Cee-Bee_A-292_SDS.pdf

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1 Identification

· Product identifier

· Trade name: Cee-Bee A-292

· Article number: 23007

· Application of the substance / the mixture paint stripper

· Details of the supplier of the safety data sheet

· Manufacturer/Supplier:

McGean-Rohco, Inc.

38521 Schoolcraft Road Livonia, MI 48150-1085

USA

msds.info@mcgean.com

· Information department: Environmental, Health, and Safety

· Emergency telephone number: Chemtrec: 800-424-9300 or 703-527-3887

2 Hazard(s) identification

· Classification of the substance or mixture d~� GHS08 Health hazard

Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Muta. 1B H340 May cause genetic defects.

Carc. 1A H350 May cause cancer.

Repr. 1 H360 May damage fertility or the unborn child.

STOT SE 1 H370 Causes damage to organs.

STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.

d~� GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2A H319 Causes serious eye irritation.

Skin Sens. 1 H317 May cause an allergic skin reaction.

Aquatic Acute 3 H402 Harmful to aquatic life.

Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.

· Label elements

· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

(Contd. on page 2) mailto:msds.info@mcgean.com

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· Hazard pictograms d~�

GHS07

d~�

GHS08

· Signal word Danger

· Hazard-determining components of labeling:

dichloromethane methanol toluene sodium dichromate, dihydrate

· Hazard statements H302 Harmful if swallowed.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

H340 May cause genetic defects.

H350 May cause cancer.

H360 May damage fertility or the unborn child.

H370 Causes damage to organs.

H373 May cause damage to organs through prolonged or repeated exposure.

H402 Harmful to aquatic life.

H412 Harmful to aquatic life with long lasting effects.

· Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P284 [In case of inadequate ventilation] wear respiratory protection.

P280 Wear protective gloves.

P280 Wear eye protection / face protection.

P273 Avoid release to the environment.

P264 Wash thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P272 Contaminated work clothing must not be allowed out of the workplace.

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P321 Specific treatment (see on this label).

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor.

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.

P363 Wash contaminated clothing before reuse.

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P304+P341 If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P314 Get medical advice/attention if you feel unwell.

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of water.

P362+P364 Take off contaminated clothing and wash it before reuse.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

· Other hazards

· Results of PBT and vPvB assessment

· PBT: Not applicable.

· vPvB: Not applicable.

3 Composition/information on ingredients

· Chemical characterization: Mixtures

· Description: Mixture of the substances listed below with nonhazardous additions.

· Dangerous components:

75-09-2 dichloromethane 85-100% 64-17-5 ethanol 5-<10% 67-56-1 methanol 3-5%

108-88-3 toluene 1.0-2.5% 68649-00-3 Isopropylamine Dodecylbenzene Sulfonate 1.0-2.5% 1336-21-6 ammonia 1.0-2.5%

10588-01-9 sodium dichromate anhydrate 0.25-<0.5% 7632-00-0 sodium nitrite 0.1-0.5%

4 First-aid measures

· Description of first aid measures

· General information:

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

· After inhalation:

Supply fresh air and to be sure call for a doctor.

In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.

· After eye contact: Rinse opened eye for several minutes under running water.

· After swallowing: Immediately call a doctor.

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· Information for doctor:

· Most important symptoms and effects, both acute and delayed No further relevant information available.

· Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Fire-fighting measures

· Extinguishing media

· Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

· Special hazards arising from the substance or mixture No further relevant information available.

· Advice for firefighters

· Protective equipment: Mouth respiratory protective device.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures Not required.

· Environmental precautions:

Do not allow product to reach sewage system or any water course.

Inform respective authorities in case of seepage into water course or sewage system.

Do not allow to enter sewers/ surface or ground water.

· Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Dispose contaminated material as waste according to item 13.

Ensure adequate ventilation.

· Reference to other sections See Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

7 Handling and storage

· Handling:

· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.

Open and handle receptacle with care.

Prevent formation of aerosols.

