684383201CG02 SDS.pdf

SAFETY DATA SHEET

Burnt Orange Non Flame 250 g/L MIL-DTL-24607B; Amend. 2; Color 22203

1. PRODUCT AND COMPANY IDENTIFICATION

MANUFACTURER

NCP Coatings, LLC 225 Fort Street Niles, MI, 269-683-3377

24 HR. EMERGENCY TELEPHONE NUMBER

CHEMTREC (US Transportation): (800)424-9300 CHEMTREC (International : 1(202)483-7616 Transportation)

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

PHYSICAL APPEARANCE : Liquid IMMEDIATE CONCERNS : Flammable liquid and vapor.

CLASSIFICATION : Aspiration Hazard 1, Carcinogenicity 2, Flammable Liquid 3, Eye Irritation 2, Skin Irritation 2, STOT RE 2, STOT SE 3 NE, STOT SE 3 RTI

PICTOGRAMS

SIGNAL WORD : Danger

GHS HAZARD STATEMENTS : H226 Flammable liquid and vapor.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H373 May cause damage to organs through prolonged or repeated exposure.

H304 May be fatal if swallowed and enters airways.

H351 Suspected of causing cancer .

H336 May cause drowsiness or dizziness.

DATE ISSUED : 6/21/2023

SDS REF. No : N-8852

PRODUCT NAME: Burnt Orange Non Flame 250 g/L MIL-DTL-24607B; Amend. 2; Color 22203

PRODUCT CODE: N-8852

PRODUCT USE: Refer to TDS and product label.

GHS PRECAUTIONARY STATEMENTS : P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P262 Do not get in eyes, on skin, or on clothing.

P241 Use explosion-proof electrical/ventilating/lighting/equipment.

P270 Do not eat, drink or smoke when using this product.

P284 (In case of inadequate ventilation) wear respiratory protection.

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P370 + P378 In case of fire: Use appropriate method to extinguish. See Section 5 of SDS.

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

P333 + P313 If skin irritation or rash occurs: Get medical advice / attention.

P342 + P313 If experiencing respiratory symptoms: Get medical advice / attention.

P501 Dispose of contents/container in accordance with local/national/international regulations.

P363 Wash contaminated clothing before reuse.

P271 Use only outdoors or in a well-ventilated area.

P240 Ground/bond container and receiving equipment.

P403 + P235 Store in a well-ventilated place. Keep cool.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name

Wt %

CAS

Number

GHS

Aluminum Trihydrate 15- 20%

21645-51-2 The substance does not meet the criteria for classification.

Parachlorbenzotrifluoride(PCBTF) 10- 15%

98-56-6 H319 Causes serious eye irritation.

H226 Flammable liquid and vapor.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

Light Aromatic Petroleum distillates

5-10% 64742-95-6 H226 Flammable liquid and vapor.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H336 May cause drowsiness or dizziness.

H351 Suspected of causing cancer.

*1,2,4 Trimethylbenzene 2.85 95-63-6 H226 Flammable liquid and vapor.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H332 Harmful if inhaled.

H335 May cause respiratory irritation.

Methyl-n-Amyl Ketone 1-5% 110-43-0 H226 Flammable liquid and vapor.

H302 Harmful if swallowed.

H332 Harmful if inhaled.

H335 May cause respiratory irritation.

H336 May cause drowsiness or dizziness.

Titanium Dioxide 1.88 13463-67-7 Conclusive but not sufficient for classification.

1-Methoxy-2-Propanol Acetate 1-5% 108-65-6 H226 Flammable liquid and vapor.

*Cobalt Carboxylates 0.053 136-52-7 H320:Causes eye irritation.

H350i: May cause cancer.

Classification is largely based on animal evidence.

H402: Harmful to aquatic life., ,

* Toxic chemical subject to the reporting requirements of section 313 of Title III and of 40 CFR 372.

4. FIRST AID MEASURES

EYES : Immediately flush eyes with water. Flush eyes with water for a minimum of 15 minutes, occasionally lifting and lowering upper lids. Get medical attention promptly.

SKIN : Wash with soap and water. Get medical attention if irritation develops or persists. Remove contaminated shoes and clothes and clean before reuse.

INGESTION : DO NOT induce vomiting. Get medical attention immediately.

INHALATION : Rescuers should put on appropriate protective gear. Remove from area of exposure. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Keep victim warm. Get immediate medical attention.

MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED

SYMPTOMS : May cause drowsiness or dizziness.

EFFECTS : Significant exposure to this chemical may adversely affect people with chronic disease of the respiratory system, central nervous system, kidney, liver, skin, and/or eyes.

5. FIRE FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIA : Water mist or fog, dry chemical, foam, carbon dioxide.

FIRE FIGHTING PROCEDURES : As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Use water with caution. Material will float and may ignite on surface of water. Water may be ineffective in fighting the fire. Water spray to cool containers or protect personnel. Use with caution. Water runoff can cause environmental damage. Dike collect water used to fight fire. Small fires: carbon dioxide or dry chemical. Large fire: alcohol-type aqueous film-forming foam or water spray.

