Crackmaster-pf-type-iv_SDS.pdf

SAFETY DATA SHEET

Issuing Date 30-April-2015 Revision Date Revision Number 0

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

GHS Product Identifier

Product Name: CrackMaster P.F., Type IV

Other Means of Identification

Product Code(s): M1076

Synonyms None

Recommended Use of the Chemical and Restrictions on Use

Recommended Use: Sealant

Uses Advised Against: No information Available

Supplier’s Details

Supplier Address ThorWorks Industries, Inc 2520 S. Campbell St.

Sandusky, OH 44870 1-800-326-1994

Emergency Telephone Number

Emergency Telephone Number Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION

Classification

Classification in accordance to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200) = 1B H350

GHS Label Elements, Including Precautionary Statements

Emergency Overview

Signal Word Danger

H350 May Cause Cancer P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P280 Wear eye protection, face protection, protective clothing, protective gloves P308 + P313 If exposed or concerned: Get medical attention P405 Store locked up P501 Dispose of contents/container to an authorized waste collection point

Describe any hazards- Hot material will burn skin.

Appearance: Black/Dark Brown Physical State: Solid at room temperature, liquid above softening point. Odor: Petroleum

Hazard Not Otherwise Classified (HNOC) Not applicable

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS Number % GHS-US classification

Extracts (petroleum), heavy paraffinic distillate solvent 64742.-04-7 0.1-20 Carc. 1B, H350

Carbon Black 1333-86-4 0-5 Carc. 2, H351 **

**Bound, not available to inhale as dust. Full text of H-phrases; see section 16.

4. FIRST AID MEASURES

Description of Necessary First-Aid Measures

General Never give anything by mouth ot an unconscious person. If exposed or concerned: Get medical advice/attention.

Eye Contact Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart.

Skin Contact Drench affected area with water for at least 15 minutes.

Inhalation Remove victim to fresh air and keep at rest in position comfortable for breathing. Get medical attention/advice.

Ingestion Get Medical attention/advice if you feel unwell.

Most Important Symptoms/Effects, Acute and Delayed

Most Important Symptoms/Effects May cause cancer Inhalation of vapors may cause respiratory irritation.

Heated product causes burns to skin and eyes.

Indication of Immediate Medical Attention and Special Treatment Needed, If Necessary

Notes to Physician Treat Symptomatically and supportively.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Class B. Carbon dioxide. Dry chemical. Foam. Water spray

Unsuitable Extinguishing Media Do not use a heavy water stream.

Specific Hazards Arising from the Chemical Fire hazard- When heated, material emits irritating fumes. Burning produces irritating, toxic, and noxious fumes.

Explosion hazard- Product is not explosive.

Reactivity- No dangerous reactions known.

Protective Equipment and Precautions for Firefighters Full protective equipment, including self-contained breathing apparatus to be worn. Do not allow run-off from fire fighting to enter drains/water courses. Exercise caution when fighting any chemical fire.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures

Personal Precautions: Avoid all eye and skin contact and do not breathe vapor and mist. Keep upwind.

For non-emergency personnel: Chemical goggles or safety glasses. Wear suitable protective clothing and gloves.

Evacuate unnecessary personnel.

For emergency responders: Chemical goggles or safety glasses. Wear suitable protective clothing and gloves. Stop leak if safe to do so.

Environmental Precautions

Environmental Precautions: Do not discharge into drains or the environment.

Methods and Materials for Containment and Cleaning Up

Methods for Containment: Stop the flow of material, if this is without risk. Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.

Methods for Cleaning Up: Allow the molten material to cool. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers.

7. HANDLING AND STORAGE

Precautions for Safe Handling

Handling: Avoid breathing vapors. Avoid contact with skin and eyes. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not eat, drink, or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking when leaving work.

Conditions for Safe Storage, Including Any Incompatibilities

Storage: Store in properly closed and labeled containers away from sources of ignition. Store containers in a well-ventilated, clean, and dry area.

Incompatible Products: Strong oxidizing agents.

Specific end use: Sealant.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control Parameters

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL

Extracts (petroleum), heavy paraffinic distillate solvent (64742-04-7)

Not applicable Not applicable

Carbon black (1333-86-4) TWA 3.5 mg/m³

Remark; Bronchitis

3.5 mg/m³

Appropriate Engineering Controls

Engineering Measures: Avoid creating mist or spray. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Use only outdoors or in a well-ventilated area.

Individual Protection Measures, such as Personal Protective Equipment

Eye/Face Protection: Chemical goggles or safety glasses. Contact with hot material- risk of serious burns. Face shield.

Skin and Body Protection: Long sleeved protective clothing. Foot protection. Insulated gloves.

Respiratory Protection: In case of inadequate ventilation wear respiratory protection. Appropriate self-contained breathing apparatus may be required.

Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties

Physical State: Solid at 77° F/ Liquid above softening point. Appearance: Black/Dark Brown Odor: Petroleum Odor Threshold: No Information Available

Property Values pH No data available Melting Point/Range 150-250° F (65.5-121.1 ° C) Boiling Point/Boiling Range >600° F (>315.6° C) Flash Point >400° F (>204.4° C ) Evaporation Rate No data available Flammability (solid, gas) No data available

Property Values Flammability Limits in Air Upper flammability limit No data available Lower flammability limit No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 1.0-1.9 Solubility No data available Solubility in other solvents No data available Density 8-16 lbs/gal

Partition coefficient: n-octanol/water No data available Autoignition Temperature >700° F (>371.1° C) Decomposition Temperature No data available Viscosity No data available

Explosive Properties No data available Oxidizing Properties No data available

Other Information

VOC Content 0%

10. STABILITY AND REACTIVITY

Reactivity: No dangerous reactions known.

Chemical Stability: Stable under normal conditions.

Possibility of Hazardous Reactions: Hazardous polymerization will not occur.

Conditions to Avoid: None known.

Incompatible Materials: Strong oxidizing agents.

Hazardous Decomposition Products: Carbon Monoxide (CO), Hydrogen Sulfide, Aldehydes, Aromatic hydrocarbons. Irritating and/or toxic fumes may be released if burned.

11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Likely routes of exposure: Skin and eye contact; Inhalation Acute toxicity: Not classified

Chemical Name LD50 Oral (Rat) LC50 Inhalation (Rat)

Carbon Black (1333-86-4) >8000 mg/kg (Rat) >4.6 mg/m³ 4 h

Skin corrosion/irritation: Not Classified Serious eye damae/irritation: Not Classified Respiratory or skin sensitization: Not Classified Germ cell mutagenicity: Not Classified Carcinogenicity: Not Classified

Chemical Name IRAC Group National Toxicology Program (NTP) Status

Carbon Black (1333-86-4) 2B- Possibly carcinogenic to humans, Inhalation of dust.

Not listed in carcinogenicity class

Reproductive Toxicity: Not Classified Specific target organ toxicity (single exposure): Not Classified Specific target organ toxicity (repeated exposure): Not Classified Aspiration hazard: Not Classified Symptoms/injury after inhalation: Inhalation of vapors may cause respiratory irritation.

Symptoms/injury after skin contact: Heated product causes burns.

Symptoms/injury after eye contact: Heated product causes burns.

12. ECOLOGICAL INFORMATION

Toxicity: No information available.

Persistence and Degradability:

Carbon Black (1333-86-4): Not readily biodegradable

Bioaccumulation Potential: No information available.

Mobility in soil: No information available.

Other Adverse Effects: No information available.

13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods:

Sewage disposal recommendations: Do not dispose of waste into sewer.

Waste disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.

14. TRANSPORTATION INFORMATION

DOT: Not considered a dangerous good for transport regulations.

15. REGULATORY INFORMATION

Legend TSCA – United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List EINECS – European Inventory of Existing Commercial Chemical Substances

U.S. Federal Regulations

Extracts (petroleum), heavy paraffinic distillate solvent (64742-04-7)- listed on the US TSCA inventory.

Carbon Black (1333-86-4)- listed on the US TSCA inventory.

International Regulations

CANADA

Extracts (petroleum), heavy paraffinic distillate solvent (64742-04-7)- listed on the Canadian DSL inventory.

Carbon Black (1333-86-4)- listed on the Canadian DSL inventory.

EU Regulations

Extracts (petroleum), heavy paraffinic distillate solvent (64742-04-7)- listed on the EEC inventory EINECS Carbon Black (1333-86-4)- listed on the EEC inventory EINECS

Classification according to Regulation (EC) No. 1272/2008 [CLP] Carc. 1B Full text of H-phrases: see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc. Cat. 2; R45

National Regulations Carbon Black (1333-86-4)- Listed on IARC (International Agency for Research on Cancer) Listed on PICCUS (Philippines Inventory of Chemicals and Chemical Substances) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on Taiwan National Chemical Inventory Listed on the Korean ECL(Existing Chemicals List) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Inventory of Existing Chemical Substances Produced or Imported in China (IECSC)

U.S. State Regulations

Carbon Black (1333-86-4) California Proposition 65 Carcinogens List: Yes California Proposition 65 Developmental Toxicity: No California Proposition 65 Reproductive Toxicity- Female: No California Proposition 65 Reproductive Toxicity- Male: No

U.S. State Right-To-Know Regulations

“X” designates that the ingredients are listed on the state right to know list.

Chemical Name New Jersey

Asphalt X

16. OTHER INFORMATION

NFPA Health Hazard: 2 Flammability: 1 Instability: 0 Physical and Chemical Hazards- HMIS Health Hazard: 2 Flammability: 1 Physical Hazard: 0 Personal Protection: X

Full text of H-phrases:

Carc. 1B- Carcinogenicity, Category 1B Carc. 2- Carcinogenicity, Category 2 H350- May Cause Cancer H351- Suspected of Causing Cancer

Revision Date: 30-April-2015 Revision Note: No information available.

General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.