H7 SOW Attachments A-G Combined.pdf

OLD PAINTING AREA

WITH DEFICIENCIES

1291410371N Highlight

#=CL#

July 09, 2021

LIMS USE: FR - JENNIFER KOTCH

LIMS OBJECT ID: 70178333

70178333 Project:

Pace Project No.:

RE:

Jennifer Kotch Stratton Air National Guard 1 Air National Guard Road Schenectady, NY 12302

METALS WIPE 6/24

Dear Jennifer Kotch:

Enclosed are the analytical results for sample(s) received by the laboratory on June 25, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.

The test results provided in this final report were generated by each of the following laboratories within the Pace Network:

• Pace Analytical Services - Melville

If you have any questions concerning this report, please feel free to contact me.

Sincerely, Lea Sherman lea.sherman@pacelabs.com

Project Manager (631)694-3040

Enclosures cc: Paige Dupont, Stratton Air National Guard

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747 (631)694-3040

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CERTIFICATIONS

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Pace Analytical Services Long Island 575 Broad Hollow Rd, Melville, NY 11747 Connecticut Certification #: PH-0435 Delaware Certification # NY 10478 Maryland Certification #: 208 Massachusetts Certification #: M-NY026 New Hampshire Certification #: 2987

New Jersey Certification #: NY158 New York Certification #: 10478 Primary Accrediting Body Pennsylvania Certification #: 68-00350 Rhode Island Certification #: LAO00340 Virginia Certification # 460302

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

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ANALYTICAL RESULTS

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Sample: DROP DOWN #1 Lab ID: 70178333001 Collected: 06/24/21 09:50 Received: 06/25/21 10:50 Matrix: Wipe

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: EPA 6010C Preparation Method: EPA 3050B Pace Analytical Services - Melville

6010 MET ICP, Wipe

Lead 6.1 Total ug/Sample 07/08/21 12:31 7439-92-107/07/21 10:180.25 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Sample: PAINT BOOTH EXHAUST #2

Lab ID: 70178333002 Collected: 06/24/21 09:50 Received: 06/25/21 10:50 Matrix: Wipe

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: EPA 6010C Preparation Method: EPA 3050B Pace Analytical Services - Melville

6010 MET ICP, Wipe

Lead 0.81 Total ug/Sample 07/08/21 12:34 7439-92-107/07/21 10:180.25 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Sample: PAINT BOOTH EXHAUST #2

Lab ID: 70178333003 Collected: 06/24/21 09:50 Received: 06/25/21 10:50 Matrix: Other

Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: EPA 6010C Preparation Method: EPA 3005A Leachate Method/Date: EPA 1311; 07/01/21 19:10 Pace Analytical Services - Melville

6010 MET ICP, TCLP

Arsenic <0.050 mg/L 07/07/21 16:33 7440-38-207/06/21 07:360.050 1 Barium <1.0 mg/L 07/07/21 16:33 7440-39-307/06/21 07:361.0 1 Cadmium 0.38 mg/L 07/07/21 16:33 7440-43-907/06/21 07:360.012 1 Chromium 6.5 mg/L 07/07/21 16:33 7440-47-307/06/21 07:360.050 1 Lead <0.025 mg/L 07/07/21 16:33 7439-92-107/06/21 07:360.025 1 Selenium <0.050 mg/L 07/07/21 16:33 7782-49-207/06/21 07:360.050 1 Silver <0.050 mg/L 07/07/21 16:33 7440-22-407/06/21 07:360.050 1

Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1311; 07/01/21 19:10 Pace Analytical Services - Melville

7470 Mercury, TCLP

Mercury <0.00020 mg/L 07/08/21 16:36 7439-97-607/07/21 16:390.00020 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Sample: EXHAUST AIR DUCT #3 Lab ID: 70178333004 Collected: 06/24/21 10:10 Received: 06/25/21 10:50 Matrix: Wipe

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: EPA 6010C Preparation Method: EPA 3050B Pace Analytical Services - Melville

6010 MET ICP, Wipe

Lead 15.0 Total ug/Sample 07/08/21 12:41 7439-92-107/07/21 10:180.25 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Sample: EXHAUST AIR DUCT #4 Lab ID: 70178333005 Collected: 06/24/21 10:20 Received: 06/25/21 10:50 Matrix: Wipe

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: EPA 6010C Preparation Method: EPA 3050B Pace Analytical Services - Melville

6010 MET ICP, Wipe

Lead 12.4 Total ug/Sample 07/08/21 12:43 7439-92-107/07/21 10:180.25 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

#=QC#

QUALITY CONTROL DATA

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

216512

EPA 7470A

EPA 7470A

7470 Mercury TCLP

Laboratory: Pace Analytical Services - Melville Associated Lab Samples: 70178333003

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 1090334

Associated Lab Samples: 70178333003

Matrix: Water

Analyzed

Mercury mg/L <0.00020 0.00020 07/08/21 16:32

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

1090335LABORATORY CONTROL SAMPLE:

LCSSpike

Mercury mg/L 0.000940.001 94 80-120

Parameter Units

MS

Result % Rec Limits Qualifiers% RecConc.

