Appendix-A_287H_Flushing_Agent-SDS.PDF

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Conforms to HazCom 2012/United States

SAFETY DATA SHEET

287H Flushing Agent

GHS product identifier Other means of identification Product type

Identified uses Flushing agent for gear boxes and hydraulic systems.

Supplier’s details : Schaeffer Mfg. Company 102 Barton Street Saint Louis, Missouri 63104 Tel: 314-865-4100 Fax: 314-865-4107 Toll Free: 1-800-325-9962 Email: safety@schaefferoil.com Web: http://www.schaefferoil.com

Emergency telephone : +1 314 865 4105 (24-hour response number) Number (with hours of Operation)

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Classification of the : Flammable Liquids – Category 4 substance mixture

GHS label elements Signal word : Warning.

Hazard statements : Combustible liquid.

Precautionary statements Prevention : Keep away from flames and hot surfaces. No smoking.

Response : Not applicable.

Storage : Store in a well-ventilated place. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Section 1. Identification

Section 2. Hazards identification

: 287H Flushing Agent : Not available.

: Liquid.

mailto:safety@schaefferoil.com http://www.schaefferoil.com/

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287H Flushing Agent

Hazards not otherwise : None known.

classified

Substance/mixture : Mixture

Ingredient name % CAS Number Naphtha, (Petroleum), heavy alkylate 4-Nonylphenol, branched, ethoxylated

10-30 1-5

64741-65-7 127087-87-0

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Description of necessary first aid measures Eye Contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.

Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact : Flush contaminated skin with plenty of water. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion : Wash out mouth with water. Remove dentures if any.

Remove victim to fresh air and keep at rest in a position

Section 2. Hazards identification

Section 3. Composition/ information on ingredients

Section 4. First aid measures

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Ingestion : comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards.

Inhalation : No known significant effects or critical hazards.

Skin contact : No known significant effects or critical hazards.

Ingestion : No known significant effects or critical hazards.

Over-exposure signs/symptoms Eye Contact : No known significant effects or critical hazards.

Inhalation : No known significant effects or critical hazards.

Skin contact : No known significant effects or critical hazards.

Ingestion : No known significant effects or critical hazards.

Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 4. First aid measures

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Extinguishing media Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media : None known.

Specific hazards arising from the chemical : No specific fire or explosion hazard.

Hazardous thermal decomposition products : Decomposition products may include the following

Materials:

carbon dioxide carbon monoxide

Special protective actions for fire-fighters : No special measures are required.

Special protective Equipement for fire-fighters : Fire-fighters should wear appropriate equipment and self-contained breathing apparatus (SCBA) with full-piece operated in positive pressure mode.

Personal precautions, protective equipment and emergency procedures For non-emergency Personnel : No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources, no flares, smoking or flames in hazard area.

Put on appropriate personal protective equipment.

Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in “For non-emergency personnel” .

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

U.S.A. regulations may require reporting spills of this material that could reach any surface waters. Report spills to all applicable Federal, State, Provincial and local authorities and/or the United States National Response Center at (800) 424-8802 as appropriate or required.

Section 5. Fire-fighting measures

Section 6. Accidental release measures

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Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Absorb with an inert dry material and place in an appropriate waste disposal container.

Dispose of via a licensed waste disposal contractor.

Large spill : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use.

Store and use away from heat, sparks, open flame or any ignition Source. Use explosion proof electrical equipment and non-sparking tools. Empty containers retain product residue and can be hazardous.

Do not reuse container.

Advice on general occupational hygiene : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink.

Eliminate all ignition sources. Separate from oxidizing materials.

Keep container tightly closed and sealed until upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Containers that have been opened must be carefully resealed and kept upright to prevent leakage.

Section 6. Accidental release measures

Section 7. Handling and storage

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Control parameters Occupational exposure limits None.

Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye/face protection : Wear eye protection such as safety glasses, chemical googles, or face shields if engineering controls or work practices are not adequate to prevent eye contact.

Skin Protection Hand protection : Use nitrile or oil resistant gloves.

Body protection : Personal protective clothing such as gloves, aprons, boots and complete facial protection should be selected based on the task being performed and the risks involved. Users should determine acceptable performance characteristics of protective clothing. Consider physical requirements and other substances present when selecting protective clothing.

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed.

Respiratory protection : If a risk assessment indicates that respiratory protection is required, use a properly fitted, air-purifying or supplied air respirator that complies with an approved standard. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Section 8. Exposure controls/personal protection

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Appearance

Physical state : Liquid Color : Clear, white Odor : Mild.

Odor threshold : Not available pH : Not applicable Melting point/Dropping : Not available Point

Boiling point : >300°C (>572°F)

Flashing point : Pensky-Martens Closed Cup 67.2°C (153°C)

Evaporation rate : Not available Flammability (solid, gas) : Not available Lower and upper explosive : Not available (flammable) limits Vapor Pressure : Not available Relative density : 0.85-0.88 Solubility : Emulsifies in water.

Partition coefficient: n- : Not available octanol/water Auto-ignition temperature : Not available Decomposition temperature : Not available

Viscosity : Kinematic (40°C): 25.0-29.0

Volatility : Not available

Reactivity : No specific test data related to reactivity available for this product or Its ingredients.

