OSP_Attach1.pdf

SP0600-14-R-0161

Attachment 1 to OSP

STANDARDIZED FORMAT FOR USE IN THE

PREPARATION OF PRODUCT TEST REPORTS

GENERAL INSTRUCTIONS

February 2010

These instructions are designed for use as a guide in preparing/formatting test reports in a consistent manner. Computer generated or typed test reports are acceptable. A Standardized Test report format is provided at Figure I and includes all tests approved for all refined products. The Test Codes used in this standard report format will be incorporated into future Electronic Data Interchange (EDI) transmissions of test result data.

The ASTM Aviation Turbine Fuel Report Form found in ASTM Method D-1655 was used as a template for the expanded “generic” standard test report form for other refined products. The codes containing an alpha character indicate alternative methods used to measure a property or characteristic. A numeric change of “1” unit indicates one or more measurements, ratings or test conditions which can be reported for a particular method. All measurements are in metric units, except for the API gravity reported at 60oF.

The use of this code provides flexibility in adding or deleting test methods while not affecting the existing methods and thus eliminates the need for additional programming. For example, an ASTM method may have an equivalent ISO or other method. If the ASTM test method number is used as a reference, the ISO equivalent may be lost unless new programming is established to make it a choice. With the code, the equivalency will continue without any additional programming. Another example is adding a new test method for Freezing Point. There are currently 3 methods (300A-C) for measuring the characteristic of freezing point. The new method would be assigned the code “300D” and would be available immediately as an alternative method for determination of freezing point while retaining the old methods without having to renumber the whole list and change associated database programming.

Each test report should be tailored to include only those rows of information that are applicable to the specific product being tested and the methods used to evaluate each property. Select only those methods authorized by the product specification unless otherwise stated in the contract. The code used should be limited to the actual test method used for a particular analysis. If an analysis is performed which is not cited by the specification, report the result, units and method used at the bottom of the report. If a test code does not appear for a specification or contract approved method, contact the Defense Energy Support Center (DLA ENERGY) at commercial (703) 767-8360.

DETAILED INSTRUCTIONS FOR THE STANDARD TEST REPORT FORMAT (FIGURE 1)

Item 1: This date is the tank approval date, which is usually the date the testing is completed or the report date.

Item 2B: The City should match the “Shipped From” city on the DD 250-series document.

Item 6A: Record the basic slate of crudes from which this product is derived.

Item 6B: Annotate the refining processes used in the production of this product (e.g., Atmospheric Distillation; Hydrogenation, Hydrocracking, etc)

Item 8: Report the quantity in US Gallons shipped from the above batch in the above tank under DLA ENERGY Contract. This entry need not be completed if the same batch will be used for subsequent shipments. In this case, assure that the tank number, batch number and report date are on the DD-250-series documents for shipments made from this tank

Items 600-series: The JFTOT test, although done using one ASTM test method, can be performed at different temperatures. Also, results for separate JFTOT analysis performed at two different temperatures can be reported on the same report. If test results for only one temperature is being reported, use Item 600 A-C to report the temperature of the test and 601, 602 and 603 as appropriate to report the results. If a second temperature is being reported, use Item 604 to report the temperature of this second run and Items 605-607 to report the corresponding values for the second test.

Item 750: Use this item to report the result of the Water Separometer Index - Modified (WSIM) which is performed for product acceptance.

Item 751: This code for this item describes what additives were present in the fuel sample tested for WSIM and for which the result was reported in Item 750. Each code value represents a combination of the five additives possible in jet fuel. The codes and corresponding combinations are found in Table A below.

Item 750X: This item is used to report the special hand blend of all additives which are required by the fuel specification, regardless of whether or not the additives are required by contract. These additives include anti-oxidant, corrosion inhibitor, fuel system icing inhibitor, static dissipater additive and, if permitted by contract, metal deactivator. The result for this special test is a report only and is used as a base line in determining if the time and/or place of additive injection affects fuel quality. This reporting requirement is in addition to other reporting requirements for WSIM.

Items 801, 811, 821, 831, and 841: These codes indicate when an additive was injected during the procurement process. It is a one-character field and is “S” if the additive was blended into the shipping tank, “I” if the additive was line injected, or blank if the additive was not injected at the refinery or terminal location.

