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Task groups are broken down by major analytical area (general parameters, metals, organochlorine pesticides, polychlorinated biphenyls (PCBs), organic compounds, etc.). The primary sample matrix will be a biological tissue sample (primarily fish fillets or whole fish) and secondarily sediments from river or lake bottom). Analyses will be performed for the parameters listed in the following tables for Tasks 1 through 13, to a detection level equal to or less than the one listed in the tables and using the most appropriate analytical methods (Attachment H7- Test Method References). All instrumental, sample preparatory, and QA/QC procedures must be met in accordance with the method. Modifications in the list of parameters and/or detection limits will be acceptable only if approved in writing by IDEM/OWQ/WAPB.
Tasks contain conditions in addition to requirements specified in the RFP and in Lieu of RFP requirements. Contractors are cautioned to note the specifications of each Task they bid. The Task Lists are as follows:
| | Task 1 | | General parameters for tissue percent moisture and percent lipid |
| | Task 2 | Generals parameters for sediments - percent solids, Total Volatile Solids (TVS), Total Organic Carbon (TOC), Ammonia as N, Acid Volatile Sulfides (AVS), Grain size and specific gravity. | |
| Task 2B | Nutrient parameters in sediment – Total Kjeldahl Nitrogen (TKN), nitrite plus nitrate (NO2+NO3), ortho-(reactive) phosphate, acid-hydrolyzable phosphorus, organic phosphorus, total phosphorus, loss on ignition. | | | |
| | Task 3 | | Total Polychlorinated biphenyls (PCB) (tissues only). |
| | Task 3B | PCB congeners. | |
| | Task 3C | Polychlorinated Dioxins and Furans. | |
| | Task 4 | | Aroclors of PCBs (sediments only). |
| | Task 5 | | Organochlorine pesticides. |
| | Task 5B | Organophosphate pesticides. | |
| | Task 5C | Chlorophenoxy herbicides. | |
| | Task 6 | | Cd, Pb, As, Se. |
| | Task 6A | Cd, Cr, Cu, Pb, Hg, Ni, Se, Zn. | |
| | Task 6B | Long list of metals. | |
| | Task 6C | Cyanide (sediments only). | |
| | Task 6D | AVS and simultaneously extracted metals (SEM) (sediments only). | |
| | Task 6E | Tributyltin | |
| | Task 6F | Arsenic Speciation | |
| | Task 6G | Total Mercury (Method 1631 only) | |
| Task 6H | | Total and Methyl-Mercury Methods 1631 and 1630 | | |
| | Task 7 | | Acid extractable semi-volatile organic compounds. |
| | Task 8 | | Base/neutral extractable semi-volatile organic compounds. |
| | Task 9 | | Volatile organic compounds (VOC) (sediments only) |
| | Task 10 | Polynuclear aromatic hydrocarbon (PAH). | |
| | Task 11 | Polybrominated diphenyl Ether (PBDE). | |
| | Task 12 | Per- and Polyfluoroalkyl Substances (PFAS). | |
| | Task 13 | Algal Toxins (tissue only) | |
Tasks may be asked for in any combination on individual samples. All parameters within the requested tasks are to be analyzed and reported.
In order for the Contractor to estimate annual workload it is anticipated that IDEM/OWQ/WAPB will submit up to approximately 200 fish tissue samples and from 0 to 10 sediment samples annually. For tissue, most samples will have tasks 1, 3, 6, 6G and 12 assigned. Approximately one fourth could also contain tasks 5 or one of the expanded lists of metals. Other tasks will only be requested for special situations and the number of samples will be limited (See also G. Special Analytical Services). Number of samples and tasks are dependent on available funds and Agency priorities.
Sediment samples will have tasks 2, 4, 5, 6D and 10 assigned. Additional tasks will be requested on a limited number of samples as needed.
A. Method Updates
Methods listed for the Tasks represent general updates. Contractors should be implementing newer, faster, more sensitive, and more cost effective methodologies, as they are implemented and acceptable to the U.S. EPA.
Proposals to substitute U.S. EPA Methods for Standard Methods will be given consideration when the methods are comparable.
B. Pricing and General Requirements
The Contractor must bid on all of the tasks in order for its proposal to be deemed responsive. Contractors are expected to provide aggressive itemized pricing, based on the estimated volume of samples. Due to the potential for a large volume of samples over the contract term IDEM/OWQ/WAPB anticipates an overall lower group pricing.
Contractors must provide pricing in accordance with the structures outlined in the RFP, the appendices, and attachments; however, Contractors may suggest alternative solutions to meet IDEM/OWQ/WAPB needs. Alternative solutions will be assessed as additional considerations or in place of the specifications outlined in a Task. To be considered as a replacement to the specifications outlined in a Task, Contractors must provide pricing comparisons between the Task and the alternative solution and make a case as to why the alternative solution provides a better choice. IDEM/OWQ/WAPB will be the sole judge of the suitability of alternative solutions.
IDEM/OWQ/WAPB reserves the right to accept an alternative solution in place of the primary specifications of a Task. Contractors have an equal opportunity to supply creative solutions to meeting IDEM/OWQ/WAPB needs.
C. Data Quality Assessment Level
Data quality and reporting are expected to be at DQA Level 4, unless otherwise specified by the responsible IDEM/OWQ/WAPB Quality Assurance Officer. Descriptions of DQA levels are listed in Attachment H3– Quality Assurance/Quality Control Criteria, Table 1.
D. Mandatory Record Keeping, Reporting, and QA/QC Requirements
Contractors must maintain dedicated original records of sample receiving and handling, bench sheets, instrumental or recorder output sheets and final reports for this project. Contractors must provide Data Quality Assessment Level 4 QC. Data must be transmitted in electronic formats. The deliverables are not complete until both the analysis reports and EDDs have been received and determined acceptable by IDEM/OWQ/WAPB.
E. Tentative Identifications for Semi-Volatile and Volatile Organic Compounds
For each sample, the Selected respondent shall execute a maximum of 20 library searches on substances not listed in Tasks 7 and 8 (Acids and Base/Neutrals) and Task 9 (Volatile Organics). The 20 substances of greatest apparent concentration not listed in Tasks 7,8 and 9 shall be tentatively identified via a forward search of the EPA/NIH (or other similar library) mass spectral library (substances with responses less than 25% of the internal standards are not required to be searched in this fashion). Only after visual comparison of sample spectra with nearest library searches will the mass spectral interpretation specialist assign a tentative identification.
F. Other Lab Services
Contractors are requested to provide a list of analytical capabilities and pricing for other potentially bioaccumulating compounds that have not been addressed in this RFP such as organophosphate pesticides, pharmaceuticals and personal care products (PPCP), chlorinated alkanes, alkylphenol ethoxylates, chlorinated naphthalene congeners, toxaphene congeners (Parlars 26, 50, and 62), and Hexabromocyclododecane (HBCD or HBCDD). We are also interested in capabilities on the determination of short chain Omega-3 Fatty Acids including Eicosapentaenoic Acid, Docosahexaenoic Acid, and other related omega-3 polyunsaturated fatty acids. Contractor’s additional capabilities will not be utilized for Cost Comparison. Contractor’s additional analytical capabilities will be utilized in the evaluation of Overall Management Judgment.
G. Special Analytical Services
Special Analytical Services (SAS) include tasks 5B, 5C, 6E, 6F, and 13. Parameters listed in these tasks are for the purposes of extended capabilities. Contractor(s) should supply contractual pricing for any parameter the Contractor is capable of performing. SAS requires the ability to determine a method’s parameters at the specified data quality level. The contractor may specify the method for these tasks even though some have already been suggested in the Task List Tables. Methods will be requested singularly and not all methods will be performed on all samples.
Task SAS -- Data Quality Assessment Data quality and reporting are to be at DQA Level 3, unless specified by the responsible IDEM/OWQ QC officer.
