B&B_9095_SDS.pdf

Safety Data Sheet

B&B 9095

SDS Revision Date: 03/24/2016

1. Identification

1.1. Product identifier

Product Identity B&B 9095

Alternate Names B&B 9095

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use See Technical Data Sheet.

Application Method See Technical Data Sheet.

1.3. Details of the supplier of the safety data sheet

Company Name B&B Tritech Inc.

875 West 20th Street

Hialeah, Florida 33010

Emergency

CHEMTREC (USA) (800) 424-9300

Customer Service: B&B Tritech Inc. (305) 888-5247

2. Hazard(s) identification

2.1. Classification of the substance or mixture

Acute Tox. 4;H302 Harmful if swallowed.

Acute Tox. 5;H313 May be harmful in contact with skin. (Not adopted by US OSHA)

Acute Tox. 4;H332 Harmful if inhaled.

Skin Corr. 1A;H314 Causes severe skin burns and eye damage.

Eye Dam. 1;H318 Causes serious eye damage.

2.2. Label elements

Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.

Danger

H302 Harmful if swallowed.

H313 May be harmful in contact with skin.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H332 Harmful if inhaled.

[Prevention]:

P261 Avoid breathing dust / fume / gas / mist / vapors / spray.

P264 Wash thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves / eye protection / face protection.

[Response]:

P301+312 IF SWALLOWED: Call a POISON CENTER or doctor / physician if you feel unwell.

P303+361+353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin with water / shower.

P304+312 IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P310 Immediately call a POISON CENTER or doctor / physician.

P330 Rinse mouth.

P331 Do NOT induce vomiting.

P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P363 Wash contaminated clothing before reuse.

[Storage]:

P405 Store locked up.

[Disposal]:

P501 Dispose of contents / container in accordance with local / national regulations.

3. Composition/information on ingredients

This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations.

Ingredient/Chemical Designations Weight % GHS Classification Notes

Benzyl alcohol CAS Number: 0000100-51-6

25 - 50 Acute Tox. 4;H332 Acute Tox. 4;H302

[1]

Hydrogen peroxide CAS Number: 0007722-84-1

5 - <8 Skin Corr. 1B; H314: 50% ≤ C < 70% Skin Irrit. 2; H315: 35% ≤ C < 50% Eye Dam. 1; H318: 8% ≤ C < 50% Skin Corr. 1A; H314: C ≥ 70% Ox. Liq. 1; H271: C ≥ 70% Ox. Liq. 2; H272: 50% ≤ C < 70%

STOT SE 3; H335: C ≥ 35%

Eye Irrit. 2; H319: 5% ≤ C < 8%

[1][2]

Aromatic Hydrocarbon CAS Number: 0070693-06-0

1 - 5 Flam. Liq. 2;H225 Skin Irrit. 2;H315

[1]

In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.

[1] Substance classified with a health or environmental hazard.

[2] Substance with a workplace exposure limit.

[3] PBT-substance or vPvB-substance.

*The full texts of the phrases are shown in Section 16.

4. First aid measures

4.1. Description of first aid measures

General In all cases of doubt, or when symptoms persist, seek medical attention.

Never give anything by mouth to an unconscious person.

Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth.

Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention.

Skin Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin cleanser.

Ingestion If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.

4.2. Most important symptoms and effects, both acute and delayed

Overview No specific symptom data available.

See section 2 for further details.

Inhalation Harmful if inhaled.

Eyes Causes serious eye damage.

Skin May be harmful in contact with skin. (Not adopted by US OSHA) Causes severe skin burns and eye damage.

Ingestion Harmful if swallowed.

5. Fire-fighting measures

5.1. Extinguishing media

Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray.

Do not use: water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition: Thermal decomposition yields oxides of carbon and nitrogen.

Avoid breathing dust / fume / gas / mist / vapors / spray.

5.3. Advice for fire-fighters

Container may explode if heated.

In the event of fire, wear full protective clothing and NIOSH Approved Self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Move container from fire area if it can be done without risk. Use water to keep fire exposed containers cool and disperse vapors.

ERG Guide No. ----

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Put on appropriate personal protective equipment (see section 8).

6.2. Environmental precautions

Do not allow spills to enter drains or waterways.

Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.

6.3. Methods and material for containment and cleaning up

Contain spill. Scoop up into DOT approved vented plastic drums. Absorb remaining liquid with inert absorbant and place in DOT approved vented plastic drums.

7. Handling and storage

7.1. Precautions for safe handling

See section 2 for further details. - [Prevention]:

7.2. Conditions for safe storage, including any incompatibilities

Handle containers carefully to prevent damage and spillage.

Do not store near combustible material (for example, alcohols, ketones, hydrocarbons, esters). Do not mix with other chemicals. Store in a cool, dry place. Avoid excessive heat. Store out of direct sunlight in a cool well-ventilated area

Incompatible materials: Avoid reducing agents, combustibles, iron and other heavy metals, copper alloys and caustics.

