1305M324Q0421 SOW_Attachment 2 HighLine 200 Side B SDS.pdf

Safety Data Sheet HighLine 200 Side B

Section 1: Identification

Product Name: HighLine 200 Side B Product Code: POL142 Material Uses: Component of a Polyurethane System Supplier:

ArmorThane USA Inc.

2660 North Eastgate Avenue Springfield, MO, USA 65803 Telephone: 417-831-5090 Fax: 417-831-4397

ArmorThane Coatings Inc.

100, 10803 – 182 Street Edmonton, AB, Canada T5S 1J5 Telephone: 780-444-6200 Fax: 780-444-9405

Emergency Contact: USA – Chemtrec: 800-424-9300 Canada – Canutec: 613-996-6666 Outside USA and Canada – call Chemtrec collect: 703-527-3887

Section 2: Hazards Identification

Physical State: Liquid OSHA/HCS Status: This material is classified as hazardous under OSHA Hazard Communication Standard 29 CFR 1910.1200.

Precautionary Statements: If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Avoid release to the environment. Wash thoroughly after handling. Do not breathe dust/fumes/gas/mist/vapors/spray. Call a POISON CENTER/doctor if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. If skin irritation occurs, get medical advice/attention. Get medical advice/attention if you feel unwell. Dispose of contents/container to an approved waste disposal plant.

Other Hazards Which Do Not Result in Classification: None known Classification of the Substance or Mixture: SPECIFIC TARGET ORGAN TOXICITY – Repeated Exposure, Category 2

SKIN IRRITATION – Category 3 EYE IRRITATION – Category 2B ACUTE AQUATIC TOXICITY – Category 3 CHRONIC AQUATIC TOXICITY – Category 3 ACUTE TOXICITY – Oral – Category 5

GHS Label Elements:

Hazard Pictograms:

Signal Word: Warning

Hazard Statements: May be harmful if swallowed.

Causes eye irritation.

Causes mild skin irritation May cause damage to organs through prolonged or repeated exposure

Harmful to aquatic life.

Harmful to aquatic life with long lasting effects.

See toxicological information (Section 11).

General Information: Read the entire SDS for a more thorough evaluation of the hazards.

Section 3: Composition/Information on Ingredients

Substance/Mixture: Mixture

Ingredient Name CAS Number Percentage Diethylene glycol 111-46-6 10-19 Quartz 14808-60-7 0.8-1.4 Aromatic amine 68479-98-1 0.7-1.1 Ethylene glycol 107-21-1 Trace

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Section 4: First Aid Measures

Eye Contact: Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses if present and easy to do

so. Continue rinsing for a duration of 15-20 minutes. Take care not to rinse the contaminated water into the unaffected eye or onto the face. If eye irritation persists, get medical advice/attention.

Skin Contact: Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs, get medical advice/attention. Wash contaminated clothing before reuse, or discard. If exposed or concerned, get medical advice/attention.

Inhalation: Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms, call a POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the POISON CENTER/doctor. If exposed/feel unwell/concerned, get medical advice/attention.

Ingestion: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery position. Give 1 or 2 glasses of milk or water to drink and refer person to medical personnel. Do not give anything by mouth to an unconscious person. If exposed or concerned, get medical advice/attention

Section 5: Firefighting Measures

Flash Point: 212oF (100oC) Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, water spray, or fog are recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.

Specific Hazards in Case of Fire: Sudden reaction and fire may result when the product is exposed to oxidizing agents.

Firefighting Procedures: Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.

Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Special Protective Actions: Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), goggles, and full protective clothing are also required. Care should always be exercised in dust/mist areas.

Section 6: Accidental Release Measures

Emergency Procedure: Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately. ELIMINATE all ignition sources (no smoking, flares, sparks, or flames in the immediate area).

Recommended Equipment: Positive pressure, full-face piece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape SCBA (NIOSH approved).

Personal Precautions: Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

Environmental Precautions: Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems and natural waterways by using sand, earth, or other appropriate barriers.

Methods and Materials for Containment and Cleanup: Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work area. Residues from spill cleanup may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste.

For major spills in the USA, call Chemtrec at 800-424-9300, and in Canada, call Canutec at 613-996-6666.

Section 7: Handling and Storage

General: Wash hands after use. Do not get in eyes, on skin, or on clothing. Do not breathe vapors or mists. Use good personal hygiene practices. Eating, drinking, and smoking in work areas is prohibited. Remove contaminated clothing and protective equipment before entering eating areas. Eyewash stations and showers should be available in areas where this material is used and stored.

