MS-D1_sds-en.pdf

Safety Data Sheet

MS-D1

Revision Date 11/25/2021

Print Date 11/25/2021

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SECTION 1. IDENTIFICATION

Product name : MS-D1

Other means of identification : MS-D1 SY, MS-D1 CI, MS-D1 G2, MS-D1 STA, MS-D1 STB, MS-D1 STC, MS-D1 STD, MS-D1 MF, MS-D1 MFB, MS-D1

MFC, MS-D1 MFD , MS-D1 NSF-61

MS-D1 STA+, MS-D1 STB+, MS-D1 STC+, MS-D1 STD+,

MS-D1 ST20, MS-D1 ST25, MS-D1 ST30, MS-D1 ST35, MS-

D1 ST40, MS-D1 ST45, MS-D1 ST50,

MS-D1 ST55, MS-D1 ST60, MS-D1 ST65, MS-D1 ST70, MS-

D1 ST75, MS-D1 ST80, MS-D1 ST85, MS-D1 ST90, MS-D1

ST95, MS-D1 ST100, MS-D1 ST105

MS-D1 ST110, MS-D1 CW, MS-D1 NE,MS-D1 SF10, MS-D1

AM, MS-D1 RT, MS-D1 X, MS-D1 X2 , MS-D1 X3

MS-D1 X SY,MS-D1 X CI, MS-D1 X G2, MS-D1 X STA, MS-

D1 X STB, MS-D1 X STC, MS-D1 X STD, MS-D1 X MF, MS-

D1 X MFB, MS-D1 X MFC,

MS-D1 X MFD, MS-D1 X STA+, MS-D1 X STB+, MS-D1 X

STC+, MS-D1 X STD+, MS-D1 X ST20, MS-D1 X ST25, MS-

D1 X ST30, MS-D1 X ST35

MS-D1 X ST40, MS-D1 X ST45, MS-D1 X ST50, MS-D1 X

ST55, MS-D1 X ST60, MS-D1 X ST65, MS-D1 X ST70, MS-

D1 X ST75, MS-D1 X ST80,

MS-D1 X ST85, MS-D1 X ST90, MS-D1 X ST95, MS-D1 X

ST100,MS-D1 X ST105, MS-D1 X ST110, MS-D1 X CW,MS-

D1 X NE, MS-D1 X SF10,MS-D1 X AM

MS-D1 X RT, MS-D1 X2 SY, MS-D1 X2 CI, MS-D1 X2 G2,

MS-D1 X2 STA, MS-D1 X2 STB, MS-D1 X2 STC, MS-D1 X2

STD, MS-D1 X2 MF,

MS-D1 X2 MFB, MS-D1 X2 MFC, MS-D1 X2 MFD, MS-D1 X2

STA+, MS-D1 X2 STB+, MS-D1 X2 STC+, MS-D1 X2 STD+,

MS-D1 X2 ST20, MS-D1 X2 ST25

MS-D1 X2 ST30, MS-D1 X2 ST35, MS-D1 X2 ST40,MS-D1

X2 ST45, MS-D1 X2 ST50, MS-D1 X2 ST55, MS-D1 X2

ST60, MS-D1 X2 ST65, MS-D1 X2 ST70

MS-D1 X2 ST75, MS-D1 X2 ST80, MS-D1 X2 ST85, MS-D1

X2 ST90, MS-D1 X2 ST95, MS-D1 X2 ST100, MS-D1 X2

ST105, MS-D1 X2 ST110,

MS-D1 X2 CW, MS-D1 X2 NE, MS-D1 X2 SF10, MS-D1 X2

AM, MS-D1 X2 RT,MS-D1 X3 RT, MS-D1 X3 CW, MS-D1 X3

NE, MS-D1 X3 SF10, MS-D1 X3 AM,

MS-D1 X3 SY, MS-D1 X3 CI, MS-D1 X3 G2, MS-D1 X3 STA,

MS-D1 X3 STB, MS-D1 X3 STC, MS-D1 X3 STD, MS-D1 X3

MF,

MS-D1 X3 MFB, MS-D1 X3 MFC, MS-D1 X3 MFD, MS-D1 X3

STA+, MS-D1 X3 STB+, MS-D1 X3 STC+, MS-D1 X3 STD+,

MS-D1 X3 ST20, MS-D1 X3 ST25

MS-D1 X3 ST30, MS-D1 X3 ST35, MS-D1 X3 ST40,MS-D1

X3 ST45, MS-D1 X3 ST50, MS-D1 X3 ST55, MS-D1 X3

ST60, MS-D1 X3 ST65, MS-D1 X3 ST70

MS-D1 X3 ST75, MS-D1 X3 ST80, MS-D1 X3 ST85, MS-D1

X3 ST90, MS-D1 X3 ST95, MS-D1 X3 ST100, MS-D1 X3

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ST105, MS-D1 X3 ST110,

MS-D1 SY CI, MS-D1 SY G2, MS-D1 SY CW, MS-D1 X SY,

MS-D1 X2 SY, MS-D1 X3 SY, MS-D1 X SY CI, MS-D1 X SY

G2, MS-D1 X SY CW,

MS-D1 X SY NE, MS-D1 X SY AM, MS-D1 X2 SY CI, MS-D1

X2 SY G2, MS-D1 X2 SY CW, MS-D1 X2 SY NE, MS-D1 X2

SY AM, MS-D1 X3 SY CI,

MS-D1 X3 SY G2, MS-D1 X3 SY CW, MS-D1 X3 SY NE, MS-

D1 X3 SY AM, MS-D1 X SY RT,MS-D1 X2 SY RT, MS-D1 X3

SY RT, MS-D1 X SF10

MS-D1 X2 SF10 , MS-D1 X3 SF10

Company name : 601, avenue Delmar Canada Pointe-Claire, QC H9R 4A9 Sika Canada Inc.

www.sika.ca

Telephone : (514) 697-2610 / 1 (800) 933-7452

Telefax : (514) 694-2792

E-mail address : ehs@ca.sika.com

Emergency telephone : CANUTEC (collect) (613) 996-6666 (24 hours)

Recommended use of the chemical and restrictions on use

: For further information, refer to product data sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the Hazardous Products Regulations Skin corrosion

: Category 1C

Serious eye damage

: Category 1

Skin sensitization

: Category 1

Carcinogenicity (Inhalation)