1090336MATRIX SPIKE SAMPLE:

MSSpike

Result 70178333003

Mercury mg/L 0.000900.001 90 75-125<0.00020

Parameter Units Dup

Result QualifiersRPDResult 70178333003

1090337SAMPLE DUPLICATE:

Mercury mg/L <0.00020<0.00020

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

216632

EPA 3050B

EPA 6010C

6010 MET Wipes

Laboratory: Pace Analytical Services - Melville Associated Lab Samples: 70178333001, 70178333002, 70178333004, 70178333005

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 1090937

Associated Lab Samples: 70178333001, 70178333002, 70178333004, 70178333005

Matrix: Wipe

Analyzed

Lead Total ug/Sample <0.25 0.25 07/08/21 12:27

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

1090938LABORATORY CONTROL SAMPLE:

LCSSpike

Lead Total ug/Sample 78.077.6 101 80-120

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

216452

EPA 3005A

EPA 6010C

6010 MET TCLP

Laboratory: Pace Analytical Services - Melville Associated Lab Samples: 70178333003

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 1089842

Associated Lab Samples: 70178333003

Matrix: Water

Analyzed

Arsenic mg/L <0.010 0.010 07/07/21 16:08 Barium mg/L <0.20 0.20 07/07/21 16:08 Cadmium mg/L <0.0025 0.0025 07/07/21 16:08 Chromium mg/L <0.010 0.010 07/07/21 16:08 Lead mg/L <0.0050 0.0050 07/07/21 16:08 Selenium mg/L <0.010 0.010 07/07/21 16:08 Silver mg/L <0.010 0.010 07/07/21 16:08

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 1087369

Associated Lab Samples: 70178333003

Matrix: Water

Analyzed

Arsenic mg/L <0.050 0.050 07/07/21 16:16 Barium mg/L <1.0 1.0 07/07/21 16:16 Cadmium mg/L <0.012 0.012 07/07/21 16:16 Chromium mg/L <0.050 0.050 07/07/21 16:16 Lead mg/L <0.025 0.025 07/07/21 16:16 Selenium mg/L <0.050 0.050 07/07/21 16:16 Silver mg/L <0.050 0.050 07/07/21 16:16

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

1089843LABORATORY CONTROL SAMPLE:

LCSSpike

Arsenic mg/L 0.490.5 98 80-120 Barium mg/L 0.490.5 98 80-120 Cadmium mg/L 0.490.5 99 80-120 Chromium mg/L 0.490.5 98 80-120 Lead mg/L 0.500.5 100 80-120 Selenium mg/L 0.490.5 98 80-120 Silver mg/L 0.250.25 100 80-120

Parameter Units

MS

Result % Rec Limits Qualifiers% RecConc.

1089845MATRIX SPIKE SAMPLE:

MSSpike

Result 30426808001

Arsenic mg/L 0.30 M10.4 74 75-125ND

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

MS

Result % Rec Limits Qualifiers% RecConc.

1089845MATRIX SPIKE SAMPLE:

MSSpike

Result 30426808001

Barium mg/L <1.00.4 82 75-125ND Cadmium mg/L 0.28 M10.4 70 75-125ND Chromium mg/L 0.21 M10.4 52 75-125ND Lead mg/L <0.025 M10.4 5 75-125ND Selenium mg/L 0.370.4 92 75-125ND Silver mg/L 0.190.2 93 75-125ND

Parameter Units Dup

Result QualifiersRPDResult 30426808001

1089844SAMPLE DUPLICATE:

Arsenic mg/L <0.050ND Barium mg/L <1.0ND Cadmium mg/L <0.012ND Chromium mg/L <0.050ND Lead mg/L <0.025ND Selenium mg/L <0.050ND Silver mg/L <0.050ND

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

#=QL#

QUALIFIERS

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.

ND - Not Detected at or above adjusted reporting limit.

TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.

MDL - Adjusted Method Detection Limit.

PQL - Practical Quantitation Limit.

RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix.

S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable.

SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

TNI - The NELAC Institute.

WORKORDER QUALIFIERS

WO: 70178333

6010 TCLP / 7470 TCLP-Volume received was not sufficient for method requirements. Per client request proceed with reduced volume.

[1]

ANALYTE QUALIFIERS

Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.:

Project:

70178333

METALS WIPE 6/24

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch

70178333001 216632 216817DROP DOWN #1 EPA 3050B EPA 6010C

70178333002 216632 216817PAINT BOOTH EXHAUST #2 EPA 3050B EPA 6010C

70178333004 216632 216817EXHAUST AIR DUCT #3 EPA 3050B EPA 6010C

70178333005 216632 216817EXHAUST AIR DUCT #4 EPA 3050B EPA 6010C

70178333003 216452 216481PAINT BOOTH EXHAUST #2 EPA 3005A EPA 6010C

70178333003 216512 216710PAINT BOOTH EXHAUST #2 EPA 7470A EPA 7470A

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/09/2021 10:58 AM

Pace Analytical Services, LLC 575 Broad Hollow Road

Melville, NY 11747

The only official copy is on-line at the SHSD website. https://www.bnl.gov/esh/shsd/sop/index_e.php Before using a printed copy, verify that it is current by checking the document issue date on the website.

BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals Date 06/23/17

IH75190

Surface Wipe Sampling for Metals

1.0 Purpose & Scope This document describes a field procedure for taking wipe samples for metals on surfaces. It is based on methodology described in NIOSH 9100 “Lead in Surface Wipe Samples” of the NIOSH Manual of Analytical Methods.

The goal of the procedure is to provide a uniform methodology to collect representative samples. Using this method will ensure repeatability between various sampling personnel and between surface configurations. It is used for characterizing surface levels for the following reasons:

o Decommissioning operational areas o Evaluating the effectiveness of clean-up of a spill o Evaluating compliance with housekeeping levels in operational areas o Characterizing a piece of equipment for release.

