ATTACHMENT_3_MSDS_Sheets.pdf

Identification of the substance/preparation and company/undertaking

SAFETY DATA SHEET

GREASECUTTER PLUS

Conforms to EU regulation EC 1907/2006 and amendments

1.

Identification of the substance or preparation

GREASECUTTER PLUSProduct name :

Company/undertaking identification

: Grill Cleaner

Product is for professional use only

Product use

Date of revision : 23 February 2010Version : 7103970ECode :

Hazards identification2.

Classification C; R35 The classification of this product is based only on its extreme pH value (in accordance with current European legislation)

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

:Human health hazards Causes severe burns.

See section 11 for more detailed information on health effects and symptoms.

Composition/information on ingredients sodium hydroxide 215-185-5 1310-73-2 2 - 5 C; R35 [1] 2-aminoethanol 205-483-3 141-43-5 2 - 5 Xn; R20/21/22

C; R34 [1] [2]

Alkylamineoxides 263-016-9 61788-90-7 0.1 - 0.25 Xi; R41, R38 N; R50

[1]

3.

Substance/preparation Preparation:

EINECS % ClassificationIngredient name

See section 16 for the full text of the R-phrases declared above

CAS

<5% amphoteric surfactants

Ingredient declaration according to detergent regulation 648/2004/EC:

Occupational exposure limits, if available, are listed in section 8.

[1] Substance classified with a health or environmental hazard

[2] Substance with a workplace exposure limit

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

[3] PBT-substance

[4] vPvB-substance

Wash out mouth with water. Move exposed person to fresh air. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention immediately.

4.

First-aid measures

Move exposed person to fresh air. Get medical attention immediately.

Ingestion

Inhalation :

First aid measures

Date of issue : 23 February 2010 Page: 1/5

GREASECUTTER PLUS

Skin contact

Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes.

Get medical attention immediately.

Eye contact

Specific treatments Not available.:

See section 11 for more detailed information on health effects and symptoms.

Fire-fighting measures5.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

In case of fire, use water spray (fog), foam, dry chemical or CO2.Extinguishing media - Suitable :

Extinguishing media - Not suitable

None known.:

Environmental precautions

Personal precautions

6. Accidental release measures

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

: Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Small spill : Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container.

Large spill : Prevent entry into sewers, water courses, basements or confined areas.

Contain and collect spillage with non-combustible, absorbent material e.g.

sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13).

Handling

Handling and storage

Storage

7.

Do not get in eyes or on skin or clothing. Do not ingest. Keep away from acids. After handling, always wash hands thoroughly with soap and water.

Packaging materials

Use original container.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Separate from acids. Keep container tightly closed and sealed until ready for use.

Recommended

Not available.:Specific uses

Store between the following temperatures: -5 and 40°C

Ingredient name Occupational exposure limits

2-aminoethanol EU OEL (Europe, 4/2006). Absorbed through skin.

STEL: 7.6 mg/m³ 15 minute(s).

STEL: 3 ppm 15 minute(s).

TWA: 2.5 mg/m³ 8 hour(s).

TWA: 1 ppm 8 hour(s).

8. Exposure controls/personal protection

Hand protection

(EN 374)

Exposure controls

A respirator is not needed under normal and intended conditions of product use.

1 - 4 hours : butyl rubber , nitrile rubber

Respiratory protection

(EN 143, 14387)

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators.

Occupational exposure controls

Date of issue : 23 February 2010 Page: 2/5

Goggles, face shield, or other full-face protection.Eye protection

(EN 166)

Skin protection

(EN 14605)

Safety apron . Suitable protective footwear.:

Physical and chemical properties

Physical state Liquid.

Odourless.Odour

Yellow. [Dark]Colour

9.

General information

Appearance

Not available.

Melting point

Boiling point

Vapour pressure

Relative density

Vapour density

Solubility

Not available.

1.05 to 1.065 g/cm3 (20 °C)

Not available.

Not applicable.

Easily soluble in cold water, hot water.

pH

Evaporation rate (butyl acetate = 1)

Not applicable.

Flash point > 100°C

Not applicable.

Not applicable.Flammability (solid, gas)

Not applicable.

12.9 to 13.9 (100%)

Viscosity Not available.

Octanol/water partition coefficient

Explosion limits

Explosive properties

Not available.Oxidising properties :

Important health, safety and environmental information

Not applicable.

Stability and reactivity

Stability

10.

Extremely reactive or incompatible with the following materials: acids.

Materials to avoid :

Do not mix with other products.

Stable under normal conditions.

Toxicological information11.

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Reproductive toxicity :

Potential acute health effects

Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

May cause burns to mouth, throat and stomach.:Ingestion

Skin contact : Causes severe burns.

Causes severe burns.:Eye contact

Ecological information12.

The product is not subject to ecological classification according to directive 1999/45/EC.

Ecotoxicity

Persistence and degradability

Date of issue : 23 February 2010 Page: 3/5

The surfactants contained in the product are biodegradable according to the requirements of the detergent regulation 648/2004/EC

Disposal considerations13.

20 01 15*European waste catalogue

(EWC)

The generation of waste should be avoided or minimised wherever possible.

Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Can be added to general waste collection after completely emptying. Use packages for recycling only when totally empty.

:Methods of disposal

ADR/RID Class

14.

International transport regulations

SODIUM HYDROXIDE SOLUTION 8 III

IMDG Class SODIUM HYDROXIDE SOLUTION 8 III

Transport information

Regulatory information

UN number Proper shipping name Class Packing group Label

UN1824

UN1824

Follow special pack instructions for air transport.

Regulatory information15.

Hazard symbol/symbols

EU regulations

Safety phrases S2- Keep out of the reach of children.

S23- Do not breathe vapour or spray.

S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.

S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

S51- Use only in well-ventilated areas.

R35- Causes severe burns.Risk phrases

Contains

: sodium hydroxide

Corrosive

Other information16.

R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.

R34- Causes burns.

R35- Causes severe burns.

R41- Risk of serious damage to eyes.

R38- Irritating to skin.

R50- Very toxic to aquatic organisms.

Full text of R-phrases referred to in sections 2 and 3 - Europe

23 February 2010

History

Date of printing

Date of revision

Version

23 February 2010

Date of issue : 23 February 2010 Page: 4/5

Prepared by

Version

The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE

COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.

Notice to reader

: Ecolab Regulatory Department Europe

Page: 5/5

Identification of product and company

Neomat GMS Conforms to EU Directive 91/155/EEC, as amended by 2001/58/EC

1.

Identification of the substance or preparation

Neomat GMSProduct name :

Company/undertaking identification

: Cleaner for scrubber dryer Product is for professional use only

Product use

Date of issue :31 July 2006Version :1100682ECode :

Composition/information on ingredients

Potassium hydroxide 215-181-3 1310-58-3 5 - 10 Xn; R22 C; R35

Alkalies 215-199-1 1312-76-1 5 - 10 C; R34 Xi; R37

Nitrilotriaceticacid[NTA] Salt 225-768-6 5064-31-3 5 - 10 Xn; R22 Xi; R36

Alkylpolyglycosides Polymer. 1 - 2 Xi; R41 Nonionic surfactants Polymer. 0.5 - 1.0 Xi; R38

N; R50 Alkylamine ethoxylates 500-152-2 61791-14-8 0.25 - 0.5 Xn; R22

Xi; R36 N; R51/53

2.

Substance/preparation Preparation

Occupational exposure limits, if available, are listed in section 8.

EINECS % ClassificationIngredient name

See section 16 for the full text of the R-phrases declared above

CAS

≥5 - <15% NTA, phosphonates <5% anionic surfactants, non-ionic surfactants

Ingredient declaration according to detergent regulation 648/2004/EC:

Hazards identification3.

Classification C; R35:

The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.

:Human health hazards Causes severe burns.

See section 11 for more detailed information on health effects and symptoms.

Do not induce vomiting unless directed to do so by medical personnel. If swallowed, rinse mouth with water (only if the person is conscious).

Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately.

4.

First-aid measures

If inhaled, remove to fresh air. In all cases of doubt, or when symptoms persist, seek medical attention.

Ingestion

Inhalation :

First-aid measures

Date of issue : 31 July 2006 Page: 1/4

Neomat GMS In case of contact with eyes, rinse immediately with plenty of water. Get medical attention immediately.

Eye contact :

Specific treatments Not available.:

See section 11 for more detailed information on health effects and symptoms.

Fire-fighting measures5.

Fire-fighters should wear proper protective equipment.Special protective equipment for fire-fighters

In case of fire, use water spray (fog), foam, dry chemical, or CO2.Extinguishing media :

Environmental precautions and clean-up methods

Personal precautions

SMALL SPILL Rinse with plenty of running water. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilt material in an appropriate container for disposa

6. Accidental release measures

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

: Large spill and leak Immediately contact safety personnel.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Handling

Handling and storage

Storage

7.

Do not get in eyes, on skin or on clothing. Do not breathe vapour or mist.

After handling, always wash hands thoroughly with soap and water. Handle and open container with care.

Packaging materials Use original container.

Keep container tightly closed. Keep away from food, drink and animal feeding stuffs. Keep only in the original container.

Recommended Not available.:Specific uses

Store between -5 and 40°C

Exposure limit values

8. Exposure controls/personal protection

Hand protection

(EN 374)

Exposure controls

A respirator is not needed under normal and intended conditions of product use.

1 - 4 hours: butyl rubber, nitrile rubber

Safety glasses.Goggles, face shield, or other full-face protection.Eye protection

(EN 166)

Respiratory protection

(EN 143, 141)

Not available.:

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators.

Occupational exposure controls

Skin protection

(EN 467)

safety apron Suitable protective footwear.:

Physical and chemical properties

Physical state Liquid.

Faint odour.Odour Blue. (Light.)Colour

9.

General information Appearance

Not available.

Melting point Boiling point

Not available.

pH

Flash point > 100°C

13 (100%)

Important health, safety and environmental information

Date of issue : 31 July 2006 Page: 2/4

Vapour pressure Relative density

Vapour density

Solubility

1.22 g/cm3 (20 °C)

Not available.

