Appendix-C_Schaefer-Oil-SDS.PDF

167 Moly Full Synthetic Gear Lube ISO 68, 100, 150, 220, 320, 460, 680, 1000 and SAE 75W-140

Not available.

Liquid.

GHS product identifier

Other means of identification

Product type

Emergency telephone number (with hours of operation)

Section 1. Identification

Supplier's details :

Identified uses

167 Moly Full Synthetic Gear Lube ISO 68, 100, 150, 220, 320, 460, 680, 1000 and SAE 75W-140

SAFETY DATA SHEET

Conforms to HazCom 2012/United States

Lubricant for enclosed gear drives and bearings.

+1 314 865-4105 (24-hour response number)

Schaeffer Mfg. Company 102 Barton Street Saint Louis, Missouri 63104 Tel: 314-865-4100 Fax: 314-865-4107 Toll Free: 1-800-325-9962 E-Mail: safety@schaefferoil.com Web: http://www.schaefferoil.com

Section 2. Hazards identification

SKIN SENSITIZATION - Category 1Classification of the substance or mixture

Signal word : Warning

Hazard statements : May cause an allergic skin reaction.

Hazard pictograms :

Precautionary statements

Prevention : Wear protective gloves. Avoid breathing vapor. Contaminated work clothing should not be allowed out of the workplace.

Response : IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention.

Storage : Not applicable.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

GHS label elements

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Hazards not otherwise classified

: None known.

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167 Moly Full Synthetic Gear Lube ISO 68, 100, 150, 220, 320, 460, 680, 1000 and SAE 75W-140

Section 3. Composition/information on ingredients

1-Decene, homopolymer, hydrogenated 60 - 100 68037-01-4 Long-chain alkyl amine 0.1 - 1 - Long-chain alkenyl amine 0.1 - 1 -

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture :

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person.

If unconscious, place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs.

Wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure.

Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : May cause an allergic skin reaction.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No known significant effects or critical hazards.

No known significant effects or critical hazards.

Adverse symptoms may include the following:

irritation redness

Eye contact : No known significant effects or critical hazards.

Potential acute health effects

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Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

No special measures are required.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon dioxide carbon monoxide Sulfur oxides phosphorus oxides metal oxide/oxides

No specific fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

None known.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

: No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. U.S.A. regulations may require reporting spills of this material that could reach any surface waters. Report spills to all applicable Federal, State, Provincial and local authorities and/or the United States National Response Center at (800) 424-8802 as appropriate or required.

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

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Section 6. Accidental release measures

Small spill

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas.

Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Contaminated absorbent material may pose the same hazard as the spilled product.

Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill :

Stop leak if without risk. Move containers from spill area. Absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

Section 8. Exposure controls/personal protection

Wear eye protection such as safety glasses, chemical goggles, or face shields if engineering controls or work practices are not adequate to prevent eye contact.

Eye/face protection :

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Appropriate engineering controls

: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Control parameters

Individual protection measures

Occupational exposure limits

None.

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Methods and materials for containment and cleaning up

Section 8. Exposure controls/personal protection

Hand protection

If a risk assessment indicates that respiratory protection is required, use a properly fitted, air-purifying or supplied air respirator that complies with an approved standard.

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Use nitrile or oil resistant gloves.

Respiratory protection :

Body protection Personal protective clothing such as gloves, aprons, boots and complete facial protection should be selected based on the task being performed and the risks involved.

Users should determine acceptable performance characteristics of protective clothing.

Consider physical requirements and other substances present when selecting protective clothing.

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved.

Section 9. Physical and chemical properties

Physical state

Vapor pressure

Relative density

Vapor density

Solubility

Liquid. [Clear.]

Not available.

0.85 to 0.87

>10 [Air = 1]

Not available.

Negligible in water.

Mild.Odor pH

Blue-Green.Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Open cup: 247 to 277°C (476.6 to 530.6°F)

Not available.

Not available.

Viscosity Kinematic (100°C): 24 to 40.99 cSt Kinematic (40C): 61.2 to 1100 cSt

Not available.Odor threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point : >300°C (>572°F)

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Volatility Negligible.:

Melting point/ Dropping Point

VOC content : Not available.

Section 10. Stability and reactivity

This material is considered stable under normal ambient and aniticpated storage and handling condtitions of temperature and pressure.

Chemical stability :

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

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Skin protection

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid May react with oxygen and strong oxidizing agents, such as chlorates, nitrates, peroxides, etc.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Reactive or incompatible with the following materials: Strong acids, bases and oxidizers.