RFP-7-65
Attachment D6 Technical Specifications Tasks List
RFP-25-81029
Attachment H6 Technical Specifications Tasks List
RFP-12-##
Technical Specifications D6
RFP-25-81029
Technical Specifications H6
| TASK 1 |
| PERCENT LIPID AND MOISTURE |
| TARGET PARAMETER LIST (TPL) |
| BIOLOGICAL | SEDIMENT | | | | |
| PARAMETER | | CRQL | UNITS | CRQL | UNITS |
| Percent Lipid | | 0.1 | | % | | NA* | | NA* |
| Percent Moisture | 0.1 | | % | | NA* | | NA* | |
| CRQL | see Attachment H2 - Definitions |
| * | NA = Not Applicable |
| % | percentage units |
TASK 2
GENERAL CHEMISTRY
TARGET PARAMETER LIST (TPL)
| BIOLOGICAL | SEDIMENTS | | | | |
| PARAMETER | | | CRQL | UNITS | CRQL | UNITS** |
| Percent Solids | | | | NA | | NA | | 1.0 | | % |
| Total Volatile Solids (E-11927) | | NA | | NA | | 0.1 | | % | | |
| Total Organic Carbon2 (E-10195) | NA | | NA | | 0.1 | | % | | | |
| Total Ammonia as N (7664-41-7) | NA | | NA | | 11.0 | | mg/kg | | | |
| Acid Volatile Sulfide (E-AVS) | | NA | | NA | | 19.0 | | mg/kg | | |
| Grain Size Analysis | | | NA | | NA | | 1.0 | | %@ | |
| Specific Gravity | | | NA | | NA | | 0.1 | | g/cm3 @@ | |
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| @ | A measure of the frequency distribution of the size ranges of particles. |
| @@ | Ratio of the mass of a given volume of sediment material at a specific temperature to an equal volume of distilled water at the same stated temperature. |
| ** | dry weight basis. |
| 2 | based on high-temperature combustion after acid treatment (Plumb 1981) |
| % | percentage units |
| mg/kg | milligrams per kilogram |
TASK 2B
GENERAL CHEMISTRY
| BIOLOGICAL | SEDIMENTS | | | |
| PARAMETER (CAS) | | CRQL | UNITS | CRQL | UNITS** |
| Nitrite + Nitrate | (E-10128) | | | NA | | NA | | 0.13 | | mg/kg |
| Total Kjeldahl Nitrogen | (E-10264) | | NA | | NA | | 6.3 | | mg/kg | |
| Extractable* Nitrogen | | | | NA | | NA | | | | mg/kg |
| Total Phosphorus (7723-14-0) | | | NA | | NA | | 3.2 | | mg/kg | |
| Ortho (reactive) Phosphorus | | | NA | | NA | | | | mg/kg | |
| Acid Hydrolyzable Phosphorus | | | NA | | NA | | | | mg/kg | |
| Organic Phosphorus | | | | NA | | NA | | | | mg/kg |
| Chemical Oxygen Demand (E-10117) | | NA | | NA | | 5.0 | | mg/kg | | |
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| * | Biologically available. |
| ** | dry weight basis. |
| mg/kg | milligrams per kilogram |
TASK 3
POLYCHLORINATED BIPHENYLS (PCB)
TARGET PARAMETER LIST (TPL)
Preparation 3540C (U.S. EPA 1996e) Method 8082A (U.S. EPA 2007d)
| CAS | BIOTA | | | SEDIMENT | | |
| PARAMETER | NUMBER | CRQL | UNITS* | | CRQL | UNITS |
Total PCBs 1336-36-3 20.0 ug/kg NA NA
| CRQL | see Attachment H2 - Definitions |
| * | wet weight basis |
| NA | Not Applicable. |
| ug/kg | micrograms per kilogram |
TASK 3B
POLYCHLORINATED BIPHENYL CONGENERS S (PCB)
SOILS, SEDIMENT, AND TISSUES BY CAPILLARY CHROMATOGRAPHY
TARGET PARAMETER LIST (TPL)
Method 1668 Rev. B (U.S. EPA 2008)
| CAS | BIOTA | | | SEDIMENT | | |
| PARAMETER | NUMBER | CRQL | UNITS* | | CRQL | UNITS** |
PCB congeners 0.5 - 20 ng/kg 0.5 - 20 ng/kg
| CRQL | see Attachment H2 – Definitions |
| * | wet weight basis |
| ** | dry weight basis |
| ng/kg | nonograms per kilogram |
Table of PCB Congeners and Other Species
| Descriptor |
| CASRN |
| Current BZ & IUPAC Number |
| IUPAC Name |
| Type |
| CP1_---_--_-- |
| 2051-60-7 |
| 1 |
| 2-Chlorobiphenyl |
| Congener |
| CP0_---_--_-- |
| 2051-61-8 |
| 2 |
| 3-Chlorobiphenyl |
| Congener |
| CP0_---_--_-- |
| 2051-62-9 |
| 3 |
| 4-Chlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 13029-08-8 |
| 4 |
| 2,2'-Dichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 16605-91-7 |
| 5 |
| 2,3-Dichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 25569-80-6 |
| 6 |
| 2,3'-Dichlorobiphenyl |
| Congener |
Task 3B continued
| Descriptor |
| CASRN |
| Current BZ & IUPAC Number |
| IUPAC Name |
| Type |
| CP1_---_--_-- |
| 33284-50-3 |
| 7 |
| 2,4-Dichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 34883-43-7 |
| 8 |
| 2,4'-Dichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 34883-39-1 |
| 9 |
| 2,5-Dichlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 33146-45-1 |
| 10 |
| 2,6-Dichlorobiphenyl |
| Congener |
| CP0_---_--_2M |
| 2050-67-1 |
| 11 |
| 3,3'-Dichlorobiphenyl |
| Congener |
| CP0_---_--_-- |
| 2974-92-7 |
| 12 |
| 3,4-Dichlorobiphenyl |
| Congener |
| CP0_---_--_-- |
| 2974-90-5 |
| 13 |
| 3,4'-Dichlorobiphenyl |
| Congener |
| CP0_---_--_2M |
| 34883-41-5 |
| 14 |
| 3,5-Dichlorobiphenyl |
| Congener |
| CP0_---_PP_-- |
| 2050-68-2 |
| 15 |
| 4,4'-Dichlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 38444-78-9 |
| 16 |
| 2,2',3-Trichlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 37680-66-3 |
| 17 |
| 2,2',4-Trichlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 37680-65-2 |
| 18 |
| 2,2',5-Trichlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 38444-73-4 |
| 19 |
| 2,2',6-Trichlorobiphenyl |
| Congener |
| CP1_---_--_2M |
| 38444-84-7 |
| 20 |
| 2,3,3'-Trichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 55702-46-0 |
| 21 |
| 2,3,4-Trichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 38444-85-8 |
| 22 |
| 2,3,4'-Trichlorobiphenyl |
| Congener |
| CP1_---_--_2M |
| 55720-44-0 |
| 23 |
| 2,3,5-Trichlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 55702-45-9 |
| 24 |
| 2,3,6-Trichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 55712-37-3 |
| 25 |
| 2,3',4-Trichlorobiphenyl |
| Congener |
| CP1_---_--_2M |
| 38444-81-4 |
| 26 |
| 2,3',5-Trichlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 38444-76-7 |
| 27 |
| 2,3',6-Trichlorobiphenyl |
| Congener |
| CP1_---_PP_-- |
| 7012-37-5 |
| 28 |
| 2,4,4'-Trichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 15862-07-4 |
| 29 |
| 2,4,5-Trichlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 35693-92-6 |
| 30 |
| 2,4,6-Trichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 16606-02-3 |
| 31 |
| 2,4',5-Trichlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 38444-77-8 |
| 32 |
| 2,4',6-Trichlorobiphenyl |
| Congener |
| CP1_---_--_-- |
| 38444-86-9 |
| 33 |
| 2,3',4'-Trichlorobiphenyl |
| Congener |
| CP1_---_--_2M |
| 37680-68-5 |
| 34 |
| 2,3',5'-Trichlorobiphenyl |
| Congener |
| CP0_---_--_2M |
| 37680-69-6 |
| 35 |
| 3,3',4-Trichlorobiphenyl |
| Congener |
| CP0_---_--_2M |
| 38444-87-0 |
| 36 |
| 3,3',5-Trichlorobiphenyl |
| Congener |
| CP0_---_PP_-- |
| 38444-90-5 |
| 37 |
| 3,4,4'-Trichlorobiphenyl |
| Congener |
| CP0_---_--_2M |
| 53555-66-1 |
| 38 |
| 3,4,5-Trichlorobiphenyl |
| Congener |
| CP0_---_--_2M |
| 38444-88-1 |
| 39 |
| 3,4',5-Trichlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 38444-93-8 |
| 40 |
| 2,2',3,3'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 52663-59-9 |
| 41 |
| 2,2',3,4-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 36559-22-5 |
| 42 |
| 2,2',3,4'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 70362-46-8 |
| 43 |
| 2,2',3,5-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 41464-39-5 |
| 44 |
| 2,2',3,5'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 70362-45-7 |
| 45 |
| 2,2',3,6-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 41464-47-5 |
| 46 |
| 2,2',3,6'-Tetrachlorobiphenyl |
