1305M324Q0421 SOW_Attachment 4 ArmorSeal 100 AL Side B SDS.pdf

Safety Data Sheet ArmorSeal 100 AL Side B

Section 1: Identification

Product Name: ArmorSeal 100 AL Side B Product Code: POL167 Material Uses: Component of a Polyurethane System Supplier:

ArmorThane USA Inc.

2660 North Eastgate Avenue Springfield, MO, USA 65803 Telephone: 417-831-5090 Fax: 417-831-4397

ArmorThane Coatings Inc.

100, 10803 – 182 Street Edmonton, AB, Canada T5S 1J5 Telephone: 780-444-6200 Fax: 780-444-9405

Emergency Contact: USA – Chemtrec: 800-424-9300 Canada – Canutec: 613-996-6666 Outside USA and Canada – call Chemtrec collect: 703-527-3887

Section 2: Hazards Identification

Physical State: Liquid OSHA/HCS Status: This material is classified as hazardous under OSHA Hazard Communication Standard 29 CFR 1910.1200.

Classification of the Substance or Mixture: Acute Aquatic Toxicity – Category 3

Acute Toxicity Dermal – Category 5 Acute Toxicity Oral – Category 4 Carcinogenicity – Category 2 Chronic Aquatic Toxicity – Category 3 Serious Eye Damage – Category 1 Skin Corrosion – Category 1C Specific Target Organ Toxicity – Repeated Exposure – Category 2 Specific Target Organ Toxicity – Single Exposure – Category 1

GHS Label Elements:

Hazard Pictograms:

Signal Word: DANGER Hazard Statements: May be harmful in contact with skin

Harmful if swallowed Suspected of causing cancer Causes serious eye damage Causes severe skin burns and eye damage May cause damage to organs through prolonged or repeated exposure Causes damage to organs Harmful to aquatic life Harmful to aquatic life with long lasting effects

Precautionary Statements: If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Avoid release to the environment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not breathe dust/fumes/gas/mist/vapors/spray.

Do not eat, drink or smoke when using this product. Call a POISON CENTER/doctor if you feel unwell. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. If exposed or concerned, get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water (or shower). Wash contaminated clothing before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Specific treatment: see section 4 of this SDS. Get medical advice/attention if you feel unwell. If exposed or concerned, call a POISON CENTER/doctor. Store locked up. Dispose of contents/container to an approved waste disposal plant.

See toxicological information (Section 11).

General Information: Read the entire SDS for a more thorough evaluation of the hazards.

Section 3: Composition/Information on Ingredients

Substance/Mixture: Mixture

Ingredient Name CAS Number Percentage Polyoxypropylenediamine 9046-10-0 21-37 Aromatic amine 68479-98-1 4-8 Dipropylene glycol 25265-71-8 2-4 1,4-Diazobicyclo (2,2,2) octane 280-57-9 1.2-2 Silica, crystalline 14808-60-7 0.9-1.4 Carbon black 1333-86-4 0.1-1

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Section 4: First Aid Measures

Eye Contact: Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses if present and easy to do

so. Continue rinsing for a duration of 15-20 minutes. Take care not to rinse the contaminated water into the unaffected eye or onto the face. If eye irritation persists, get medical advice/attention.

Skin Contact: Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs, get medical advice/attention. Wash contaminated clothing before reuse, or discard. If exposed or concerned, get medical advice/attention.

Inhalation: Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms, call a POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the POISON CENTER/doctor. If exposed/feel unwell/concerned, get medical advice/attention.

Ingestion: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery position. Give 1 or 2 glasses of milk or water to drink and refer person to medical personnel. Do not give anything by mouth to an unconscious person. If exposed or concerned, get medical advice/attention

Section 5: Firefighting Measures

Flash Point: 201oF (94oC) Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, water spray, or fog are recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.

Specific Hazards in Case of Fire: Sudden reaction and fire may result when the product is exposed to oxidizing agents.

Firefighting Procedures: Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.

Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Special Protective Actions: Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), goggles, and full protective clothing are also required. Care should always be exercised in dust/mist areas.

Section 6: Accidental Release Measures

Emergency Procedure: Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately. ELIMINATE all ignition sources (no smoking, flares, sparks, or flames in the immediate area).

Recommended Equipment: Positive pressure, full-face piece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape SCBA (NIOSH approved).

Personal Precautions: Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

Environmental Precautions: Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems and natural waterways by using sand, earth, or other appropriate barriers.

Methods and Materials for Containment and Cleanup: Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work area. Residues from spill cleanup may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste.

For major spills in the USA, call Chemtrec at 800-424-9300, and in Canada, call Canutec at 613-996-6666.

Section 7: Handling and Storage

General: Wash hands after use. Do not get in eyes, on skin, or on clothing. Do not breathe vapors or mists. Use good personal hygiene practices. Eating, drinking, and smoking in work areas is prohibited. Remove contaminated clothing and protective equipment before entering eating areas. Eyewash stations and showers should be available in areas where this material is used and stored.

Ventilation Requirements: Use only with adequate ventilation to control air contaminants to their exposure limits.