Ventilation Requirements: Use only with adequate ventilation to control air contaminants to their exposure limits.

The use of local ventilation is recommended to control emissions near the source.

Storage Room Requirements: Keep container(s) tightly closed and properly labelled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong oxidizers, and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be carefully resealed to prevent leakage. Empty containers retain residue and may be dangerous. Use non-sparking ventilation systems, approved explosion-proof equipment, and intrinsically safe electrical systems in areas where this product is used and stored. Store in tightly sealed containers to protect from atmospheric moisture. Store in a cool dry area. Store liquid in containers above ground and surround by dikes to contain spills or leaks. Ground and bond containers and receiving equipment. Avoid static electricity by grounding.

Section 8: Exposure Controls/Personal Protection

Exposure Limits Ingredient

OSHA TWA (mg/m3)

OSHA

Tables Z1,2,3

NIOSH

TWA

(mg/m3)

NIOSH

Carcinogen

AGCIH

TWA

(mg/m3)

ACGIH STEL

(mg/m3)

Ethylene Glycol

C 100

Quartz (10 mg/m3 percent SiO2+2/250 percent SiO2+5 mppcf); (30 mg/m3 percent SiO2+2)

1,3 0.05e 1 0.025 (R)

Appropriate Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value.

Individual Protection Measures:

Eye/Face Protection: Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If additional protection is needed for entire face, use in combination with a face shield.

Skin Protection: Use of gloves approved to be relevant standards made from the following material may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Use of an apron and over-boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin sensitization. The type of protective equipment must be selected according to the concentrations and amount of the dangerous substance at the specific workplace. Launder soiled clothes or properly dispose of contaminated material, which cannot be decontaminated.

Respiratory Protection: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection program that meets or is equivalent to OSHA 29 CFR

1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective equipment suppliers. When airborne concentrations exceed or are expected to exceed the TLV, us MSHA/NIOSH approved positive pressure supplied air respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing apparatus.

Section 9: Physical and Chemical Properties

Physical State: Liquid Odor: Mild chemical Odor Threshold: Not available pH: Not available Boiling/Condensation Point: Low: 302oF (150oC), High: Not available Melting/Freezing Point: Not available Flash Point and Method Used: 212oF (100oC) Evaporation Rate: Slower than ether Flammability: Not available

Lower and Upper Explosive Limits: Not available Vapor Pressure: Not available Vapor Density: Heavier than air Density: 8.79 lb/gal Solubility in Water: Not available Partition Co-Efficient: n-octanol/water: Not available Auto-Ignition Temperature: Not available Decomposition Temperature: Not available Viscosity: Not available Specific Gravity: 1.05 VOC Regulatory: 0.00 lb/gal VOC Side A & B Combined: Not available

Section 10: Stability and Reactivity

Chemical Stability: This product is stable at standard temperature and pressure.

Possibility of Hazardous Reaction: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to Avoid: Heat, high temperature, open flame, and moisture. Avoid contact with incompatible materials.

Incompatible Materials: This product will react with any material containing isocyanates. Some reactions can be violent.

Hazardous Decomposition Products: Combustion products are organic vapors and thermal decomposition fragments.

Section 11: Toxicological Information

Skin Corrosion/Irritation: Product may be absorbed through skin and cause nausea, headache and general discomfort. Causes mild skin irritation.

Serious Eye Damage/Irritation: Vapors can irritate the eyes. Chemical burns may result due to overexposure.

Effects of exposure may be delayed. Causes eye irritation.

Carcinogenicity: No data available Respiratory/Skin Sensitization: Inhalation: Severe overexposure may induce respiratory sensitization with asthma like symptoms. These symptoms may be immediate or delayed up to several hours after exposure. Chronic exposures may result in permanent decreases in lung function.

Skin sensitization may develop after repeated and/or prolonged contact.

Germ Cell Mutagenicity: No data available Reproductive Toxicity: No data available Specific Target Organ Toxicity – Single Exposure: No data available Specific Target Organ Toxicity – Repeated Exposure: May cause damage to organs through prolonged or repeated exposure.

Aspiration Hazard: No data available Acute Toxicity:

If ingested: In humans, irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion, and injury may be severe and cause death.

Repeated and prolonged exposure at low levels may result in adverse skin and eye effects, liver and kidney disorders.

