This Project Grant award of $600,000 from the National Science Foundation's (NSF) Division of Chemistry was granted to Texas A&M University on July 15, 2025. The award supports fundamental research into the reactivity and applications of transition metal complexes containing boron-metal bonds, known as "boryl-centered pincer complexes." The key objectives of this 3-year project are to: Develop a deeper understanding of the unique reactivity and bond-forming/breaking mechanisms of...
This $600,000 Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences (CFDA 47.049) program will support research at the University of Michigan and Trinity University to investigate the structural and electronic properties of high-valent cobalt, nickel, and copper-oxo complexes. The project aims to improve understanding of how metal-oxo versus metal-oxyl character impacts the stability and reactivity of these unstable, yet potentially useful,...
This $575,000 Project Grant from the National Science Foundation's Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), will fund research at the University of California, San Diego to synthesize and study the reactivity of unusual main group elements stabilized by transition metal isocyanide complexes, from July 1, 2023 to June 30, 2026. Specifically, Professor Joshua S. Figueroa will manipulate boron monofluoride and diphosphorus molecules, which are...
The National Science Foundation Division of Chemistry awarded a $525,000 Project Grant to The Trustees of the University of Pennsylvania to support research into the activation and functionalization of volatile alkanes under mild conditions with earth-abundant base metals. The grant falls under the Mathematical and Physical Sciences program (CFDA 47.049), which aims to strengthen the nation's scientific enterprise through increased fundamental knowledge and understanding of major problems....
This Project Grant from the National Science Foundation Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), provides $550,000 to The Trustees of the University of Pennsylvania from July 1, 2023 to June 30, 2026. The award will support research at the University of Pennsylvania aimed at developing new base metal complexes capable of efficiently activating aliphatic C-H bonds through two complementary objectives. First, ligand scaffolds will be created to...
This $550,000 Project Grant from the National Science Foundation Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), supports research at Texas A&M University from August 1, 2022 to July 31, 2025. Professor François Gabbaï and his team will investigate the synthesis and coordination chemistry of novel ambiphilic ligands featuring a carbenium ion positioned next to a phosphine- or carbene-based metal-binding site. When coordinated to late transition...
The National Science Foundation Division of Chemistry awarded a three-year Project Grant totaling $600,000 to the Massachusetts Institute of Technology under the Mathematical and Physical Sciences federal grant program (CFDA 47.049). The grant supports research by Dr. Alexander Radosevich and his team to develop new metal-phosphorus complexes as homogeneous catalysts for small molecule conversion chemistry. Specifically, the grant funding will allow Dr. Radosevich's lab to pursue experiments...
This Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences Federal Grant Program (CFDA 47.049) is supporting research conducted by Professor Tim Jackson of the Department of Chemistry at the University of Kansas. The $479,856 award aims to develop new types of manganese and iron complexes that mimic intermediates in biological metal-dependent enzymes. The goal is to use these new complexes to improve proton-coupled electron-transfer reactions,...
This $520,000 three-year Project Grant from the National Science Foundation's (NSF) Mathematical and Physical Sciences program (CFDA 47.049) supports research into advancing the understanding of transition metal-carbon bonding through integrated spectroscopy and theory methods. Principal investigators Lucy Ziurys of the University of Arizona and Nathan Deyonker of the University of Memphis will combine experimental and computational approaches to explore the ground electronic states of small...
This Project Grant award of $340,000 from the National Science Foundation's (NSF) Mathematical and Physical Sciences program supports research into polymer nanocomposites. The research aims to provide fundamental understanding of the chemistry, physics, and engineering principles that can be leveraged to develop advanced functional materials, such as those with applications in energy storage and water purification. Key objectives include: 1) elucidating how brush charge density affects...
This Project Grant award, funded by the National Science Foundation's (NSF) Mathematical and Physical Sciences program (CFDA 47.049), supports research at the University of Pennsylvania focused on developing well-defined metal complexes to challenge current paradigms of acid-base chemistry. Specifically, the $600,000 award, with a performance period from July 2025 to June 2028, aims to synthesize and isolate earth-abundant metal complexes containing elements like titanium, niobium, and vanadium that can form metal-ligand multiple bonds. This modular approach allows researchers to tune the metal ion and ligand to probe the super-basicity of the ligand, as well as leverage these complexes to activate and functionalize hydrocarbon carbon-hydrogen bonds. The research program integrates student training and public outreach to communicate the laboratory experiments. No sub-awards are planned under this grant.