UNUSUAL FIRE AND EXPLOSION HAZARD : Flammable liquid and vapor. Vapors can travel to a source of ignition and flash back. Empty containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT pressurize, cut, weld, braze, solder, grind or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. Also, do not reuse container without commercial cleaning or reconditioning.

COMBUSTION PRODUCTS : During combustion carbon monoxide and/or carbon dioxide may be formed.

6. ACCIDENTAL RELEASE MEASURES

SMALL SPILL : Eliminate all sources of ignition. Provide good ventilation and minimize the breathing of vapors and avoid skin contact. Dike spill area and absorb the spilled liquid with earth, sawdust or a commercially available absorbent. Shovel spent absorbent into recovery or salvage drums for appropriate disposal.

LARGE SPILL : Wear appropriate personal protective equipment. Eliminate all ignition sources.

Prevent additional discharge of material if able to do so safely. Do not touch or walk through spilled material. Avoid runoff into storm sewers and ditches which lead to waterways. Ventilate spill area. Stay upwind of spill. Use only non-combustible material for cleanup. Use clean, non-sparking tools to collect absorbed materials. Absorb spill with inert material (e.g. dry sand, earth or sawdust), then place in a chemical waste collector.

EMERGENCY PRECAUTIONS : Eliminate ignition sources. Avoid large exposures to vapors.

7. HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING : Use only in a well ventilated area. Avoid breathing vapor, fumes, or mist. Avoid contact with eyes, skin, and clothing. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Always open containers slowly to allow any excess pressure to vent. Follow all SDS/label precautions even after containers are emptied because they may retain product residues.

CONDITIONS FOR SAFE STORAGE, INCLUDING INCOMPATIBILITIES : Keep away from heat, sparks, and flame. Store containers in a cool, well ventilated place. Keep container closed when not in use.

8. EXPOSURE CONTROLS\PERSONAL PROTECTION

EXPOSURE LIMITS

Components CAS Limits Aluminum Trihydrate 21645-51-2 ACGIH TLV 10 mg/m3 TWA

OSHA PEL 15 mg/m3 TWA Parachlorbenzotrifluoride(PCBTF) 98-56-6 ACGIH TLV NE

OSHA PEL NE

Light Aromatic Petroleum distillates

64742-95-6 OSHA PEL 100 PPM TWA

ACGIH TLV 100 PPM TWA

*1,2,4 Trimethylbenzene 95-63-6 ACGIH TLV 25 PPM TWA

OSHA PEL 25 PPM TWA

Methyl-n-Amyl Ketone 110-43-0 ACGIH TLV 50 PPM TWA

OSHA PEL 100 PPM TWA

Titanium Dioxide 13463-67-7 OSHA PEL 10 mg/m3 TWA Total Dust

ACGIH TLV 10 mg/m3 Total Dust 1-Methoxy-2-Propanol Acetate 108-65-6 OSHA PEL NE

ACGIH TLV NE

*Cobalt Carboxylates 136-52-7 ACGIH TLV 0.02 mg/m3

OSHA PEL 0.1 mg/m3

OSHA TABLE COMMENTS:

NE = Not Established

ENGINEERING CONTROLS : Engineering controls should be in place to minimize exposure to vapors and any ignition sources.

PERSONAL PROTECTIVE EQUIPMENT

EYES AND FACE : Wear safety glasses with side shields, goggles, or a face shield.

SKIN : Wear impervious gloves to prevent contact with skin. Wear protective gear as needed -apron, suit, boots.

RESPIRATORY : NIOSH/MSHA approved respirators may be necessary if airborne concentrations are expected to exceed exposure limits.

WORK HYGIENIC PRACTICES : Do not eat, drink, or smoke in areas where this material is used. Avoid breathing vapors. Remove contaminated clothing and wash before reuse. Wash thoroughly after handling. Wash hands before eating.

OTHER USE PRECAUTIONS : Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE : Liquid

ODOR : Typical

ODOR THRESHOLD : Not determined.

pH : Not determined.

MELTING POINT/FREEZING POINT: Not determined.

INITIAL BOILING POINT : 282 F BOILING RANGE: Not determined.

FLASH POINT AND METHOD : 104ºF(40ºC)

SETAFLASH CLOSED CUP

EVAPORATION RATE: Not determined.

FLAMMABILITY (SOLID,GAS): Not determined.

EXPLOSIVE LIMITS : 0.9 TO 12.6

VAPOR PRESSURE : Not determined.

VAPOR DENSITY : Heavier than air

SPECIFIC GRAVITY : 1.5968602

SOLUBILITY: Not determined.

PARTITION COEFFICIENT: N-OCTANOL/WATER: Not determined.

AUTO-IGNITION TEMPERATURE : Not determined.

DECOMPOSITION TEMPERATURE: Not determined.

VISCOSITY: Semi-viscous.