Table A

Code Additives Code Additives Code Additives Code Additives Code Additives

01 Neat 07 AO/CI 13 CI/MDA 19 AO/CI/MDA 25 FSII/SDA/MDA

02 AO 08 AO/FSII 14 FSII/SDA 20 AO/FSII/MDA 26 AO/CI/FSII/SDA

03 CI 09 AO/SDA 15 FSII/MDA 21 AO/FSII/SDA 27 AO/FSII/SDA/MDA

04 FSII 10 AO/MDA 16 MDA/SDA 22 AO/SDA/MDA 28 CI/FSII/SDA/MDA

05 SDA 11 CI/FSII 17 AO/CI/FSII 23 CI/FSII/SDA 29 AO/CI/FSII/SDA/MDA

06 MDA 12 CI/SDA 18 AO/CI/SDA 24 CI/FSII/MDA

FIGURE I - STANDARD TEST REPORT FORMAT

1 REPORT DATE: (MM/DD/YY)_______________________

2A CONTRACTOR: __________________________________________

2B REFINERY CITY: __________________________________________

2C STATE/COUNTRY: __________________________________________

3A CONTRACT NUMBER: (SPO600-YY-D-NNNN)____________________

3B CONTRACT LINE ITEM NUMBER: __________________________________________

3C DLA ENERGY ORDER NUMBER _________________________________

4A TANK NUMBER: _________________

4B BATCH NUMBER (In Tank): ____________________

4C SAMPLE NUMBER: __________________________

5 PRODUCT: __________________

6A CRUDE OIL SLATE: ___________________________________________

6B CRUDE PROCESSING TECHNIQUE: ___________________________________________

7 SHIPPED TO: ___________________________________________

8 QUANTITY FROM TANK SHIPPED TO DLA ENERGY: __________________________________USG

APPEARANCE

Code Method Test Unit Code Method Test Unit

010A D-156 Saybolt Color 1-Color 010B D-6045 Saybolt Color (Spectro) 1-Color

020 D-4176 Visual appearance C&B

021 D-4176 Haze Rating Method

030A D-1500 ASTM Color 0.5-Color 030B D-6045 ASTM Color (Spectro) 0.5-Color

COMPOSITION

100A D-664 Total Acid Number – Potent mg KOH/g 100B D-974 Acid Number - Color Titrat mg KOH/g 100C D-3242 Acidity in Aviation Fuels mg KOH/g 100D D-3339 Acid Number, Semi-Micro mg KOH/g 100IPA IP-354 Total Acidity mg KOH/g 101 IP-182 Inorganic Acid Number mg KOH/g

102 FTM-5101 Neutrality Method

104 D-1093 Acidity/Alkalinity Acidic/Basic/Neutral

110A D-1319 Aromatics vol% 110B D-4420 Aromatics by GC vol% 110C D-5580 Aromatics by GC vol% 110D D-6379 Aromatics by LC w/RI vol% 110IPA IP-156 Aromatics -Flourescent Indicator vol% 110IPB IP-436 Aromatics-LC w/RI vol%

115 D-1319 Olefins vol% 120 D-1840 Naphthalene vol% 125A D-4420 Benzene vol% 125B D-3606 Benzene vol% 125C D-5580 Benzene – GC vol%

130 D-3227 Mercaptan Sulfur mass %

130IPA IP-342 Sulfur (Mercaptan) mass% 130ISA ISO-3012 Mercaptan Sulfur mass%

135A D-3231 Phosphorous 0.1 mg/L 135D IP-501 Phosphorous mg/kg

140 D-4952 Doctor Test Pos/Neg 140IPA IP-30 Sulfur (Doctor Test) Pos/Neg

150A D-129 Sulfur by Oxygen Bomb mass % 150B D-1266 Sulfur by Lamp mass % 150C D-1552 Sulfur - Furnace mass % 150D D-2622 Sulfur by X-Ray Spec mass % 150E D-3120 Trace Sulfur ppm 150F D-4294 Sulfur by X-Ray Flour mass % 150G D-5453 Sulfur by UV ppm 150IPA IP-336 Sulfur Content mass % 150IPB IP-107 Sulfur Content mass % 150IPC IP-243 Sulfur Content mg/kg(ppm) 150IPD IP-373 Sulfur Content mg/kg 150IPE IP-447 Sulfur Content mass % 150ISA ISO-4260 Sulfur Content mass % 150ISB ISO-8754 Sulfur – X-ray Fluoresence mass % 150ISC ISO-14596 Sulfur Content mass % 150L D-6920 Total Sulfur ppm 150M D7039 Total Sulfur ppm

