SDS_AFC-3MS.PDF

Safety Data Sheet

This safety data sheet complies with the requirements of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)

Product name ANSULITE 3% AFFF (AFC-3MS-C)

1. Identification

Product name ANSULITE 3% AFFF (AFC-3MS-C)

Product code 442710 Synonyms None Chemical Family No information available

Recommended use Fire extinguishing agent.

Uses advised against Consumer use.

Contact point Product Stewardship at 1-715-735-7411 E-mail address psra@tycofp.com

Emergency telephone CHEMTREC 001-800-424-9300 or 001-703-527-3887

2. Hazards Identification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation - Category 1 Skin Sensitization - Category 1B

1.1. Product Identifier

1.2. Other means of identification

1.3. Recommended use of the chemical and restrictions on use

1.4. Details of the Supplier of the Safety Data Sheet

Company Name Tyco Fire Protection Products

One Stanton Street Marinette, WI 54143-2542 Telephone: 715-735-7411

1.5. Emergency Telephone Number

Classification

2.2. Label Elements

Signal Word

DANGER

Hazard Statements Causes serious eye damage May cause an allergic skin reaction

Revision date 11-Jan-2019 Version 5

Product code 442710 / Product name ANSULITE 3%

AFFF (AFC-3MS-C)

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Precautionary Statements

Prevention Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapors/spray.

Contaminated work clothing should not be allowed out of the workplace.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Disposal Dispose of contents/container to an approved waste disposal plant.

Not Applicable.

3. Composition/information on Ingredients

The following component(s) in this product are considered hazardous under applicable OSHA(USA)

Chemical name CAS No. weight-% 2-(2-Butoxyethoxy)ethanol 112-34-5 10 - 30 Laurylamidopropyl betaine 4292-10-8 1 - 5

Caprylcaprilyl glucoside 68515-73-1 1 - 5 Polyfluorinated alkyl polyamide Proprietary 1 - 5 Octylphenoxypolyethoxyethanol 9036-19-5 1 - 5

Polyfluorinated alkyl quaternary amine chloride Proprietary 0.1 - 1

4. First aid measures

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.

Consult a physician.

Skin contact Wash skin with soap and water. Get medical attention if irritation develops and persists.

Inhalation Remove to fresh air. If breathing is difficult, give oxygen. (Get medical attention immediately if symptoms occur.).

Ingestion Rinse mouth. Do not induce vomiting without medical advice. If swallowed, call a poison control center or physician immediately.

Symptoms No information available.

Note to physicians Treat symptomatically.

5. Fire-fighting measures

2.3. Hazards Not Otherwise Classified (HNOC)

2.4. Other Information

3.1. Mixture

4.1. Description of first aid measures

4.2. Most Important Symptoms and Effects, Both Acute and Delayed

4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed

AFFF (AFC-3MS-C)

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Hazardous Combustion Products

Carbon oxides, Fluorinated oxides, Nitrogen oxides (NOx), Oxides of sulfur

Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

6. Accidental release measures

Personal Precautions Ensure adequate ventilation, especially in confined areas.

For emergency responders Use personal protection recommended in Section 8.

Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information.

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Pick up and transfer to properly labeled containers.

7. Handling and Storage

Advice on safe handling Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice.

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases.

5.1. Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.2. Unsuitable Extinguishing Media

None.

5.3. Specific Hazards Arising from the Chemical

None known.

5.4. Explosion Data

5.5. Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental Precautions

6.3. Methods and material for containment and cleaning up

7.1. Precautions for Safe Handling

7.2. Conditions for safe storage, including any incompatibilities

AFFF (AFC-3MS-C)

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8. Exposure Controls/Personal Protection

Exposure guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL

2-(2-Butoxyethoxy)ethanol 112-34-5

TWA: 10 ppm inhalable fraction and vapor

ACGIH (American Conference of Governmental Industrial Hygienists) OSHA (Occupational Safety and Health Administration of the US Department of Labor) NIOSH IDLH Immediately Dangerous to Life or Health

Engineering controls Ensure adequate ventilation, especially in confined areas.

Eye/Face Protection Avoid contact with eyes. Tight sealing safety goggles.

Skin and Body Protection Wear protective gloves and protective clothing.

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits

9. Physical and Chemical Properties

Physical State Liquid

8.1. Control Parameters

8.2. Appropriate Engineering Controls

8.3. Individual protection measures, such as personal protective equipment

8.4. General hygiene considerations

Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.