2.0 Responsibilities

2.1 Demonstrated Competency: This procedure is administered through persons who have demonstrated competency in performing this procedure in accordance with Section 7 are qualified to use this procedure.

2.2 Chain of Custody procedures: The qualified sampler is responsible for samples until they have been properly transferred to the IH Group laboratory using the IH51200 IH Laboratory Equipment & Sample Processing procedure.

2.3 Hazard Analysis of the Sampling Task: It is the responsibility of persons using this method and their supervisors to:

• Use appropriate personal protective equipment; see section 5.3.

• Obtain required training and qualification for hazards in areas.

• Comply with all work planning and work permit system requirements.

3.0 Definitions

Surface Wipe- a technique for the determination of metal on surfaces conducted by wiping the loose dust from the surface with a cloth/paper media and analysis of the metal on the media by laboratory or XRF measurement.

Definitions associated with surface wipe criteria are cited in Attachment 9.3

4.0 Prerequisites

Area Access:

4.1 Training for hazards may be needed for entry into areas with hazards, such as radiological areas..

The only official copy is on-line at the SHSD website.

Before using a printed copy, verify that it is current by checking the document issue date on the website.

BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals Date 06/23/17

4.2 Contact the appropriate Facility Support Representative or Technician to obtain approval to enter radiological areas.

4.3 Review and sign the Work Permit or Radiological Work Permit if needed.

4.4 Use appropriate PPE for area.

5.0 Precautions

5.1 Hazard assessment: Taking surface wipe samples may cause some exposure to health risks.

Sampling may be performed in areas with metal, chemical or radiological contamination. These hazards must be assessed on a case-by-case basis by a competent individual knowledgeable of the hazards of the area.

5.2 Job Risk Assessment: Consult the Job Risk Assessment SHSD-JRA-05 for the risk analysis of this operation based on the hazards and controls of this SOP.

5.3 Personal Protective Equipment: Use appropriate personal protective equipment when implementing this procedure.

• Hand: Use gloves in areas of known or suspected metal, chemical or radiological contamination.

Exam-style, splash gloves are acceptable. Acceptable polymers are: Nitrile, PVC, and Natural Rubber. The gloves must have sufficient impermeability to the surface contaminant and solvent used on the collection media to allow safe handling. See Table 1.

• Body: Use a disposable suit if contact of the body with contaminated surfaces is anticipated.

Acceptable chemical protective equipment materials include: Tyvek®, KleenGuard®, and cotton.

Contact the ECR for disposable of garments. If personal clothing items become contaminated, they must be surrender for BNL cleaning or disposal.

• Foot: Use disposable shoe coverings, boots or booties if contact of the feet with contaminated surfaces is anticipated. Acceptable material include: Tyvek®, KleenGuard®, and rubber. If personal shoes become contaminated, they must be surrendered for BNL cleaning or disposal.

• Respiratory: Under normal use, respiratory protection is not required. Use a respirator in an area with the potential to exceed the OSHA, ACGIH, or DOE standards. The person collecting using respiratory protection must comply with the BNL Respiratory Protection Program.

• Eye: Use safety glasses with side shields in laboratories, construction, and general industry areas.

5.4 Radioactive Concerns: It is possible that some surfaces to be tested may have radioactive contamination. In these cases, personal protective equipment and administrative controls must be implemented for the radiological contaminant hazard.

In addition, the collected sample must be analyzed for the radiological hazard before it can be submitted to the IH Group for analysis. The radiological contamination must be below the permissible release limits to the general public.

5.5 Work Planning: All requirements of work permits and work planning system reviews must be met in performing this procedure.

5.6 Personal Hygiene: Remove PPE and wash hands after sampling and before eating or drinking.

http://www.bnl.gov/esh/shsd/OHSAS/WordDocs/ESHQ/SHSD/SHSD_JRAs/JRA_05_IH_sampling%20.doc

Before using a printed copy, verify that it is current by checking the document issue date on the website.

BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

5.7 Environmental Impact and Waste Disposal: This technique does not have adverse impact on the environment. Based on WMD testing of similar PPE material, the templates and gloves can be disposed as normal trash. See Attachment 9.4.

6.0 Procedure

6.1 Equipment

Sample container (either):

Bag, plastic, sealable with “zip” type seal.

Vial, glass or plastic. (Glass is needed for hexane solvents based samples).

Sample media (any of these):

Gauze: 2” x 2” or 4” x 4” cotton gauze Paper: Ashless quantitative filter paper (typical diameter is 1.5 to 4 inches) Pre-moistened wipe: manufacturer foil wrapped, solvent soaked disposable cloths (such as GhostWipes or LeadWipe

• The type of wipe is dependent on the lab to be used. Check with the lab for appropriate media for the metals to be analyzed.

• For multiple metals, check with the lab to ensure they can all be done on a single wipe

Gloves Appropriate for contaminant and solvent (see Table 1) and site hazards.

Solvent Distilled water, Isopropanol, ethanol, methanol, n-hexane, or pre-moistened. See Table 1 for recommended solvent for each contaminant.

Template Plastic sheet or cardboard: See Table 1 for size needed

• 100cm2: 10 cm x 10 cm square –or- circle of 11.24 cm diameter.

• 1ft2: 1foot x 1 foot, or other shape totaling 144 in2.

