Amendment 1 - Attachment 1 - Technical Specifications.pdf

Amendment 1 - Attachment 1 – Technical Specifications

1/20/2022

****NOTE: Customer will reuse the existing Bruker Ultra Shield-PLUS 600 MHz magnet as well as the following existing accessories:

1) Bruker Helium-cooled Cryoprobe (CP-TCI H-C/N-D-05 Z) with Cryo-ATM and corresponding Cryoplatform CU/4 and Helium Compressor.

2) Bruker SampleJet High Throughput Sample Changer

3) Bruker BCU05 Chiller

4) Bruker Room temperature PA BBO BB-H-D-05Z 5mm liquids probe

5) Bruker PH MASVTN BL2.5N N-P/H solids probe

6) Bruker PH HRMAS HCND 4mm (high resolution MAS probe)

7) Phoenix HXY Probe; 1.6mm and 4mm probeheads

****Console needs to be compatible to control all accessories listed above, as well as the technical specifications below****

- NMR CONSOLE 600 MHZ – QTY 1

o NMR Console to operate a 600 MHz spectrometer for both solid and liquid state NMR.

Ethernet ports for internal and external spectrometer devices such as high-throughput sample changers, variable temperature control, and operational platforms for helium cooled probes. Must also support high resolution gradient amplifiers.

- RF CHANNEL (TRX1200) – QTY 3

o The TRX1200 is a highly integrated NMR RF transceiver (transmit and receive) unit with built-in pulse program engine (Sequencer, NCO/DDS, Shapes, etc.).

o Features:

5 to 1200 MHz (transmit and receive) 12.5ns timing resolution

- 12.5ns simultaneous setting of amplitude & phase & frequency

- 1GB sequencer waveform memory

- 1852 MHz high intermediate frequency (IF)

- up to 7.5 MHz spectral width

- digital resolution (effective dynamic range) > 17 Bit (SWH < 5 MHz) > 19 Bit (SWH < 1 MHz) > 23 Bit (SWH < 6 kHz)

- 240 MSPS / 16 Bit ADC, Digital Down Converter (DDC)

- 960 MSPS DAC, Digital Up Converter (DUC)

- RF Amplifiers:

o Alinear single channel high RF power amplifier for 1H (and 19F) observe and decoupling.

o It has a built-in ethernet interfaced, computer controlled RF amplifier safety with forward/reflected RF power monitoring and diagnostics.

o Frequency ranges:

o Model H-Channel

200-600 180-600 MHz (A) 700-900 650-900 MHz (B) 950-1000 890-1000 MHz (C)

RF power A: Min. 500/100W RF peak power (max. 50/20W CW)

B: Min. 500/100W RF peak power (max. 50/20W CW) C: Min. 500/100W RF peak power (max. 50/20W CW)

Aa linear double channel high RF power amplifier for X-nuclei observe and decoupling.

Each channel provides two identical RF outputs for connecting to different preamplifiers when appropriate (no manual re-wiring).

o Frequency range:

o Model BB-Channel 1 BB-Channel 2 200-600 15-600MHz (A1) 15-600MHz (A2) o Features(each):

RF power A1: Min. 500W RF peak power (max. 50W CW)

A2: Min. 500W RF peak power (max. 50W CW) Pulse program controlled blanking

- HPPR1H Preamplifier – QTY 1 o preamplifier for 1H and 19F observe, 1H and 19F decoupling and 19F lock operation.

- HPPR XBB31P 2H PASS Preamplifier – QTY 2 o Preamplifier for observe and decoupling of nuclei from 57Fe up to 31P with built-in 1H Stop RF filter.

o # Designed for broad banded Solid State NMR probes o # >= 700 MHz: Also for broad banded High Resolution NMR probes

- HPPR XBB19F 2H PASS Preamplifier – QTY 1 o preamplifier for observe and decoupling of nuclei from 57Fe up to 19F with built-in 1H

Stop RF filter.

o # Designed for broad banded High Resolution NMR probes

- HPPR 2H Preamplifier – QTY 1 o preamplifier for 2H observe, 2H decoupling and 2H lock operation.

o # No external filters required

- HPPR 13C Preamplifier – QTY 1 o The HPPR 13C is a linear, low noise, GaAs FET transistor technology based preamplifier for 13C or 79Br observe and decoupling operation.