9.1. Information on basic physical and chemical properties

Odor Characteristic Color Light yellow Odor Threshold No data available

Property Values Remarks • Method pH 7 - 8.5 Melting point/freezing point No data available Boiling point / boiling range No data available Flash Point No data available Evaporation Rate No data available Flammability (solid, gas) No data available Flammability limit in air

Upper flammability limit: No data available Lower flammability limit: No data available

Vapor Pressure No data available Vapor Density No data available Specific gravity No data available Water Solubility No data available

AFFF (AFC-3MS-C)

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VOC content (%) 18.7575 Density 1.02

10. Stability and Reactivity

Stable under recommended storage conditions.

None under normal processing.

Hazardous Polymerization Hazardous polymerization does not occur.

Extremes of temperature and direct sunlight.

Strong oxidizing agents. Strong acids. Strong bases.

Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur. Fluorinated oxides.

11. Toxicological Information

Product information

Inhalation No data available.

Eye Contact Corrosive to the eyes and may cause severe damage including blindness.

Skin contact May cause allergic skin reaction.

Ingestion No data available.

Component Information Acute Toxicity

Chemical name Oral LD50 Dermal LD50 Inhalation LC50 2-(2-Butoxyethoxy)ethanol

112-34-5 = 5660 mg/kg ( Rat ) = 2700 mg/kg ( Rabbit ) -

Solubility in Other Solvents No data available Partition coefficient No data available Autoignition Temperature No data available Decomposition Temperature No data available Kinematic viscosity No data available

10.1. Chemical Stability

10.2. Reactivity

No data available

10.3. Possibility of hazardous reactions

10.4. Conditions to Avoid

10.5. Incompatible Materials

10.6. Hazardous decomposition products

11.1. Information on Likely Routes of Exposure

AFFF (AFC-3MS-C)

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Laurylamidopropyl betaine 4292-10-8

> 2000 mg/kg ( Rat ) - -

Polyfluorinated alkyl polyamide >2000 mg/kg >2000 mg/kg >5.11 mg/l

Octylphenoxypolyethoxyethanol 9036-19-5

= 4190 mg/kg ( Rat ) = 1700 mg/kg ( Rat )

Polyfluorinated alkyl quaternary amine chloride

>300 - <2000 mg/kg - -

Symptoms No information available.

Component Information Polyfluorinated alkyl quaternary amine chloride Method species Exposure Route Effective dose Exposure time Results OECD Test No. 439: In Vitro Skin Irritation: Reconstructed Human Epidermis Test Method

EPISKIN™ in vitro Non-irritant

Serious eye damage/eye irritation Risk of serious damage to eyes.

Component Information Polyfluorinated alkyl polyamide Method species Exposure Route Effective dose Exposure time Results OECD Test No. 405: Acute Eye Irritation/Corrosion

Rabbit eye Class 4 on a 1 to 8 scale according to a modified Kay and Calandra classification system. Mild eye irritation

Sensitization May cause sensitization by skin contact.

Component Information Polyfluorinated alkyl polyamide Method species Exposure Route Results OECD Test No. 429: Skin Sensitisation:

Local Lymph Node Assay mouse dermal sensitizing

Polyfluorinated alkyl quaternary amine chloride Method species Exposure Route Results OECD Test No. 429: Skin Sensitisation:

Local Lymph Node Assay mouse dermal sensitizing

Component Information Polyfluorinated alkyl polyamide Method species Results OECD Test No. 473: In vitro Mammalian Chromosome Aberration Test in vitro Non-clastogenic to human lymphocytes in vitro.

Carcinogenicity No information available.

Reproductive Toxicity No information available.

STOT - Single Exposure No information available.

STOT - Repeated Exposure No information available.

Aspiration Hazard No information available.

11.2. Information on Toxicological Effects

11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure

AFFF (AFC-3MS-C)

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The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 5101 mg/kg ATEmix (dermal) 12061 mg/kg ATEmix (inhalation-dust/mist) 129.5 mg/l

12. Ecological Information

Chemical name Algae/aquatic plants Fish Crustacea 2-(2-Butoxyethoxy)ethanol

112-34-5 EC50 (96h) > 100 mg/L

Desmodesmus subspicatus LC50 (96h) static = 1300 mg/L

Lepomis macrochirus EC50 (48h) > 100 mg/L Daphnia magna EC50 (24h) = 2850 mg/L

Daphnia magna 2-Methyl-2,4-pentanediol

107-41-5

- LC50 (96h) static = 10700 mg/L

Pimephales promelas LC50 (96h) static = 10000 mg/L Lepomis macrochirus LC50 (96h) flow-through = 8690 mg/L