The use of local ventilation is recommended to control emissions near the source.

Storage Room Requirements: Keep container(s) tightly closed and properly labelled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong oxidizers, and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be carefully resealed to prevent leakage. Empty containers retain residue and may be dangerous. Use non-sparking ventilation systems, approved explosion-proof equipment, and intrinsically safe electrical systems in areas where this product is used and stored. Store in tightly sealed containers to protect from atmospheric moisture. Store in a cool dry area. Store liquid in containers above ground and surround by dikes to contain spills or leaks. Ground and bond containers and receiving equipment. Avoid static electricity by grounding.

Section 8: Exposure Controls/Personal Protection

Exposure Limits

Ingredient OSHA TWA

OSHA

Tables Z1,2,3

NIOSH

TWA NIOSH

Carcinogen

AGCIH

TWA

Carbon black 3.5 1 3.5a mg/m3

1 3 (l|) mg/m3

Silica, crystalline a ppm [10 mg/m3 percent SiO2+2/250 percent SiO2+5 mppcf]; [30 mg/m3 percent SiO2+2]

1,3 0.05e mg/m3

1 0.025 (R) mg/m3

Appropriate Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value.

Individual Protection Measures:

Eye/Face Protection: Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If additional protection is needed for entire face, use in combination with a face shield.

Skin Protection: Use of gloves approved to be relevant standards made from the following material may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Use of an apron and over-boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin sensitization. The type of protective equipment must be selected according to the concentrations and amount of the dangerous substance at the specific workplace. Launder soiled clothes or properly dispose of contaminated material, which cannot be decontaminated.

Respiratory Protection: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection program that meets or is equivalent to OSHA 29 CFR

1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective equipment suppliers. When airborne concentrations exceed or are expected to exceed the TLV, us MSHA/NIOSH approved positive pressure supplied air respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing apparatus.

Section 9: Physical and Chemical Properties

Physical State: Liquid Appearance: Pigmented liquid Odor: Mild chemical Odor Threshold: N/A pH: N/A Boiling/Condensation Point: Low: 302oF (150oC), High: N/A Melting/Freezing Point: N/A Flash Point: 201oF (94oC) Evaporation Rate: Slower than ether Flammability: N/A Lower and Upper Explosive Limits: N/A Vapor Pressure: N/A Vapor Density: Heavier than air Density: 8.76 lb/gal Solubility in Water: N/A Partition Co-Efficient: n-octanol/water: N/A Auto-Ignition Temperature: N/A Decomposition Temperature: N/A Viscosity: N/A Specific Gravity: 1.06 VOC Regulatory: 0.00 lb/gal VOC Side A & B Combined: Not available

Section 10: Stability and Reactivity

Chemical Stability: This product is stable at standard temperature and pressure.

Conditions to Avoid: Heat, high temperature, open flame, and moisture. Avoid contact with incompatible materials.

Hazardous Reactions/Polymerization: Will not occur.

Incompatible Materials: This product will react with any material containing isocyanates. Some reactions can be violent.

Hazardous Decomposition Products: Combustion products are organic vapors and thermal decomposition fragments.

Section 11: Toxicological Information

Skin Corrosion/Irritation: Product may be absorbed through skin and cause nausea, headache and general discomfort. Causes severe skin burns and eye damage.

Serious Eye Damage/Irritation: Vapors can irritate the eyes. Chemical burns may result due to overexposure.

Effects of exposure may be delayed. Causes serious eye damage.

Carcinogenicity: Suspected of causing cancer.

Respiratory/Skin Sensitization: Inhalation: Severe overexposure may induce respiratory sensitization with asthma like symptoms. These symptoms may be immediate or delayed up to several hours after exposure. Chronic exposures may result in permanent decreases in lung function.

Skin sensitization may develop after repeated and/or prolonged contact.

Germ Cell Mutagenicity: No data available Reproductive Toxicity: No data available Specific Target Organ Toxicity – Single Exposure: Causes damage to organs.

Specific Target Organ Toxicity – Repeated Exposure: May cause damage to organs through prolonged or repeated exposure.

Aspiration Hazard: No data available Acute Toxicity:

If ingested: In humans, irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion, and injury may be severe and cause death.

Repeated and prolonged exposure at low levels may result in adverse skin and eye effects, liver and kidney disorders.

May be harmful in contact with skin. Harmful if swallowed.

Chronic Exposure:

Silica, crystalline: Prolonged inhalation of respirable crystalline silica dust can result in lung disease (i.e. silicosis and/or lung cancer). Symptoms include coughing, shortness of breath, wheezing and reduced pulmonary function.

Carbon black: In 1996, the IARC re-evaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to carbon black for which there is inadequate human evidence, but sufficient animal evidence. Prolonged inhalation of carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and reduced pulmonary function.

Potential Health Effects – Miscellaneous:

Carbon black: Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This chemical is known to the State of California to cause cancer.

Silica, crystalline: Is an IARC, NTP, or OSHA carcinogen. Repeated overexposure to crystalline silica may lead to x-ray changes and chronic lung disease. Inhalation of high dust concentrations may cause breathing difficulties and/or lung injury. WARNING: This chemical is known to the State of California to cause cancer.

