt (Co) |
| 6020x |
| Thallium (Tl) |
| 6020x |
| Copper (Cu) |
| 6020x |
| Vanadium (V) |
| 6020x |
SOIL/SEDIMENT/SLUDGE*
| METAL (to be requested and priced by individual metal) |
| METHOD |
| METAL (to be requested and priced by individual metal) |
| METHOD |
| Antimony (Sb) |
| 6020x |
| Lead (Pb) |
| 6020x |
| Arsenic (As) |
| 6020x |
| Manganese (Mn) |
| 6020x |
| Barium (Ba) |
| 6020x |
| Molybdenum (Mo) |
| 6020x |
| Beryllium (Be) |
| 6020x |
| Nickel (Ni) |
| 6020x |
| Cadmium (Cd) |
| 6020x |
| Selenium (Se) |
| 6020x |
| Chromium (Cr) |
| 6020x |
| Silver (Ag) |
| 6020x |
| Cobalt (Co) |
| 6020x |
| Thallium (Tl) |
| 6020x |
| Copper (Cu) |
| 6020x |
| Vanadium (V) |
| 6020x |
ICPMS 200.8 for Waters*
WATERS
| METAL (to be requested and priced by individual metal) |
| METHOD |
| METAL (to be requested and priced by individual metal) |
| METHOD |
| Aluminum (Al) |
| 200.8 |
| Lead (Pb) |
| 200.8 |
| Antimony (Sb) |
| 200.8 |
| Manganese (Mn) |
| 200.8 |
| Arsenic (As) |
| 200.8 |
| Molybdenum (Mo) |
| 200.8 |
| Barium (Ba) |
| 200.8 |
| Nickel (Ni) |
| 200.8 |
| Beryllium (Be) |
| 200.8 |
| Selenium (Se) |
| 200.8 |
| Cadmium (Cd) |
| 200.8 |
| Silver (Ag) |
| 200.8 |
| Chromium (Cr) |
| 200.8 |
| Thallium (Tl) |
| 200.8 |
| Cobalt (Co) |
| 200.8 |
| Vanadium (V) |
| 200.8 |
| Copper (Cu) |
| 200.8 |
| Zinc (Zn) |
| 200.8 |
Mercury by EPA 200 and 7000 Series – Soils, Sediments, Sludges, and Water
| Hg (soil, sludge, sediment)* |
| 7471x |
EPA Method 6010 for Soils, Sediments, Sludges, Bulk, and Waters*
SOILS/SEDIMENT/BULK*
| METAL (to be requested and priced by individual metal) |
| METHOD |
| METAL (to be requested and priced by individual metal) |
| METHOD |
| Aluminum (Al) |
| 6010x |
| Magnesium (Mg) |
| 6010x |
| Arsenic (As) |
| 6010x |
| Nickel (Ni) |
| 6010x |
| Barium (Ba) |
| 6010x |
| Potassium (K) |
| 6010x |
| Beryllium (Be) |
| 6010x |
| Selenium (Se) |
| 6010x |
| Cadmium (Cd) |
| 6010x |
| Silver (Ag) |
| 6010x |
| Calcium (Ca) |
| 6010x |
| Sodium (Na) |
| 6010x |
| Chromium (Cr) |
| 6010x |
| Strontium (Sr) |
| 6010x |
| Iron (Fe) |
| 6010x |
| Zinc (Zn) |
| 6010x |
EPA Method 6010 for Soils, Sediments, Sludges, Bulk, and Waters*
WATERS*
| METAL (to be requested and priced by individual metal) |
| METHOD |
| METAL (to be requested and priced by individual metal) |
| METHOD |
| Aluminum (Al) |
| 6010x |
| Magnesium (Mg) |
| 6010x |
| Calcium (Ca) |
| 6010x |
| Potassium (K) |
| 6010x |
| Iron (Fe) |
| 6010x |
| Sodium (Na) |
| 6010x |
| Lead (Pb) |
| 6010x |
| Zinc (Zn) |
| 6010x |
EPA Method 200.7 for Water
WATER
| METAL (to be requested and priced by individual metal) |
| METHOD |
| METAL (to be requested and priced by individual metal) |
| METHOD |
| Aluminum (Al) |
| 200.7 |
| Magnesium (Mg) |
| 200.7 |
| Boron (B) |
| 200.7 |
| Potassium (K) |
| 200.7 |
| Calcium (Ca) |
| 200.7 |
| Sodium (Na) |
| 200.7 |
| Iron (Fe) |
| 200.7 |
| Zinc (Zn) |
| 200.7 |
MICROBIOLOGY AND AQUATIC TOXICITY ANALYSES
| PARAMETER |
| METHOD |
| MATRICES |
| Total Coliform – Quantitative/MPN |
| Any method or methods approved in both 40CFR141 (SDWA) and 40 CFR136CFR136 (CWA) (specify method) |
| Water |
| Total Coliform (MPN) followed by E. Coli (Quantitative/MPN) (both reported) |
| Any method or methods approved in both 40CFR141 (SDWA) and 40 CFR136CFR136 (CWA) (specify method) |
| Water |
| Fecal Coliform – Quantitative/MPN |
| Any method or methods approved in both 40CFR141 (SDWA) and 40 CFR136CFR136 (CWA) (specify method) |
| Water |
| Aquatic Toxicity (WET), acute, C. dubia |
| EPA 2002 |
| Water |
| Aquatic Toxicity (WET), acute, P. promelas |
| EPA 2000 |
| Water |
| Aquatic Toxicity (WET), acute, D. magna |
| EPA 2021 |
| Water |
Department of the Army Medical Command