6.2. Wipe Technique: BNL SHSD IH Group has selected the NIOSH method of collecting wipe samples. For uniformity, this method should be used for all sampling surface to be sampled (Visually depicted in Figure A)

Figure A: NIOSH Surface Wipe Method

6.2.1 Use a moistened sample media or pre-moistened wipe (e.g. GhostWipe™). Apply only enough solvent to moisten approximately 80% of the area of the media. Avoid excess

Before using a printed copy, verify that it is current by checking the document issue date on the website.

BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals solvent on the filter or pad as it may cause drips and running on the surface thus diluting the sample.

Table 1 Contaminant Media(1) Solvent(2) PPE Glove(2)

Disposable Style Sample Size

Lead Gauze or Filter 1 -2 ml Distilled Water Natural Latex Rubber, Nitrile, PVC, or Polyethylene

1 square foot, 100 cm2 requires advanced approval by IH professional verifying that sensitivity is adequate

Pre-moistened Wipe (should be cut in half) (3) n/a

Beryllium Gauze or Filter 1 - 2 ml Distilled Water Isopropanol, Methanol, Ethanol

Natural Latex Rubber, Nitrile, PVC, or Polyethylene

1 square foot minimum needed always

Pre-moistened Wipe (should be cut in half) (4) n/a

Arsenic, Cadmium

Gauze or Filter 1-2 ml of Distilled Water Natural Latex Rubber, Nitrile, PVC, or Polyethylene

100 cm2 typically acceptable Pre-moistened Wipe (should be cut in half) (4) n/a

Hexavalent Chromium

Preferred Medias:

See Attachment 9.2

None: For chrome plating operations, see stabilizing solution in Attachment 9.2.

Powderless:

Natural Latex Rubber, Nitrile, PVC, or Polyethylene

100 cm2 typically acceptable

Notes for Table 1:

(1) Some pre-moistened media may not be compatible is certain laboratory analytical equipment. Check with the laboratory analyzing the samples prior to sampling to ensure the brand of media is compatible.

(2) Solvent: The solvent is not critical for lead, beryllium, and most heavy metals such as cadmium, nickel, and chromium. In doing wipes for these compounds, it is allowable to choose the solvent that will have the least impact (residues) on the owner of the equipment being sampled (i.e. some equipment is sensitive to water residues and an alcohol or other solvent may be preferred by the equipment owner.)

(3) Selection criteria: Breakthrough time greater than 1 hour of continuous contact. Source of data is DOE Guidelines for the Selection of

Chemical Protective Clothing, 1991.

(4) The use of full size pre-moistened may cause the sample not to meet the minimum level of detection. To increase sensitivity, cut wipe in half to reduce the size of the wipe.

6.2.2 Place the template over the area to be sampled or measure out 1 ft2 or 100-cm2 surface area, as per Table 1. If the object has a total surface area of less than 1 ft2 or 100 cm2, sample the whole surface area, if possible, and record the surface area. If the surface does not allow the use of a template, carefully determine the dimensions that will equal 1 ft2 or 100 cm2.

6.2.3 Wipe the surface with firm pressure, using “S” strokes, covering the entire surface (edge to edge). If the surface is very rough (such as concrete), a dabbing action may be substituted for the full contact pressure rubbing of the media across the surface. When dabbing, make sure to completely cover the same area as in the S-stroke wipe. Indicate dabbing done on sample form.

Fold the exposed side of the pad or filter inward (i.e. fold in half).

6.2.4 Using the once-folded media, wipe the same area S-strokes (see Figure A), starting at right angles to the first wipe. Fold the exposed side of the pad or filter inward.

Before using a printed copy, verify that it is current by checking the document issue date on the website.

BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

6.2.5 Using the twice-folded media, wipe with S-strokes (see Figure A) starting at the original point and wipe in the same direction. Fold the exposed side of the pad or filter in.

6.2.6 Place the media in a plastic bag or vial. Seal the zip lock or vial. Record the sample identification on the bag or vial.

6.2.7 Thoroughly clean reusable templates or discard paper templates in preparation of the next sample. Based on WMD testing of similar material, templates can be disposed as normal trash.

6.2.8 Remove gloves by pulling them off inside-out and discard appropriately before handling the next filter or pad.

6.2.9 Record the sample identification, surface area sampled, and description of the sample and surface on the sample form (Attachment 9.5) in the electronic SHSD forms page Surface Wipe (Metals)- Field Sampling Records & Chain of Custody.

6.2.10 Include 1 blank filter or pad (moisten and placed in bags or vials) with each set of samples

(provide 1 blank per 6 samples).

6.3 Surface Wipe Technique for Hexavalent Chromium: see Attachment 9.2.

6.4 Determine HOW MANY samples to take. It is not possible to provide definitive guidance on the number of samples to be taken in every case. Table 2 provides general guidance on which to base professional judgment determining the number of samples. Factors that should be considered in selecting the number of samples include: the size of the area to be tested, the predicted uniformity of contamination over the surface area, and the eventual fate of the surface area (disposal, remediation, background measurement, etc.)

If more than six (6) samples are to be taken, it is suggested that at least one (1) duplicate sample be taken in close proximity to one other to verify the precision (repeatability) of the sampling.

Table 2: Statistical sampling plan Surface Configuration Minimum Number of

Samples Qualifier

Entire Surface is less than 100 cm2 (example: a small article) 1 If possible, sample the whole item, one sample is usually sufficient.