Not applicable.

Easily soluble in cold water, hot water.

Evaporation rate (butyl acetate = 1)

Not applicable.

Not applicable.

Not applicable.Flammability (solid, gas)

Not applicable.

Viscosity Not available.

Octanol/water partition coefficient

Explosion Limits Explosive properties

Not available.Oxidising properties :

Not applicable.

Stability and reactivity

Stability

10.

Highly reactive or incompatible with the following materials: acids.

Non-reactive or compatible with the following materials: organic materials, metals, alkalis and moisture.

Materials to avoid :

Do not mix with other products.

Stable under normal conditions.

Toxicological information11.

No known significant effects or critical hazards.Reproductive toxicity :

Potential acute health effects Inhalation : No specific hazard.

Causes severe burns.:Ingestion Skin contact : Severely corrosive to the skin.

Severely corrosive to the eyes.:Eye contact

Ecological information12.

The surfactants contained in the product are biodegradable according to the requirements of the detergent regulation 648/2004/EC

The product is not subject to ecological classification according to directive 1999/45/EC.

Ecotoxicity

Persistence and degradability

Disposal considerations13.

Not applicable.:Waste classification 200115*European waste catalogue

(EWC)

Waste must be disposed of according to applicable regulations. Use as much of the contents as possible, according to instructions. Can be added to general waste collection after completely emptying. Use packages for recycling only when totally empty

:Methods of disposal

Date of issue : 31 July 2006 Page: 3/4

ADR/RID Class

14.

International transport regulations

POTASSIUM HYDROXIDE SOLUTION 8 II

IMDG Class POTASSIUM HYDROXIDE SOLUTION 8 II

Transport information

8POTASSIUM HYDROXIDE SOLUTION IIUN1814

Regulatory information

UN number Proper shipping name Class Packing group

Label

UN1814

UN1814

ADN Class

Follow special pack instructions for air transport.

Regulatory information15.

Hazard symbol/symbols EU regulations

Safety phrases S2- Keep out of the reach of children.

S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.

S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

R35- Causes severe burns.Risk Phrases Contains

: Potassium hydroxide

Corrosive

Other information16.

R22- Harmful if swallowed.

R34- Causes burns.

R35- Causes severe burns.

R36- Irritating to eyes.

R37- Irritating to respiratory system.

R38- Irritating to skin.

R41- Risk of serious damage to eyes.

R50- Very toxic to aquatic organisms.

R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Full text of R-phrases referred to in sections 2 and 3 - Europe

31 July 2006 History Date of printing Date of issue Version Prepared by

31 July 2006

Version

The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE

COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.

Notice to reader

Page: 4/4

OVEN CLEANER POWER

Conforms to EU Directive 91/155/EEC, as amended by 2001/58/EC

1.

Identification of the substance or preparation

OVEN CLEANER POWERProduct name :

Company/undertaking identification

: Grill Cleaner Product is for professional use only

Product use

Date of issue : 26 March 2007Version : 2108458ECode :

Composition/information on ingredients potassium hydroxide 215-181-3 1310-58-3 5 - 10 Xn; R22 C; R35

Alkylamineoxides 273-281-2 68955-55-5 0.25 - 0.5 Xi; R41, R38 N; R50

2.

Substance/preparation Preparation

Occupational exposure limits, if available, are listed in section 8.

EINECS % ClassificationIngredient name

See section 16 for the full text of the R-phrases declared above

CAS

<5% non-ionic surfactants, phosphates

Ingredient declaration according to detergent regulation 648/2004/EC:

Hazards identification3.

Classification C; R35:

The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.

:Human health hazards Causes severe burns.

See section 11 for more detailed information on health effects and symptoms.

Do not induce vomiting unless directed to do so by medical personnel. If swallowed, rinse mouth with water (only if the person is conscious).

Skin contact

In case of contact with eyes, rinse immediately with plenty of water. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately.

4.

First-aid measures

If inhaled, remove to fresh air. In all cases of doubt, or when symptoms persist, seek medical attention.

Ingestion

Inhalation

Eye contact

First-aid measures

Specific treatments Not available.:

See section 11 for more detailed information on health effects and symptoms.

Date of issue : 26 March 2007 Page: 1/4

OVEN CLEANER POWER

Fire-fighting measures5.

Fire-fighters should wear proper protective equipment.Special protective equipment for fire-fighters

In case of fire, use water spray (fog), foam, dry chemical, or CO2.Extinguishing media :

Environmental precautions and clean-up methods

Personal precautions

Small spill: Rinse with plenty of running water. For large spills, dyke spilt material or otherwise contain material to ensure runoff does not reach a waterway. Place spilt material in an appropriate container for disposa

6. Accidental release measures

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

: Large spill and leak Immediately contact safety personnel.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Handling

Handling and storage

Storage

7.

Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Keep away from acids. After handling, always wash hands thoroughly with soap and water.

Packaging materials Use original container.

Keep container tightly closed. Keep away from food, drink and animal feeding stuffs. Keep only in the original container.

