1A.W81XWH-18-Q-0058_PWSAttachment_A.pdf

ATTACHMENT A:

Analysis, Procedures and Quantitation Limits

Analysis Code Description Procedure Description Compound Code Compound Description Units Quantitation Limit

PCBs (as Aroclors) EPA 525.2 or 525.3 or

EPA 505

12674-11-2 Aroclor 1016 ug/L

0.08 see Aroclor 1016 11104-28-2 Aroclor 1221 ug/L 0.19 see Aroclor 1016 11141-16-5 Aroclor 1232 ug/L 0.23 see Aroclor 1016 53469-21-9 Aroclor 1242 ug/L 0.26 see Aroclor 1016 12672-29-6 Aroclor 1248 ug/L 0.1 see Aroclor 1016 11097-69-1 Aroclor 1254 ug/L 0.1 see Aroclor 1016 11096-82-5 Aroclor 1260 ug/L 0.2

PCBs (as Decachlorobiphenyl) EPA 508A PCBs (as Decachlorobiphenyl) ug/L 0.1

Pesticides EPA 525.2 or 525.3 or

EPA 505

15972-60-8 Alachlor ug/L 0.2 see alachlor 309-00-2 Aldrin ug/L 0.1 see alachlor 1912-24-9 Atrazine ug/L 0.1 see alachlor 57-74-9 Chlordane ug/L 0.2 see alachlor 60-57-1 Dieldrin ug/L 0.1 see alachlor 72-20-8 Endrin ug/L 0.02 see alachlor 58-89-9 gamma-HCH {gamma-BHC, Lindane} ug/L 0.02 see alachlor 76-44-8 Heptachlor ug/L 0.04 see alachlor 1024-57-3 Heptachlor epoxide ug/L 0.02 see alachlor 118-74-1 Hexachlorobenzene ug/L 0.1 see alachlor 77-47-4 Hexachlorocyclopentadiene ug/L 1 see alachlor 72-43-5 Methoxychlor ug/L 0.1 see alachlor 122-34-9 Simazine ug/L 0.1 see alachlor 8001-35-2 Toxaphene ug/L 1

