TECHNOLOGY/BUSINESS OPPORTUNITY Method of producing optical element with thicker substrate engraved meta-surface layer

Opportunity:

Lawrence Livermore National Laboratory (LLNL), operated by the Lawrence Livermore National Security (LLNS), LLC under contract no. DE-AC52-07NA27344 (Contract 44) with the U.S. Department of Energy (DOE), is offering the opportunity to enter into a collaboration to further develop and commercialize its method of producing optical element with thicker substrate engraved meta-surface layer.

Background:

Optical phase plates, filters, holograms, Fresnel lenses and other diffractive optical elements are difficult to fabricate with arbitrarily tailored varying spatial structures, especially down to the micron scale and with high damage threshold. This method not only solves these challenges but further enables the possibility of fabricating many new optical elements that would not be possible otherwise from a greater variety of substrates materials (including sapphire) and operating over a great spectral range (including the UV).

Description:

This invention (US Patent No. 11,294,103) is an extension of another LLNL invention, US Patent No. 10,612,145, which utilizes a thin sacrificial metal mask layer deposited on a dielectric substrate (e.g. fused silica) and subsequently nanostructured through a laser generated selective thermal de-wetting process. Local variation of the laser exposure controls the thermal de-wetting process yielding the mask’s desired metal nanoparticle distribution. The arbitrarily tailored sacrificial nanostructured mask is etched away through, for example, Reactive Ion Etching to leave the substrate with a subwavelength nanotextured surface that features an effective refractive index pattern imprinted from the mask structure. This specific invention (US Patent No. 11,294,103) achieves a thicker substrate-engraved meta-surface layer over US Patent No. 10,612,145 by using multiple depositions of the same or different metals layers to achieve the desired mask properties on different substrates with different dewetting characteristics and etch resistance.

Advantages/Benefits: 

• Allows meta-surface engraving of a wider variety of substrates including sapphire.
• Allows deeper meta-surface engraving for broader spectral response including the UV.
• Allows for the arbitrary tailoring of the refractive index profile of a substrate surface layer down to the micron level.
• Featuring the high damage threshold of the intrinsic substrate material.
• Resulting refractive index pattern can be wavelength and angle insensitive (unlike thin film multi-layer dielectric solutions).
• Resulting surface texture is ultra-hydrophobic and is in principle self-cleaning.
• Produces arbitrarily large, but lightweight optical elements.
• Flexibility to pattern planar and non-planar surfaces.

Potential Applications: 

• High power laser systems for industrial applications
• High energy lasers systems for scientific applications

Development Status: 

Current stage of technology development:  TRL 2-3

LLNL has patent(s) on this invention.

U.S. Patent No. 11,294,103 System and Method for Repeated Metal Deposition-Dewetting Steps to Form a Nano-Particle Etching Mask Producing Thicker Layer of Engraved Metasurface published 4/5/2022

U.S. Patent No. 10,612,145 Nanostructured layer for graded index freeform optics published 4/7/2020

LLNL is seeking industry partners with a demonstrated ability to bring such inventions to the market. Moving critical technology beyond the Laboratory to the commercial world helps our licensees gain a competitive edge in the marketplace. All licensing activities are conducted under policies relating to the strict nondisclosure of company proprietary information. 

Please visit the IPO website at https://ipo.llnl.gov/resources for more information on working with LLNL and the industrial partnering and technology transfer process.

Note:  THIS IS NOT A PROCUREMENT.  Companies interested in commercializing LLNL's method of producing optical element with thicker substrate engraved meta-surface layer should provide an electronic OR written statement of interest, which includes the following:

1. Company Name and address.
2. The name, address, and telephone number of a point of contact.
3. A description of corporate expertise and/or facilities relevant to commercializing this technology.

Please provide a complete electronic OR written statement to ensure consideration of your interest in LLNL's method of producing optical element with thicker substrate engraved meta-surface layer.

The subject heading in an email response should include the Notice ID and/or the title of LLNL’s Technology/Business Opportunity and directed to the Primary and Secondary Point of Contacts listed below.

Written responses should be directed to:

Lawrence Livermore National Laboratory

Innovation and Partnerships Office

P.O. Box 808, L-779

Livermore, CA  94551-0808

Attention:   IL-13146andIL-13450