Recommended Not available.:Specific uses

Store between the following temperatures: 0 and 40°C

Exposure limit values

8. Exposure controls/personal protection

Hand protection

(EN 374)

Exposure controls

A respirator is not needed under normal and intended conditions of product use.

1 - 4 hours: butyl rubber, nitrile rubber

Safety glasses. Goggles, face shield, or other full-face protection.Eye protection

(EN 166)

Respiratory protection

(EN 143, 141)

Not available.:

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators.

Occupational exposure controls

Skin protection

(EN 467)

safety apron Suitable protective footwear.:

Physical and chemical properties

Physical state Liquid.

Odourless.Odour Yellow. [Light]Colour

9.

General information Appearance

Not available.

Melting point Boiling point

Not available.

pH

Flash point > 100°C

Not applicable.

Not applicable.Flammability (solid, gas)

12.9 to 13.9 (100%)

Explosion Limits Explosive properties

Not available.Oxidising properties :

Important health, safety and environmental information

Not applicable.

Date of issue : 26 March 2007 Page: 2/4

Relative density

Vapour density

Solubility

1.11 to 1.13 g/cm3 (20 °C)

Not available.

Not applicable.

Easily soluble in cold water, hot water.

Evaporation rate (butyl acetate = 1)

Not applicable.

Not applicable.

Viscosity Not available.

Octanol/water partition coefficient

Stability and reactivity

Stability

10.

Extremely reactive or incompatible with the following materials: acids.

Materials to avoid :

Do not mix with other products.

Stable under normal conditions.

Toxicological information11.

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Reproductive toxicity :

Potential acute health effects Inhalation : No known significant effects or critical hazards.

Causes burns to mouth, throat and stomach.:Ingestion Skin contact : Severely corrosive to the skin.

Severely corrosive to the eyes.:Eye contact

Ecological information12.

The surfactants contained in the product are biodegradable according to the requirements of the detergent regulation 648/2004/EC.

The product is not subject to ecological classification according to directive 1999/45/EC.

Ecotoxicity

Persistence and degradability

Disposal considerations13.

200115*European waste catalogue

(EWC)

Waste must be disposed of according to applicable regulations. Use as much of the contents as possible, according to instructions. Can be added to general waste collection after completely emptying. Use packages for recycling only when totally empty.

:Methods of disposal

ADR/RID Class

14.

International transport regulations

POTASSIUM HYDROXIDE SOLUTION 8 II

IMDG Class POTASSIUM HYDROXIDE SOLUTION 8 II

Transport information

8POTASSIUM HYDROXIDE SOLUTION IIUN1814

Regulatory information

UN number Proper shipping name Class Packing group

Label

UN1814

UN1814

ADN Class

Date of issue : 26 March 2007 Page: 3/4

Follow special pack instructions for air transport.

Regulatory information15.

Hazard symbol/symbols EU regulations

Safety phrases S2- Keep out of the reach of children.

S23- Do not breathe aerosol .

S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.

S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

S51- Use only in well-ventilated areas.

R35- Causes severe burns.Risk Phrases Contains

: potassium hydroxide

Corrosive

Other information16.

R22- Harmful if swallowed.

R35- Causes severe burns.

R41- Risk of serious damage to eyes.

R38- Irritating to skin.

R50- Very toxic to aquatic organisms.

Full text of R-phrases referred to in sections 2 and 3 - Europe

26 March 2007 History Date of printing Date of issue Version Prepared by

26 March 2007

Version

The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE

COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.

Notice to reader

SOLID MEGA

Conforms to EU regulation EC 1907/2006 and amendments

1.

Identification of the substance or preparation

SOLID MEGAProduct name :

Company/undertaking identification

: Machine Warewashing Detergent

Product is for professional use only

Product use

Date of revision : 20 May 2008Version : 3107823ECode :

Hazards identification2.

Classification C; R35 R31 R52/53

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

:Human health hazards Causes severe burns. Contact with acids liberates toxic gas.

:Environmental hazards Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

See section 11 for more detailed information on health effects and symptoms.

Composition/information on ingredients sodium hydroxide 215-185-5 1310-73-2 30 - 50 C; R35 sodium carbonate 207-838-8 497-19-8 5 - 10 Xi; R36 troclosene sodium, dihydrate 220-767-7 51580-86-0 2 - 5 Xn; R22

Xi; R36/37 R31 N; R50/53 disodium metasilicate 229-912-9 6834-92-0 1 - 2 C; R34 Xi; R37

3.

Substance/preparation Preparation

Occupational exposure limits, if available, are listed in section 8.

EINECS % ClassificationIngredient name

See section 16 for the full text of the R-phrases declared above

CAS

≥ 30% phosphates <5% anionic surfactants, non-ionic surfactants, polycarboxylates, chlorine-based bleaching agents

Ingredient declaration according to detergent regulation 648/2004/EC:

Wash out mouth with water. Move exposed person to fresh air. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention immediately.

4.

First-aid measures

Move exposed person to fresh air. Get medical attention immediately.

Ingestion

Inhalation :

Date of issue : 20 May 2008 Page: 1/5

SOLID MEGA

Skin contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Get medical attention immediately.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes.

Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.