Herbicides, Regulated EPA 515.3 or 515.4 93-72-1 2,4,5-TP {Silvex} ug/L 0.1

EPA 515.3 or 515.4 94-75-7 2,4-D ug/L 0.1

EPA 515.3 or 515.4 75-99-0 Dalapon ug/L 1

EPA 515.3 or 515.4 88-85-7 Dinoseb ug/L 0.7

EPA 515.3 or 515.4 87-86-5 Pentachlorophenol ug/L 0.04

EPA 515.3 or 515.4 1918-02-1 Picloram ug/L 0.1

EDB/DBCP EPA 504.1 96-12-8 1,2-Dibromo-3-chloropropane ug/L 0.02

106-93-4 1,2-Dibromoethane ug/L 0.01

Diquat/Paraquat EPA 549.2 85-00-7 Diquat ug/L 2

1910-42-5 Paraquat ug/L 2

Haloacetic Acids - HAA5 EPA 552.2 or 631-64-1 Dibromoacetic Acid ug/L 1

EPA 552.3 79-43-6 Dichloroacetic Acid ug/L 1

(552.3 preferred) E701185 Haloacetic Acids (HAA5) ug/L 6

79-08-3 Monobromoacetic Acid ug/L 1

79-11-8 Monochloroacetic Acid ug/L 2

76-03-9 Trichloroacetic Acid ug/L 1

Carbamates EPA 531.2 16655-82-6 3-Hydroxycarbofuran ug/L 1.5

116-06-3 Aldicarb ug/L 0.5

1646-88-4 Aldicarb Sulfone ug/L 0.8

1646-87-3 Aldicarb sulfoxide ug/L 0.5

114-26-1 Baygon (Propoxur) ug/L 1.5

63-25-2 Carbaryl ug/L 1.5

1563-66-2 Carbofuran ug/L 0.9

2032-65-7 Methiocarb ug/L 1.5

16752-77-5 Methonyl ug/L 1.5

23135-22-0 Oxamyl (Vydate) ug/L 1.5

Glyphosate/AMPA EPA 547 1071-83-6 Glyphosate ug/L 50

EPA 547 74341-63-2 AMPA ug/L 50

Dioxin (2,3,7,8-TCDD only) EPA 1613B 1746-01-6 2,3,7,8-TetraCDD pg/L 3

Trihalomethanes/TTHMs EPA 524.2 75-27-4 Bromodichloromethane ug/L 1

75-25-2 Bromoform ug/L 1

67-66-3 Chloroform ug/L 1

124-48-1 Dibromochloromethane ug/L 1

E701045 Total Trihalomethanes {TTHMs} ug/L 4

UV Absorption, 254nm (filtered) SM 5910B or EPA 415.3

(1.1) E1640549 UV Absorption, 254nm cm -1 0.01

UV Absorption, 254nm (Unfiltered) SM 5910B or EPA 415.3

(1.1) E1640549U UV Absorption, 254nm (unfiltered) cm -1 0.01

Endothall EPA 548.1 145-73-3 Endothall ug/L 10

Turbidity EPA 180.1 (2.0) or SM

2130B E1640507 Turbidity NTU

ATTACHMENT 1:

Analysis Code Description Procedure Description Compound Code Compound Description Units Quantitation Limit