Very low ~1.4dB system noise figure Max. 500W peak power RF capability Active transmit/receive switch Factory calibrated for accurate tuning and matching o # No external filters required

- NMR WS MONITOR 24" LCD – QTY 1

o 24" TFT Monitor for NMR Workstations

- NMR Workstation (LINUX) – QTY 1 o Configured NMR Workstation

- NMR Acquisition and Processing Software Basic license – QTY 1

- 5mm BBF/1H Room Temperature Probe – QTY 1 o X nuclei optimized 5mm double resonance broad banded Probe designed for direct X-nuclei observation with 1H decoupling and for 1H observation (indirect detection). The X-nuclei range corresponds to 19F and the broad band range 31P-109Ag (BBF) excluding 171Yb-9Be.

o Required Features:

Designed for BBF observation and decoupling BBF range: 19F, 31P-109Ag excluding 171Yb-9Be Designed for 1H decoupling and observation 2H lock Z-gradient with 5 G/A*cm Fast Automated Tuning & Matching (2G ATM) VT range: -150 °C to +150 °C VT gas: Nitrogen

- Shim Current Board– QTY 2 o Features 20 shim current sources 20Bit digital resolution each Shim current range +/- 1A each

- Helium CryoPlatform Ethernet Upgrade – QTY 1 o Cryo Platform CU Ethernet interface upgrade kit for He-CryoProbe cooling units (CU).

Ethernet based communication o # Compatible with CU/1, CU/2, CU/3 and CU/4 o # Not required for CU/5 (has built-in Ethernet interface) o

- Z Gradients for shimming

10A max.

16Bit resolution Pulslength up to 50ms per second Built-in pre-emphasis o # lineshape optimization o # XYZ-gradient operation

- HR NMR RF FILTER 2H Stop -QTY 1 o 2H Stop RF Filter to be used together with broad banded High Resolution NMR RT probes

Stop Band: 2H Pass Band: 19F - 75As, 17O - 57Fe

- PROBE RF FILTER 15N-NR LP – QTY 1

o 15N Low Pass RF Filter to be used together with broad banded or selective High Resolution NMR RT probes.

Pass Band: 15N Stop Band: 2H, 19F - 1H o # NR style (= Non-Reflective for overtones of 15N)

- 2H Lock RF Unit (L-TRX) – QTY 1 o 2H lock RF transceiver (transmit and receive) unit with incorporated 5W RF amplifier for field lock operation on deuterated solvents.

- VT Control Unit – QTY 1 o integrated gas flow system to control NMR sample lift (inject/eject) and VT temperatures within the probe.

Digital temperature sensor resolution better than 5 mK Excellent temperature stability of about 10 mK/K (*) Supports various temperature sensors (e.g. thermocouple T or E, PT100) Mass-flow based VT gas flow control and monitoring, up to 3000 l/h Built-in sample freeze protection together with CryoProbes Up to 4 independent heater channels (e.g. Flow probes) High Temperature NMR ready (> 300°C with HT NMR probes) Easy sample insertion with different kinds of spinner (ceramic, KEL-F, etc.).

N o # (*) e.g. SmartProbe, depends on environment and probe type

- VT GAS COOLER (BCU-II) – QTY 1

o chiller for VT gas cooling of NMR probes. Achievable temperature within the probe depends on probe and selected VT gas flow but may be as low as about ~ -40 °C.

VT gas temperature about -80 °C (at the end of the transferline) Up to 3600 litre per hour o # Requires dry VT gas with at least -80 °C (at 1 bar) dew point temperature

- Adaptor Type-T (standard probes) – QTY 1 o TC-T VT Adapter for NMR probes with Thermocouple type 'T' temperature sensors.

Probe Thermocouple type T interface (2x) Probe heater interface Probe heater safety sensor interface o # For Standard Temperature NMR probes (up to 200°C)

- Solid-State Magic Angle Spin Controller – QTY 1 o Micro processor based fully automatic pneumatic MAS control unit

Spinning rate counter Precision regulaing valves Pressure stabilization Sample insert/eject (with dedicated probes) Automated spin-up and spin-down of rotors Spinning speed regulation to < 0.1% Remote control from acquisition work station Manual control using touch display of front panel o # Set of required cables and hoses should be included o # Required but not included:

o # - Suitable rotor transfer system

- NMR ON SITE INSTALL

- One Day Training Course