Eye contact

Specific treatments Not available.:

See section 11 for more detailed information on health effects and symptoms.

Fire-fighting measures5.

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. This material is harmful to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Hazardous thermal decomposition products

Decomposition products may include the following materials:

carbon oxides nitrogen oxides phosphorus oxides halogenated compounds metal oxide/oxides

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

In case of fire, use water spray (fog), foam, dry chemical or CO2. This material is harmful to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Extinguishing media - Suitable :

Extinguishing media - Not suitable

None known.:

Environmental precautions

Personal precautions

6. Accidental release measures

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

: Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Provide adequate ventilation.

Water polluting material.

Small spill: : Move containers from spill area. Vacuum or sweep up material and place in a designated, labelled waste container.

Large spill : Prevent entry into sewers, water courses, basements or confined areas.

Vacuum or sweep up material and place in a designated, labelled waste container.

Handling

Handling and storage

Storage

7.

Do not get in eyes or on skin or clothing. Do not ingest. Keep away from acids. After handling, always wash hands thoroughly with soap and water.

Packaging materials

Use original container.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Separate from acids. Keep container tightly closed and sealed until ready for use.

Recommended

Not available.:Specific uses

Do not store above the following temperature: 40°C

Date of issue : 20 May 2008 Page: 2/5

Exposure limit values

8. Exposure controls/personal protection

Hand protection

(EN 374)

Exposure controls

A respirator is not needed under normal and intended conditions of product use.

1 - 4 hours : butyl rubber , nitrile rubber

Safety glasses. Goggles, face shield, or other full-face protection.Eye protection

(EN 166)

Respiratory protection

(EN 143, 141)

Not available.:

Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. If user operations generate dust, fumes or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.

Occupational exposure controls

Skin protection

(EN 467)

Safety apron . Suitable protective footwear.:

Physical and chemical properties

Physical state Solid.

Odourless.Odour

White.Colour

9.

General information

Appearance

Not available.

Melting point

Boiling point

Vapour pressure

Relative density

Vapour density

Solubility

Not available.

1.6 to 1.65 g/cm3 (20 °C)

Not available.

Not applicable.

Easily soluble in cold water, hot water.

pH

Evaporation rate (butyl acetate = 1)

Not applicable.

Flash point > 100°C

Not applicable.

Not applicable.Flammability (solid, gas)

Not applicable.

12.4 to 12.6 (1%)

Viscosity Not available.

Octanol/water partition coefficient

Explosion limits

Explosive properties

Not available.Oxidising properties :

Important health, safety and environmental information

Not applicable.

Stability and reactivity

Stability

10.

Extremely reactive or incompatible with the following materials: acids.

Materials to avoid :

Do not mix with other products.

Stable under normal conditions.

Date of issue : 20 May 2008 Page: 3/5

Toxicological information11.

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Reproductive toxicity :

Potential acute health effects

Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

May cause burns to mouth, throat and stomach.:Ingestion

Skin contact : Causes severe burns.

Causes severe burns.:Eye contact

Ecological information12.

The surfactants contained in the product are biodegradable according to the requirements of the detergent regulation 648/2004/EC

R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Ecotoxicity

Persistence and degradability

Disposal considerations13.

200115*European waste catalogue

(EWC)

The generation of waste should be avoided or minimised wherever possible.

Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Can be added to general waste collection after completely emptying. Use packages for recycling only when totally empty.

:Methods of disposal

ADR/RID Class

14.

International transport regulations

SODIUM HYDROXIDE, SOLID mixture 8 II

IMDG Class SODIUM HYDROXIDE, SOLID mixture 8 II

Transport information

Regulatory information

UN number Proper shipping name Class Packing group Label

UN1823

UN1823

Follow special pack instructions for air transport.

Regulatory information15.

Hazard symbol/symbols

EU regulations

Corrosive

Date of issue : 20 May 2008 Page: 4/5

Safety phrases S2- Keep out of the reach of children.

S7- Keep container tightly closed.

S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.

S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

R35- Causes severe burns.

R31- Contact with acids liberates toxic gas.

R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Risk phrases

Contains

: sodium hydroxide

Other information16.

R22- Harmful if swallowed.

R34- Causes burns.

R35- Causes severe burns.

R36- Irritating to eyes.

R37- Irritating to respiratory system.

R36/37- Irritating to eyes and respiratory system.

R31- Contact with acids liberates toxic gas.

R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Full text of R-phrases referred to in sections 2 and 3 - Europe

20 May 2008

History

Date of printing

Date of revision

Version

Prepared by

20 May 2008

Version

The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE

COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.

Notice to reader

Page: 5/5

Spitaderm P.M.C.Reg.Min.Sal.N.11653

Conforms to EU Directive 91/155/EEC, as amended by 2001/58/EC

1.

Identification of the substance or preparation

Spitaderm P.M.C.Reg.Min.Sal.N.11653Product name :

Company/undertaking identification

: Hand disinfectant

Product is for professional use only

Product use

Date of revision : 25 September 2007Version : 1112117ECode :

Hazards identification2.

Classification F; R11 Xi; R36 R67

The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.

