Patchmaster-Pothole-Patch_SDS.pdf

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Competitive Selection OH|DOT10226-8
Contract number
DOT10226-8
Issued by
Ohio

About this file

This document is a Safety Data Sheet (SDS) for PatchMaster Pothole Patch, a road repair product manufactured by ThorWorks Industries, Inc., located in Sandusky, Ohio. The SDS is dated April 17, 2023, and provides comprehensive safety, handling, and regulatory information about the product. While not a contract document, it contains critical information for government and municipal agencies that may use this pothole repair material.

The product is a liquid/solid mix with a black appearance and hydrocarbon odor, primarily composed of limestone (80-98%) and asphalt (2-10%), with small amounts of diesel fuel and additives. The SDS indicates the product is not classified as hazardous under OSHA standards, though it carries a warning for potential harm if swallowed. The document covers detailed safety protocols, including first aid measures, fire-fighting procedures, handling and storage instructions, exposure controls, and personal protective equipment recommendations. It also notes compliance with various regulatory inventories including the U.S. Toxic Substances Control Act (TSCA) and Canadian Domestic Substances List, and lists state-level right-to-know regulations for ingredients like limestone and asphalt.

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Text version

SAFETY DATA

SHEET

Issuing Date 15-Dec-2014 Revision Date 17-Apr-2023 Revision Number 4

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

GHS Product Identifier

Product Name: PatchMaster Pothole Patch

Other Means of Identification

Product Code(s): M1150

Synonyms None

Recommended Use of the Chemical and Restrictions on Use

Recommended Use: No Information Available

Uses Advised Against: No information Available

Supplier’s Details

Manufacturer Address

ThorWorks Industries, Inc.

2520 S. Campbell St.

Sandusky, OH 44870 www.sealmaster.net

1-800-326-1994

Emergency Telephone Number Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION

Classification

This product is not considered hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200).

GHS Label Elements, Including Precautionary Statements

Emergency Overview

Signal Word Warning

●Harmful if swallowed

Appearance: Black Physical State: Liquid/Solid Mix Odor: Hydrocarbon

Precautionary Statements

Prevention ●None

General Advice ●None

Storage ●Store in a well-ventilated place.

Disposal ● Dispose of according to the appropriate state, regional, or local regulations. See Section 13.

Hazard Not Otherwise Classified (HNOC)

Not applicable

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS Number Weight % Trade Secret

Limestone 1317-65-3 80-98 *

Asphalt 8052-42-4 2-10 *

Fuels, Diesel, No. 2 68476-34-6 <3 *

Additives N/A <3 *

*The exact percentage of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

Description of Necessary First-Aid Measures

Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician.

Skin Contact Wash off immediately with soap and plenty of water. In the case of skin irritation or allergic reactions, see a physician.

Inhalation Move to fresh air. If symptoms persist, call a physician.

Ingestion Drink plenty of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Consult a physician if necessary.

Most Important Symptoms/Effects, Acute and Delayed

Most Important Symptoms/Effects No information available

Indication of Immediate Medical Attention and Special Treatment Needed, If Necessary

Notes to Physician Treat Symptomatically. May cause sensitization by skin contact.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Carbon Dioxide (CO2). Dry Chemical. Foam. Water Fog.

Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may scatter and spread fire.

Specific Hazards Arising from the Chemical

Fire may produce corrosive, irritating and/or toxic gases.

Explosion Data

Sensitivity to Mechanical Impact None

Sensitivity to Static Discharge None

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure- demand MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures

Personal Precautions: Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personal protective equipment.

Environmental Precautions

Environmental Precautions: See Section 12 for additional Ecological Information

Methods and Materials for Containment and Cleaning Up

Methods for Containment: Prevent further spillage if safe to do so.

Methods for Cleaning Up: Collect spillage. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. Do not contaminate water.

7. HANDLING AND STORAGE

Precautions for Safe Handling

Handling:

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes, and clothing. Wear personal protective equipment. Avoid breathing vapors or mists. Do not eat, drink, or smoke when using this product. Wash thoroughly after handling. Do not heat above 120º F when using.

Conditions for Safe Storage, Including Any Incompatibilities

Storage: Keep container tightly closed. Store away from incompatible materials. Incompatible

Products: Strong oxidizing agents. Acids.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control Parameters

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Asphalt 8052-42-

TWA: 0.5 mg/m³ benzene soluble aerosol fume, inhalable fraction

Ceiling: 5 mg/m³ fume 15 min.

Fuels, Diesel, No. 2 68476-

34-6

TWA: 100 mg/m³

Inhalable fraction and vapor

Appropriate Engineering Controls

Engineering Measures: Showers

Eyewash Stations

Ventilation Systems

Individual Protection Measures, such as Personal Protective Equipment Eye/Face Protection: Safety glasses with side shields.

Skin and Body Protection: Impervious gloves.

Respiratory Protection: No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn.

Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Do not smoke.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties

Physical State: Liquid/Solid Mix Appearance: Black

Odor: Hydrocarbon Odor Threshold: No Information Available

Property

Values Remarks/Method pH No data available None known

Melting Point/Range No data available None known

Boiling Point/Boiling Range 200° C None known

Flash Point >200° F Cleveland Open Cup

Evaporation Rate No data available None known

Flammability (solid, gas)

Flammability Limits in Air

No data available None known

Upper flammability limit No data available

Lower flammability limit No data available

Vapor Pressure No data available None known

Vapor Density No data available None known

Specific Density 2.433

Solubility No data available None known

Partition coefficient: n-octanol/water No data available None known

Autoignition Temperature No data available None known

Decomposition Temperature No data available None known

Viscosity No data available None known

Flammable Class IIIB

Explosive Properties No data available

Oxidizing Properties No data available

VOC Content Less than 100 g/l

10. STABILITY AND REACTIVITY

Reactivity: No data available

Chemical Stability: Stable under recommended storage conditions.

Possibility of Hazardous Reactions: None under normal processing.

Hazardous Polymerization: Hazardous polymerization does not occur.

Conditions to Avoid: Heat, Sparks, Flame. Avoid high temperatures.

Incompatible Materials: Strong oxidizing agents. Acids.

Hazardous Decomposition Products: Carbon Monoxide (CO), Carbon Dioxide (CO²), Hydrogen Sulfide, Nitrogen Dioxide

11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure

Product Information

Inhalation: Inhalation of fumes/vapors may cause irritation of respiratory tract.

Eye Contact: Contact with eyes may cause irritation.

Skin Contact: May cause irritation.

Ingestion: Ingestion may cause stomach discomfort.

Chemical Name LD50 Oral LD50 Dermal LD50 Inhalation

Asphalt 5000 mg/kg (Rat) >2000 mg/kg (Rabbit) -

Symptoms Related to the Physical, Chemical, and Toxicological Characteristics

Symptoms: No information available.

Delayed and Immediate Effects and also Chronic Effects from Short and Long Term Exposure

Sensitization: No information available. Mutagenic Effects:

No information available.

Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen.

The IARC, NTP, and OSHA do not list asphalt as a carcinogen. In general, the oxidation of polycyclic aromatic hydrocarbons destroys their carcinogenic potential. Petroleum asphalt, shale oil asphalts, and coal tars show distinct variation in their relative carcinogenicity for experimental animals.

Chemical Name ACGIH IARC NTP OSHA

Asphalt A3 Group 2B Reasonably

Anticipated

X

Fuels, Diesel, No. 2 Group 3

ACGIH: (American Conference of Governmental Industrial Hygienists)

A3 – Animal Carcinogen

IRAC: (International Agency for Research on Cancer)

Group 2B – Possibly Carcinogenic to Humans

Group 3 – Not Classifiable as to Carcinogenicity to Humans

NTP: (National Toxicity Program)

Reasonably Anticipated – Reasonably Anticipated to be a Human Carcinogen OSHA:

(Occupational Safety & Health Administration)

X – Present

Reproductive Toxicity: No information available.

STOT - Single Exposure: No information available.

STOT – Repeated Exposure: No information available.

Aspiration Hazard: No information available

12. ECOLOGICAL INFORMATION

Ecotoxicity

This product has no know eco-toxicological effects.

Persistence and Degradability: No information available.

Bioaccumulation

Chemical Name Log Pow

Asphalt 6.006

Other Adverse Effects:

No information available.

13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods:

This material, as supplied, is not a hazardous waste according to Federal regulations (40

CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.

Contaminated Packaging: Do not re-use empty containers.

14. TRANSPORTATION INFORMATION

DOT: Not regulated

15. REGULATORY INFORMATION

International Inventories TSCA

– Complies

DSL/NDSL – Complies

Legend

TSCA – United States Toxic Substances Control Act Section 8(b) Inventory

DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List

U.S. Federal Regulations

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

SARA 311/312 Hazard Categories

Acute Health Hazard No

Chronic Health Hazard No

Fire Hazard No

Sudden Release of Pressure Hazard No

Reactive Hazard

Safe Drinking Water Act (SDWA) Not Regulated

CERCLA

No

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive

Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and

Reauthorization Act (SARA) (40 CFR 355). There may be specific requirements at the local, regional, or state level pertaining to releases of this material.

U.S. State Regulations

California Proposition 65: This product does not contain any Proposition 65 chemicals.

U.S. State Right-To-Know Regulations

“X” designates that the ingredients are listed on the state right to know list.

Chemical Name New Jersey Massachusetts Pennsylvania Illinois Rhode Island

Limestone X X X X

Asphalt X X X X

Fuels, Diesel, No. 2 X X

U.S. EPA Label Information

EPA Pesticide Registration Number: Not applicable

16. OTHER INFORMATION

NFPA Health Hazard: 1 Flammability: 1 Instability: 0 Physical and

Chemical Hazards-

HMIS Health Hazard: 1 Flammability: 1 Physical Hazard: 0 Personal

Protection: X

Revision Date: 17-Apr-2023

Revision Note: Supersedes 8-Nov-2021

General Disclaimer

The information provided on this SDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.

File details come from the government source that posted it. Updated .