Avoid contact with eyes, skin and clothing. Avoid breathing vapors. Keep container closed when not in use. Store in a cool area away from combustibles. Empty drums do contain residues.

See section 2 for further details. - [Storage]:

7.3. Specific end use(s)

No data available.

8. Exposure controls and personal protection

8.1. Control parameters

Exposure

CAS No. Ingredient Source Value

0000100-51-6 Benzyl alcohol OSHA No Established Limit

ACGIH No Established Limit

NIOSH No Established Limit

Supplier No Established Limit

0007722-84-1 Hydrogen peroxide OSHA TWA 1 ppm (1.4 mg/m3)

ACGIH TWA: 1 ppm

NIOSH TWA 1 ppm (1.4 mg/m3)

Supplier No Established Limit

0070693-06-0 Aromatic Hydrocarbon OSHA No Established Limit

ACGIH No Established Limit

NIOSH No Established Limit

Supplier No Established Limit

8.2. Exposure controls

Respiratory If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators.

Eyes Chemical splash goggles.

Skin Gloves, face shield, chemical resistant clothing, boots.

Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn.

Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.

See section 2 for further details. - [Prevention]:

9. Physical and chemical properties

Appearance Viscous White Emulsion

Odor Mild

Odor threshold Not determined pH 6.7 +/- 0.3

Melting point / freezing point Not Measured

Initial boiling point and boiling range 214F

Flash Point Not Measured

Evaporation rate (Ether = 1) Slower than ether

Flammability (solid, gas) Not Applicable

Upper/lower flammability or explosive limits Lower Explosive Limit: Not Measured

Upper Explosive Limit: Not Measured

Vapor pressure (Pa) VOC Vapor Pressure < 0.2 mmHg @ 20C VOC 484 gm/L

Vapor Density Not Measured

Specific Gravity 1.01

Solubility in Water Not Measured

Partition coefficient n-octanol/water (Log Kow) Not Measured

Auto-ignition temperature Not Measured

Decomposition temperature Not Measured

Viscosity (cSt) Not Measured

VOC Content 35%

9.2. Other information

No other relevant information.

10. Stability and reactivity

10.1. Reactivity

Hazardous Polymerization will not occur.

10.2. Chemical stability

Stable under normal circumstances.

10.3. Possibility of hazardous reactions

No data available.

10.4. Conditions to avoid

Avoid heat, open flames and prolonged storage at elevated temperatures.

10.5. Incompatible materials

Avoid reducing agents, combustibles, iron and other heavy metals, copper alloys and caustics.

10.6. Hazardous decomposition products

Thermal decomposition yields oxides of carbon and nitrogen.

11. Toxicological information

Acute toxicity

Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate).

Ingredient Oral LD50, mg/kg

Skin LD50, mg/kg

Inhalation Vapor LC50, mg/L/4hr

Inhalation Dust/Mist LC50, mg/L/4hr

Inhalation Gas LC50, ppm

Benzyl alcohol - (100-51-6) 1,230.00, Rat - Category: 4

2,000.00, Rabbit -

Category: 4

No data available

4.178, Rat - Category: 4

No data available

Hydrogen peroxide - (7722-84-1) 801.00, Rat - Category: 4

2,000.00, Rat - Category: 4

No data available

No data available

No data

Aromatic Hydrocarbon - (70693-06-0) No data available

No data available

No data

No data available

No data

Carcinogen Data

CAS No. Ingredient Source Value

0000100-51-6 Benzyl alcohol OSHA Select Carcinogen: No

NTP Known: No; Suspected: No

IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;

0007722-84-1 Hydrogen peroxide OSHA Select Carcinogen: No

NTP Known: No; Suspected: No

IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No;

0070693-06-0 Aromatic Hydrocarbon OSHA Select Carcinogen: No

NTP Known: No; Suspected: No

IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;

Classification Category Hazard Description

Acute toxicity (oral) 4 Harmful if swallowed.

Acute toxicity (dermal) 5 May be harmful in contact with skin. (Not adopted by

US OSHA)

Acute toxicity (inhalation) 4 Harmful if inhaled.

Skin corrosion/irritation 1A Causes severe skin burns and eye damage.

Serious eye damage/irritation 1 Causes serious eye damage.