Physical/chemical hazards : Highly flammable.

:Human health hazards Irritating to eyes. Vapours may cause drowsiness and dizziness.

See section 11 for more detailed information on health effects and symptoms.

Composition/information on ingredients propan-2-ol 200-661-7 67-63-0 50 - 100 F; R11 Xi; R36 R67

D-gluconic acid, compound with N,N''-bis(4-chlorophenyl)-3,12-diimino-2,4,11,13-tetraazatetradecanediamidine (2:1)

242-354-0 18472-51-0 0.5 - 1.0 Xi; R41 N; R50

3.

Substance/preparation Preparation

Occupational exposure limits, if available, are listed in section 8.

EINECS % ClassificationIngredient name

See section 16 for the full text of the R-phrases declared above

CAS

Do not induce vomiting unless directed to do so by medical personnel. If swallowed, rinse mouth with water (only if the person is conscious).

Skin contact

In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water.

4.

First-aid measures

If inhaled, remove to fresh air.

Ingestion

Inhalation

Eye contact

First-aid measures

Specific treatments Not available.:

Date of issue : 25 September 2007 Page: 1/5

Spitaderm P.M.C.Reg.Min.Sal.N.11653

Special exposure hazards Highly flammable liquid and vapour. Vapour may cause flash fire. Vapours may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear proper protective equipment.Special protective equipment for fire-fighters

In case of fire, use water spray (fog), foam, dry chemical, or CO2.Extinguishing media :

Environmental precautions and clean-up methods

Personal precautions

Small spill: Rinse with plenty of running water. For large spills, dyke spilt material or otherwise contain material to ensure runoff does not reach a waterway. Place spilt material in an appropriate container for disposal.

6. Accidental release measures

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

: Large spill and leak Immediately contact safety personnel. Eliminate all ignition sources. Keep unnecessary personnel away. Do not touch or walk through spilt material.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Handling

Handling and storage

Storage

7.

Do not ingest. Avoid contact with eyes, skin and clothing. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. After handling, always wash hands thoroughly with soap and water.

Packaging materials

Use original container.

Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use.

Avoid all possible sources of ignition (spark or flame).

Recommended

Not available.:Specific uses

Store between the following temperatures: 5 and 40°C

Exposure limit values

8. Exposure controls/personal protection

Hand protection

(EN 374)

Exposure controls

A respirator is not needed under normal and intended conditions of product use.

1-4 hour(s) (breakthrough time): butyl rubber , nitrile rubber

Safety glasses.Eye protection

(EN 166)

Respiratory protection

(EN 143, 141)

Not available.:

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators.

Occupational exposure controls

Skin protection

(EN 467)

No special recommendations.:

Date of issue : 25 September 2007 Page: 2/5

Physical and chemical properties

Physical state Liquid.

Floral.Odour

Colourless.Colour

9.

General information

Appearance

Not available.

Melting point

Boiling point

Vapour pressure

Relative density

Vapour density

Solubility

Not available.

0.86 g/cm3 (20 °C)

Not available.

Not applicable.

Easily soluble in cold water, hot water.

pH

Evaporation rate (butyl acetate = 1)

Not applicable.

Flash point 20 °C (Closed cup)

Not applicable.

Not applicable.Flammability (solid, gas)

Not applicable.

7.3 (100%)

Viscosity Not available.

Octanol/water partition coefficient

Explosion limits

Explosive properties

Not available.Oxidising properties :

Important health, safety and environmental information

Not applicable.

Stability and reactivity

Stability

10.

Do not mix with other products.

Stable under normal conditions.

Toxicological information11.

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Reproductive toxicity :

Potential acute health effects

Inhalation : Harmful by inhalation.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

Irritating to eyes.:Eye contact

Ecological information12.

The ecological evaluation of the product is based on data from the raw material and/or comparable substances.

The total of the organic components contained in the product achieve > 60% BOD/COD or CO2 liberation, or > 70% DOC reduction in tests for ease of degradability - threshold values for 'readily degradable' (e.g. to OECD method 301).

The product is not subject to ecological classification according to directive 1999/45/EC.

Ecotoxicity

Date of issue : 25 September 2007 Page: 3/5

Disposal considerations13.

200113*European waste catalogue

(EWC)

Waste must be disposed of according to applicable regulations. Use as much of the contents as possible, according to instructions. Can be added to general waste collection after completely emptying. Use packages for recycling only when totally empty.

:Methods of disposal

ADR/RID Class

14.

International transport regulations

ISOPROPANOL solution 3 II

IMDG Class ISOPROPANOL solution 3 II

Transport information

3ISOPROPANOL solution IIUN1219

Regulatory information

UN number Proper shipping name Class Packing group

Label

UN1219

UN1219

ADN Class

Follow special pack instructions for air transport.

Regulatory information15.

Hazard symbol/symbols

EU regulations

Safety phrases S2- Keep out of the reach of children.

S16- Keep away from sources of ignition - No smoking.

S23- Do not breathe vapour.

S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S51- Use only in well-ventilated areas.

R11- Highly flammable.

R36- Irritating to eyes.

R67- Vapours may cause drowsiness and dizziness.