Volatiles Organics EPA 524.2 630-20-6 1,1,1,2-Tetrachloroethane ug/L 0.5

71-55-6 1,1,1-Trichloroethane ug/L 0.5

79-34-5 1,1,2,2-Tetrachloroethane ug/L 0.5

79-00-5 1,1,2-Trichloroethane ug/L 0.5

75-34-3 1,1-Dichloroethane ug/L 0.5

75-35-4 1,1-Dichloroethene ug/L 0.5

563-58-6 1,1-Dichloropropene ug/L 0.5

87-61-6 1,2,3-Trichlorobenzene ug/L 0.5

96-18-4 1,2,3-Trichloropropane ug/L 0.5

120-82-1 1,2,4-Trichlorobenzene ug/L 0.5

95-63-6 1,2,4-Trimethylbenzene ug/L 0.5

96-12-8 1,2-Dibromo-3-chloropropane ug/L 0.5

106-93-4 1,2-Dibromoethane ug/L 0.5

95-50-1 1,2-Dichlorobenzene ug/L 0.5

107-06-2 1,2-Dichloroethane ug/L 0.5

78-87-5 1,2-Dichloropropane ug/L 0.5

108-67-8 1,3,5-Trimethylbenzene ug/L 0.5

541-73-1 1,3-Dichlorobenzene ug/L 0.5

142-28-9 1,3-Dichloropropane ug/L 0.5

106-46-7 1,4-Dichlorobenzene ug/L 0.5

594-20-7 2,2-Dichloropropane ug/L 0.5

95-49-8 2-Chlorotoluene ug/L 0.5

106-43-4 4-Chlorotoluene ug/L 0.5

99-87-6 4-Isopropyltoluene ug/L 0.5

71-43-2 Benzene ug/L 0.5

108-86-1 Bromobenzene ug/L 0.5

74-97-5 Bromochloromethane ug/L 0.5

75-27-4 Bromodichloromethane ug/L 1

75-25-2 Bromoform ug/L 1

74-83-9 Bromomethane ug/L 0.5

56-23-5 Carbon tetrachloride ug/L 0.5

108-90-7 Chlorobenzene ug/L 0.5

75-00-3 Chloroethane ug/L 0.5

67-66-3 Chloroform ug/L 1

74-87-3 Chloromethane ug/L 0.5

156-59-2 cis-1,2-Dichloroethene ug/L 0.5

10061-01-5 cis-1,3-Dichloropropene ug/L 0.5

124-48-1 Dibromochloromethane ug/L 1

74-95-3 Dibromomethane ug/L 0.5

75-71-8 Dichlorodifluoromethane ug/L 0.5

100-41-4 Ethylbenzene ug/L 0.5

87-68-3 Hexachlorobutadiene ug/L 0.5

98-82-8 Isopropylbenzene ug/L 0.5

E966689 m,p-Xylene ug/L 0.5

1634-04-4 Methyl tert-butyl ether {MtBE} ug/L 0.5

75-09-2 Methylene chloride ug/L 0.5

91-20-3 Naphthalene ug/L 0.5

104-51-8 n-Butylbenzene ug/L 0.5

103-65-1 n-Propylbenzene ug/L 0.5

95-47-6 o-Xylene ug/L 0.5

135-98-8 sec-Butylbenzene ug/L 0.5

100-42-5 Styrene ug/L 0.5

98-06-6 tert-Butylbenzene ug/L 0.5

127-18-4 Tetrachloroethene {PCE} ug/L 0.5

108-88-3 Toluene ug/L 0.5

E701045 Total Trihalomethanes {TTHMs} ug/L 4

156-60-5 trans-1,2-Dichloroethene ug/L 0.5

10061-02-6 trans-1,3-Dichloropropene ug/L 0.5

79-01-6 Trichloroethene {TCE} ug/L 0.5

75-69-4 Trichlorofluoromethane ug/L 0.5

75-01-4 Vinyl chloride ug/L 0.5

1330-20-7 Xylenes, total ug/L 1.5

Chlorine Demand SM 2350B CT Chlorine Contact Time Hours NA

E1641703 Chlorine Demand mg/L 0.05

E17027624 Chlorine Dose mg/L 0.05

E1644335 pH pH Units 0.1

E1645704 Temperature degrees C NA

7782-50-5(R) Residual Chlorine mg/L 0.05

Cyanide, total (CN)

EPA 335.4 or other EPA-approved drinking water method

57-12-5 Cyanide {CN} mg/L

0.02

Semivolatiles (regulated) EPA 525.2 or 525.3 50-32-8 Benzo[a]pyrene ug/L 0.02

EPA 525.2 or 525.3 103-23-1 Di(2-ethylhexyl)adipate ug/L 0.6

EPA 525.2 or 525.3 117-81-7 Di(2-ethylhexyl)phthalate ug/L 0.6

Analysis Code Description Procedure Description Compound Code Compound Description Units Quantitation Limit

Sulfate (SO4)

EPA 300.0 or 300.1 or other EPA-approved drinking water method

14808-79-8 Sulfate {SO4} mg/L

2.5

Bromide

EPA 300.0 or 300.1 or other EPA-approved drinking water method for fluoride

24959-67-9 Bromide {Br} mg/L 0.05

Fluoride see sulfate 7782-41-4 Fluoride {F} mg/L 0.1

Chloride see sulfate 16887-00-6 Chloride {Cl} mg/L 2.5

Bromate EPA 317 (2.0) 15541-45-4 Bromate {BrO3} ug/L 1

Chlorite EPA 300.0 14998-27-7 Chlorite {ClO2} ug/L 10

Chlorate EPA 300.0 or 300.1 14866-68-3 Chlorate ug/L 20

Nitrate-N (NO3-N)

EPA 300.0 or other EPA-approved drinking water method

14797-55-8 Nitrate {NO3} mg/L N

0.1

Nitrite-N (NO2-N)

EPA 300.0 or other EPA-approved drinking water method

14797-65-0 Nitrite {NO2} mg/L N

0.1

Nitrite/Nitrate-N (NO2NO3), total

EPA 353.2 or other EPA-approved drinking water method

E701177 Total Nitrite/Nitrate, as N mg/L N

0.2

Ortho Phosphate-P EPA 300.0 or 300.1 or

EPA 365.1

14265-44-2 o-Phosphate {PO4} mg/L P

0.05

Dissolved Organic Carbon (DOC) EPA 415.3 (1.1) or SM

5310C (48 hr hold time) DOC Dissolved Organic Carbon {DOC} mg/L

0.5

Total Organic Carbon (TOC) EPA 415.3 (1.1) or SM

5310 B, C, or D E701250 Total Organic Carbon {TOC} mg/L

0.5

Color SM 2120B E1641752 Color (apparent) color unit 5

Foaming Agents (MBAS) SM 5540C E52450962 Foaming Agents (MBAS) mg/L 0.05

Odor SM 2150B E1640465 Odor (threshold odor number) TON 1

Alkalinity (ALK) SM 2320B E1640192 Alkalinity, total mg/L CaCO3 2

Specific Conductance SM 2510B E1640291 Conductivity umhos/cm 2

Total Dissolved Solids (TDS) SM 2540C E1642222 Total dissolved solids {TDS} ppm 10 pH EPA 150.1, 150.2, or SM

4500-H+ B E1644335 pH pH Units

0.1 increments

Asbestos EPA 100.2 1332-21-4 Asbestos, total MFL 0.7

Perchlorate EPA 331 14797-73-0 Perchlorate {ClO4} ug/L 1

Total Coliform (Quantitative) EPA approved drinking water method- SM 9000 series E761700 Total coliform MPN/100 mL 1

E. Coli (Quantitative) EPA approved drinking water method- SM 9000 series 68583-22-2 E. Coli MPN/100 mL 1

Giardia/cryptosporidium EPA 1623 E761684 Cryptosporidium oocysts/100L 1

EPA 1623 E761718 Giardia cysts/100L 1

DBP Formation Potential SM5710B Formation Potential see HAA5, TTHM, and chlorine demand limits above