| Congener |
Task 3B continued
| Descriptor |
| CASRN |
| Current BZ & IUPAC Number |
| IUPAC Name |
| Type |
| ---_4CL_PP_-- |
| 2437-79-8 |
| 47 |
| 2,2',4,4'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 70362-47-9 |
| 48 |
| 2,2',4,5-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 41464-40-8 |
| 49 |
| 2,2',4,5'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 62796-65-0 |
| 50 |
| 2,2',4,6-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 68194-04-7 |
| 51 |
| 2,2',4,6'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 35693-99-3 |
| 52 |
| 2,2',5,5'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 41464-41-9 |
| 53 |
| 2,2',5,6'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 15968-05-5 |
| 54 |
| 2,2',6,6'-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 74338-24-2 |
| 55 |
| 2,3,3',4-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 41464-43-1 |
| 56 |
| 2,3,3',4'-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 70424-67-8 |
| 57 |
| 2,3,3',5-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 41464-49-7 |
| 58 |
| 2,3,3',5'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74472-33-6 |
| 59 |
| 2,3,3',6-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_PP_-- |
| 33025-41-1 |
| 60 |
| 2,3,4,4'-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 33284-53-6 |
| 61 |
| 2,3,4,5-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 54230-22-7 |
| 62 |
| 2,3,4,6-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 74472-34-7 |
| 63 |
| 2,3,4',5-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 52663-58-8 |
| 64 |
| 2,3,4',6-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 33284-54-7 |
| 65 |
| 2,3,5,6-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_PP_-- |
| 32598-10-0 |
| 66 |
| 2,3',4,4'-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 73575-53-8 |
| 67 |
| 2,3',4,5-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 73575-52-7 |
| 68 |
| 2,3',4,5'-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 60233-24-1 |
| 69 |
| 2,3',4,6-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 32598-11-1 |
| 70 |
| 2,3',4',5-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 41464-46-4 |
| 71 |
| 2,3,4,6-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 41464-42-0 |
| 72 |
| 2,3,5,5-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74338-23-1 |
| 73 |
| 2,3,5,6-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_PP_-- |
| 32690-93-0 |
| 74 |
| 2,4,4,5-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 32598-12-2 |
| 75 |
| 2,4,4,6-Tetrachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 70362-48-0 |
| 76 |
| 2,3,4,5-Tetrachlorobiphenyl |
| Congener |
| CP0_4CL_PP_2M |
| 32598-13-3 |
| 77 |
| 3,3,4,4-Tetrachlorobiphenyl |
| Congener |
| CP0_4CL_--_2M |
| 70362-49-1 |
| 78 |
| 3,3,4,5-Tetrachlorobiphenyl |
| Congener |
| CP0_4CL_--_2M |
| 41464-48-6 |
| 79 |
| 3,3,4,5-Tetrachlorobiphenyl |
| Congener |
| CP0_4CL_--_2M |
| 33284-52-5 |
| 80 |
| 3,3,5,5-Tetrachlorobiphenyl |
| Congener |
| CP0_4CL_PP_2M |
| 70362-50-4 |
| 81 |
| 3,4,4,5-Tetrachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-62-4 |
| 82 |
| 2,2,3,3,4-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 60145-20-2 |
| 83 |
| 2,2,3,3,5-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-60-2 |
| 84 |
| 2,2,3,3,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 65510-45-4 |
| 85 |
| 2,2,3,4,4-Pentachlorobiphenyl |
| Congener |
Task 3B continued
| Descriptor |
| CASRN |
| Current BZ & IUPAC Number |
| IUPAC Name |
| Type |
| ---_4CL_--_2M |
| 55312-69-1 |
| 86 |
| 2,2,3,4,5-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 38380-02-8 |
| 87 |
| 2,2,3,4,5-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 55215-17-3 |
| 88 |
| 2,2,3,4,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 73575-57-2 |
| 89 |
| 2,2,3,4,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 68194-07-0 |
| 90 |
| 2,2,3,4,5-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 68194-05-8 |
| 91 |
| 2,2’,3,4’,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-61-3 |
| 92 |
| 2,2’,3,5,5’-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 73575-56-1 |
| 93 |
| 2,2’,3,5,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 73575-55-0 |
| 94 |
| 2,2’,3,5,6’-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 38379-99-6 |
| 95 |
| 2,2’,3,5’,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 73575-54-9 |
| 96 |
| 2,2’,3,6,6’-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 41464-51-1 |
| 97 |
| 2,2’,3,4’,5’-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 60233-25-2 |
| 98 |
| 2,2’,3,4’,6’-Pentachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 38380-01-7 |
| 99 |
| 2,2’,4,4’,5-Pentachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 39485-83-1 |
| 100 |
| 2,2’,4,4’,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 37680-73-2 |
| 101 |
| 2,2’,4,5,5’-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 68194-06-9 |
| 102 |
| 2,2’,4,5,6’-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 60145-21-3 |
| 103 |
| 2,2’,4,5’,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 56558-16-8 |
| 104 |
| 2,2’,4,6,6’-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_PP_2M |
| 32598-14-4 |
| 105 |
| 2,3,3’,4,4’-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 70424-69-0 |
| 106 |
| 2,3,3’,4,5-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 70424-68-9 |
| 107 |
| 2,3,3’,4’,5-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 70362-41-3 |
| 108 |
| 2,3,3’,4,5’-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74472-35-8 |
| 109 |
| 2,3,3’,4,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 38380-03-9 |
| 110 |
| 2,3,3’,4’,6-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 39635-32-0 |
| 111 |
| 2,3,3’,5,5’-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74472-36-9 |
| 112 |
| 2,3,3’,5,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 68194-10-5 |
| 113 |
| 2,3,3’,5’,6-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_PP_2M |
| 74472-37-0 |
| 114 |
| 2,3,4,4’,5-Pentachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 74472-38-1 |
| 115 |
| 2,3,4,4’,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 18259-05-7 |
| 116 |
| 2,3,4,5,6-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 68194-11-6 |
| 117 |
| 2,3,4',5,6-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_PP_2M |
| 31508-00-6 |
| 118 |
| 2,3',4,4',5-Pentachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 56558-17-9 |
| 119 |
| 2,3',4,4',6-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 68194-12-7 |
| 120 |
| 2,3',4,5,5'-Pentachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 56558-18-0 |
| 121 |
| 2,3',4,5',6-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 76842-07-4 |
| 122 |
| 2,3,3',4',5'-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_PP_2M |
| 65510-44-3 |
| 123 |
| 2,3',4,4',5'-Pentachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 70424-70-3 |
| 124 |
| 2,3',4',5,5'-Pentachlorobiphenyl |
| Congener |
Task 3B continued
| Descriptor |
| CASRN |
| Current BZ & IUPAC Number |
| IUPAC Name |
| Type |
| ---_4CL_--_2M |
| 74472-39-2 |
| 125 |
| 2,3',4',5',6-Pentachlorobiphenyl |
| Congener |
| CP0_4CL_PP_2M |
| 57465-28-8 |