Risk phrases

Highly flammable, Irritant

Other information16.

R11- Highly flammable.

R41- Risk of serious damage to eyes.

R36- Irritating to eyes.

R67- Vapours may cause drowsiness and dizziness.

R50- Very toxic to aquatic organisms.

Full text of R-phrases referred to in sections 2 and 3 - Europe

25 September 2007

History

Date of printing

Date of revision

Version

Prepared by

25 September 2007

Notice to reader

Date of issue : 25 September 2007 Page: 4/5

Version

The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE

COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.

1 Page: 5/5

Scheda di sicurezza

SALE RICRISTALLIZZATO INDUSTRIALE SENZA ANTIMPACCANTE

In conformità con la regolamentazione 91/155/EEC Versione del 14.04.2005 Pagina 1 di 5

Sezione 1: Identificazione del prodotto e del fornitore

Informazioni sul prodotto:

Articolo: 48391

Denominazione: SALE RICRISTALLIZZATO INDUSTRIALE SENZA ANTIMPACCANTE

Fornitore: Südsalz GmbH Salzgrund 67

74076 Heilbronn Germania Tel: +49 7131 6490-0

Luogo di provenienza: Controllo Qualità e Modalità Tecniche

Südsalz GmbH Salzgrund 67 74076 Heilbronn Tel: +49 7131 6494 116 Fax: +49 7131 6494 177

Sezione 2: Composizione ed informazioni sui componenti

Composizione chimica: NaCI - Cloruro di Sodio

(Eventuali apporti di additivi, quali antimpaccanti, agenti di scorrevolezza o sostanze coloranti per il riconoscimento del prodotto, non vengono considerati in questo paragrafo e, comunque, non hanno alcuna incidenza sul comportamento generale del prodotto).

Nr. EINECS: 231-598-3

Nr. CAS: 7647-14-5

Sezione 3: Identificazione sostanze tossiche Nessuna conosciuta

Il prodotto non è pericoloso né per l’uomo né per l’ambiente in conformità alla leggi sui prodotti chimici e sulle sostanze pericolose (Germania) e alla direttiva CEE 91/155.

In conformità con la regolamentazione: 91/155/EEC Versione del 14.04.2005 Pagina 2 di 5

Sezione 4: Misure di primo soccorso

In caso di contatto con la pelle: Sciacquare con acqua.

In caso di contatto con gli occhi: Sciacquare con acqua.

In caso di ingestione: Bere molta acqua.

Sezione 5: Misure antincendio

Mezzo di estinzione raccomandato: n.a., in quanto il prodotto non è infiammabile.

Pericoli particolari: Nessuno.

Altre indicazioni: - fare attenzione alla solubilità del prodotto in acqua.

- applicare misure antincendio adeguate

- smaltire l’acqua utilizzata in conformità con le disposizioni locali

Sezione 6: Misure in caso di fuoriuscita

Precauzioni per il personale: Non è necessaria alcuna precauzione particolare.

Protezione ambientale: Fare riferimento alle disposizioni locali in materia.

Misure di pulizia: Rimuovere a secco la maggiore quantità possibile e smaltire. Lavare con acqua i residui.

Sezione 7: Stoccaggio e manipolazione

Stoccaggio: Tenere all’asciutto e proteggere dall’umidità.

Manipolazione: Nessuna avvertenza particolare.

Non sono necessarie particolari misure antincendio o anti-esplosione.

Versione del 14.04.2005 Pagina 3 di 5

Sezione 8: Misure particolari di protezione

Informazioni aggiuntive relative alle condizioni di utilizzo sugli impianti: vedi punto 7.

Fattori da controllare in postazione di lavoro:

Valore limite generico delle polveri (MAK) 6,0 mg/m3

Protezione personale

Misure di protezione generali: Al termine del lavoro lavarsi le mani. Si consiglia di proteggere la pelle preventivamente.

Protezione delle vie respiratorie: Indossare maschere protettive, nel caso si sviluppi molta polvere.

Protezione delle mani: Non necessaria.

Protezione degli occhi: In genere non necessaria.

Protezione del corpo: Non necessaria.

Sezione 9: Proprietà chimiche e fisiche

Forma: Cristallina, compatta Colore: Bianco (senza additivi) Odore: Inodore

Punto di fusione: 801 °C Punto di ebollizione: 1461 °C

Punto di fiamma: - Punto di ignizione - Limiti di esplosione minimo : - massimo: -

Pressione di Vapore: (20° C ) 0 mbar

Densità: (20° C ) 2,16 g/cm3

Densità Apparente: ca. 1.200 kg/m3

(in rapporto allo spettro granulometrico)

Solubilità in acqua: (20° C) 358 g/l Solubiltà in altre sostanze: dati non disponibili

Valore pH (50g/l) (20°C) 6-9

Versione del 14.04.2005 Pagina 4 di 5

Sezione 10: Stabilità e reattività

Non si conoscono reazioni pericolose in caso di appropriato stoccaggio e manipolazione.

Reazione pericolosa: L’acido solforico concentrato può liberare acido cloridrico.