155A App A, Spec C-10 Content mass % 156 App A, Spec Other Hydrocarbon mass % 157 App A, Spec MCH Content mass % 160A D-3343 Hydrogen Content mass % 160B D-3701 Hydrogen Content - NMR mass % 160C D-4808 Hydrogen Cont LoRes NMR mass % 160D D-5291 Hydrogen Cont – Instrument mass% 160E D-7171 Hydrogen Cont LoRes NMR mass%

165 D-5184 Al plus Si (ISO 10478) ppm 165A IP-501 Aluminum and Silicon mg/kg

170A D-3237 Lead in Gasoline by AA g/L 170B D-3341 Lead in Gasoline by ICl g/L 170C D-5059 Lead in Gasoline by X-Ray g/L

180A D-4815 Ethers and Alcohols by GC mass %

180B D-5845 Ethers and Alcohols by IR mass %

190A D-3605 Trace Metals - Calcium mg/L 190B D-7111 Trace Metals - Calcium mg/L 190C IP-501 Calcium mg/kg 191A D-3605 Trace Metals - Lead mg/L 191B D-7111 Trace Metals - Lead mg/L 192A D-3605 Trace Metals - Na & K mg/L 192B D-7111 Trace Metals - Na & K mg/L 193A D-3605 Trace Metals - Vanadium mg/L 193B ISO14597 Trace Metals – Vanadium mg/L 193C D-5863 Trace Metals-Vanadium mg/kg 193D D-7111 Trace Metals – Vanadium mg/L193E IP- 501 Vanadium mg/kg 194 IP-501 Zinc mg/kg 195 D-3703 Peroxide Content mg/kg

VOLATILITY

200A D-86 Distillation by Auto/Manual 200B D-2887 Distillation by GC 200IPA IP-123 Distillation by ATM °C 200IPB IP-406 Distillation by ATM °C 2001SA ISO-3405 Distillation by Apparatus °C 201 Initial Boiling Point oC 202 10% Recovered oC 203 20% Recovered oC 204 50% Recovered oC 205 85% Recovered oC 206 90% Recovered oC 207 95% Recovered oC 208 Evaporated @ 70oC vol% 209 Evaporated @ 100oC vol% 210 Evaporated @ 180oC vol% 211 Final Boiling Point oC 212 % Recovered vol% 213 % Residue vol% 214 % Loss vol% 215 % Residue + Loss vol%

220A D-56 Flash Point - Tag oC 220B D-93 Flash Point - P/M oC 220C D-3828 Flash Point - Seta, Method A oC 220D D-3828 Flash Point - Seta, Method B oC 220E D-92 Flash Point - COC oC 220F D-6450 Flash Point – CCCFP °C

220IPA IP-170 Flash Point – Abel °C 220IPB IP-523 Flash Point – RECC °C 220ISA ISO-3679 Flash Point – Abel °C 221 D-3828 Flash Point - Seta (Flash/No F) “F” or “N”

230A D-1298 Density @ 15oC -Hydrom kg/L 230B D-4052 Density @ 15oC - Digital kg/L 230IPA IP-365 Density @ 15°C Oscillation U-tube kg/m3

230IPB IP-160 Density @15°C – Hydrom kg/m3 230ISA ISO-3675 Density @15°C-Hydrom kg/L 230ISB ISO-12185 Density @15°C-Digital g/mL

231A D-1298 API Gravity @ 60oF oAPI 231B D-4052 API Gravity @ 60oF oAPI 231C D-287 API Gravity @ 60oF oAPI

240A D-323 RVP kPa 240B D-4953 Vapor Press - Dry Meth kPa 240C D-5190 Vapor Press - Automatic kPa 240D D-5191 Vapor Press - Mini Meth kPa 240E D-5482 Vapor Press - Mini -Atm kPa

250A D-2533 V/L Ratio - Buret Unit@oC 250B D-5188 V/L Ratio - Evac Chamb Unit@oC 250C D-4814 Estimated V/L Ratio Unit@oC 260 STANAG 7090 - Vapor Lock Index

FLUIDITY

300A D-2386 Freezing Point oC 300B D-5901 Freezing Point oC 300C D-5972 Freezing Point oC 300D D-4305 Freezing Point, Low Temps oC 300E D-7153 Freezing Point oC 300F D-7154 Freezing Point °C 300IPA IP16 Freezing Point °C 300IPB IP-435 Freezing Point °C 300IPC IP-528 Freezing Point °C 300IPD IP-529 Freezing Point °C