| 126 |
| 3,3',4,4',5-Pentachlorobiphenyl |
| Congener |
| CP0_4CL_--_2M |
| 39635-33-1 |
| 127 |
| 3,3',4,5,5'-Pentachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 38380-07-3 |
| 128 |
| 2,2',3,3',4,4'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 55215-18-4 |
| 129 |
| 2,2',3,3',4,5-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-66-8 |
| 130 |
| 2,2',3,3',4,5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 61798-70-7 |
| 131 |
| 2,2',3,3',4,6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 38380-05-1 |
| 132 |
| 2,2',3,3',4,6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 35694-04-3 |
| 133 |
| 2,2',3,3',5,5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52704-70-8 |
| 134 |
| 2,2',3,3',5,6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52744-13-5 |
| 135 |
| 2,2',3,3',5,6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 38411-22-2 |
| 136 |
| 2,2',3,3',6,6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 35694-06-5 |
| 137 |
| 2,2',3,4,4',5-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 35065-28-2 |
| 138 |
| 2,2',3,4,4',5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 56030-56-9 |
| 139 |
| 2,2',3,4,4',6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 59291-64-4 |
| 140 |
| 2,2',3,4,4',6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52712-04-6 |
| 141 |
| 2,2',3,4,5,5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 41411-61-4 |
| 142 |
| 2,2',3,4,5,6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 68194-15-0 |
| 143 |
| 2,2',3,4,5,6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 68194-14-9 |
| 144 |
| 2,2',3,4,5',6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 74472-40-5 |
| 145 |
| 2,2',3,4,6,6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 51908-16-8 |
| 146 |
| 2,2',3,4',5,5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 68194-13-8 |
| 147 |
| 2,2',3,4',5,6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74472-41-6 |
| 148 |
| 2,2',3,4',5,6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 38380-04-0 |
| 149 |
| 2,2',3,4',5',6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_-- |
| 68194-08-1 |
| 150 |
| 2,2',3,4',6,6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-63-5 |
| 151 |
| 2,2',3,5,5',6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 68194-09-2 |
| 152 |
| 2,2',3,5,6,6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 35065-27-1 |
| 153 |
| 2,2',4,4',5,5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 60145-22-4 |
| 154 |
| 2,2',4,4',5,6'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 33979-03-2 |
| 155 |
| 2,2',4,4',6,6'-Hexachlorobiphenyl |
| Congener |
| CP1_4CL_PP_2M |
| 38380-08-4 |
| 156 |
| 2,3,3',4,4',5-Hexachlorobiphenyl |
| Congener |
| CP1_4CL_PP_2M |
| 69782-90-7 |
| 157 |
| 2,3,3',4,4',5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 74472-42-7 |
| 158 |
| 2,3,3',4,4',6-Hexachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 39635-35-3 |
| 159 |
| 2,3,3',4,5,5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 41411-62-5 |
| 160 |
| 2,3,3',4,5,6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74472-43-8 |
| 161 |
| 2,3,3',4,5',6-Hexachlorobiphenyl |
| Congener |
| CP1_4CL_--_2M |
| 39635-34-2 |
| 162 |
| 2,3,3',4',5,5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74472-44-9 |
| 163 |
| 2,3,3',4',5,6-Hexachlorobiphenyl |
| Congener |
Task 3B continued
| Descriptor |
| CASRN |
| Current BZ & IUPAC Number |
| IUPAC Name |
| Type |
| ---_4CL_--_2M |
| 74472-45-0 |
| 164 |
| 2,3,3',4',5',6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74472-46-1 |
| 165 |
| 2,3,3',5,5',6-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 41411-63-6 |
| 166 |
| 2,3,4,4',5,6-Hexachlorobiphenyl |
| Congener |
| CP1_4CL_PP_2M |
| 52663-72-6 |
| 167 |
| 2,3',4,4',5,5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 59291-65-5 |
| 168 |
| 2,3',4,4',5',6-Hexachlorobiphenyl |
| Congener |
| CP0_4CL_PP_2M |
| 32774-16-6 |
| 169 |
| 3,3',4,4',5,5'-Hexachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 35065-30-6 |
| 170 |
| 2,2',3,3',4,4',5-Heptachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 52663-71-5 |
| 171 |
| 2,2',3,3',4,4',6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-74-8 |
| 172 |
| 2,2',3,3',4,5,5'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 68194-16-1 |
| 173 |
| 2,2',3,3',4,5,6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 38411-25-5 |
| 174 |
| 2,2',3,3',4,5,6'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 40186-70-7 |
| 175 |
| 2,2',3,3',4,5',6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-65-7 |
| 176 |
| 2,2',3,3',4,6,6'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-70-4 |
| 177 |
| 2,2',3,3',4,5',6'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-67-9 |
| 178 |
| 2,2',3,3',5,5',6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-64-6 |
| 179 |
| 2,2',3,3',5,6,6'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 35065-29-3 |
| 180 |
| 2,2',3,4,4',5,5'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 74472-47-2 |
| 181 |
| 2,2',3,4,4',5,6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 60145-23-5 |
| 182 |
| 2,2',3,4,4',5,6'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 52663-69-1 |
| 183 |
| 2,2',3,4,4',5',6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_PP_-- |
| 74472-48-3 |
| 184 |
| 2,2',3,4,4',6,6'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52712-05-7 |
| 185 |
| 2,2',3,4,5,5',6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74472-49-4 |
| 186 |
| 2,2',3,4,5,6,6'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-68-0 |
| 187 |
| 2,2',3,4',5,5',6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74487-85-7 |
| 188 |
| 2,2',3,4',5,6,6'-Heptachlorobiphenyl |
| Congener |
| CP1_4CL_PP_2M |
| 39635-31-9 |
| 189 |
| 2,3,3',4,4',5,5'-Heptachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 41411-64-7 |
| 190 |
| 2,3,3',4,4',5,6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 74472-50-7 |
| 191 |
| 2,3,3',4,4',5',6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 74472-51-8 |
| 192 |
| 2,3,3',4,5,5',6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 69782-91-8 |
| 193 |
| 2,3,3',4',5,5',6-Heptachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 35694-08-7 |
| 194 |
| 2,2',3,3',4,4',5,5'-Octachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 52663-78-2 |
| 195 |
| 2,2',3,3',4,4',5,6-Octachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 42740-50-1 |
| 196 |
| 2,2',3,3',4,4',5,6'-Octachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 33091-17-7 |
| 197 |
| 2,2',3,3',4,4',6,6'-Octachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 68194-17-2 |
| 198 |
| 2,2',3,3',4,5,5',6-Octachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-75-9 |
| 199 |
| 2,2',3,3',4,5,5',6'-Octachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-73-7 |
| 200 |
| 2,2',3,3',4,5,6,6'-Octachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 40186-71-8 |
| 201 |
| 2,2',3,3',4,5',6,6'-Octachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 2136-99-4 |
| 202 |
| 2,2',3,3',5,5',6,6'-Octachlorobiphenyl |
| Congener |
Task 3B continued
| Descriptor |
| CASRN |
| Current BZ & IUPAC Number |
| IUPAC Name |