Surface Area of object or area is greater than 100 cm2 but only a few square feet (example: table top on which a process is done)

1 If only one sample is taken, select the area with highest potential contamination

Surface Area of object or area is greater than a few square feet (example: floor or wall of a room)

1 - 3 Ideally three samples are taken, but fewer samples may be taken depending on the purpose for sampling https://intranet.bnl.gov/esh/shsd/sop/IH_SOPs/e_Forms_C_of_C/index_e_Forms.php

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BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

Table 2: Statistical sampling plan Surface Configuration Minimum Number of

Samples Qualifier

Multiple surfaces in a large area with the same exposure potential to source (example, many rooms in a building with a common source such as the HVAC system)

1 – 3 for each surface, 6 or more for the whole area

Assumes all the surfaces have similar exposure potential, else treat each area separately.

6.5 Determine WHAT KIND of samples (LOCATION). Consider these locations when characterizing levels of surface metals:

- surfaces that are frequently accessed,

- surfaces that hazardous metal object rest on,

- surfaces that are infrequently cleaned or disturbed (such as top of cabinets or high shelves)

- sources of the contamination (such as process equipment, lab apparatus, site of known spills),

- areas where contamination is not expected (these serve as a control), and

- areas where contamination would not be permissible (such as lunch rooms).

6.6 Results interpretation: Normalize the units of sampling results from the laboratory to the base units of the Surface Level Criteria Requirements & Recommendations listed in Attachment 9.3.

Conversion of data between various laboratory reporting units of measures: Data can be converted from the various regulatory reporting and laboratory reporting units of measure based on the following values: 1 sq.ft. = 929 cm2 1 mg = 1000 ug

Convert form: Multiply by ug/100 cm2 to ug/sq. ft 9.29 ug/sq. ft to ug/100 cm2 0.1076

6.7 Posting equipment or areas: Consult with Attachment 9.1 for recommended wording to be used for labelling equipment or areas when a warning is needed for toxic metal hazards.

6.8 Reporting results: Convey the assessment of results to the requestor of the sampling, in a written analysis documenting: sampling and analysis methods, contamination levels measured, compliance with regulatory and recommended levels, and recommended corrective actions (if necessary).

7.0 Implementation and Training

Qualification Criteria: Use of this SOP is limited to persons who have demonstrated the competency to satisfactorily use the procedure, as evidenced by experience and training. All persons must have demonstrated competency in the qualification criteria set in the Job Performance Measure (Attachment 9.6.) or e-Exam IH75190. Qualification on this JPM is required on a 3 year basis.

8.0 References

8.1 ACGIH: Threshold Limit Values 2005

8.2 DOE: 10CFR 850 Chronic Beryllium Disease Prevention Program

8.3 EPA: Toxic Substance Control Act (TSCA) 40CFR745.227

https://intranet.bnl.gov/esh/shsd/sop/

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BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

8.4 Ness, S.A.; Surface and Dermal Monitoring for Toxic Exposures, Van Nostrand Reinhold, 1994.

8.5 NIOSH: Manual of Analytical Method, Method 9100: Lead in Surface Wipe Samples.

8.6 OSHA: 29CFR1910.1000 Table Z1, Z2; and 1910.1027.

8.7 OSHA: Technical Manual Section II, Chapter 2.

9.0 Attachments

9.1 Sample of Signs for Areas and Equipment

9.2 Wipe Sampling Technique for Hexavalent Chromium

9.3 Surface Wipe Criteria Requirements & Recommendations

9.4 Environmental Evaluation of Surface Wipe Sampling

9.5 Sample of Surface Contamination Sampling Form

9.6 SHSD Job Performance Measure (JPM) Completion Certificate

10.0 Procedure Documentation

ISM Review - Hazard Categorization: High; Moderate; Low/Skill of the craft

Validation: Formal Walkthrough Desk Top Review SME Review

Re Revision Log

0 New document. Prepared By R. Selvey, CIH 02/25/2000; Technical Reviewed By: N. Bernholc, CIH 02/27/00; RCD Facility Support Approved By: 04/22/01 N. Foster Procedure Committee Review; QA Review : E. Tucker; SHSD Approved By: R. Selvey 03/02/2000

1 Revised for minor correction noted in training classes. Reviewed By: R. Selvey 10/6/00

2 Added new format, SBMS header and reviewed sections on Hazard assessment, PPE. Added Waste Disposal and Environmental Impact text.

Reviewed By: R. Selvey 02/05/01

3 Minor format change. Converted SOP number from IH-FP-3.2 to new system IH75190. Reviewed By: R. Selvey 03/09/01 4 Revised to include RCD Facility Support Procedure Committee Review comments. Reviewed By: R. Selvey 04/22/01

5 Updated Table 1 adding Arsenic and Cadmium Media. Update Table 3 with Arsenic and Cadmium Release Criteria and update EPA Lead Criteria. Reviewed By: R. Selvey 04/10/02

6 Updated Table 1 to correct error in lead criteria. Insert Section 7 and transfer information from section 4. Renumbered attachments. Reviewed By: R. Selvey 4/17/02

7 Added Best Management Practice release criteria for Arsenic and Cadmium to Table 3. Reviewed By R. Selvey 08/16/02:

8 Added Best Management Practice release criteria for Nickel to Table 3. Reviewed By: R. Selvey 10/17/02

9 Full review of SOP. Significant text changes. Deleted OSHA Method for procedure & PCB criteria. Updated Attachments 9.1 and 9.2. Added Attachment 9.3. Reviewed By: R. Selvey 05/21/04

Added reference and link to JRA-05 in 5.1. Added text to 6.2.2 to clarify using Table 1 to determine 100cm2 versus 1 sq ft. Changed “S-stroke” wording in 6.2.3.through 6.2.5 to avoid confusion with the S-stroke used the Health Physics terminology. The two patterns are different.