· Information about protection against explosions and fires: Keep respiratory protective device available.

· Conditions for safe storage, including any incompatibilities

· Storage:

· Requirements to be met by storerooms and receptacles: No special requirements.

· Information about storage in one common storage facility: Not required.

· Further information about storage conditions: Keep receptacle tightly sealed.

· Specific end use(s) No further relevant information available.

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8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.

· Control parameters

· Components with limit values that require monitoring at the workplace:

The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.

At this time, the other constituents have no known exposure limits.

75-09-2 dichloromethane PEL Short-term value: 125 ppm

Long-term value: 25 ppm see 29 CFR 1910.1052

REL See Pocket Guide App. A TLV Long-term value: 174 mg/m³, 50 ppm

BEI

64-17-5 ethanol PEL Long-term value: 1900 mg/m³, 1000 ppm REL Long-term value: 1900 mg/m³, 1000 ppm TLV Short-term value: 1880 mg/m³, 1000 ppm 67-56-1 methanol PEL Long-term value: 260 mg/m³, 200 ppm REL Short-term value: 325 mg/m³, 250 ppm

Long-term value: 260 mg/m³, 200 ppm Skin

TLV Short-term value: 328 mg/m³, 250 ppm Long-term value: 262 mg/m³, 200 ppm Skin; BEI

108-88-3 toluene PEL Long-term value: 200 ppm

Ceiling limit value: 300; 500* ppm *10-min peak per 8-hr shift

REL Short-term value: 560 mg/m³, 150 ppm Long-term value: 375 mg/m³, 100 ppm

TLV Long-term value: 75 mg/m³, 20 ppm

BEI

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7789-12-0 sodium dichromate, dihydrate PEL Long-term value: 0.005* mg/m³

Ceiling limit value: 0.1** mg/m³ *as Cr(VI) **as CrO3; see 29 CFR 1910.1026

REL Long-term value: 0.0002 mg/m³ as Cr; See Pocket Guide Apps. A and C

TLV Long-term value: 0.05 mg/m³ as Cr; BEI

· Ingredients with biological limit values:

75-09-2 dichloromethane BEI 0.3 mg/L

Medium: urine Time: end of shift Parameter: Dichloromethane (semi-quantitative)

67-56-1 methanol BEI 15 mg/L

Medium: urine Time: end of shift Parameter: Methanol (background, nonspecific)

108-88-3 toluene BEI 0.02 mg/L

Medium: blood Time: prior to last shift of workweek Parameter: Toluene

0.03 mg/L Medium: urine Time: end of shift Parameter: Toluene

0.3 mg/g creatinine Medium: urine Time: end of shift Parameter: o-Cresol with hydrolysis (background)

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7789-12-0 sodium dichromate, dihydrate BEI 25 µg/L

Medium: urine Time: end of shift at end of workweek Parameter: Total chromium (fume)

10 µg/L Medium: urine Time: increase during shift Parameter: Total chromium (fume)

· Additional information: The lists that were valid during the creation were used as basis.

· Exposure controls

· Personal protective equipment:

· General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing.

Wash hands before breaks and at the end of work.

Store protective clothing separately.

Avoid contact with the eyes and skin.

· Breathing equipment:

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.

· Protection of hands:

_S Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

· Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.

· Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

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· Eye protection:

Safety glasses

_R Tightly sealed goggles

9 Physical and chemical properties

· Information on basic physical and chemical properties

· General Information

· Appearance:

Form: Highly viscous Color: Light brown

· Odor: Ammonia-like

· Odor threshold: Not determined.

· pH-value: Not determined.

· Change in condition Melting point/Melting range: Undetermined.

Boiling point/Boiling range: 40 °C (104 °F)

· Flash point: Not applicable.

· Flammability (solid, gaseous): Not applicable.

· Ignition temperature: 425 °C (797 °F)

· Decomposition temperature: Not determined.