| Type |
| ---_4CL_PP_2M |
| 52663-76-0 |
| 203 |
| 2,2',3,4,4',5,5',6-Octachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 74472-52-9 |
| 204 |
| 2,2',3,4,4',5,6,6'-Octachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 74472-53-0 |
| 205 |
| 2,3,3',4,4',5,5',6-Octachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 40186-72-9 |
| 206 |
| 2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl |
| Congener |
| ---_4CL_PP_2M |
| 52663-79-3 |
| 207 |
| 2,2',3,3',4,4',5,6,6'-Nonachlorobiphenyl |
| Congener |
| ---_4CL_--_2M |
| 52663-77-1 |
| 208 |
| 2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl |
| Congener |
| ---_---_--_-- |
| 2051-24-3 |
| 209 |
| Decachlorobiphenyl |
| Congener |
27323-18-8
| Monochlorobiphenyl |
| Homolog |
25512-42-9
25323-68-6
| Trichlorobiphenyl |
| Homolog |
26914-33-0
| Tetrachlorobiphenyl |
| Homolog |
25429-29-2
| Pentachlorobiphenyl |
| Homolog |
26601-64-9
| Hexachlorobiphenyl |
| Homolog |
28655-71-2
| Heptachlorobiphenyl |
| Homolog |
55722-26-4
| Octachlorobiphenyl |
| Homolog |
53742-07-7
| Nonachlorobiphenyl |
| Homolog |
12674-11-2
147601-87-4
151820-27-8
11104-28-2
37234-40-5
11141-16-5
71328-89-7
53469-21-9
12672-29-6
165245-51-2
89577-78-6
11097-69-1
11096-82-5
37324-23-5
11100-14-4
12767-79-2
| Aroclor (unspecified) |
| Mixture |
1336-36-3
| Polychlorinated biphenyl (PCB) |
| Category |
TASK 3C
POLYCHLORINATED DIOXINS AND FURANS
Method 1613 Rev. B (U.S. EPA 1994b)
| | CAS | BIOLOGICAL | | SEDIMENT |
| PARAMETER | NUMBER | CRQL | UNITS* | CRQL | UNITS** |
| 2,3,7,8-TCDF | | 51207-31-9 | 1.0 | | ng/kg | | 1.0 | | ng/kg | |
| 2,3,7,8-TCDD (Dioxin) | 1746-01-6 | 1.0 | | ng/kg | | 1.0 | | ng/kg | | |
| 1,2,3,7,8-PeCDF | 57117-41-6 | 2.5 | | ng/kg | | 2.5 | | ng/kg | | |
| 2,3,4,7,8-PeCDF | 57117-31-4 | 2.5 | | ng/kg | | 2.5 | | ng/kg | | |
| 1,2,3,7,8-PeCDD | 40321-76-4 | 2.5 | | ng/kg | | 2.5 | | ng/kg | | |
| 1,2,3,4,7,8-HxCDF | 70648-26-9 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| 1,2,3,6,7,8-HxCDF | 57117-44-9 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| 2,3,4,6,7,8-HxCDF | 60851-34-5 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| 1,2,3,4,7,8-HxCDD | 39227-28-6 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| 1,2,3,6,7,8-HxCDD | 57653-85-7 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| 1,2,3,7,8,9-HxCDD | 19408-74-3 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| 1,2,3,7,8,9-HxCDF | 72918-21-9 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| 1,2,3,4,6,7,8-HpCDF | 67562-39-4 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| 1,2,3,4,6,7,8-HpCDD | 35822-46-9 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| 1,2,3,4,7,8,9-HpCDF | 55673-89-7 | 5.0 | | ng/kg | | 5.0 | | ng/kg | | |
| OCDD | | | 3268-87-9 | 5.0 | | ng/kg | | 5.0 | | ng/kg |
| OCDF | | | 39001-02-0 | 5.0 | | ng/kg | | 5.0 | | ng/kg |
| CRQL | see Attachment H2 – Definitions |
| * | wet weight basis |
| ** | dry weight basis |
| TCDD | = Tetrachlorodibenzo-dioxin |
| TCDF | = Tetrachlorodibenzofuran |
| PeCDD | = Pentachlorodibenzo-p-dioxin |
| PeCDF | = Pentachlorodibenzofuran |
| HxCDD | = Hexachlorodibenzo-p-dioxin |
| HxCDF | = Hexachlorodibenzofuran |
| HpCDD | = Heptachlorodibenzo-p-dioxin |
| HpCDF | = Heptachlorodibenzofuran |
| OCDD | = Octachlorodibenzo-p-dioxin |
| OCDF | = Octachlorodibenzofuran |
RFP-25-81029
Attachment D6 Technical Specifications Tasks List ng/kg nanograms per kilogram
TASK 4
POLYCHLORINATED BIPHENYLS (PCB) AROCLORS
TARGET PARAMETER LIST (TPL)
Method 8082A (U.S. EPA 2007d)
| | CAS | BIOLOGICAL | | SEDIMENT |
| PARAMETER | NUMBER | CRQL | UNITS* | CRQL | UNITS** |
| Aroclor - 1016 | 12674-11-2 | NA* | NA* | 20.0 | ug/kg |
| Aroclor - 1221 | 11104-28-2 | NA* | NA* | 20.0 | ug/kg |
| Aroclor - 1232 | 11141-16-5 | NA* | NA* | 20.0 | ug/kg |
| Aroclor - 1242 | 53469-21-9 | NA* | NA* | 20.0 | ug/kg |
| Aroclor - 1248 | 12672-29-6 | NA* | NA* | 20.0 | ug/kg |
| Aroclor - 1254 | 11097-69-1 | NA* | NA* | 20.0 | ug/kg |
| Aroclor - 1260 | 11096-82-5 | NA* | NA* | 20.0 | ug/kg |
| Aroclor - 1262 | 37324-23-5 | NA* | NA* | 20.0 | ug/kg |
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 5
ORGANOCHLORINE PESTICIDES
TARGET PARAMETER LIST (TPL)
Method 8081B (U.S. EPA 2007c)
| CAS | BIOTA | | | SEDIMENT | | |
| PARAMETER | NUMBER | CRQL | UNITS* | | CRQL | UNIT** |
| Aldrin | | | 309-00-2 | 2.5 | | | | ug/kg | | 2.5 | | ug/kg |
| BHC, alpha- | | 319-84-6 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | |
| BHC, beta- | | 319-85-7 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | |
| BHC, delta- | | 319-86-8 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | |
| BHC, gamma- | | 58-89-9 | | 2.5 | | | ug/kg | | 2.5 | | ug/kg | |
| Chlordane, gamma(trans) | 5103-74-2 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | | |
| Chlordane, alpha(cis) | 5103-71-9 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | | |
| DDD, o,p'- | | 53-19-0 | | 2.5 | | | ug/kg | | 2.5 | | ug/kg | |
| DDD, p,p'- | | 72-54-8 | | 5.0 | | | ug/kg | | 5.0 | | ug/kg | |
| DDE, o,p'- | | 3424-82-6 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | |
| DDE, p,p'- | | 72-55-9 | | 5.0 | | | ug/kg | | 5.0 | | ug/kg | |
| DDT, o,p'- | | 789-02-6 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | |
| DDT, p,p'- | | 50-29-3 | | 5.0 | | | ug/kg | | 5.0 | | ug/kg | |
| Dieldrin | | 60-57-1 | | 5.0 | | | ug/kg | | 5.0 | | ug/kg | |
| Endosulfan I | | 959-98-8 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | |
| Endosulfan II | | 33213-65-9 | 5.0 | | | ug/kg | | 5.0 | | ug/kg | | |
| Endosulfan sulfate | 1031-07-8 | 5.0 | | | ug/kg | | 5.0 | | ug/kg | | | |
| Endrin | | | 72-20-8 | | 5.0 | | | ug/kg | | 5.0 | | ug/kg |
| Endrin aldehyde | 7421-93-4 | 5.0 | | | ug/kg | | 5.0 | | ug/kg | | | |
| Endrin ketone | | 53494-70-5 | 5.0 | | | ug/kg | | 5.0 | | ug/kg | | |
| Heptachlor | | 76-44-8 | | 2.5 | | | ug/kg | | 2.5 | | ug/kg | |
| Heptachlor epoxide | 1024-57-3 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | | |
| Hexachlorobenzene | 118-74-1 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | | |
| Methoxychlor | | 72-43-5 | | 25.0 | | | ug/kg | | 25.0 | | ug/kg | |
| Mirex | | | 2385-85-5 | 5.0 | | | ug/kg | | 5.0 | | ug/kg | |
| cis- Nonachlor | | 5103-73-1 | 5.0 | | | ug/kg | | 5.0 | | ug/kg | | |
| trans- Nonachlor | 39765-80-5 | 5.0 | | | ug/kg | | 5.0 | | ug/kg | | | |
| Oxychlordane | | 27304-13-8 | 5.0 | | | ug/kg | | 5.0 | | ug/kg | | |
| Pentachloroanisole | 1825-21-4 | 2.5 | | | ug/kg | | 2.5 | | ug/kg | | | |
| Toxaphene | | 8001-35-2 | 75.0 | | | ug/kg | | 75.0 | | ug/kg | | |
| CRQL | see Attachment H2 - Definitions | |
| * | wet weight basis | |
| ** | dry weight basis ug/kg | micrograms per kilogram |
TASK 5B
ORGANOPHOSPHATE PESTICIDES
TARGET PARAMETER LIST (TPL)
Method 8141B (U.S. EPA 2007c)
| CAS | BIOTA | | | SEDIMENT | | |
| PARAMETER | NUMBER | CRQL | UNITS* | | CRQL | UNIT** |
| Chlorpyrifos | 2921-88-2 | 10 | | | ug/kg | | 10 | | ug/kg |
| Diazinon | 333-41-5 | 10 | | ug/kg | | 10 | | ug/kg | |
| Disulfoton | 298-04-4 | 10 | | ug/kg | | 10 | | ug/kg | |
| Ethion | | 563-12-2 | 10 | | ug/kg | | 10 | | ug/kg |
| Terbufos | 13071-79-9 | 10 | | ug/kg | | 10 | | ug/kg | |