Changed the qualification criteria in Section 7 to reflect the unified qualification policy. Updated the Sample form (Attachment 9.1) to reflect the Compliance Suite order of sample numbering. Reviewed By: R. Selvey 02/21/06

Reworded the “S-stroke” wording in 6.2.3.through 6.2.5 to avoid confusion with the S-stroke used the Health Physics terminology. Passage on “dabbing” was modified to indicate that the dabbing action replacing pulling the media, but does not replace the S-pattern. Minor typo corrections in Section 5 and 6. Reviewed By: R. Selvey 02/21/06

Section 6.3 was added with a reference to new Attachment 9.4; Table 1: was updated to include hexavalent chromium. Attachment 9.4 was added to include Liberty Mutual Wipe Sample Method. Liberty Mutual method was added. Section 8 References and Attachment 9.4 was added and included in Section 9.0 Attachments. Reviewed By: J. Peters 11/28/06; Reviewed By: R. Selvey 12/05/06

13 Added Section 4.1, 4.2 and 5.6. Revised 5.2. Added document control to attachment 9.3 and 9.4. Reviewed By: R. Selvey 05/23/07

14 Table 3: Updated to include Cobalt and description of calculation. Changed IH training link in Step 7.1.

Reviewed By: M.Chuc 09/22/08 Reviewed By: R. Selvey 10/13/08

15 Added Attachment 9.5. Reviewed By: R. Selvey 02/09/09

16 Edited section 4.0 and 5.2 for brevity. Added definition for Release and Housekeeping Criteria. Changed Cr6 release level based on OSHA recommendation. Added ANSI Caution to Attachment 9.1 sign. Revised directions in Attachment 9.2. Reviewed By: R. Selvey 03/21/11

17 Full review of steps 1 to 7. Expanded and revised Release and Housekeeping Criteria definitions in Section 3 and in Table3. Reviewed By: R.

Selvey 04/27/11

18 Corrected error in units in section 3: mg/100cm2 to ug/100 cm2. Reviewed By: R. Selvey 05/10/11 19 Edited Section s 2 and 7 to remove reference to rescinded HP65100. Changed format of Section 9. Reviewer: R. Selvey 03/04/14

Total review and revision. Replaced Table 3 with Appendix 9.3 and added OSHA Technical Manual ratio. Removed criteria for Al, Ba, Co, Cu, Hf, In, Mn, Mo, Pt, Rh, Se, Ag, Ta, Te, Tl, Sn, W, Y, Yt, and Zr. Added link to e-Exam and e-form. Added short-life disclaimer to Cr6 in Attachment 9.2. Revised by: R. Selvey 06/13/8/16

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BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

21 Revised Attachment 9.3 to correct Cr+6. Added column for ug/sq ft. Corrected error in Table 1 Attachment 3. Revised by; R. Selvey 09/13/16.

22 Revised Attachment 9.3 to remove no-regulated Nickel and CrIII and adjusted values for Arsenic and CrVI to match OSHA Housekeeping philosophy. Added proposed changes for all release criteria to allow comments on impact. Revised by; R. Selvey 05/01/17.

23 Team reviewed revision to Attachment 9.3. Values aligned with OSHA, EPA/HUD and DOE policies. Approved by: R. Selvey 06/23/17

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BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

Attachment 9.1

Samples of Signs for Areas and Equipment

CAUTION

Cadmium Surface Contamination

Some surfaces in this area have Cadmium levels above BNL Guidelines o Do NOT perform operations that causes the dust to become airborne (such as using an air hose to clean surfaces or dry sweeping) o Contact SHSD IH Group x-7475 prior to Building Renovations or Demolition o Wash hands prior to eating, drinking, chewing gum, or smoking o Do not eat or drink in this area.

CCLLEEAANN

The material on this pallet is below (i.e. cleaner than) the SHSD Best Management Practice Surface Release Guidelines for Lead and Cadmium

It is appropriate to be released and used anywhere at BNL without any specific precautions.

EExxcceeeeddss GGuuiiddeelliinneess ffoorr LLeeaadd oorr CCaaddmmiiuumm

The material on this pallet is above (i.e. not cleaner than) the

SHSD Best Management Practice Surface Release Guidelines for Lead and/or Cadmium

Specific precautions are needed in areas where this material is used or stored.

No operations that cause airborne dust (such as air hoses, blowers, or dry sweeping) Wash hands prior to eating, drinking, chewing gums, or smoking.

Do not eat or drink in this area.

Notify occupants of the area of the presence of Lead/Cadmium on these surfaces.

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BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

Attachment 9.2

WIPE SAMPLING TECHNIQUE FOR HEXAVALENT CHROMIUM

Note: Hexavalent Chromium has a short life on surfaces. Sampling and analyzed needs to be completed within a few days of generation. For sampling of long term dust accumulations, use Cr3 sampling.

Materials supplied by the lab:

Sampling media:

• For chrome plating: PVC or binderless quartz filter. All other operations:

- 5 um, 37-mm PVC filter for smooth surfaces

- 0.45 mm thick 37-or 47-mm binderless quartz fiber filter for rough surfaces (preferred media for both smooth and rough surfaces)

• Immediately after sampling, place the filter sample in a vial containing 10% Na2CO3 with 2% NaHCO3 to stabilize the

Cr+6.

• Do not use Ghost wipe®, Whatman, mixed cellulose ester (MCE) or glass fiber filter as they convert Cr+6 to Cr+3.