: Category 1A

Specific target organ toxicity

- single exposure

: Category 3 (Respiratory system)

Specific target organ toxicity

- repeated exposure

: Category 1 (Lungs)

GHS label elements Hazard pictograms

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Signal Word

: Danger

Hazard Statements

: H314 Causes severe skin burns and eye damage.

H317 May cause an allergic skin reaction.

H335 May cause respiratory irritation.

H350 May cause cancer by inhalation.

H372 Causes damage to organs (Lungs) through prolonged or repeated exposure.

Precautionary Statements

: Prevention:

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P260 Do not breathe dust.

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response:

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.

P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.

P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.

P308 + P313 IF exposed or concerned: Get medical advice/ attention.

P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.

P362 + P364 Take off contaminated clothing and wash it before reuse.

Storage:

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Disposal:

P501 Dispose of contents/ container to an approved waste dis-posal plant.

Additional Labeling There are no ingredients with unknown acute toxicity used in a mixture at a concentration >= 1%.

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Other hazards None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Components Chemical name CAS-No. Classification Concentra-tion (% w/w) Quartz (SiO2) >5µm 14808-60-7 Carc. 1A; H350i

STOT RE 1; H372

STOT SE 3; H335

>= 60 - < 80

Cement 65997-15-1 Skin Corr. 1C; H314 Eye Dam. 1; H318 Skin Sens. 1; H317

STOT SE 3; H335

>= 10 - < 30

Actual concentration or concentration range is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Consult a physician.

Show this material safety data sheet to the doctor in attend-ance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.

Wash off with soap and plenty of water.

Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficul-ty.

In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-sue damage and blindness.

In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Continue rinsing eyes during transport to hospital.

Remove contact lenses.

Keep eye wide open while rinsing.

If swallowed : Clean mouth with water and drink afterwards plenty of water.

Do not induce vomiting without medical advice.

Do not give milk or alcoholic beverages.

Never give anything by mouth to an unconscious person.

Take victim immediately to hospital.

Most important symptoms and effects, both acute and delayed

: Health injuries may be delayed.

corrosive effects irritant effects sensitizing effects Cough

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Respiratory disorder Allergic reactions Dermatitis May cause an allergic skin reaction.

Causes serious eye damage.

May cause respiratory irritation.

May cause cancer by inhalation.

Causes damage to organs through prolonged or repeated exposure.

Causes severe burns.

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.

Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Special protective equipment for fire-fighters

: In the event of fire, wear self-contained breathing apparatus.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec-tive equipment and emer-gency procedures

: Use personal protective equipment.