Ethylene Glycol: LD50 (oral, rat): 5.89 g/kg, 8.54 g/kg, 13.0 g/kg (5); LD50 (oral, mouse): 7.5 g/kg, 15.28 g/kg (5,6);

LD50 (oral, guinea pig): 6.6 g/kg, 11.0 g/kg (5); LD50 (oral, rabbit): 5.0 g/kg (5); LD50 (dermal, rabbit): 9.5 g/kg (6)

Chronic Exposure:

Quartz: Prolonged inhalation of respirable crystalline silica dust can result in lung disease (i.e. silicosis and/or lung cancer). Symptoms include coughing, shortness of breath, wheezing and reduced pulmonary function.

Potential Health Effects – Miscellaneous:

Quartz: Quartz is an IARC, NTP or OSHA carcinogen. Repeated overexposure to crystalline silica may lead to x-ray changes and chronic lung disease. Inhalation of high dust concentrations may cause breathing

Section 12: Ecological Information

Toxicity: Toxic to aquatic life with long lasting effects. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.

Mobility in Soil: No data available Other Adverse Effects: No data available

Section 13: Disposal Considerations

Waste Disposal: Under RCRA, it is the responsibility of the user of the product, to determine at the time of disposal whether the product meets RCRA criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld, or use for any other purposes. Return drums to reclamation centers for proper cleaning and reuse.

Disposal should be in accordance with applicable regional, national, and local laws and regulations

Section 14: Transport Information

Proper Shipping Name:

DOT: Not regulated TDG: Not regulated IMDG: Not regulated IATA: Not regulated

Section 15: Regulatory Information

Diethylene Glycol (CAS #111-46-6) (10-19% by weight) Regulations Lists: DSL, SARA 312, VOC, TSCA Quartz (CAS #14808-60-7) (0.8-1.4% by weight) Regulation Lists: DSL, SARA312, TSCA, California Proposition 65 Aromatic Amine (CAS #68479-98-1) (0.4-0.7% by weight) Regulation Lists: DSL, SARA 312, VOC, TSCA Ethylene Glycol (CAS #107-21-1) (Trace by weight) Regulation Lists: DSL, CERCLA, HAPS, SARA 312, SARA 313, VHAPS, VOC, TSCA

Section 16: Other Information

Preparation Date: September 14, 2017

Disclaimer: The data set forth in this sheet is based on information provided by the suppliers of the raw materials and chemicals used in the manufacture of the aforementioned product. ArmorThane makes no warranty with respect to the accuracy of the information provided by their suppliers, and disclaims all liability of reliance thereof.

ArmorThane USA Inc. and/or ArmorThane Coatings Inc. make no representations or warranties as to the results of the use of the products and assume no obligation in connection therewith. Any written, oral, testing, or technical application advice is to the best of ArmorThane’s knowledge and believed to be correct. It is to be considered only an indication without obligation. Customer is reminded that he must satisfy himself that the product supplied by ArmorThane is suitable for his purpose and conditions of use. Application, uses, and transformation of the products which are beyond our control, are the exclusive responsibility of the customer/applicator. Liability of ArmorThane for all claims, whether arising out of breach of warranty, negligence, strict liability, or otherwise, is limited to the purchase price of the material only.

User’s Responsibility: A bulletin as this cannot be expected to cover all possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where, precautions, in addition to those described herein, are required. Any health hazard and safety information herein should be passed on to your customers and employees, as the case may be.

For Your Protection: ArmorThane warrants only that its products meet the specification stated in the sales contract. Typical properties, where stated, are to be considered as representative of current production and should not be treated as specifications. While all the information presented in this document is believed to be reliable and to represent the best available data on these products, no guaranty, warranty, or representation is made, intended, or implied as to the correctness, or sufficiency of any information, or as to the merchantability or suitability or fitness or any chemical compounds or other products for any particular use or purpose, or that any chemical compounds or other compounds or the use thereof are not subject to a claim by a third party for infringement of any patent or other intellectual property right. The user should conduct sufficient investigation to establish the suitability of any product for its intended use. Liability of ArmorThane for all claims, whether arising out of breach of warranty, negligence, strict liability, or otherwise, is limited to the purchase price of the material.

Products may be toxic and require special precautions in handling. For all products listed, the user should obtain detailed information on toxicity, together with proper shipping, handling, and storage procedures, and comply with all applicable safety and environmental standards. Toxicity and risk characteristics of chemical compounds and other products may differ when used with other materials or in a manufacturing or other process. Those risk characteristics should be determined by the user and made known to handlers, processors, and end users.