Chemical stability : This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Possibility of hazardous : May react with oxygen and strong oxidizing agents, such as chlorates, reactions nitrates, peroxides, etc.

Conditions to avoid : No specific data.

Incompatible materials : Reactive or incompatible with the following materials: Strong acids, bases and oxidizers.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced.

Section 9. Physical and chemical properties

Section 10. Stability and reactivity

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Information on toxicological effects Acute toxicity There is no data available.

Irritation/Corrosion There is no data available.

Sensitization There is no data available.

Carcinogenicity Classification

Product/ingredient name OSHA IARC NTP ACGIH EPA NIOSH White mineral oil (petroleum) - - - A4 - -

Specific target organ toxicity (single exposure) There is no data available.

Specific target organ toxicity (repeated exposure) There is no data available.

Aspiration hazard There is no data available.

Information on the likely : Dermal contact. Eye contact. Inhalation. Ingestion.

routes of exposure

Potential acute health effects Eye contact : No known significant effects or critical hazards.

Inhalation : No known significant effects or critical hazards.

Skin contact : No known significant effects or critical hazards.

Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No known significant effects or critical hazards.

Inhalation : No known significant effects or critical hazards.

Skin contact : No known significant effects or critical hazards.

Ingestion : No known significant effects or critical hazards.

Section 11. Toxicological information

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Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : No known significant effects or critical hazards.

effects

Potential delayed effects : No known significant effects or critical hazards.

Long term exposure Potential immediate : No known significant effects or critical hazards.

effects

Potential delayed effects : No known significant effects or critical hazards.

Potential chronic health effects General : No known significant effects or critical hazards.

Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.

Teratogenicity : No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates There is no data available.

Toxicity There is no data available.

Persistence and degradability There is no data available.

Bioaccumulative potential There is no data available.

Mobility in soil Soil/water partition : Not available.

Coefficient (Koc)

Section 11. Toxicological information

Section 12. Ecological information

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Other adverse effects : No known significant effects or critical hazards.

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled

DOT Classification IMDG IATA

UN number NA1993 Not regulated Not regulated

UN proper shipping name

COMBUSTIBLE LIQUID,

N.O.S.(Naphtha (petroleum), heavy alkylate)

Transport hazard class(es)

Combustible liquid. - -

Packing group III - -

Environmental hazards

No. No. No.

Additional information

This product may be re-classified as “Combustible Liquid”, unless transported by vessel or aircraft. Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials in package sizes less than 119 gal.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Transport in bulk according : Not available.

to Annex II of MARPOL

Section 12. Ecological information

Section 13. Disposal considerations

Section 14. Transport information

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U.S. Federal regulations : TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me; 4-Nonylphenol, Branched, ethoxylated TSCA 8(a) CDR Exempt/Partial exemption: Not determined.

United States inventory (TSCA 8b): All components are listed or exempted.

Clean Air Act Section 112 : Not listed.

(b) Hazardous Air Pollutants (HAPs)

Clean Air Act Section 602 : Not listed.

Class I Substances

Clean Air Act Section 602 : Not listed Class II Substances

DEA List I Chemicals : Not listed (Precursor Chemicals)

DEA List II Chemicals : Not listed

SARA 302/304

Composition/information on ingredients

No products were found.

SARA 304 RQ : Not applicable.

SARA 311/312

Classification : Immediate (acute) health hazards.

Composition/information on ingredients

Name % Fire Hazard

Sudden release of pressure

Reactive Immediate (acute) Health Hazard

Delayed (chronic) health hazard

4- Nonylphenol, branched, ethoxylated

1-5 No. No. No. Yes. No.

Section 15. Regulatory information

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Massachusetts : None of the components are listed.

New York : None of the components are listed.

New Jersey : The following components are listed: White mineral oil (petroleum)

Pennsylvania : None of the components are listed.

California Prop. 65

No products were found.

Hazardous Material Information System (U.S.A.)

Health : 0 Flammability : 1 Physical hazards : 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J.J.

Keller.

This customer is responsible for determining the PPE code for this material.

National Fire Protection Association (U.S.A.)

Health : 0 Flammability : 1 Instability : 0

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of classified classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

US Tariff Heading Number : 2710.19.3070

Schedule B Code : 2710.19.3070

History

Date of issue mm/dd/yyyy : 06/15/2018

Version : 1

Prepared by : Schaeffer Manufacturing Company

Section 15. Regulatory information

Section 16. Other information

SARA 313

No products were found.

State regulations

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Although the information and recommendations set forth herein (hereafter referred to as information) are presented in good faith and believed to be accurate and factual as of the date hereof, Schaeffer Mfg. Company makes no representation as to the completeness or accuracy thereof. Information is supplied upon the condition that the person receiving the dame will make their own determination as to its safety and suitability for their purposes prior to use. In no event will Schaeffer Mfg. Company be responsible for damages of any natures whatsoever resulting from the use or reliance upon information. No representation or warranty, either expressed or implied, of merchantability or fitness for a particular purpose is made with respect to information of the product to which the information refers. Compliance with all applicable federal, state and local regulations remains the responsibility of the user.

Section 16. Other information