Avoid breathing dust.

Deny access to unprotected persons.

Environmental precautions

: Do not flush into surface water or sanitary sewer system.

If the product contaminates rivers and lakes or drains inform respective authorities.

Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up

: Pick up and arrange disposal without creating dust.

Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on protection against fire and explosion

: Avoid dust formation.

Provide appropriate exhaust ventilation at places where dust is formed.

Advice on safe handling : Avoid formation of respirable particles.

Avoid exceeding the given occupational exposure limits (see section 8).

Do not get in eyes, on skin, or on clothing.

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For personal protection see section 8.

Persons with a history of skin sensitization problems or asth-ma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.

Smoking, eating and drinking should be prohibited in the ap-plication area.

Follow standard hygiene measures when handling chemical products.

Conditions for safe storage : Store in original container.

Keep in a well-ventilated place.

Observe label precautions.

Store in accordance with local regulations.

Materials to avoid : Explosives Oxidizing agents Poisonous gases Dangerous when wet Flammable solids Organic peroxides Poisonous liquids Spontaneously Combustible Substances

Further information on stor-age stability

: Keep in a dry place.

No decomposition if stored and applied as directed.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters Components CAS-No. Value type

(Form of exposure)

Control parame-ters / Permissible concentration

Basis

Quartz (SiO2) >5µm 14808-60-7 TWA (Res-pirable par-ticulates)

0.025 mg/m3 CA AB OEL

TWA (Res-pirable frac-tion)

0.1 mg/m3 CA ON OEL

TWAEV

(respirable dust)

0.1 mg/m3 CA QC OEL pirable)

0.025 mg/m3 (Silica)

CA BC OEL

0.025 mg/m3 CA BC OEL

0.025 mg/m3

CA BC OEL

pirable par-ticulate mat-ter)

0.025 mg/m3 ACGIH

TWA (Res- 0.025 mg/m3 ACGIH

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0.025 mg/m3 ACGIH ticulate mat-ter)

0.025 mg/m3 (Silica)

ACGIH

Cement 65997-15-1 TWA 10 mg/m3 CA AB OEL TWA (Res-

1 mg/m3 CA BC OEL

(respirable dust)

5 mg/m3 CA QC OEL

TWAEV (to-tal dust)

10 mg/m3 CA QC OEL ticulate mat-ter)

1 mg/m3 ACGIH fumes, silica 69012-64-2 TWA (Total fume)

4 mg/m3 CA BC OEL pirable fume)

1.5 mg/m3 CA BC OEL pirable frac-tion - fume)

2 mg/m3 CA ON OEL

(Respirable fume)

2 mg/m3 CA QC OEL

Particles of nuisance dust

Form of exposure Value type Control parameters Basis total dust TWA 15 mg/m3 OSHA Z-3 respirable fraction TWA 5 mg/m3 OSHA Z-3

Engineering measures : Use of adequate ventilation should be sufficient to control worker exposure to airborne contaminants. If the use of this product generates dust, fumes, gas, vapor or mist, use pro-cess enclosures, local exhaust ventilation or other engineer-ing controls to keep worker exposure below any recommend-ed or statutory limits.

Personal protective equipment Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed respirator complying with an approved standard if a risk as-sessment indicates this is necessary.

The filter class for the respirator must be suitable for the max-

8 / 13 imum expected contaminant concentration (gas/vapor/aerosol/particulates) that may arise when han-dling the product. If this concentration is exceeded, self-contained breathing apparatus must be used.

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is nec-essary.

Eye protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-tration and amount of dangerous substances, and to the spe-cific work-place.

Hygiene measures : Avoid contact with skin, eyes and clothing.

Wash hands before breaks and immediately after handling the product.

Remove contaminated clothing and protective equipment before entering eating areas.

Wash thoroughly after handling.

Avoid breathing dust.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : powder

Color : gray

Odor : odorless

Odor Threshold : No data available pH : No data available

Melting point/range / Freezing point

: No data available

Boiling point/boiling range : No data available

Flash point : No data available

Evaporation rate : No data available

Flammability (solid, gas)

Upper explosion limit / Upper flammability limit

Lower explosion limit / Lower flammability limit

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Vapor pressure : No data available

Relative vapor density : No data available

Density : ca. 2.5 g/l (20 °C (68 °F))

Solubility(ies) Water solubility : insoluble

Solubility in other solvents : No data available

Partition coefficient: n-octanol/water

Autoignition temperature : No data available

Decomposition temperature : No data available

Viscosity Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous reac-tions

: Stable under recommended storage conditions.