· Auto igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Explosion limits:

Lower: 13.0 Vol % Upper: 22.0 Vol %

· Vapor pressure at 20 °C (68 °F): 453 hPa (340 mm Hg)

· Density at 20 °C (68 °F): 1.19 g/cm³ (9.931 lbs/gal)

· Relative density Not determined.

· Vapor density Not determined.

· Evaporation rate Not determined.

· Solubility in / Miscibility with Water: Not miscible or difficult to mix.

· Partition coefficient (n-octanol/water): Not determined.

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· Viscosity:

Dynamic: Not determined.

Kinematic: Not determined.

· Solvent content:

Organic solvents: 90.0 % VOC content: 11.0 %

130.8 g/l / 1.09 lb/gl

Solids content: 17.6 %

· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity No further relevant information available.

· Chemical stability

· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.

· Possibility of hazardous reactions No dangerous reactions known.

· Conditions to avoid No further relevant information available.

· Incompatible materials: No further relevant information available.

· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information

· Information on toxicological effects

· Acute toxicity:

· LD/LC50 values that are relevant for classification:

75-09-2 dichloromethane Oral LD50 1600 mg/kg (rat) Inhalative LC50/4 h 88 mg/l (rat) 67-56-1 methanol Oral LD50 5628 mg/kg (rat) Dermal LD50 15800 mg/kg (rabbit)

· Primary irritant effect:

· on the skin: No irritant effect.

· on the eye: No irritating effect.

· Sensitization:

Sensitization possible through inhalation.

Sensitization possible through skin contact.

· Additional toxicological information:

The product shows the following dangers according to internally approved calculation methods for preparations:

Harmful

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Irritant Carcinogenic.

The product can cause inheritable damage.

· Carcinogenic categories

· IARC (International Agency for Research on Cancer)

75-09-2 dichloromethane 2B 108-88-3 toluene 3

10588-01-9 sodium dichromate anhydrate 1 108-10-1 methyl isobutyl ketone 2B 71-43-2 benzene 1

· NTP (National Toxicology Program) 75-09-2 dichloromethane R

10588-01-9 sodium dichromate anhydrate K 71-43-2 benzene K

· OSHA-Ca (Occupational Safety & Health Administration) 75-09-2 dichloromethane 71-43-2 benzene

12 Ecological information

· Toxicity

· Aquatic toxicity: No further relevant information available.

· Persistence and degradability No further relevant information available.

· Behavior in environmental systems:

· Bioaccumulative potential No further relevant information available.

· Mobility in soil No further relevant information available.

· Ecotoxical effects:

· Remark: Harmful to fish

· Additional ecological information:

· General notes:

Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system.

Danger to drinking water if even small quantities leak into the ground.

Harmful to aquatic organisms

· Results of PBT and vPvB assessment

· PBT: Not applicable.

· vPvB: Not applicable.

· Other adverse effects No further relevant information available.

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13 Disposal considerations

· Waste treatment methods

· Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

· Uncleaned packagings:

· Recommendation: Disposal must be made according to official regulations.

14 Transport information

· UN-Number

· DOT, IMDG, IATA UN2810

· UN proper shipping name

· DOT Toxic, liquids, organic, n.o.s. (Dichloromethane)

· IMDG, IATA TOXIC LIQUID, ORGANIC, N.O.S. (DICHLOROMETHANE)

· Transport hazard class(es)

· DOT

dc̀k|�

· Class 6.1 Toxic substances

· Label 6.1

· IMDG, IATA

dc̀k|

· Class 6.1 Toxic substances

· Label 6.1

· Packing group

· DOT, IMDG, IATA II

· Environmental hazards:

· Marine pollutant: No

· Special precautions for user Warning: Toxic substances

· Danger code (Kemler): 60

· EMS Number: F-A,S-A

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· Segregation groups Liquid halogenated hydrocarbons

· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.