Pimephales promelas LC50 (96h) flow-through 10500 - 11000 mg/L

Pimephales promelas

EC50 (48h) 2700 - 3700 mg/L Daphnia magna t-Butanol 75-65-0

EC50 (72h) > 1000 mg/L Desmodesmus subspicatus

LC50 (96h) flow-through 6130 - 6700 mg/L Pimephales promelas

EC50 (48h) = 933 mg/L Daphnia magna EC50 (48h) Static 4607 -

6577 mg/L Daphnia magna Polyethylene Glycol

25322-68-3

- LC50 (24h) > 5000 mg/L Carassius auratus

Sodium chloride 7647-14-5

- LC50 (96h) flow-through 4747 - 7824 mg/L Oncorhynchus mykiss

LC50 (96h) semi-static = 7050 mg/L Pimephales promelas LC50 (96h) static = 12946 mg/L Lepomis macrochirus LC50 (96h) static 6020

- 7070 mg/L Pimephales promelas LC50 (96h) flow-through 5560 - 6080 mg/L Lepomis macrochirus

LC50 (96h) static 6420 - 6700 mg/L Pimephales promelas

EC50 (48h) Static 340.7 - 469.2 mg/L Daphnia magna EC50 (48h) =

1000 mg/L Daphnia magna

4,4'-bis-(sulfostyryl)-biphenyl disodium salt 27344-41-8

EC50 (72h) = 10 mg/L Desmodesmus subspicatus EC50

(96h) 10.0 - 11.0 mg/L Desmodesmus subspicatus

LC50 (96h) static = 76 mg/L Brachydanio rerio

EC50 (48h) = 1000 mg/L Daphnia magna

Polyfluorinated alkyl polyamide Method Species Endpoint type Effective dose Exposure time Results OECD Test No. 203: Fish, Acute Toxicity Test

Oncorhynchus mykiss (rainbow trout)

LC50 >14 mg/l 96h NOEC: 14 mg/L No toxic effects at saturation.

OECD Test No. 201:

Freshwater Alga and Cyanobacteria, Growth Inhibition Test

Algae ErC50 >15 mg/l 72h Growth rate >15, Yield

13. NOEC: 4.0 mg/L, LOEC: 8.5 mg/L

OECD Test No. 202: Daphnia sp., Acute Immobilization Test

Daphnia magna EC50 >20 mg/l 48h NOEC: 20 mg/L No toxic effects at saturation.

Polyfluorinated alkyl quaternary amine chloride Method Species Endpoint type Effective dose Exposure time Results

11.4. Numerical Measures of Toxicity - Product information

12.1. Ecotoxicity

AFFF (AFC-3MS-C)

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OECD Test No. 211: Daphnia magna Reproduction Test

Daphnia magna NOEC 5.38 mg/L 21 days

OECD Test No. 202: Daphnia sp., Acute Immobilization Test

Daphnia magna EC50 2.6 mg/L 48h

OECD Test No. 210: Fish, Early-Life Stage Toxicity Test

Pimephales promelas NOEC 11.8 mg/L 33 days

OECD Test No. 203: Fish, Acute Toxicity Test

Cyprinus carpio LC50 98 mg/L 96h

OECD Test No. 201:

Freshwater Alga and Cyanobacteria, Growth Inhibition Test

Pseudokirchneriella subcapitata

EC50 788 mg/L 96h

No information available.

No information available.

No information available

13. Disposal Considerations

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging Do not reuse container.

14. Transport Information

DOT NOT REGULATED

TDG NOT REGULATED

MEX NOT REGULATED

ICAO (air) NOT REGULATED

IATA NOT REGULATED

IMDG NOT REGULATED

15. Regulatory Information

TSCA Complies DSL/NDSL Does not comply ENCS Does not comply IECSC Does not comply

12.2. Persistence and Degradability

12.3. Bioaccumulation

12.4. Other Adverse Effects

13.1. Waste Treatment Methods

15.1. International Inventories

AFFF (AFC-3MS-C)

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KECL Does not comply PICCS Does not comply AICS Does not comply

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical name SARA 313 - Threshold Values % 2-(2-Butoxyethoxy)ethanol - 112-34-5 1.0 SARA 311/312 Hazard Categories

Acute Health Hazard Yes Chronic health hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42)

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

California Proposition 65 This product contains the following Proposition 65 chemicals

Chemical name California Proposition 65 Perfluorooctanoic acid - 335-67-1 Developmental Toxicity

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania 2-(2-Butoxyethoxy)ethanol

112-34-5 X - X

16. Other information, including date of preparation of the last revision

15.2. US Federal Regulations

15.3. US State Regulations

AFFF (AFC-3MS-C)

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Revision date 11-Jan-2019 Revision note SDS sections updated, 2, 11, 12.

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

NFPA Health Hazards 2 Flammability 0 Instability 0 Physical and chemical properties -

HMIS Health Hazards 2 Flammability 0 Physical Hazards 0 Personal Protection X