| CRQL | see Attachment H2 - Definitions | |
| * | wet weight basis | |
| ** | dry weight basis ug/kg | micrograms per kilogram |
TASK 5C
CHLOROPHENOXY HERBICIDES
TARGET PARAMETER LIST (TPL)
GC-MS
| CAS | BIOTA | | | SEDIMENT | | |
| PARAMETER | NUMBER | CRQL | UNITS* | | CRQL | UNIT** |
Oxyfluorfen 42874-03-3 10 ug/kg 10 ug/kg
| CRQL | see Attachment H2 - Definitions | |
| * | wet weight basis | |
| ** | dry weight basis ug/kg | micrograms per kilogram |
TASK 6
INORGANICS
TARGET PARAMETER LIST (TPL)
Method 6020A (U.S. EPA 2007a)
| CAS | BIOLOGICAL | | | SEDIMENT | | |
| PARAMETER | NUMBER | CRQL | UNITS* | | CRQL | UNITS** |
| Cadmium | 7440-43-9 | 10.0 | | ug/kg | | 200.0 | | ug/kg | |
| Lead | | 7439-92-1 | 70.0 | | ug/kg | | 500.0 | | ug/kg |
| Arsenic | | 7440-38-2 | 1,000 | | ug/kg | | 2,000 | | ug/kg |
| Selenium | 7782-49-2 | 100 | | ug/kg | | 500 | | ug/kg | |
| CRQL | see Attachment H2 – Definitions |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 6A
INORGANICS
TARGET PARAMETER LIST (TPL)
Method 6020A (U.S. EPA 2007a)
| CAS | BIOLOGICAL | | | SEDIMENT | | |
| PARAMETER | NUMBER | CRQL | UNITS* | | CRQL | UNITS** |
| Cadmium | 7440-43-9 | 10.0 | | ug/kg | | 200 | | ug/kg | |
| Chromium | 7440-47-3 | 100 | | ug/kg | | 800 | | ug/kg | |
| Copper | | 7440-50-8 | 100 | | ug/kg | | 500 | | ug/kg |
| Lead | | 7439-92-1 | 70.0 | | ug/kg | | 500 | | ug/kg |
| Mercury | 7439-97-6 | 20.0 | | ug/kg | | 20.0 | | ug/kg | |
| Nickel | | 7440-02-0 | 1,000 | | ug/kg | | 250 | | ug/kg |
| Selenium | 7782-49-2 | 100 | | ug/kg | | 500 | | ug/kg | |
| Zinc | | 7440-66-6 | 2,000 | | ug/kg | | 500 | | ug/kg |
| CRQL | see Attachment H2 - Definitions |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 6B
INORGANICS
TARGET PARAMETER LIST (TPL)
Method 6020A (U.S. EPA 2007a)
| CAS | BIOLOGICAL | SEDIMENT | | | |
| PARAMETER | NUMBER | CRQL | UNITS* | CRQL | UNITS** |
| Aluminum | 7429-90-5 | 5,000 | | ug/kg | | 1,500 | | ug/kg | |
| Antimony | 7440-36-0 | 2,000 | | ug/kg | | 1,000 | | ug/kg | |
| Arsenic | | 7440-38-2 | 1,000 | | ug/kg | | 2,000 | | ug/kg |
| Barium | | 7440-39-3 | 5,000 | | ug/kg | | 1,500 | | ug/kg |
| Beryllium | 7440-41-7 | 500 | | ug/kg | | 1,500 | | ug/kg | |
| Cadmium | 7440-43-9 | 10.0 | | ug/kg | | 200 | | ug/kg | |
| Calcium | 7440-70-2 500,000 | | ug/kg | | 5,000 | | ug/kg | | |
| Chromium | 7440-47-3 | 100 | | ug/kg | | 800 | | ug/kg | |
| Cobalt | | 7440-48-4 | 5,000 | | ug/kg | | 200 | | ug/kg |
| Copper | | 7440-50-8 | 100 | | ug/kg | | 500 | | ug/kg |
| Iron | | 7439-89-6 | 5,000 | | ug/kg | | 5,000 | | ug/kg |
| Lead | | 7439-92-1 | 70.0 | | ug/kg | | 500 | | ug/kg |
| Magnesium | 7439-95-4 500,000 | | ug/kg | | 3,000 | | ug/kg | | |
| Manganese | 7439-96-5 1,500 | | ug/kg | | 200 | | ug/kg | | |
| Mercury | 7439-97-6 | 20.0 | | ug/kg | | 20.0 | | ug/kg | |
| Nickel | | 7440-02-0 | 1,000 | | ug/kg | | 250 | | ug/kg |
| Potassium | 7440-09-7 500,000 | | ug/kg | | 60,000 | | ug/kg | | |
| Selenium | 7782-49-2 | 100 | | ug/kg | | 500 | | ug/kg | |
| Silver | | 7440-22-4 | 500 | | ug/kg | | 200 | | ug/kg |
| Sodium | | 7440-23-5 10,000 | | ug/kg | | 6,000 | | ug/kg | |
| Thallium | 7440-28-0 | 1,000 | | ug/kg | | 500 | | ug/kg | |
| Vanadium | 7440-62-2 | 2,000 | | ug/kg | | 1,000 | | ug/kg | |
| Zinc | | 7440-66-6 | 2,000 | | ug/kg | | 500 | | ug/kg |
| CRQL | see Attachment H2 - Definitions |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 6C
INORGANICS
TARGET PARAMETER LIST (TPL)
Method 1678 (U.S. EPA 1999a) Method 9012 (U.S. EPA 2004a) Method 9014 (U.S. EPA 1996f)
| CAS | BIOLOGICAL | | SEDIMENT | | | |
| PARAMETER | NUMBER | CRQL | | UNITS | CRQL | UNITS** |
Total Cyanide 57-12-5 NA NA 250 ug/kg
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 6D
ACID VOLATILE SULFIDE (AVS) AND SIMULTANEOUSLY EXTRACTED METALS (SEM)
TARGET PARAMETER LIST (TPL)
Method Draft: (U.S. EPA 1991a)
| CAS | BIOLOGICAL | | SEDIMENT | | | |
| PARAMETER | NUMBER | CRQL | | UNITS | CRQL | UNITS** |
| Acid Volatile Sulfide@ | E-AVS | NA | | NA | | 20.0 | | ug/kg | | |
| Cadmium @ | | 7440-43-9 | NA | | NA | | 500 | | ug/kg | |
| Copper @ | | 7440-50-8 | NA | | NA | | 500 | | ug/kg | |
| Lead @ | | | 7439-92-1 | NA | | NA | | 500 | | ug/kg |
| Mercury @ | | 7439-97-6 | NA | | NA | | 20.0 | | ug/kg | |
| Nickel @ | | 7440-02-0 | NA | | NA | | 500 | | ug/kg | |
| Zinc @ | | | 7440-66-6 | NA | | NA | | 500 | | ug/kg |
| CRQL | see Attachment H2 - Definitions | | | | | | | | | |
| NA | Not Applicable. | | | | | | | | | |
| ** | dry weight basis | | | | | | | | | |
| ug/kg | micrograms per kilogram | | | | | | | | | |
| @ | Must also be reported in micromoles/gram (umole/g) dry sediment weight basis. The sample data summary report must include a proper calculation of the ratio of simultaneously extracted metals to acid volatile sulfides as described in Section 14 page 16 of the analytical method (U.S. EPA, 1991). | | | | | | | | | |
TASK 6E
ORGANOTIN
TARGET PARAMETER LIST (TPL)
Method 8323 (U.S. EPA 2003b)
| CAS | BIOLOGICAL | | SEDIMENT | | | |
| PARAMETER | NUMBER | CRQL | | UNITS* | CRQL | UNITS** |
Tributyltin 688-73-3 10.0 ug/kg 10.0 ug/kg
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 6F
Arsenic Speciation
TARGET PARAMETER LIST (TPL)
Method 1632A (U.S. EPA 1998)
| CAS | BIOLOGICAL | | SEDIMENT | | | |
| PARAMETER | NUMBER | CRQL | | UNITS* | CRQL | UNITS** |
Total Inorganic
| Arsenic (As) | 7439-97-6 | 10.0 | ug/kg | 10.0 | ug/kg |
| Arsenite (As+3) | 7784-46-5 | 10.0 | ug/kg | 10.0 | ug/kg |
| Arsenate (As+5) | 15584-04-0 | 20.0 | ug/kg | 20.0 | ug/kg |
Monomethylarsonic Acid (MMA) 124-58-3 10.0 ug/kg 10.0 ug/kg Dimethylarsinic Acid DMA 75-60-5 10.0 ug/kg 10.0 ug/kg
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 6G
Total Mercury
Method 1631 (U.S. EPA 2001b)
| CAS | BIOLOGICAL | | SEDIMENT | | | |
| PARAMETER | NUMBER | CRQL | | UNITS* | CRQL | UNITS** |
Mercury 7439-97-6 1.0 ug/kg 1.0 ug/kg
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 6F
Total Mercury Methyl Mercury
Method 1631 (U.S. EPA 2001b) Method 1630 (U.S. EPA 2001a)
| CAS | BIOLOGICAL | | SEDIMENT | | | |
| PARAMETER | NUMBER | CRQL | | UNITS* | CRQL | UNITS** |
| Mercury | 7439-97-6 | 1.0 | ug/kg | 1.0 | ug/kg |
| Methyl Mercury | 22967-92-6 | 1.0 | ug/kg | 1.0 | ug/kg |
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 7
ACID EXTRACTABLE SEMIVOLATILE ORGANICS
TARGET PARAMETER LIST (TPL)
Method 8270D (U.S. EPA 2007e)
| CAS | BIOLOGICAL | | | SEDIMENT | | |
| PARAMETER | | | NUMBER | CRQL | UNITS* | CRQL | UNITS** |
| Benzoic acid | | 65-85-0 | 330 | | ug/kg | | 660 | | ug/kg |
| Chlorophenol, 2- | 95-57-8 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dichlorophenol, 2,4- | 120-83-2 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dimethylphenol, 2,4- | 105-67-9 | 330 | | ug/kg | | 660 | | ug/kg | |
| Nitrophenol, | 2- | 88-75-5 | 330 | | ug/kg | | 660 | | ug/kg |
| Dinitrophenol, 2,4- | 51-28-5 | 330 | | ug/kg | | 660 | | ug/kg | |
| Methylphenol, 2- | 95-48-7 | 330 | | ug/kg | | 660 | | ug/kg | |
| Methylphenol, 4- | 106-44-5 | 330 | | ug/kg | | 660 | | ug/kg | |
Chloro-3- Methylphenol, 4- 59-50-7 330 ug/kg 660 ug/kg Dinitro-2-
| Methylphenol, 4,6- | 534-52-1 | 330 | | ug/kg | | | 660 | | | ug/kg | | |
| Nitrophenol, 4- | | 100-02-7 | 330 | | ug/kg | | | 660 | | | ug/kg | |