Conditions to avoid : No data available

Incompatible materials : No data available

Hazardous decomposition products

: No decomposition if stored and applied as directed.

SECTION 11. TOXICOLOGICAL INFORMATION

Not classified based on available information.

Skin corrosion/irritation Causes severe burns.

Serious eye damage/eye irritation Causes serious eye damage.

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Respiratory or skin sensitization

Skin sensitization May cause an allergic skin reaction.

Respiratory sensitization Not classified based on available information.

Germ cell mutagenicity Not classified based on available information.

Carcinogenicity May cause cancer by inhalation.

IARC Group 1: Carcinogenic to humans

Quartz (SiO2) >5µm 14808-60-7 (Silica dust, crystalline)

OSHA OSHA specifically regulated carcinogen

(crystalline silica)

NTP Known to be human carcinogen

(Silica, Crystalline (Respirable Size))

Reproductive toxicity Not classified based on available information.

STOT-single exposure May cause respiratory irritation.

STOT-repeated exposure Causes damage to organs (Lungs) through prolonged or repeated exposure.

Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

Prolonged exposure can cause silicosis.

Aspiration toxicity Not classified based on available information.

Further information

Product:

Quartz (14808-60-7): This classification is relevant when ex-posed to Quartz (silicon dioxide) in dust or powder form only, including cured product that is subject to sanding, grinding, cutting, or other surface preparation activities.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity No data available

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Persistence and degradability No data available

Bioaccumulative potential No data available

Mobility in soil No data available

Other adverse effects

Product:

Additional ecological infor-mation

: Do not empty into drains; dispose of this material and its con-tainer in a safe way.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods Waste from residues : Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Contaminated packaging : Empty containers should be taken to an approved waste han-dling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulations

IATA-DGR

Not regulated as a dangerous good

IMDG-Code Not regulated as a dangerous good

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.

Domestic regulation

TDG

Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

Canadian lists No substances are subject to a Significant New Activity Notification.

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SECTION 16. OTHER INFORMATION

Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) CA AB OEL : Canada. Alberta, Occupational Health and Safety Code (table

2: OEL)

CA BC OEL : Canada. British Columbia OEL CA ON OEL : Ontario Table of Occupational Exposure Limits made under the Occupational Health and Safety Act.

CA QC OEL : Québec. Regulation respecting occupational health and safe-ty, Schedule 1, Part 1: Permissible exposure values for air-borne contaminants

OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-eral Dusts

ACGIH / TWA : 8-hour, time-weighted average CA AB OEL / TWA : 8-hour Occupational exposure limit CA BC OEL / TWA : 8-hour time weighted average CA ON OEL / TWA : Time-Weighted Average Limit (TWA) CA QC OEL / TWAEV : Time-weighted average exposure value OSHA Z-3 / TWA : 8-hour time weighted average

ADR : Accord européen relatif au transport international des marchandises Dangereuses par Route CAS : Chemical Abstracts Service DNEL : Derived no-effect level EC50 : Half maximal effective concentration GHS : Globally Harmonized System IATA : International Air Transport Association IMDG : International Maritime Code for Dangerous Goods LD50 : Median lethal dosis (the amount of a material, given all at once, which causes the death of 50% (one half) of a group of test animals)

LC50 : Median lethal concentration (concentrations of the chemical in air that kills 50% of the test animals during the observation period)

MARPOL : International Convention for the Prevention of Pollution from Ships, 1973 as modified by the Protocol of 1978

OEL : Occupational Exposure Limit PBT : Persistent, bioaccumulative and toxic PNEC : Predicted no effect concentration REACH : Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Reg-istration, Evaluation, Authorisation and Restriction of Chemi-cals (REACH), establishing a European Chemicals Agency

SVHC : Substances of Very High Concern vPvB : Very persistent and very bioaccumulative

Notice to Reader:

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The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This information is not intended to address, nor does it ad-dress the use or application of the identified Sika product in combination with any other material, product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone number listed.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING

FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL

THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE

FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY

OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.

All sales of Sika products are subject to its current terms and conditions of sale available at www.sika.ca or 514-697-2610.

Revision Date : 11/25/2021 Date format : mm/dd/yyyy

Prepared by : R & D of Sika Canada Inc.

Material number : 645,690

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