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Section 11. Toxicological information

Acute toxicity

Carcinogenicity

Irritation/Corrosion

Sensitization

Information on the likely routes of exposure

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : May cause an allergic skin reaction.

No known significant effects or critical hazards.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation No known significant effects or critical hazards.:

Eye contact : No known significant effects or critical hazards.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Aspiration hazard

Name Result

Information on toxicological effects

: Dermal contact. Eye contact. Inhalation. Ingestion.

Potential acute health effects

There is no data available.

There is no data available.

There is no data available.

Classification

Product/ingredient name

Molybdenum, bis[O,O-bis(2-ethylhexyl) phosphorodithioato-κS,κS ']dioxodi-μ-thioxodi-, (Mo-Mo)

- - - A3 - -

ACGIH EPA NIOSHNTPIARCOSHA

There is no data available.

There is no data available.

1-Decene, homopolymer, hydrogenated ASPIRATION HAZARD - Category 1

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Section 11. Toxicological information

Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Skin contact

Ingestion No known significant effects or critical hazards.

Adverse symptoms may include the following:

irritation redness

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Acute toxicity estimates

Potential immediate effects

: No known significant effects or critical hazards.

Short term exposure

Potential delayed effects : No known significant effects or critical hazards.

Potential immediate effects

: No known significant effects or critical hazards.

Long term exposure

Potential delayed effects : No known significant effects or critical hazards.

There is no data available.

Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

Toxicity

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

There is no data available.

There is no data available.

1-Decene, homopolymer, hydrogenated

>6.5 - high

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Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Section 14. Transport information

Not regulated.

Not regulated. Not regulated.

DOT Classification IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No. No. No.

AERG : Not applicable

Special precautions for user

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

Section 15. Regulatory information U.S. Federal regulations

Clean Water Act (CWA) 307: Naphthalene; Ethylbenzene

Clean Water Act (CWA) 311: Naphthalene; Potassium hydroxide; Ethylbenzene; Xylene

Clean Air Act Section 112

(b) Hazardous Air Pollutants (HAPs)

: Not listed

TSCA 4(a) final test rules: 2,2',6,6'-Tetra-tert-butyl-4,4'-methylenediphenol

TSCA 8(a) PAIR: Naphthalene; Siloxanes and Silicones, di-Me

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): Not determined.

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Section 15. Regulatory information

None of the components are listed.

WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer.

Massachusetts :

SARA 313

Cumene Yes. No. No. No.

Ethylbenzene Yes. No. 41 µg/day (ingestion) No.

54 µg/day (inhalation) Naphthalene Yes. No. Yes. No.

Ingredient name Cancer Reproductive No significant risk level

Maximum acceptable dosage level

California Prop. 65

Clean Air Act Section 602 Class I Substances

: Not listed

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

DEA List II Chemicals (Essential Chemicals)

: Not listed

New York : None of the components are listed.

New Jersey : None of the components are listed.

Pennsylvania : None of the components are listed.

State regulations

SARA 302/304

SARA 304 RQ : Not applicable.

Composition/information on ingredients

SARA 311/312

Classification : Immediate (acute) health hazard

Name % Fire hazard

Sudden release of pressure

Reactive Immediate (acute) health hazard

Delayed (chronic) health hazard

Composition/information on ingredients

No products were found.

Long-chain alkyl amine 0.1 - 1 No. No. No. Yes. No.

Long-chain alkenyl amine 0.1 - 1 No. No. No. Yes. No.

No products were found.

Section 16. Other information Hazardous Material Information System (U.S.A.)

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA).

HMIS® materials may be purchased exclusively from J. J. Keller.

The customer is responsible for determining the PPE code for this material.

Health : 1* Flammability :1 Physical hazards : 0

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Section 16. Other information

History

Prepared by :

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Date of issue mm/dd/yyyy

Version :

04/15/2015

KMK Regulatory Services Inc.

Health : 011 Instability :Flammability :

US Tariff Heading Number

Schedule B Code

: 3403.19.0000

3403.19.0000

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

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Although the information and recommendations set forth herein (hereafter referred to as information) are presented in good faith and believed to be accurate and factual as of the date hereof, Schaeffer Mfg. Company makes no representation as to the completeness or accuracy thereof. Information is supplied upon the condition that the person receiving the same will make their own determination as to its safety and suitability for their purposes prior to use. In no event will Schaeffer Mfg. Company be responsible for damages of any natures whatsoever resulting from the use or reliance upon information.

No representation or warranty, either expressed or implied, of merchantability or fitness for a particular purpose is made with respect to information of the product to which the information refers. Compliance with all applicable federal, state, and local regulations remains the responsibility of the user.

National Fire Protection Association (U.S.A.)