| Pentachlorophenol | 87-86-5 | 330 | | ug/kg | | | 660 | | | ug/kg | | |
| Phenol | | | 108-95-2 | 330 | | ug/kg | | | 660 | | | ug/kg |
| Trichlorophenol, 2,4,5- | 95-95-4 | 330 | | ug/kg | | | 660 | | | ug/kg | | |
| Trichlorophenol, 2,4,6- | 88-06-02 | 330 | | ug/kg | | | 660 | | | ug/kg | | |
| CRQL | see Attachment H2 - Definitions |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 8
BASE/NEUTRAL EXTRACTABLE SEMIVOLATILE ORGANICS
TARGET PARAMETER LIST (TPL)
Method 8270D (U.S. EPA 2007e)
| CAS | BIOLOGICAL | | SEDIMENT | | |
| PARAMETER | | NUMBER | CRQL | UNITS* | CRQL | UNITS** |
| Acenaphthylene | 208-96-8 | 330 | | ug/kg | | 660 | | ug/kg | |
| Acenaphthene | | 83-32-9 | 330 | | ug/kg | | 660 | | ug/kg |
| Anthracene | | 120-12-7 | 330 | | ug/kg | | 660 | | ug/kg |
| Benzo(a)anthracene | 56-55-3 | 330 | | ug/kg | | 660 | | ug/kg | |
| Benzo(a)pyrene | | 50-32-8 | 330 | | ug/kg | | 660 | | ug/kg |
| Benzo(b)fluoranthene | 205-99-2 | 330 | | ug/kg | | 660 | | ug/kg | |
| Benzo(k)fluoranthene | 207-08-9 | 330 | | ug/kg | | 660 | | ug/kg | |
| Benzo(g,h,i)perylene | 191-24-2 | 330 | | ug/kg | | 660 | | ug/kg | |
| Benzyl alcohol | | 100-51-6 | 330 | | ug/kg | | 660 | | ug/kg |
Bis(2-chloroethoxy)
| Methane | | 111-91-1 | 330 | | ug/kg | | 660 | | ug/kg |
| Bis(2-chloroethyl) Ether | 111-44-4 | 330 | | ug/kg | | 660 | | ug/kg | |
Oxybis- (1-Chloropropane),
| 2,2'- | | 108-60-1 | 330 | | ug/kg | | 660 | | ug/kg |
| Bis(2-ethylhexyl) Phthalate | 117-81-7 | 330 | | ug/kg | | 660 | | ug/kg | |
Bromophenyl Phenyl
| Ether, 4- | | 101-55-3 | 330 | | ug/kg | | 660 | | ug/kg |
| Butylbenzylphthalate | 85-68-7 | 330 | | ug/kg | | 660 | | ug/kg | |
| Carbazole | | 86-74-8 | 330 | | ug/kg | | 660 | | ug/kg |
| Chloroaniline, 4- | 106-47-8 | 330 | | ug/kg | | 660 | | ug/kg | |
| Chloronaphthalene, 2- | 91-58-7 | 330 | | ug/kg | | 660 | | ug/kg | |
| Chlorophenyl Phenyl Ether, 4- | 7005-72-3 | 330 | | ug/kg | | 660 | | ug/kg | |
| Chrysene | | 218-01-9 | 330 | | ug/kg | | 660 | | ug/kg |
| Dibenzo(a,h)anthracene | 53-70-3 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dibenzofuran | | 132-64-9 | 330 | | ug/kg | | 660 | | ug/kg |
| Di-N-butylphthalate | 84-74-2 | 330 | | ug/kg | | 660 | | ug/kg | |
| Diethylphthalate | 84-66-2 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dimethylphthalate | 131-11-3 | 330 | | ug/kg | | 660 | | ug/kg | |
| Di-N-Octylphthalate | 117-84-0 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dichlorobenzene, 1,2- | 95-50-1 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dichlorobenzene, 1,3- | 541-73-1 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dichlorobenzene, 1,4- | 106-46-7 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dichlorobenzidine, 3,3'- | 91-94-1 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dinitrotoluene, 2,4- | 121-14-2 | 330 | | ug/kg | | 660 | | ug/kg | |
| Dinitrotoluene, 2,6- | 606-20-2 | 330 | | ug/kg | | 660 | | ug/kg | |
| Fluorene | | 86-73-7 | 330 | | ug/kg | | 660 | | ug/kg |
| Fluoranthene | | 206-44-0 | 330 | | ug/kg | | 660 | | ug/kg |
| Hexachlorobenzene | 118-74-1 | 330 | | ug/kg | | 660 | | ug/kg | |
Task 8 continued
| CAS | BIOLOGICAL | | SEDIMENT | | |
| PARAMETER | | NUMBER | CRQL | UNITS* | CRQL | UNITS** |
| Hexachlorobutadiene | 87-68-3 | 330 | | ug/kg | | | 660 | | ug/kg | | |
| Hexachlorocyclopentadiene | 77-47-4 | 330 | | ug/kg | | | 660 | | ug/kg | | |
| Hexachloroethane | 67-72-1 | 330 | | ug/kg | | | 660 | | ug/kg | | |
| Indeno(1,2,3-cd)pyrene | 193-39-5 | 330 | | ug/kg | | | 660 | | ug/kg | | |
| Isophorone | | 78-59-1 | 330 | | ug/kg | | | 660 | | ug/kg | |
| Methylnaphthalene, 2- | 91-57-6 | 330 | | ug/kg | | | 660 | | ug/kg | | |
| Naphthalene | | 91-20-3 | 330 | | ug/kg | | | 660 | | ug/kg | |
| Nitroaniline, 2- | | 88-74-4 | 330 | | ug/kg | | | 660 | | ug/kg | |
| Nitroaniline, 3- | | 99-09-2 | 330 | | ug/kg | | | 660 | | ug/kg | |
| Nitroaniline, 4- | | 100-01-6 | 330 | | ug/kg | | | 660 | | ug/kg | |
| Nitrobenzene | | 98-95-3 | 330 | | ug/kg | | | 660 | | ug/kg | |
| Nitrosodiphenylamine, N- | 86-30-6 | 330 | | ug/kg | | | 660 | | ug/kg | | |
| N-Nitrosodi-n-propylamine | 621-64-7 | 330 | | ug/kg | | | 660 | | ug/kg | | |
| Phenanthrene | | 85-01-8 | 330 | | ug/kg | | | 660 | | ug/kg | |
| Pyrene | | | 129-00-0 | 330 | | ug/kg | | | 660 | | ug/kg |
| Trichlorobenzene, 1,2,4- | 120-82-1 | 330 | | ug/kg | | | 660 | | ug/kg | | |
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 9
VOLATILE ORGANICS
TARGET PARAMETER LIST (TPL)
Method 8260C (U.S. EPA 2006)
| CAS | BIOLOGICAL | | SEDIMENT | | |
| PARAMETER | | NUMBER | CRQL | UNITS* | CRQL | UNITS** |
| Acetone | | | 67-64-1 | 10.0 | | ug/kg | | 10.0 | | ug/kg |
| Benzene | | | 71-43-2 | 5.0 | | ug/kg | | 5.0 | | ug/kg |
| Bromodichloromethane | 75-27-4 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | |
| Bromomethane | | 74-83-9 | 10.0 | | ug/kg | | | 10.0 | | ug/kg |
| Butanone, 2- (MEK) | 78-93-3 | 10.0 | | ug/kg | | | 10.0 | | ug/kg | |
| Carbon Disulfide | | 75-15-0 | 5.0 | | ug/kg | | | 5.0 | | ug/kg |
| Chlorobenzene | | 108-90-7 | 5.0 | | ug/kg | | | 5.0 | | ug/kg |
| Chloroethane | | 75-00-3 | 10.0 | | ug/kg | | | 10.0 | | ug/kg |
| Chloroethyl-Vinyl-Ether, 2- | 110-75-8 | 10.0 | | ug/kg | | | 10.0 | | ug/kg | |
| Chloromethane | | 74-87-3 | 10.0 | | ug/kg | | | 10.0 | | ug/kg |
| Dibromochloromethane | 124-48-1 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | |
| Dichloroethane, 1,1- | 75-34-3 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | |
| Dichloroethane, 1,2,- | 107-06-2 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | |
| Dichloroethene, 1,1- | 75-35-4 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | |
| Dichloroethene, 1,2-(total) | 540-59-0 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | |
Dichloromethane
| (Methylene chloride) | 75-09-2 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | | |
| Dichloropropane,1,2- | 78-87-5 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | | |
| Dichloropropene, cis-1,3- | 10061-01-5 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | | |
| Dichloropropene, trans-1,3- | 10061-02-6 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | | |
| Ethylbenzene | | 100-41-4 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | |
| Hexanone, 2- (MBK) | 591-78-6 | 10.0 | | ug/kg | | | 10.0 | | ug/kg | | |
| Methyl-2-pentanone, 4- | 108-10-1 | 10.0 | | ug/kg | | | 10.0 | | ug/kg | | |
| Styrene | | | 100-42-5 | 5.0 | | ug/kg | | | 5.0 | | ug/kg |
| Tetrachloroethane, 1,1,2,2- | 79-34-5 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | | |
| Tetrachloroethene, | 127-18-4 | 5.0 | | ug/kg | | | 5.0 | | ug/kg | | |
Tetrachloromethane (Carbon tetrachloride) 56-23-5 5.0 ug/kg 5.0 ug/kg Tribromomethane
| (Bromoform) | | 75-25-2 | 5.0 | | ug/kg | | 5.0 | | ug/kg |
| Trichloroethane, 1,1,1- | 71-55-6 | 5.0 | | ug/kg | | 5.0 | | ug/kg | |
| Trichloroethane, 1,1,2- | 79-00-5 | 5.0 | | ug/kg | | 5.0 | | ug/kg | |
| Trichloroethene | | 79-01-6 | 5.0 | | ug/kg | | 5.0 | | ug/kg |
Trichloromethane
| (Chloroform) | 67-66-3 | 5.0 | | ug/kg | | 5.0 | | ug/kg | |
| Toluene | | 108-88-3 | 5.0 | | ug/kg | | 5.0 | | ug/kg |
