Project Grant 2304884
- This three-year, $274,094 National Science Foundation project grant supports collaborative research between Duke University and the University of South Carolina to develop metal-containing polymers that respond chemically to mechanical stress. Funded through NSF's Mathematical and Physical Sciences program (CFDA 47.049), the researchers aim to establish structure-activity relationships and reaction mechanisms for mechanochemical cleavage of metal-cyclopentadienyl bonds. They will synthesize...
- The National Science Foundation Division of Chemistry awarded the University of South Carolina $395,000 under the Mathematical and Physical Sciences program (CFDA 47.049) to support collaborative research on mechanochemistry of metallocenes from October 1, 2022 to September 30, 2025. Professors Chuanbing Tang of the University of South Carolina and Stephen L. Craig of Duke University will develop a class of metal-containing polymers that respond chemically to mechanical stress through common...
- The National Science Foundation (NSF) Division of Chemistry awarded a $624,973 Project Grant under the Mathematical and Physical Sciences (CFDA 47.049) program to Stanford University for the research project "PROBING AND DESIGNING CASCADE REACTIVITY IN CONSECUTIVE MECHANOACTIVATION OF COVALENT BONDS". This 3-year grant will support experimental and computational investigations by Professors Yan Xia and Todd Martinez into understanding force-driven reaction pathways and cascade...
- The National Science Foundation Division of Chemistry awarded The University of Akron $420,000 under the Mathematical and Physical Sciences federal grant program (CFDA 47.049) to develop mechanically active degradable polymers. Professor Junpeng Wang and students will design and synthesize a class of polymers that can undergo two-step degradation: mechanochemical activation followed by degradation. This degradation mechanism will allow polymer breakdown to be controlled by mechanical force while...
- This Project Grant award from the National Science Foundation's (NSF) Division of Chemistry, under the Mathematical and Physical Sciences federal grant program (CFDA 47.049), provides $600,000 to Professor Dean Tantillo of the University of California, Davis Department of Chemistry. The funding supports research to explore the limits of reactivity principles for organic reactions using modern computational chemistry methods. The goal is to provide a fundamental understanding of factors that...
- The National Science Foundation (NSF) Division of Chemistry awarded a $539,999 Project Grant to the University of Houston under the Mathematical and Physical Sciences program (CFDA 47.049) to carry out computational quantum chemistry research. The purpose of the research is to explore, test, and validate molecular-level design principles for functional carbon-rich materials, such as light-responsive polymers, nanotubes, and organic electronics. The expected outcomes include the development of...
- This three-year, $398,984 project grant from the National Science Foundation's Division of Chemistry will support research into mechanochemical activation carriers and mechanisms. Dr. Silvina Pagola of Old Dominion University will investigate fundamental aspects of mechanochemical reactions and their mechanisms to develop methods for determining activation barriers. Three types of mechanochemical reactions will be studied: the mechanosynthesis of a metal-organic framework, two Diels-Alder...
- This Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences (CFDA 47.049) program will enable research on a new class of "active polymers" that can respond to local energy fluctuations. The $495,000 award to the University of Massachusetts (UMass) will support the development of experimental methods to produce and study the mobility of these active polymers, with a focus on how energy injection at the molecular level impacts their behavior...
- The National Science Foundation (NSF) Division of Chemistry awarded a $570,000 Project Grant to Yale University under the Mathematical and Physical Sciences (CFDA 47.049) program. The grant supports the "Design of Lewis Acid Tethered Chain-End Capping Agents for Stereocontrolled Radical Polymerization" research project led by Dr. Mingjiang Zhong. The project aims to develop innovative catalytic systems to achieve stereocontrolled radical polymerization, which can produce polymeric...
- The National Science Foundation Division of Chemistry awarded University of California, Santa Barbara a $495,000 Project Grant under the Mathematical and Physical Sciences program (CFDA 47.049) to develop new cyclopentadiene-based materials with self-healing and depolymerizing properties using metal-free and inexpensive "click" chemistry approaches. Professor Read de Alaniz and students will construct polymers capable of these properties leveraging Diels-Alder chemistry, and develop an...
This National Science Foundation (NSF) Chemistry Division Project Grant, awarded to Duke University, provides $800,000 over 4 years (from September 1, 2023 to August 31, 2027) to study how mechanical forces can accelerate and control chemical reactions in polymeric materials. The primary objective is to establish a quantitative foundation for understanding "mechanochemistry" - the impact of mechanical forces on covalent chemical reactions along polymer backbones. The research aims to provide insights into the structure of transition states and reaction potential energy surfaces, leveraging advanced experimental techniques like single-molecule atomic force microscopy. Expected outcomes include developing new mechanically responsive and self-healing polymeric materials, as well as educational modules and research experiences to broaden participation in STEM fields. This award aligns with the NSF's Mathematical and Physical Sciences program (CFDA 47.049), which supports the advancement of scientific knowledge and the nation's scientific enterprise.
Mod # | Description | ReasonForModification | Federal Obligation | Date |
|---|---|---|---|---|
| Not listed | $800.0k | 7/21/23 |