Template (10 cm x 10 cm) Teflon coated or plastic tweezers Empty glass vials Glass vials containing 5 ml aqueous solution of 10% Na2CO3 with 2% NaHCO3 for chrome plating samples Powderless gloves

Sampling Technique:

1. Prepare a sufficient number of vials, each labeled with a unique number.

2. Sketch a diagram of the room or area to be sampled.

3. Wear a new pair of clean gloves for each sample. DO NOT use powdered gloves.

4. Record the sample vial number and location where the sample is taken.

5. Remove the filter from the carrying container with a clean PTFE-coated tweezers or plastic tweezers. DO NOT use metal tweezers to handle the filters, as they could deposit Cr+6 onto the filters.

Note: Surfaces should not be wetted with water as the water will allow any metal interference to interact with Cr+6 thereby affecting the results.

6. Use firm pressure when wiping the surface. Start at the one corner moving to the opposite side then upward one wipe width and wipe back to the starting side. Repeat to cover the whole surface area. Fold inward and repeat wiping the entire surface again. Fold in and repeat a third time.

7. After wiping, fold the filter with the contaminant side inward. Place the filter immediately in the sample vial and cap.

Filter samples taken in chrome plating operation must be placed in a vial containing 10% Na2CO3 with 2% NaHCO3 to stabilize the Cr+6.

8. Submit at least one blank wipe filter, treated in the same fashion, but without wiping.

9. Sample results will be reported as ug/100cm2. OSHA’s target concentration is 0.050ug/100 cm2.

10. Ship samples immediately. If unable to ship immediately, keep cold then ship next day air to the lab.

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BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

Attachment 9.3

Required and Recommended Surface Wipe Criteria 06/26/17

Compound Criteria Criteria type

R = Requirement; G= Guidance, Recommended, Non-regulatory

OSHA PEL

ug/m3 ug/100cm2 ug/ft2

Arsenic (As)

29CFR1910.1018

100 929 G OSHA Regulated Areas [AFAP] & Operational Areas: Floors & accessible surfaces 10 ug/m3

6.7 62 G Non-Operational Areas: Floors & accessible surfaces

Beryllium (Be)

10CFR850

3.0 28 R DOE Regulated Areas & Be Operational Areas: Floors & accessible surfaces [Housekeeping]

2 ug/m3

0.2 1.9 G Non-Operational Areas & Public Areas: Floors & accessible surfaces

3.0 28 R Equipment Release to Be Operational Areas

0.2 1.9 R Equipment Release to Non-beryllium Area of a DOE facility & Public

Cadmium (Cd)

29CFR1910.1027

50 465 G OSHA Regulated Areas [AFAP] & Operational Areas: Floors & accessible surfaces

5 ug/m3 [.1027] 200 ug/m3 [Z.2] 3.3 31 G Non-Operational Areas: Floors & accessible surfaces

Chromium, hexavalent (Cr) VI

29CFR1910.1026

50 465 G OSHA Regulated Areas [AFAP] & Operational Areas: Floors & accessible surfaces

5 ug/m3

3.3 31 G Non-Operational Areas: Floors & accessible surfaces

Lead (Pb)

29CFR1910.1025

500 4645 G Accelerator Operational Areas & OSHA Regulated Areas [AFAP]:

Floors & accessible surfaces

50 ug/m3

50 465 G Laboratory Operational Areas: Floors & accessible surfaces

22 200 G Non-Operational Areas: Floors & accessible surfaces

22 200 G OSHA 1926.62 Construction Sites: change areas, storage facilities, & lunchrooms [Housekeeping]

4.3 40 G Eating & food prep surfaces

43 400 G Public/Lodging/Childcare- Window troughs

27 250 G Public/Lodging/Childcare- Window sills

4.3 40 G Public/Lodging/Childcare- Floors, Eating & food prep surfaces

Acrylonitrile 29CFR1910.1045 43 400 G OSHA Regulated Areas [AFAP] & Operational Areas: Floors & accessible surfaces [2 ppm]

4.3 ug/m3

Dibromodicloro-propane 29CFR1910.1044 1.0 9.3 G OSHA Regulated Areas [AFAP] & Operational Areas: Floors & accessible surfaces [1 ppb]

0.01 ug/m3

Methylenedianiline 29CFR1910.1050 0.8 7.5 G OSHA Regulated Areas [AFAP] & Operational Areas: Floors & accessible surfaces [10 ppb]

0.08 ug/m3

Definition (for purposes of the table above):

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BROOKHAVEN NATIONAL LABORATORY

Safety & Health Services Division - Industrial Hygiene Group

Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

AFAP: As Free As Practicable; Housekeeping- All surfaces shall be maintained as free as practicable of accumulations of [OSHA Regulated Substances]: Arsenic:

1910.1018(k); Cadmium: 1910.1027(k); Chromium: 1910.1026(j); Lead: 1910.1025(h); Acrylonitrile: 1910.1045(k) DBCP: 1910.1044(k); MDA: 1910.1050(l).

The enumerated guidance criteria level is based on: OSHA Technical Manual; Section II: Chapter 2 Surface Contaminants, Skin Exposure, Biological Monitoring and Other Analyses; III. Wipe Sampling, Field Portable X-Ray Fluorescence Sampling, Dermal Sampling and Biological Monitoring; A. Surface Wipe Sampling.