310 D-445 Viscosity cSt 310IPA IP-71 Viscosity @ 20°C mm2/s 310ISA ISO-3104 Viscostiy @20° C mm2/s 311 D-445 Viscosity Temperature oC

320A D-2500 Cloud Point oC

320B D-5771 Cloud Point (Optical) oC 320C D-5772 Cloud Point (Linear Cool) oC 320D D-5773 Cloud Point (Constant Cool) oC

321A IP-309 Cold Filter Plugging Point oC 321B D-6371 Cold Filter Plugging Point oC 321C D-6371(M)Cold Filter Plugging Point oC 321D D-4539 Low Temp Flow Test °C

330A D-97 Pour Point oC 330B D-5949 Pour Point – Pulsing Method oC 330C D-5950 Pour Point oC 330D D-5985 Pour Point-Rational Method °C

340A D-5001 Lubricity (BOCLE) 0.01mm 340B D-6079 Lubricity (Wear Scar) 0.01 mm

COMBUSTION

400A D-240 Neat Heat by Bomb MJ/kg 400B D-1405 Net Heat (Anal-Grav(oF),S) MJ/kg 400C D-3338 Net Heat (Aromat,API,Dist,S) MJ/kg 400D D-4529 Net Heat (Dens-Anal(oC),S) MJ/kg 400E D-4809 Net Heat by Bomb-Precision MJ/kg 400F D-4868 Net and Gross Heat MJ/kg 400G D-6446 Net Heat of Aviation Fuels MJ/kg 400H D-2382 Net Heat by Bomb – Precision MJ/kg 400IPA IP-12 Net Heat of Combustion-Av Fuels J/g 400IPB IP-355 Net Heat of Combustion-Av Fuels MJ/kg

410 D-1740 Luminometer Number Unit 420 D-1322 Smoke Point mm 420IPA IP-57 Smoke Point mm 420ISA ISO-3014 Smoke Point mm 430 D-482 Ash Content mass %

440A D-189 Conradson Carbon Res mass % 440B D-524 Ramsbottom Carbon Res mass % 440C D-4530 Carbon Residue - Micro mass %

CORROSION

500 D-130 Copper Strip Corrosion Method 500IPA IP-154 Copper Strip Corrosion Method

500ISA ISO-2160 Copper Strip Corrosion Method 510A IP-227 Silver Strip Corrosion Method

STABILITY

600A D-3241 JFTOT @ 275oC Method 600B D-3241 JFTOT @ 260oC Method 600C D-3241 JFTOT @ 245oC Method 600IPA IP-323 JFTOT@275°C Method 600IPB IP-323 JFTOT@260°C Method 600IPC IP-323 JFTOT@245°C Method 601 D-3241 Pressure Change mm Hg 602 D-3241 Visual Rating Method 603 D-3241 Spun Rating Method 604 D-3241 Other JFTOT Temperature oC 605 D-3241 Pressure Change @ Other Temp mm Hg

606 D-3241 Visual Rating @ Other Temp Method 607 D-3241 Spun Rating @ Other Temp Method 608 D-3241 Serial Number for 600A Tube 609 D-3241 Serial Number for 604 Tube

610A D-525 Ox Stability -Gasoline minute 610C D-873 Ox Stability – Aviation Fuels mg/100mL

620A D-2274 Accelerated Stability mg/100mL 620B D-5304 Accelerated Stab - O2 Opres mg/100mL 620C ISO10307 Tot Sed in Residual Fuels %mass

CONTAMINANTS

700 IP-225 Copper Content ppb 710 D-381 Existent Gum mg/100mL 710IPA IP-540 Existent Gum mg/100mL 711 D-381 Washed Gum mg/100mL

720A D-2276 Particulate Cont mg/L 720B D-5452 Particulate Cont mg/L 720D D-6217 Particulate Cont – Middle Dist mg/L 730 Annex Filtration Time minutes

740 D-1094 Water Reaction - Interface Method 741 D-1094 Water Reaction - Separation Method 742 D-1094 Water Reaction - Vol Chng Method

