Phosphorus(IV) as a missing link in phosphorus cosmochemical evolution

Ended Grant For Research Awarded Last action

Contract number
80NSSC23K0019
Awardee
Awarding agency
Obligated
$454,298

Award facts

Contract value 100% obligated
$454,298.00 Current and potential, with all options
Completion date 100% complete
Current and potential, with all options
NAICS code
Not on record
Set-aside
No set-aside
Competition
Full and Open Competition Basic Research
Pricing
Other
Place of performance
Tampa, FL 33620, USA

Award details come from SAM.gov/FPDS.

Transactions

Action Obligated Date
Other Administrative Action P00005 $0
Other Administrative Action P00004 $0
Funding Only Action P00003 · We thus propose to investigate 1) the speciation of phosphorus as IT oxidizes under high temperature conditions (500-1000 c) by extracting p phases using… $92,409
Funding Only Action P00002 $175,793
Other Administrative Action P00001 · We thus propose to investigate 1) the speciation of phosphorus as IT oxidizes under high temperature conditions (500-1000 c) by extracting p phases using… $0
Original award $186,096

About this award

The University of South Florida received a $454,298 research grant from a civilian federal agency for a project investigating phosphorus speciation and oxidation states in cosmochemical evolution. The research addresses three primary objectives: examining phosphorus oxidation processes at high temperatures (500-1000°C) using isotopically-labeled water and advanced analytical techniques such as 31P nuclear magnetic resonance and mass spectrometry; investigating phosphorus speciation in synthetic and natural phosphoran olivine to determine whether intermediate oxidation states of phosphorus exchange with silicate structures; and identifying whether partially-oxidized schreibersite forms phosphonic acids more readily than other phosphorus sources through the generation of free radicals. The work is directly aligned with the Emerging Worlds Program, which supports research into the chemistry and evolution of materials present during early solar system formation, particularly focusing on differentiation and accretion processes.

This research grant carries an ultimate completion date of October 4, 2026, with an award date of October 5, 2022. No set-aside designation was applied to this contract. The work is expected to yield insights into phosphorus mineralogy in meteorites, the origins of specific meteorite minerals and organic compounds, and the role of intermediate phosphorus oxidation states as a potential chemical bridge between phosphide and phosphate forms. The research combines nuclear magnetic resonance, electron probe microanalysis, and electron paramagnetic resonance techniques to advance understanding of phosphorus behavior during early solar system development, with implications for comprehending unusual phosphorus mineralogic features observed in cosmochemical samples.

Quick answers

Who was awarded contract 80NSSC23K0019?

80NSSC23K0019 was awarded to University Of South Florida by Shared Services Center (National Aeronautics and Space Administration) on October 5, 2022.

How much is contract 80NSSC23K0019 worth?

The government has obligated $454,298 on 80NSSC23K0019.

Was contract 80NSSC23K0019 competed?

The extent of competition for 80NSSC23K0019 was full and open competition.

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