Mercury (Hg) EPA 200.8 or 245.1 7439-97-6 Mercury mg/L 0.001

Analysis Code Description Procedure Description Compound Code Compound Description Units Quantitation Limit

Aluminum (Al) EPA 200.7 or 200.8 7429-90-5 Aluminum mg/L 0.005

Antimony (Sb) EPA 200.8 7440-36-0 Antimony mg/L 0.001

Arsenic (As) EPA 200.8 7440-38-2 Arsenic mg/L 0.004

Barium (Ba) EPA 200.8 7440-39-3 Barium mg/L 0.02

Beryllium (Be) EPA 200.8 7440-41-7 Beryllium mg/L 0.004

Boron (B) EPA 200.7 7440-42-8 Boron mg/L 0.1

Cadmium (Cd) EPA 200.8 7440-43-9 Cadmium mg/L 0.005

Calcium (Ca) EPA 200.7 7440-70-2 Calcium mg/L 0.1

Chromium (Cr) EPA 200.8 7440-47-3 Chromium mg/L 0.005

Cobalt (Co) EPA 200.8 7440-48-4 Cobalt mg/L 0.005

Copper (Cu) EPA 200.8 7440-50-8 Copper mg/L 0.01

Iron (Fe) EPA 200.7 7439-89-6 Iron mg/L 0.03

Lead (Pb) EPA 200.8 7439-92-1 Lead mg/L 0.001

Lithium (Li) EPA 200.7 or 200.8 7439-93-2 Lithium mg/L 0.002

Magnesium (Mg) EPA 200.7 7439-95-4 Magnesium mg/L 0.2

Manganese (Mn) EPA 200.8 7439-96-5 Manganese mg/L 0.005

Molybdenum (Mo) EPA 200.8 7439-98-7 Molybdenum mg/L 0.004

Nickel (Ni) EPA 200.8 7440-02-0 Nickel mg/L 0.001

Potassium (K) EPA 200.7 7440-09-7 Potassium mg/L 0.5

Selenium (Se) EPA 200.8 7782-49-2 Selenium mg/L 0.005

Silver (Ag) EPA 200.8 7440-22-4 Silver mg/L 0.005

Sodium (Na) EPA 200.7 7440-23-5 Sodium mg/L 0.2

Thallium (Tl) EPA 200.8 7440-28-0 Thallium mg/L 0.001

Uranium (U) EPA 200.8 7440-61-1 Uranium mg/L 0.001

Vanadium (V) EPA 200.8 7440-62-2 Vanadium mg/L 0.005

Zinc (Zn) EPA 200.7 or 200.8 7440-66-6 Zinc mg/L 0.05

Perfluorinated Alkyl Substances

(PFAS)/Perfluorinated Chemicals (PFCs) EPA 537 Rev 1.1

1763-23-1 perfluorooctanesulfonic acid (PFOS) ng/L

335-67-1 perfluorooctanoic acid (PFOA) ng/L 2

375-95-1 perfluorononanoic acid (PFNA) ng/L 2

355-46-4 perfluorohexanesulfonic acid

(PFHxS) ng/L

375-85-9 perfluoroheptanoic acid (PFHpA) ng/L 2

375-73-5 perfluorobutanesulfonic acid (PFBS) ng/L 2

335-76-2 Perfluorodecanoic acid (PFDA) ng/L 5

307-55-1 Perfluorododecanoic acid (PFDoA) ng/L 5

307-24-4 Perfluorohexanoic acid (PFHxA) ng/L 5

376-06-7 Perfluorotetradecanoic acid (PFTA) ng/L 5

72629-94-8 Perfluorotridecanoic acid (PFTrDA) ng/L 5

2058-94-8 Perfluoroundecanoic acid (PFUnA) ng/L 5

2991-50-6 N-ethyl perfluorooctanesulfonamidoacetic acid ng/L

2355-31-9

N-methyl perfluorooctanesulfonamidoacetic acid

(NMeFOSAA) ng/L

Pharmaceuticals and Personal Care

Products (PPCP)

EPA 1694 or equivalent method Sucralose ng/L no specific criteria

Triclosan ng/L no specific criteria

Caffeine ng/L no specific criteria

Carbamazepine ng/L no specific criteria

Cotinine ng/L no specific criteria

DEET ng/L no specific criteria

*Provide quantitation limits for evaluation*

*Provide other compounds that are reported with the method*