750 D-3948 WSIM Method 751 Additives Present (See Note) (List A) 750X D-3948 WSIM - Special (See Note) Method

760 D-4814 Phase Separation (Haze) oC 761 D-4814 Phase Separation (Sep) oC

770 D-1401 Demulsification @ 25oC minutes 780A D-1796 Water & Sed vol% 780B D-2709 Water & Sed vol%

781A D-95 Water by Distillation vol% 781B D-6304 Water by Karl Fischer mg/kg

782 D-473 Sediment by Extraction mass %

795 SW-846 EPA Metals - As Method 796 SW-846 EPA Metals - Cd Method 797 SW-846 EPA Metals - Cr Method 798 SW-846 EPA Metals - Pb Method 799 SW-846 Total Halogens Method

ADDITIVES

Code Method Test/Additive Unit Code Method Test/Additive Unit

800A Antioxidant Topanol A mg/L 800B Antioxidant HITEC 4733 mg/L 800C Antioxidant AN 733 mg/L 800D Antioxidant AO-31 mg/L 800E Antioxidant AO-30 mg/L 800F Antioxidant AO-29 mg/L 800G Antioxidant Nalco EC5208A mg/L 800H Antioxidant TOLAD 3915 mg/L 800I Antioxidant TOLAD 3920 mg/L 800J Antioxidant TOPANOL AN mg/L 800K Antioxidant CHIMIC 4327 mg/L 800L Antioxidant AO-37 mg/L 800M Antioxidant BETZ BQ203 mg/L 800N Antioxidant Chemlink No 4650 mg/L 800O Antioxidant Petroxylin E219 mg/L 800P Antioxidant Kerobit TP-26 mg/L 800Q Antioxidant Pet411K mg/L 800R Antioxidant ISONOX 133 mg/L 800S Antioxidant AO-37B mg/L 800T Antioxidant ISONOX 75 mg/L 800U Antioxidant HITEC 4775 mg/L 800V Antioxidant BETZ 8Q2065 mg/L 800W Antioxidant BHT mg/L 800X Antioxidant HITEC 4778 mg/L 800Y Antioxidant Octel 37/70 mg/L 801 Additive Injection Point (Note)

810A Metal Deactivator (DMD) mg/L 810B Metal Deactivator (DMD-2) mg/L 811 Additive Injection Point (Note)

820 Conductivity Improver mg/L 821 Additive Injection Point (Note)

830A FSII (D-5006) vol% 830B FSII (FTM-5327) vol%

830C FSII (FTM-5340) vol% 830D FSII (FTM-5340) - EGME vol% 830E FSII – Calculated vol% 831 Additive Injection Point (Note)

840A Corr Inhibitor PRI-19 mg/L 840B Corr Inhibitor DCI-4A mg/L 840C Corr Inhibitor DCI-6A mg/L 840D Corr Inhibitor HITEC 580 mg/L 840E Corr Inhibitor Petrolite NC-351 mg/L 840F Corr Inhibitor NALCO 5403 mg/L 840G Corr Inhibitor TOLAD 3220 mg/L 840H Corr Inhibitor UNICOR J mg/L 840I Corr Inhibitor IPC-4410 mg/L 840J Corr Inhibitor IPC-4445 mg/L 840K Corr Inhibitor MOBILAD F800 mg/L 840L Corr Inhibitor NALCO 5405 mg/L 840M Corr Inhibitor NUCHEM PCI-105 mg/L 840N Corr Inhibitor TOLAD 249 mg/L 840O Corr Inhibitor WELCHEM 91120 mg/L 840P Corr Inhibitor SPEC-AID 8021 mg/L 840Q Corr Inhibitor RPS-613 mg/L 840R Corr Inhibitor SPEC AID 8Q22 mg/L 840S Corr Inhibitor TOLAD 4410 mg/L 841 Additive Injection Point (Note)

850 Thermal Stability Additive mg/L 851 Additive Injection Point (Note)

860 Diesel Fuel Stabilizer Additive mg/L 861 Additive Injection Point (Note)

870 Ignition Improver mg/L 871 Additive Injection Point (Note)

OTHER TESTS

900 D-2624 Conductivity pS/m 900IPA IP-274 Conductivity pS/m 901 D-2624 Temperature at Measurement oC

910A D-976 Calc Cetane Index - 2 Var Method 910B D-4737 Calc Cetane Index - 4 Var Method

911 D-613 Cetane Number Method

920A D-2699 Research Octane Number Method

920B D-2885 Research Octane Number Method

921A D-2700 Motor Octane Number Method 921B D-2885 Motor Octane Number Method

930 D-611 Aniline Point oC 940 D-4814 Water Tolerance oC