The National Science Foundation (NSF) Division of Chemistry has awarded a 3-year, $316,588 Project Grant to Long Island University (LIU) under the Mathematical and Physical Sciences program (CFDA 47.049). The purpose of this grant is to support the development of novel carbon nanosphere-encapsulated bimetallic catalysts and metal-CeO2 interfaces for the conversion of carbon dioxide (CO2) to value-added chemicals. The key objectives of this research project are to: (I) leverage the confinement of carbon nanospheres to protect Fe-M nanoparticles and retain their reduced state, (II) exploit the abundant oxygen vacancies on CeO2, (III) take advantage of the hydrophobic and graphitic nature of carbon nanospheres with defect sites, and (IV) utilize the short diffusion length inside the carbon nanosphere pores to minimize undesired olefin secondary reactions. Through an integrated approach of synthesis, evaluation, advanced characterization, and density functional theory calculations, the research team aims to identify the dominant factors affecting the catalytic performance for the efficient conversion of CO2 to useful chemicals and fuels. The project also includes a significant educational component to engage undergraduate students in hands-on research experiences.
Mod # | Description | Reason For Modification | Federal Obligation (Click to sort descending) | Date (Click to sort ascending) |
|---|---|---|---|---|
| Not listed | $316.6k | 8/21/23 |