· Transport/Additional information:

· DOT

· Quantity limitations On passenger aircraft/rail: 60 L

On cargo aircraft only: 220 L

· IMDG

· Limited quantities (LQ) 5L

· Excepted quantities (EQ) Code: E1

Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml

· UN "Model Regulation": UN2810, Toxic, liquids, organic, n.o.s. (Dichloromethane), 6.1, II

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture

· Sara

· Section 355 (extremely hazardous substances):

None of the ingredients is listed.

· Section 313 (Specific toxic chemical listings):

75-09-2 dichloromethane 67-56-1 methanol

108-88-3 toluene 1336-21-6 ammonia

10588-01-9 sodium dichromate anhydrate 7632-00-0 sodium nitrite 108-10-1 methyl isobutyl ketone 71-43-2 benzene

· TSCA (Toxic Substances Control Act):

All ingredients are listed.

· Proposition 65

· Chemicals known to cause cancer:

75-09-2 dichloromethane 10588-01-9 sodium dichromate anhydrate

108-10-1 methyl isobutyl ketone 71-43-2 benzene

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· Chemicals known to cause reproductive toxicity for females:

108-88-3 toluene

10588-01-9 sodium dichromate anhydrate

· Chemicals known to cause reproductive toxicity for males:

10588-01-9 sodium dichromate anhydrate

71-43-2 benzene

· Chemicals known to cause developmental toxicity:

64-17-5 ethanol 67-56-1 methanol

108-88-3 toluene 10588-01-9 sodium dichromate anhydrate

108-10-1 methyl isobutyl ketone 71-43-2 benzene

· Carcinogenic categories

· EPA (Environmental Protection Agency)

75-09-2 dichloromethane L 108-88-3 toluene II

10588-01-9 sodium dichromate anhydrate A(inh), D(oral), K/L(inh), CBD(oral) 108-10-1 methyl isobutyl ketone I 71-43-2 benzene A, K/L

· TLV (Threshold Limit Value established by ACGIH) 75-09-2 dichloromethane A3 64-17-5 ethanol A3

108-88-3 toluene A4 10588-01-9 sodium dichromate anhydrate A1

107-22-2 glyoxal A4 71-43-2 benzene A1

· NIOSH-Ca (National Institute for Occupational Safety and Health) 75-09-2 dichloromethane

10588-01-9 sodium dichromate anhydrate 71-43-2 benzene

· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

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· Hazard pictograms d~�

GHS07

d~�

GHS08

· Signal word Danger

· Hazard-determining components of labeling:

dichloromethane methanol toluene sodium dichromate, dihydrate

· Hazard statements H302 Harmful if swallowed.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

H340 May cause genetic defects.

H350 May cause cancer.

H360 May damage fertility or the unborn child.

H370 Causes damage to organs.

H373 May cause damage to organs through prolonged or repeated exposure.

H402 Harmful to aquatic life.

H412 Harmful to aquatic life with long lasting effects.

· Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P284 [In case of inadequate ventilation] wear respiratory protection.

P280 Wear protective gloves.

P280 Wear eye protection / face protection.

P273 Avoid release to the environment.

P264 Wash thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P272 Contaminated work clothing must not be allowed out of the workplace.

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P321 Specific treatment (see on this label).

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor.

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.

P363 Wash contaminated clothing before reuse.

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P304+P341 If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P314 Get medical advice/attention if you feel unwell.

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of water.

P362+P364 Take off contaminated clothing and wash it before reuse.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

· National regulations:

· Information about limitation of use:

Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.

Exceptions can be made by the authorities in certain cases.

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Department issuing SDS: Environment Health and Safety

· Contact: Darla Rivera

· Date of preparation / last revision 08/19/2016 / 6

· Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit BEI: Biological Exposure Limit Acute Tox. 4: Acute toxicity – Category 4 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A Resp. Sens. 1: Respiratory sensitisation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1

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Muta. 1B: Germ cell mutagenicity – Category 1B Carc. 1A: Carcinogenicity – Category 1A Repr. 1: Reproductive toxicity – Category 1 STOT SE 1: Specific target organ toxicity (single exposure) – Category 1 STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2 Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard – Category 3 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3