LV-MasterSeal_pavementsealer_SDS.pdf

SAFETY DATA SHEET

Issuing Date 15-Dec-2014 Revision Date 30-Sept-2016 Revision Number 2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

GHS Product Identifier Product Name: SealMaster LV Concentrate

Other Means of Identification Product Code(s): S1002 Synonyms None

Recommended Use of the Chemical and Restrictions on Use Recommended Use: No Information Available Uses Advised Against: No Information Available

Supplier Address Manufacturer Address SealMaster SealMaster Locations Nationwide Locations Nationwide www.sealmaster.net www.sealmaster.net 1-800-341-7325 1-800-341-7325

Emergency Telephone Number Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION

Classification

Carcinogenicity Category 1B

GHS Label Elements, Including Precautionary Statements

Emergency Overview

Signal Word Danger

● May cause cancer

● Harmful if swallowed

● May cause skin irritation

Appearance: Black Physical State: Liquid Odor: Asphaltic/Coal Tar Odor

Precautionary Statements Prevention ● Obtain special instructions before use.

● Do not handle until all safety precautions have been read and understood.

● Use personal protective equipment as required.

Inhalation: May cause irritation of respiratory tract.

Eye Contact: Contact with eyes may cause irritation.

Skin Contact: May cause irritation.

Ingestion: Ingestion may cause stomach discomfort.

General Advice ● If exposed or concerned: Get medical attention/advice.

Storage ● Store locked up.

Disposal ● Dispose of contents/container to an approved waste disposal plant.

Hazard Not Otherwise Classified (HNOC) Not applicable

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS Number Weight % Trade Secret

Limestone 1317-65-3 20-40 *

Asphalt 8052-42-4 20-40 *

Coal Tar Pitches 65996-93-2 <20 *

Kaolin 1332-58-7 <10 *

Bentonite 1302-78-9 <10 *

*The exact percentage of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

Description of Necessary First-Aid Measures Eye Contact Rinse thoroughly with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician.

Skin Contact Wash off immediately with soap and plenty of water. In the case of skin irritation or allergic reactions, see a physician.

Inhalation Move to fresh air. If symptoms persist, call a physician.

Ingestion Drink plenty of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Consult a physician if necessary.

Most Important Symptoms/Effects, Acute and Delayed Most Important Symptoms/Effects No information available

Indication of Immediate Medical Attention and Special Treatment Needed, If Necessary Notes to Physician Treat Symptomatically. May cause sensitization by skin contact.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Carbon Dioxide (CO2). Dry Chemical. Foam. Water Fog.

Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient.

Specific Hazards Arising from the Chemical No information available

Explosion Data Sensitivity to Mechanical Impact None Sensitivity to Static Discharge None

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure- demand MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures Personal Precautions: Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personal protective equipment.

Environmental Precautions Environmental Precautions: See Section 12 for additional Ecological Information

Methods and Materials for Containment and Cleaning Up Methods for Containment: Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up: Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly

7. HANDLING AND STORAGE

Precautions for Safe Handling Handling: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes, and clothing. Wear personal protective equipment. Avoid breathing vapors or mists. Do not eat, drink, or smoke when using this product. Wash thoroughly after handling.

Conditions for Safe Storage, Including Any Incompatibilities Storage: Keep container tightly closed Incompatible Products: Strong oxidizing agents. Acids.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control Parameters Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Limestone 1317-65-3

TWA: 15 mg/m³ TWA: 5 mg/m³

(vacated) TWA: 15 mg/m³ (vacated) TWA: 5 mg/m³

TWA: 5 mg/m³ respirable dust

TWA 10 mg/m³ total dust

Asphalt 8052-42-4

TWA: 0.5 mg/m³ benzene soluble aerosol fume, inhalable fraction

Ceiling: 5 mg/m³ fume 15 min.

Coal Tar Pitches 65996-93-2

TWA: 0.2 mg/m³benzene soluble aerosol

TWA: 0.2 mg/m³benzene soluble fraction

(vacated) TWA: 0.2 mg/m³benzene soluble fraction

IDLH: 80 mg/m³ TWA: 0.1 mg/m³

Cyclohexane-extractable fraction

Kaolin 1332-58-7

TWA: 15 mg/m³ total dust TWA: 5 mg/m³ respirable fraction (vacated) TWA: 10 mg/m³ total dust (vacated) TWA 5 mg/m³ respirable fraction

TWA: 15 mg/m³ total dust TWA: 5 mg/m³ respirable dust

Bentonite 1302-78-9

TWA 1 mg/m³ respirable fraction

Appropriate Engineering Controls Engineering Measures: Showers Eyewash Stations Ventilation Systems

Individual Protection Measures, such as Personal Protective Equipment

Eye/Face Protection: If splashes are likely to occur, wear: Safety glasses with side shields.

Skin and Body Protection: Impervious gloves.

Respiratory Protection: No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn.

Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties Physical State: Liquid Appearance: Black Odor: Asphaltic/Coal Tar Odor Odor Threshold: No Information Available

Property Values Remarks/Method pH No data available None known Melting Point/Range No data available None known Boiling Point/Boiling Range 100° C None known Flash Point No data available None known Evaporation Rate No data available None known Flammability (solid, gas) No data available None known

Flammability Limits in Air Upper flammability limit No data available Lower flammability limit No data available Vapor Pressure No data available None known Vapor Density No data available None known Specific Density 1.20 @ 77 F None known Water Solubility Easily dispersible None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition Temperature No data available None known Decomposition Temperature No data available None known Viscosity No data available None known Flammable Properties Not Flammable Explosive Properties No data available Oxidizing Properties No data available VOC Content Less than 15 g/l

10. STABILITY AND REACTIVITY

Reactivity: No data available Chemical Stability: Stable under recommended storage conditions.

Possibility of Hazardous Reactions: None under normal processing.

Hazardous Polymerization: Hazardous polymerization does not occur.

Conditions to Avoid: Incompatible Products.

Incompatible Materials: Strong oxidizing agents. Acids.

Hazardous Decomposition Products: Carbon Oxides, Nitrogen Oxides (NOx), Sulfur Oxides

11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure Product Information Inhalation: May cause irritation of respiratory tract.

Eye Contact: Contact with eyes may cause irritation.

Skin Contact: May cause irritation.

Ingestion: Ingestion may cause stomach discomfort.

Chemical Name LD50 Oral LD50 Dermal LD50 Inhalation

Asphalt 5000 mg/kg (Rat) >2000 mg/kg (Rabbit) -

Bentonite >5000 mg/kg (Rat) - -

Symptoms Related to the Physical, Chemical, and Toxicological Characteristics Symptoms: No information available.

Delayed and Immediate Effects and also Chronic Effects from Short and Long Term Exposure

Sensitization: No information available.

Mutagenic Effects: No information available.

Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen.

The IARC, NTP, and OSHA do not list asphalt as a carcinogen. In general, the oxidation of polycyclic aromatic hydrocarbons destroys their carcinogenic potential. Petroleum asphalt, shale oil asphalts, and coal tars show distinct variation in their relative carcinogenicity for experimental animals.

Chemical Name ACGIH IARC NTP OSHA

Asphalt A3 Group 2B Reasonably Anticipated

X

Coal Tar Pitches A1 Group 1 Known X

ACGIH: (American Conference of Governmental Industrial Hygienists) A3 – Animal Carcinogen A1 – Known Human Carcinogen IRAC: (International Agency for Research on Cancer) Group 2B – Possibly Carcinogenic to Humans Group 1 – Carcinogenic to Humans NTP: (National Toxicity Program) Reasonably Anticipated – Reasonably Anticipated to be a Human Carcinogen Known – Known Carcinogen OSHA: (Occupational Safety & Health Administration) X – Present

Reproductive Toxicity: No information available.

STOT - Single Exposure: No information available.

STOT – Repeated Exposure: No information available.

Aspiration Hazard: No information available.

Numerical Measures of Toxicity – Product The following values are calculated based on Chapter 3.1 of the GHS document

LD50 Oral: 92162 mg/kg; Acute toxicity estimate LD50 Dermal 6181 mg/kg, Acute toxicity estimate

12. ECOLOGICAL INFORMATION

Ecotoxicity The environmental impact of this product has not been fully investigated.

Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to

Microorganisms Daphnia Magna

(Water Flea)

Bentonite 1302-78-9

LC50 96 h: 8.0-19.0 g/L (Salmo gairdneri)

LC50 96 h: = 19000 mg/L static (Oncorhynchus mykiss)

Persistence and Degradability: No information available.

Bioaccumulation

Chemical Name Log Pow

Asphalt 6..006

Coal Tar Pitches 6.04

Other Adverse Effects: No information available.

13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods: This material, as supplied, is not a hazardous waste according to Federal regulations (40

CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.

Contaminated Packaging: Do not re-use empty containers.

14. TRANSPORTATION INFORMATION

DOT: Not regulated

15. REGULATORY INFORMATION

International Inventories TSCA – Complies DSL/NDSL – Complies

Legend TSCA – United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List

U.S. Federal Regulations Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

Chemical Name CAS Number Weight % SARA 313 – Threshold

Values %

Asphalt 8052-42-4 20-40 0.1

SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific requirements at the local, regional, or state level pertaining to releases of this material.

U.S. State Regulations California Proposition 65: This product does not contain any Proposition 65 chemicals.

U.S. State Right-To-Know Regulations “X” designates that the ingredients are listed on the state right to know list.

Chemical Name New Jersey Massachusetts Pennsylvania Illinois Rhode Island

Limestone X X X X

Asphalt X X X X

Coal Tar Pitches X X X X

Kaolin X X X X

Carbon Black X X X X X

U.S. EPA Label Information EPA Pesticide Registration Number: Not applicable

16. OTHER INFORMATION

NFPA Health Hazard: 1 Flammability: 0 Instability: 0 Physical and Chemical Hazards- HMIS Health Hazard: 1* Flammability: 0 Physical Hazard: 0 Personal Protection: X *Indicates a chronic health hazard.

Revision Date: 30-Sept-2016 Revision Note: Supersedes 24-July-2015

General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.