Respiratory sensitization --- Not Applicable

Skin sensitization --- Not Applicable

Germ cell mutagenicity --- Not Applicable

Carcinogenicity --- Not Applicable

Reproductive toxicity --- Not Applicable

STOT-single exposure --- Not Applicable

STOT-repeated exposure --- Not Applicable

Aspiration hazard --- Not Applicable

12. Ecological information

12.1. Toxicity

Toxic to aquatic life

Aquatic Ecotoxicity

Ingredient 96 hr LC50 fish, mg/l 48 hr EC50 crustacea, mg/l ErC50 algae, mg/l

Benzyl alcohol - (100-51-6) 10.00, Lepomis macrochirus

55.00, Daphnia magna 700.00 (72 hr), Algae

Hydrogen peroxide - (7722-84-1) 22.00, Oncorhynchus mykiss

2.32, Daphnia magna 0.71 (72 hr), Microcystis pulverea ssp. incerta

Aromatic Hydrocarbon - (70693-06-0) Not Available Not Available Not Available

12.2. Persistence and degradability

There is no data available on the preparation itself.

12.3. Bioaccumulative potential

Not Measured

12.4. Mobility in soil

No data available.

12.5. Results of PBT and vPvB assessment

This product contains no PBT/vPvB chemicals.

12.6. Other adverse effects

No data available.

13. Disposal considerations

13.1. Waste treatment methods

Observe all federal, state and local regulations when disposing of this substance.

14. Transport information

DOT (Domestic Surface

Transportation) IMO / IMDG (Ocean Transportation)

ICAO/IATA

14.1. UN number Not Applicable Not Regulated Prohibited

14.2. UN proper shipping

name

Not Regulated Not Regulated Prohibited

14.3. Transport hazard

class(es)

DOT Hazard Class: Not Applicable

IMDG: Not Applicable Sub Class: Not Applicable

Air Class: Prohibited

14.4. Packing group Not Applicable Not Applicable Not Applicable

14.5. Environmental hazards

IMDG Marine Pollutant: No;

14.6. Special precautions for user

No further information

15. Regulatory information

Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented.

Toxic Substance Control Act ( TSCA)

All components of this material are either listed or exempt from listing on the TSCA Inventory.

WHMIS Classification D2B E

US EPA Tier II Hazards Fire: No

Sudden Release of Pressure: No

Reactive: No

Immediate (Acute): Yes

Delayed (Chronic): No

EPCRA 311/312 Chemicals and RQs:

To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.

EPCRA 302 Extremely Hazardous:

Hydrogen peroxide

EPCRA 313 Toxic Chemicals:

To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.

Proposition 65 - Carcinogens (>0.0%):

To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.

Proposition 65 - Developmental Toxins (>0.0%):

To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.

Proposition 65 - Female Repro Toxins (>0.0%):

To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.

Proposition 65 - Male Repro Toxins (>0.0%):

To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.

New Jersey RTK Substances (>1%):

Hydrogen peroxide

Pennsylvania RTK Substances (>1%):

Benzyl alcohol

Hydrogen peroxide

16. Other information

The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.

We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.

The full text of the phrases appearing in section 3 is:

H225 Highly flammable liquid and vapor.

H226 Flammable liquid and vapor.

H271 May cause fire or explosion; strong oxidizer.

H272 May intensify fire; oxidizer.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H314 Causes severe skin burns and eye damage.

H315 Causes skin irritation.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H332 Harmful if inhaled.

H335 May cause respiratory irritation.

H336 May cause drowsiness and dizziness.

The Information presented herein is based either upon data or opinion. To the best of our knowledge such data is true and accurate, although updated data may change earlier information thereby creating changes in available information. Therefore, this report is limited to the date hereof. Such opinion is believed to be expert, and therefore, generally, reliable, but in some instances there are conflicts in expert opinions and in those instances, we have relied upon the opinion which in our best judgment, appeared to be the most reasonable. All information herein is presented without guaranty or warranty and is merely intended to provide users with information as specified in this data sheet.

B&B TRITECH, INC. SPECIFICALLY DISCLAIMS ANY AND ALL IMPLIED WARRANTIES OF MERCHANTABILITY

OR FITNESS FOR A PARTICULAR PURPOSE OF THE PRODUCT DESCRIBED IN THE INFORMATION

CONTAINED HEREIN. B&B TRITECH. INC. FURTHER SPECIFICALLY DISCLAIMS ANY AND ALL

CONSEQUENTIAL DAMAGES INCLUDING INJURY 'TO PERSONS OR PROPERTY WHICH MAY ARISE

DIRECTLY OR INDIRECTLY OUT OF THE USE OF THIS PRODUCT. B&B TRITECH INCS SOLE OBLIGATION WITH REGARD TO THE INFORMATION HEREIN CONTAINED AND TO THE PROOUCT HEREIN DESCRIBED SHALL BE TO REPLACE THAT PORTION OF THE PRODUCT PROVEN TO BE DEFECTIVE. This information is not intended to be all inclusive and the manner and conditions of use and handling of the product described herein may involve other or additional considerations. Further, nothing contained herein should be construed or constitute a recommendation as to the use of a product for a specific purpose or otherwise. The data provided in this material safety data sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or process.

End of Document