Sezione 11: Informazioni tossicologiche

Tossicità orale:

Nell’ambito dell’assunzione orale il sale alimentare non è tossico (LD 500 mg/kg uomo)

Fonte: “Registry of Toxic Effects” R.Lewis sr.

US-Department of Health National Institute for Occupation, Safety and Health Cincinnati 1979

LD 50 ratti 3000 mg/kg

Informazioni aggiuntive: possibile irritazione della pelle e delle mucose.

Sezione 12: Informazioni ambientali Effetti eco-tossici acuti: Pesci (diverse specie), LC 50 (96 h), > 10 000 mg/l Alghe (Ankistrodesmus falcatus), EC 50, 4 800 mg/l Crostacei (Daphnia magna), LC 50 (24 h), > 3 000 mg/l

Mobilità: Possibile accumulo di cloruro nel terreno e nelle piante.

Ulteriori informazioni ecologiche: Non si registrano problemi di tipo ecologico, se il prodotto viene manipolato e utilizzato correttamente.

Sezione 13: Informazioni per lo smaltimento

- Per lo smaltimento osservare le norme legislative locali e nazionali

- Catalogazione rifiuti Nr. 060304 (NaCl in soluzione) e 060305 (NaCl stabile) in accordo al catalogo rifiuti europeo (EAK)

- non menzionato né nella lista 1 né nella lista 2 della Direttiva CE del 4 Maggio 1976 riguardante lo scarico di sostanze pericolose nelle acque

- elencato nel catalogo dei prodotti inquinanti delle acque: classe WGK 1 (prodotto minimamente inquinante)

- introdurre solo in forma disciolta negli impianti di depurazione

- gli imballi vanno svuotati completamente e preferibilmente riutilizzati o riconvertiti, attenendosi alle disposizioni locali vigenti.

Versione del 14.04.2005 Pagina 5 di 5

14. Informazioni logistiche

Nessuna raccomandazione in quanto trattasi di materiale non pericoloso.

15. Informazioni giuridiche

Identificazione del prodotto in ottemperanza alle direttive CE

Nessuna classificazione e identificazione come sostanza pericolosa in accordo con la Direttiva CE 67/548.

Disposizioni nazionali (Germania)

Disposizioni in caso di incidente -

Normativa sulle sostanze pericolose non menzionato

Guida tecnica per la salvaguardia della pulizia dell’aria nessuna classificazione

16. Informazioni aggiuntive

Il cloruro di sodio non è una sostanza pericolosa; non sussiste pertanto alcun obbligo legislativo che imponga l’emissione di una scheda di sicurezza. Tuttavia, al fine di fornire ai ns. clienti informazioni dettagliate sull’utilizzo del prodotto, è stato deciso di redigere questa scheda di sicurezza.

Le informazioni qui contenute descrivono esclusivamente i possibili requisiti di sicurezza del prodotto e si basano sulle nostre conoscenze attuali. Non rappresentano alcuna garanzia sulle caratteristiche del prodotto, in conformità alle condizioni di garanzia contrattuali.

Questa scheda di sicurezza sostituisce la precedente del 23 Febbraio 2005.

Identification of the substance/preparation and of the company/undertaking

Toprinse Perfect IT

Conforms to EU regulation EC 1907/2006 and amendments

1.

Identification of the substance or preparation

Toprinse Perfect ITProduct name :

Company/undertaking identification

: Rinse Additive

Product is for professional use only

Product use

Date of revision : 22 November 2007Version : 2110983ECode :

Hazards identification2.

Classification Not classified.:

The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.

See section 11 for more detailed information on health effects and symptoms.

Composition/information on ingredients

Fattyalcohol ethoxylates > 5EO Polymer. 5 - 10 N; R50 Alkylethoxy-propoxylates Polymer. 1 - 2 Xi; R38

N; R50 Alkylethoxy-propoxylates Polymer. 1 - 2 Xi; R38

N; R50

3.

Substance/preparation Preparation

Occupational exposure limits, if available, are listed in section 8.

EINECS % ClassificationIngredient name

See section 16 for the full text of the R-phrases declared above

CAS

≥5 - <15% non-ionic surfactants contains preservatives: (Glutaral)

Ingredient declaration according to detergent regulation 648/2004/EC:

Do not induce vomiting unless directed to do so by medical personnel. If swallowed, rinse mouth with water (only if the person is conscious).

Skin contact

In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water.

4.

First-aid measures

If inhaled, remove to fresh air.

Ingestion

Inhalation

Eye contact

First aid measures

Specific treatments Not available.:

Date of issue : 22 November 2007 Page: 1/4

Toprinse Perfect IT

Fire-fighters should wear proper protective equipment.Special protective equipment for fire-fighters

In case of fire, use water spray (fog), foam, dry chemical, or CO2.Extinguishing media :

Environmental precautions and clean-up methods

Personal precautions

Small spill: Rinse with plenty of running water. For large spills, dyke spilt material or otherwise contain material to ensure runoff does not reach a waterway. Place spilt material in an appropriate container for disposal.

6. Accidental release measures

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

: Large spill and leak Immediately contact safety personnel.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Handling

Handling and storage

Storage