Accessible surfaces: Surfaces that can reasonably be expected to be contacted during typical operations. This would include table tops, desks tops, and other surfaces where contact with hands, arms and body are likely. [BNL]

Eating & Food Prep Surfaces = Surfaces on which food preparation, eating & drinking are done. This includes lunchroom counters/tables; kitchen counter tops, stove tops; water cooler surfaces; and tables/desks in offices/conference rooms where food and beverage consumption is permitted. [BNL]

Equipment Release to Operational Area [Beryllium] = Maximum removable contamination on equipment that is being released to a facility using the beryllium.

Equipment must be labeled and sealed in impermeable bag or container. [DOE 10CFR850.31]

Equipment Release to Operational Area [OSHA Regulated Substance] = Maximum removable contamination on equipment that is being released to a facility using the regulated substance. [BNL]

Equipment Release to Non-Operational Area or Public [Beryllium] = Maximum removable contamination on equipment that is being released to the general public or to a non-beryllium area of a DOE facility. Equipment release is conditioned on the recipient's commitment to implement controls that will prevent foreseeable beryllium exposure, considering the nature of the equipment or item and its future use and the nature of the beryllium contamination. [DOE 10CFR850.31]

Equipment Release to Non-Operational Area or Public [OSHA Regulated Substance] = Maximum removable contamination on equipment that is being released to the general public or to a Non-Operational Area. [BNL]

Housekeeping = Maximum level allowed on accessible surfaces in Operational Areas during Non-Operational periods. Surfaces contaminated with dusts and waste must not exceed a removable contamination level criterion during Non-Operational periods. This sampling would not include the interior of installed closed systems such as enclosures, glove boxes, chambers, or ventilation systems. [DOE 10CFR850.30]

Non-Beryllium Area = Area where beryllium is not used in a DOE facility. [DOE 10CFR 850.31]

Non-Operational Area [Beryllium] = Area where beryllium is not used and where workers are not trained in hazards and controls. Personal hygiene control practices are not in place (hand washing is not expected on exiting the area) and eating & drinking are permitted. [BNL]

Non-Operational Area [OSHA Regulated Substance] = Area where an OSHA Regulated Substance is not used and where workers are not trained in hazards and controls. Personal hygiene control practices are not in place (hand washing is not expected on exiting the area) and eating & drinking are permitted. [BNL]

Operational Area [Beryllium] = Area where workers are routinely in the presence of beryllium as part of their work activity. [DOE 10CFR850.3]

Operational Area [OSHA Regulated Substance] = Area where workers are routinely in the presence of an OSHA Regulated Substance as part of their work activity.

Workers who handle the substance have been trained in hazards and controls. Substances are routinely used, handled or stored and personal hygiene control practices are in place (e.g. eating, drinking are prohibited in the area; hand washing is expected on exiting the area). Examples: lead shielding blocks, shops, and accelerator areas using organic and inorganic metallic compounds. [BNL]

OSHA Regulated Substance = A substance regulated in 29CFR1910.1003-1054 in the expanded health standards:

o Metals:

o Arsenic 29CFR1910.1018;

o Cadmium 29CFR1910.1027;

o Chromium, hexavalent 29CFR1910.1026;

o Lead 29CFR1910.1025 o Chemicals:

o Acrylonitrile 29CFR1910.1045;

o Benzene 29CFR1910.1028;

o Dibromodicloro- propane 29CFR1910.1044;

o Formaldehyde 29CFR1910.1048;

o Methylenedianiline 29CFR1910.1050;

o Methylene Chloride 29CFR1910.1052;

o OSHA 13 carcinogens = 4-Nitrobiphenyl, Chemical Abstracts Service Register Number (CAS No.) 92933; alpha-Naphthylamine, CAS No. 134327; methyl chloromethyl ether, CAS No. 107302; 3,3'-Dichlorobenzidine (and its salts) CAS No. 91941; bis-Chloromethyl ether, CAS No. 542881; beta- Naphthylamine, CAS No. 91598; Benzidine, CAS No. 92875; 4-Aminodiphenyl, CAS No. 92671; Ethyleneimine, CAS No. 151564; beta-Propiolactone, CAS No. 57578; 2-Acetylaminofluorene, CAS No. 53963; 4-Dimethylaminoazo-benzene, CAS No. 60117; and N-Nitrosodimethylamine, CAS No. 62759.

[OSHA]

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Standard Operating Procedure Number IH75190 Revision Rev23

Subject: Surface Wipe Sampling for Metals

Public = Persons who are not: DOE employees, BSA employees, contractors, sub-contractors, and persons with Student, Intern, User or Guest appointments. The public includes visitors and family members living in residence at Upton. They are not trained by BNL in hazards and controls of toxic substances. [BNL]

Public/ Lodging/Childcare Areas = Area open to the public for periods longer than short visits or tours or areas intended for frequent access by visitors and/or family members. Eating and drinking is allowed in public areas. Occupants are not trained in the hazards of the metal or control measures. Hand washing is not expected on exit of the area. Public areas include: Science Museum (935), Coin Laundry (363), Berkner Hall (388), Swimming Pool (462), Gymnasium (461), Brookhaven Center (30), Research Support Building (400), BNL Upton on-site housing: Cavendish (153), Compton (170), Curie (258), Fleming (180), Guest House (257), Danish House (388), Apartments, Efficiencies; and areas with high occupancy by children: Child Development Center (370), Recreation Hall (317), School House (373) [BNL]

Regulated Area [Beryllium] = Area demarcated by the responsible employer in which the airborne concentration of beryllium exceeds, or can reasonably be expected to exceed, the action…