Carbon Black: LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3) Polyoxypropylenediamine: LD50 (dermal, rabbit): 2090 mg/kg (based on raw material SDS); LD50 (oral, rat): 480 mg/kg (based on raw material SDS)

Section 12: Ecological Information

Toxicity: Harmful to aquatic life. Harmful to aquatic life with long lasting effects.

Mobility in Soil: No data available Other Adverse Effects: No data available Persistence and Degradability: Carbon Black: Carbon black’s insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in the natural environment.

Bio-accumulative Potential: Carbon Black: A relevant bioaccumulation potential of carbon black is not expected based on its insolubility in organic solvents and in water. Furthermore, since the aggregate diameter of carbon black varies between 80 nm and 810 nm, bioaccumulation of particulate carbon black is not likely owing to the large diameter of the solid aggregate particles.

Section 13: Disposal Considerations

Waste Disposal: Under RCRA, it is the responsibility of the user of the product, to determine at the time of disposal whether the product meets RCRA criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld, or use for any other purposes. Return drums to reclamation centers for proper cleaning and reuse.

Disposal should be in accordance with applicable regional, national, and local laws and regulations

Section 14: Transport Information

Proper Shipping Name:

DOT: UN/NA # 2735

UN Proper Shipping Name: AMINES, LIQUID, CORROSIV, N.O.S. (POLYOXYPROPYLENEDIAMINE) Hazard Class: 8 Packing Group III Placard: Corrosive

IMDG: UN/NA # 2735

UN Proper Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. (POLYOXYPROPYLENEDIAMINE) Hazard Class: 8 Placard: Corrosive Marine Pollutant: No data available

IATA: UN/NA # 2735

UN Proper Shipping Name: AMINES, LIQUID, CORROSIV, N.O.S. (POLYOXYPROPYLENEDIAMINE) Hazard Class: 8 Packing Group III Placard: Corrosive

Section 15: Regulatory Information

Polyoxypropyenediamine (9046-10-0, 21-37% by weight): DSL, TSCA Aromatic Amine (68479-98-1, 4-8% by weight): DSL, SARA312, VOC, TSCA Dipropylene Glycol (25265-71-8, 2-4% by weight): DSL, SARA312, VOC, TSCA 1,4-Diazobicyclo (2,2,2) Octane (280-57-0, 1.202% by weight): DSL, SARA312, TSCA Silica, crystalline (14808-60-7, 0.9-1.4% by weight): DSL, SARA312, TSCA, California Proposition 65 Carbon Black (1333-86-4, 0.1-1% by weight): DSL, SARA312, TSCA, California Proposition 65

Section 16: Other Information

Preparation Date: August 1, 2019

Disclaimer: The data set forth in this sheet is based on information provided by the suppliers of the raw materials and chemicals used in the manufacture of the aforementioned product. ArmorThane makes no warranty with respect to the accuracy of the information provided by their suppliers, and disclaims all liability of reliance thereof.

ArmorThane USA Inc. and/or ArmorThane Coatings Inc. make no representations or warranties as to the results of the use of the products and assume no obligation in connection therewith. Any written, oral, testing, or technical application advice is to the best of ArmorThane’s knowledge and believed to be correct. It is to be considered only an indication without obligation. Customer is reminded that he must satisfy himself that the product supplied by ArmorThane is suitable for his purpose and conditions of use. Application, uses, and transformation of the products which are beyond our control, are the exclusive responsibility of the customer/applicator. Liability of ArmorThane for all claims, whether arising out of breach of warranty, negligence, strict liability, or otherwise, is limited to the purchase price of the material only.

User’s Responsibility: A bulletin as this cannot be expected to cover all possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where, precautions, in addition to those described herein, are required. Any health hazard and safety information herein should be passed on to your customers and employees, as the case may be.

For Your Protection: ArmorThane warrants only that its products meet the specification stated in the sales contract. Typical properties, where stated, are to be considered as representative of current production and should not be treated as specifications. While all the information presented in this document is believed to be reliable and to represent the best available data on these products, no guaranty, warranty, or representation is made, intended, or implied as to the correctness, or sufficiency of any information, or as to the merchantability or suitability or fitness or any chemical compounds or other products for any particular use or purpose, or that any chemical compounds or other compounds or the use thereof are not subject to a claim by a third party for infringement of any patent or other intellectual property right. The user should conduct sufficient investigation to establish the suitability of any product for its intended use. Liability of ArmorThane for all claims, whether arising out of breach of warranty, negligence, strict liability, or otherwise, is limited to the purchase price of the material.

Products may be toxic and require special precautions in handling. For all products listed, the user should obtain detailed information on toxicity, together with proper shipping, handling, and storage procedures, and comply with all applicable safety and environmental standards. Toxicity and risk characteristics of chemical compounds and other products may differ when used with other materials or in a manufacturing or other process. Those risk characteristics should be determined by the user and made known to handlers, processors, and end users.