Project Grant 2154121

Award Date 9/1/22
Completion Date 8/31/25
Dollars Obligated $520K
Federal Grant Program
47.049
Assistance Type
Project Grant
Place of Performance
Tucson, AZ 85719, USA
Similar Awards
This $575,000 Project Grant from the National Science Foundation's Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), will fund research at the University of California, San Diego to synthesize and study the reactivity of unusual main group elements stabilized by transition metal isocyanide complexes, from July 1, 2023 to June 30, 2026. Specifically, Professor Joshua S. Figueroa will manipulate boron monofluoride and diphosphorus molecules, which are...
The National Science Foundation (NSF) awarded a $111,099 Project Grant under the Mathematical and Physical Sciences program (CFDA 47.049) to the University of Montana to conduct a comparative study of the high harmonic generation (HHG) spectra of transition metal compounds. The 3-year project aims to leverage advancements in laser technology to better understand the complex electronic structures and chemical properties of transition metal compounds, which have wide-ranging applications in...
This $600,000 Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences (CFDA 47.049) program will support research at the University of Michigan and Trinity University to investigate the structural and electronic properties of high-valent cobalt, nickel, and copper-oxo complexes. The project aims to improve understanding of how metal-oxo versus metal-oxyl character impacts the stability and reactivity of these unstable, yet potentially useful,...
The National Science Foundation (NSF) awarded a $684,062 Project Grant to the University of Memphis Chemistry Department under the Mathematical and Physical Sciences program (CFDA 47.049) to support the synthesis and study of bimetallic and multi-metallic complexes bridged by redox-active, exocyclic imine ligands. The project aims to develop new electronic materials by exploiting the electronic properties of these conjugated bridging ligands, with the goal of constructing molecular wires and...
The University of Utah will use a $550,000 Project Grant from the National Science Foundation Division of Chemistry to examine thermochemistry of metal-ligand bonds and protonated peptides from June 15, 2023 to May 31, 2026. The work falls under the NSF Mathematical and Physical Sciences program (CFDA 47.049), which aims to advance scientific knowledge and understanding in these fields. Professor Peter B. Armentrout and his research group will utilize guided ion beam tandem mass spectrometry...
This $550,000 Project Grant from the National Science Foundation Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), supports research at Texas A&M University from August 1, 2022 to July 31, 2025. Professor François Gabbaï and his team will investigate the synthesis and coordination chemistry of novel ambiphilic ligands featuring a carbenium ion positioned next to a phosphine- or carbene-based metal-binding site. When coordinated to late transition...
This Project Grant award of $600,000 from the National Science Foundation's (NSF) Division of Chemistry was granted to Texas A&M University on July 15, 2025. The award supports fundamental research into the reactivity and applications of transition metal complexes containing boron-metal bonds, known as "boryl-centered pincer complexes." The key objectives of this 3-year project are to: Develop a deeper understanding of the unique reactivity and bond-forming/breaking mechanisms of...
The University of Utah will provide research services under a $515,000 Project Grant from the National Science Foundation Division of Chemistry through the Mathematical and Physical Sciences federal grant program (CFDA 47.049). Professor Michael Morse and his students will employ laser spectroscopy techniques to study the electronic structure, chemical bonding, and bond dissociation energies of small transition metal and lanthanide molecules. They will generate a molecular beam using laser...
This $550,000 National Science Foundation project grant supports research into the role of non-covalent interactions in the excited state dynamics of heterocyclic compounds. Funded under the NSF's Mathematical and Physical Sciences program (CFDA 47.049), Professor de Vries at the University of California, Santa Barbara will experimentally study how such compounds respond to ultraviolet radiation using gas phase spectroscopy. Computational chemists will model the results to compare quantum...
This Project Grant from the National Science Foundation's Division of Chemistry provides $138,894 to Drs. Eranda Nikolla of Wayne State University and Will Medlin of the University of Colorado from January 2023 through December 2023. The funding supports research under the Mathematical and Physical Sciences program (CFDA 47.049) to develop an understanding of solid metal/metal oxide interfaces in inverted catalytic systems. Specifically, the researchers are synthesizing controlled metal...

This $520,000 three-year Project Grant from the National Science Foundation's (NSF) Mathematical and Physical Sciences program (CFDA 47.049) supports research into advancing the understanding of transition metal-carbon bonding through integrated spectroscopy and theory methods. Principal investigators Lucy Ziurys of the University of Arizona and Nathan Deyonker of the University of Memphis will combine experimental and computational approaches to explore the ground electronic states of small molecules containing transition metals. Their work will employ high-resolution gas-phase rotational spectroscopy techniques from 4 GHz to 850 GHz to investigate chemical bonding in metal carbide and acetylide species containing metals such as nickel, cobalt, titanium, and iron. Experimental results will be validated through higher-order ab initio calculations involving single reference coupled cluster and multi-reference configuration interaction theories. This collaborative effort aims to provide predictive theoretical and spectroscopic properties applicable to larger metal-carbon molecules relevant to catalysis, synthesis, materials chemistry, and chemical biology. A subaward of $100,000 supports the University of Memphis's contributions to the project integrating spectroscopy and theory from September 1, 2022 through August 31, 2025.

Generated 1/7/24, 11:58 AM