| Vinyl Acetate | 108-05-4 | 10.0 | | ug/kg | | 10.0 | | ug/kg | |
| Vinyl Chloride | 75-01-4 | 10.0 | | ug/kg | | 10.0 | | ug/kg | |
| Xylenes, Total | 1330-20-7 | 5.0 | | ug/kg | | 5.0 | | ug/kg | |
| CRQL | see Attachment H2 - Definitions | | |
| NA | Not Applicable. | * | wet weight basis |
| ** | dry weight basis | ug/kg | micrograms per kilogram |
TASK 10
POLYNUCLEAR AROMATIC HYDROCARBONS
TARGET PARAMETER LIST (TPL)
Method GCMS-SIM HP-5973 Method 8270D (U.S. EPA 2007e) Method 8310 (U.S. EPA 1986)
| CAS | BIOLOGICAL | | SEDIMENT | | |
| PARAMETER | | NUMBER | CRQL | UNITS* | CRQL | UNITS** |
| Naphthalene | | 91-2-03 | 100 | | | ug/kg | | 33.0 | | ug/kg | |
| 1-Methyl Naphthalene | 90-12-0 | 100 | | | ug/kg | | 16.0 | | ug/kg | | |
| 2-Methyl Naphthalene | 91-57-6 | 100 | | | ug/kg | | 16.0 | | ug/kg | | |
| Acenaphthylene | 208-96-8 | 125 | | ug/kg 67.0 ug/kg | | | | | | | |
| Acenaphthene | | 83-32-9 | 50.0 | | | ug/kg | | 33.0 | | ug/kg | |
| Fluorene | | 86-73-7 | 10.0 | | | ug/kg | | 3.3 | | ug/kg | |
| Phenanthrene | | 85-01-8 | 5.0 | | | ug/kg | | 3.3 | | ug/kg | |
| Anthracene | | 120-12-7 | 7.5 | | | ug/kg | | 3.3 | | ug/kg | |
| Chrysene | | 218-01-9 | 5.0 | | | ug/kg | | 3.3 | | ug/kg | |
| Fluoranthene | | 206-44-0 | 7.5 | | | ug/kg | | 5.0 | | ug/kg | |
| Pyrene | | | 129-00-0 | 2.0 | | | ug/kg | | 3.3 | | ug/kg |
| Benzo (a) anthracene | 56-55-3 | 5.0 | | | ug/kg | | 3.3 | | ug/kg | | |
| Benzo (b) fluoranthene | 205-99-2 | 5.0 | | | ug/kg | | 3.3 | | ug/kg | | |
| Benzo (k) fluoranthene | 207-08-9 | 5.0 | | | ug/kg | | 3.3 | | ug/kg | | |
| Benzo (a) pyrene | 50-32-8 | 10.0 | | | ug/kg | | 3.3 | | ug/kg | | |
| Dibenzo (a,h) anthracene | 53-70-3 | 15.0 | | | ug/kg | | 6.7 | | ug/kg | | |
| Benzo (g,h,i) perylene | 191-24-2 | 12.5 | | | ug/kg | | 6.7 | | ug/kg | | |
Indeno (1,2,3-c,d) Pyrene 193-39-5 7.5 ug/kg 6.7 ug/kg
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |
TASK 11
POLYBROMINATED DIPHENYL ETHERS (PBDE)
TARGET PARAMETER LIST
Method 1614 (DRAFT) Tissues and Soils by HRGC/HRMS (U.S. EPA 2003a)
| Congener | | IUPAC # | MDL ug/kg | CRQL ug/kg | |
| | | | (ww) | (ww) |
| 2-MonoBDE | | | | |
| 1 | | | | |
| 0.5 | | | | |
| 1.5 | | | | |
| 2,2',4-TriBDE |
| 17 |
| 0.03 |
| 0.1 |
| 2,3',4-TriBDE |
| 25 |
| 0.03 |
| 0.1 |
| 2,4,4'-TriBDE |
| 28 |
| 0.03 |
| 0.1 |
| 2,4',6-TriBDE |
| 32 |
| 0.03 |
| 0.1 |
| 2',3,4-TriBDE |
| 33 |
| 0.00 |
| 0.1 |
| 3,3',4-TriBDE |
| 35 |
| 0.03 |
| 0.1 |
| 3,4,4'-TriBDE |
| 37 |
| 0.03 |
| 0.1 |
| 2,2',4,4'-TetraBDE |
| 47 |
| 0.02 |
| 0.1 |
| 2,2',4,5'-TetraBDE |
| 49 |
| 0.02 |
| 0.1 |
| 2,3',4,4'-TetraBDE |
| 66 |
| 0.03 |
| 0.1 |
| 2,3',4',6-TetraBDE |
| 71 |
| 0.02 |
| 0.1 |
| 2,4,4',6-TetraBDE |
| 75 |
| 0.02 |
| 0.1 |
| 3,3',4,4'-TetraBDE |
| 77 |
| 0.02 |
| 0.1 |
| 2,2',3,4,4'-PentaBDE |
| 85 |
| 0.03 |
| 0.1 |
| 2,2',4,4',5-PentaBDE |
| 99 |
| 0.03 |
| 0.1 |
| 2,2',4,4',6-PentaBDE |
| 100 |
| 0.02 |
| 0.1 |
| 2,3,3',4,4'-PentaBDE |
| 105 |
| 0.02 |
| 0.1 |
| 2,3,4,5,6-PentaBDE |
| 116 |
| 0.02 |
| 0.1 |
| 2,3',4,4',6-PentaBDE |
| 119 |
| 0.02 |
| 0.1 |
| 3,3',4,4',5-PentaBDE |
| 126 |
| 0.02 |
| 0.1 |
| 2,2',3,4,4',5'-HexaBDE |
| 138 |
| 0.08 |
| 0.2 |
| 2,2',3,4,4',6'-HexaBDE |
| 140 |
| 0.06 |
| 0.2 |
| 2,2',4,4',5,5'-HexaBDE |
| 153 |
| 0.07 |
| 0.2 |
| 2,2',4,4',5,6'-HexaBDE |
| 154 |
| 0.05 |
| 0.2 |
| 2,2',4,4',6,6'-HexaBDE |
| 155 |
| 0.06 |
| 0.2 |
| 2,3,4,4',5,6-HexaBDE |
| 166 |
| 0.00 |
| 0.2 |
| 2,2',3,4,4',5,6-HeptaBDE |
| 181 |
| 0.07 |
| 0.2 |
| 2,2',3,4,4',5',6-HeptaBDE |
| 183 |
| 0.05 |
| 0.2 |
| 2,3,3',4,4',5,6-HeptaBDE |
| 190 |
| 0.10 |
| 0.3 |
| 2,2',3,3',4,4',5,5',6-NonaBDE |
| 206 |
| 0.14 |
| 0.5 |
| 2,2',3,3',4,4',5,6,6'-NonaBDE |
| 207 |
| 0.14 |
| 0.5 |
| 2,2',3,3',4,5,5',6,6'-NonaBDE |
| 208 |
| 0.14 |
| 0.5 |
| 2,2',3,3',4,4',5,5',6,6'-DecaBDE |
| 209 |
| 1.10 |
| 3.5 |
IUPAC=International Union of Pure and Applied Chemistry MDL=method detection limit DL=detection limit.
TASK 12
PER- AND POLYFLUOROALKYL SUBSTANCES (PFAS)
TARGET PARAMETER LIST (TPL)
Method: 1633A (EPA Dec. 2024)
| Measurement |
| Units |
| Reporting Limit |
PFAS
| Perfluoro-1-octanesulfonate (C8, PFOS) |
| µg/kg ww |
| 0.5 |
| Perfluoro-1-butanesulfonate (C4, PFBS) |
| µg/kg ww |
| 0.5 |
| Perfluoro-1-hexanesulfonate (C6, PFHxS) |
| µg/kg ww |
| 0.5 |
| Perfluoro-n-octanoic acid (C8, PFOA) |
| µg/kg ww |
| 0.5 |
| Perfluoro-n-butanoic acid (C4 PFBA) |
| µg/kg ww |
| 2 |
| Perfluoro-n-pentanoic acid (C5, PFPeA) |
| µg/kg ww |
| 1 |
| Perfluoro-n-hexanoic acid (C6, PFHxA) |
| µg/kg ww |
| 0.5 |
| Perfluoro-n-heptanoic acid (C7, PFHpA) |
| µg/kg ww |
| 0.5 |
| Perfluoro-n-nonanoic acid (C9, PFNA) |
| µg/kg ww |
| 0.5 |
| Perfluoro-n-decanoic acid (C10, PFDA) |
| µg/kg ww |
| 0.5 |
| Perfluoro-n-undodecanoic acid (C11, PFUnA) |
| µg/kg ww |
| 0.5 |
| Perfluoro-n-dodecanoic acid (C12, PFDoA) |
| µg/kg ww |
| 0.5 |
| Perfluoro-1-octanesulfonamide (PFOSA) |
| µg/kg ww |
| 0.5 |
| Perfluorotridecanoic acid (PFTrDA) |
| µg/kg ww |
| 0.5 |
| Perfluorotetradecanoic acid (PFTeDA) |
| µg/kg ww |
| 0.5 |
| Perfluorohexadecanoic acid (PFHxDA) |
| µg/kg ww |
| NA |
| Perfluorooctandecanoic acid (PFODA) |
| µg/kg ww |
| NA |
| Perfluoropentanesulfonic acid (PFPeS) |
| µg/kg ww |
| 0.5 |
| Perfluoroheptanesulfonic acid (PFHpS) |
| µg/kg ww |
| 0.5 |
| Perfluorononanesulfonic acid (PFNS) |
| µg/kg ww |
| 0.5 |
| Perfluorodecanesulfonic acid (PFDS) |
| µg/kg ww |
| 0.5 |
| Perfluorododecanesulfonic acid (PFDoS) |
| µg/kg ww |
| 0.5 |
| N-methyl perfluorooctanesulfonamidoacetic acid - br/lin (NMeFOSAA) |
| µg/kg ww |
| 0.5 |
| N-ethyl perfluorooctanesulfonamidoacetic acid - br/lin (NEtFOSAA) |
| µg/kg ww |
| 0.5 |
| 4:2 Fluorotelomer sulfonic acid (4:2 FTS) |
| µg/kg ww |
| 2 |
| 6:2 Fluorotelomer sulfonic acid (6:2 FTS) |
| µg/kg ww |
| 2 |
| 8:2 Fluorotelomer sulfonic acid (8:2 FTS) |
| µg/kg ww |
| 2 |
| 10:2 Fluorotelomer sulfonic acid (10:2 FTS) |
| µg/kg ww |
| NA |
| 4,8-dioxa-3H-perfluorononanoic acid (ADONA) |
| µg/kg ww |
| 2 |
| 9-Chlorohexadecafluoro-3-oxanone-1-sulfonic acid (9Cl-PF3ONS) |
| µg/kg ww |
| 2 |
| 11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11Cl-PF3OUdS) |
| µg/kg ww |
| 2 |
| Hexafluoropropylene oxide dimer acid (HFPO-DA) |
| µg/kg ww |
| 2 |
| 3-Perfluoropropyl propanoic acid (FPrPA) (3:3FTCA) |
| µg/kg ww |
| 2.5 |
| 2H,2H,3H,3H-Perfluorooctanoic acid (FPePA) (5:3FTCA) |
| µg/kg ww |
| 12.5 |
| 3-Perfluoroheptyl propanoic acid (FHpPA) (7:3FTCA) |
| µg/kg ww |
| 12.5 |
| Perfluoro(2-ethoxyethane) sulfonic acid (PFEESA) |
| µg/kg ww |
| 1 |
| Perfluoro-3-methoxypropanoic acid (PFMPA) |
| µg/kg ww |
| 1 |
| Perfluoro-4-methoxybutanoic acid (PFMBA) |
| µg/kg ww |
| 1 |
| Nonafluoro-3,6-dioxaheptanoic acid (NFDHA) |
| µg/kg ww |
| 1 |
** All results reported as ug/kg wet weight
TASK 13
Algal Toxins
Method: 10110C ALGAL TOXIN ANALYSIS —TOTAL MICROCYSTINS AND NODULARINS Chemical Oxidation and LC-MS/MS Analysis for Total Microcystins and Nodularins (Standard Methods 2023)
| CAS | BIOLOGICAL | | SEDIMENT | | | |
| PARAMETER | NUMBER | CRQL | | UNITS* | CRQL | UNITS** |
Microcystins and Nodularins 77238-39-2 2.5 ug/kg NA ug/kg
| CRQL | see Attachment H2 - Definitions |
| NA | Not Applicable. |
| * | wet weight basis |
| ** | dry weight basis |
| ug/kg | micrograms per kilogram |