VOC EPA METHOD 24 : 2.0497393 lb/gal

10. STABILITY AND REACTIVITY

STABILITY : No information available.

CONDITIONS TO AVOID : Avoid impact, friction, heat, sparks, flame and source of ignition.

INCOMPATIBLE MATERIALS : Prevent contact with strong oxidizing agents.

HAZARDOUS DECOMPOSITION PRODUCTS: During combustion carbon monoxide and/or carbon dioxide may be formed.

HAZARDOUS POLYMERIZATION : No information available.

11. TOXICOLOGICAL INFORMATION

SIGNS AND SYMPTOMS OF OVEREXPOSURE :

ACUTE EFFECTS :

EYE : Causes eye irritation.

SKIN : Causes skin irritation. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash).

INHALATION : Vapors are irritating to nasal passages and throat. High concentrations can cause stupor and headaches. May cause dizziness and drowsiness.

INGESTION : Irritating to mouth, throat, and stomach. May cause headache. May cause dizziness and drowsiness and/or stupor.

CHRONIC EFFECTS : Significant exposure to this chemical may adversely affect people with chronic disease of the respiratory system, central nervous system, kidney, liver, skin, and/or eyes.

Primary Route(s) of Entry: Eye Contact, Ingestion, Inhalation, Skin Contact

ACUTE TOXICITY VALUES : The acute effects of this product have not been tested. Data on individual components are listed below.

1,2,4 Trimethylbenzene(95-63-6)

ORAL LD50:5000 mg/kg

Dermal LD50:>5000 mg/kg

Vapor LC50:18 mg/L

1-Methoxy-2-Propanol Acetate(108-65-6)

None known.

Aluminum Trihydrate(21645-51-2)

Acute toxicity not classified.

Light Aromatic Petroleum distillates(64742-95-6)

Oral LD50: >3,000 mg/kg

Dermal LD50: >3,160 mg/kg

Vapor LC50: >20 mg/L

Methyl-n-Amyl Ketone(110-43-0)

Oral LD50:>1600 mg/kg

Dermal LD50: >2000 mg/kg

Vapr LC50: >16.7 mg/L

Parachlorbenzotrifluoride(PCBTF)(98-56-6)

Oral LD50: 13,000

Dermal LD50: 2,700

Vapor LC50: 33

Titanium Dioxide(13463-67-7)

Vapor LC50: >6.82lg/L Rat

Dermal LD50: >10,000 mg/kg Rabbit

Oral LD50: >5,000 mg/kg Rat

12. ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION: Information not available on mixture. Information on individual components is listed below if available.

1,2,4 Trimethylbenzene(95-63-6)

No information available.

1-Methoxy-2-Propanol Acetate(108-65-6)

96h LC50: 161 mg/L (fathead minnow)

Aluminum Trihydrate(21645-51-2)

No expected to be harmful to aquatic organisms.

Light Aromatic Petroleum distillates(64742-95-6)

No information available.

Methyl-n-Amyl Ketone(110-43-0)

No Information available.

Parachlorbenzotrifluoride(PCBTF)(98-56-6)

No Information available.

Titanium Dioxide(13463-67-7)

96h LC50: >1,000 mg/L (fathead minnow)

72h EC50: 61 mg/L (green algae)

48h EC50: >1,000 gm/L (water flea)

13. DISPOSAL CONSIDERATIONS

DISPOSAL METHOD : Dispose of waste in accordance with all local, state, and federal regulations.

14. TRANSPORT INFORMATION

UN NUMBER/ PROPER SHIPPING NAME/ TRANSPORT HAZARD CLASS/ PACKING GROUP

: UN1263;PAINT;3;III

15. REGULATORY INFORMATION

REGULATORY OVERVIEW: The regulatory data in section 15 is not intended to be all-inclusive, only selected regulations are represented.

TSCA: All components of this material are either listed or exempt from listing on the TSCA Inventory. This material contains no substances that are subject to TSCA 12(b) export notification.

SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)

311/312/313 REPORTABLE INGREDIENTS: See Section 3.

EPA HAZARDS:

FIRE : Yes PRESSURE GENERATING : No REACTIVITY : No ACUTE : Yes CHRONIC : Yes

DSL: All components of this material are on or exempt from listing on the Canadian Domestic Substances List(DSL).

16. OTHER INFORMATION

HMIS RATING

Health : 2 Flammability : 2 Reactivity : 0 Personal Protection : G

HMIS and NFPA rating scale: (0=minimal hazard; 4=severe hazard)

REVISION INDICATOR : 1/31/23

MANUFACTURER DISCLAIMER : The foregoing data has been compiled from sources which the company, in good faith, believes to be dependable and is accurate and reliable to the best of our knowledge and belief. However, the company cannot make any warranty or representation respecting the accuracy or completeness of the data and assumes no responsibility for any liability or damages relating thereto or for advising you regarding the protection of your employees, customers, or others. User should consult OSHA and other applicable safety laws and regulations before use.

NFPA CODES

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