This Project Grant award from the Division of Chemistry at the National Science Foundation (CFDA 47.049 - Mathematical and Physical Sciences) provides $450,395 to the University of Illinois Chicago (UIC) to develop novel pro-aromatic heavy-atom-free organic chromophores for triplet photochemistry applications. The Principal Investigator, Dr. Jean-Luc Ayitou, will lead this research to exploit the intrinsic molecular properties of diketopyrrolopyrroles (DPP) and dipyrrolonaphthyridine-diones...
This Project Grant award of $510,759 from the National Science Foundation (NSF) Division of Chemistry supports a research collaboration led by Professors Andrew Mitchell of Illinois State University and Dean Tantillo of UC-Davis. The goal is to develop new chemical reactions with connections to biology, medicine, physics, materials, and environmental sustainability. Key products include: Advancing oxidopyrylium-based [5+2] cycloaddition reactions to construct important heterocyclic small...
The National Science Foundation (NSF) has awarded a $450,262 Project Grant to the University of Connecticut (UConn) under the Mathematical and Physical Sciences (CFDA 47.049) federal grant program. The funding supports UConn's research on pyrrole-modified porphyrins, a class of pigments involved in metabolic processes and light harvesting. The 3-year project, led by Professor Brueckner, aims to better understand the fundamental properties and potential applications of these modified...
This $574,999 Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences (MPS) program will support a study led by Professor Jonathan S. Lindsey of North Carolina State University on synthesizing the key pigments involved in photosynthesis - chlorophylls and bacteriochlorophylls. The objectives are to streamline a recently developed synthetic route, explore a dehydrogenation approach to access different photosynthetic tetrapyrroles, and demonstrate...
This $550,000 Project Grant from the National Science Foundation Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), supports research at Texas A&M University from August 1, 2022 to July 31, 2025. Professor François Gabbaï and his team will investigate the synthesis and coordination chemistry of novel ambiphilic ligands featuring a carbenium ion positioned next to a phosphine- or carbene-based metal-binding site. When coordinated to late transition...
This National Science Foundation (NSF) Project Grant, awarded under the CFDA Program 47.049 - Mathematical and Physical Sciences, provides $575,000 in funding to the University of Illinois Chicago (UIC) to develop new metal-catalyzed reactions to synthesize medium-sized ring compounds. Led by Professor Tom G. Driver, the project aims to leverage the unique reactivity of metal carbenes to construct important carbocyclic and heterocyclic scaffolds that are underrepresented in pharmaceutical...
The National Science Foundation awarded a $962,856 Project Grant to the University of Arizona under the Mathematical and Physical Sciences program (CFDA 47.049) to support research on redox-active biopyrrin pigments in supramolecular radical assemblies. Dr. Elisa Tomat and colleagues will synthesize novel supramolecular materials using biologically inspired pigments, with the goal of achieving tunable magnetic and photophysical properties. This work aims to further fundamental understanding of...
This Project Grant award from the National Science Foundation (NSF), under the Mathematical and Physical Sciences program (CFDA 47.049), supports a study by Professor Neal Mankad of the University of Illinois Chicago on earth-abundant metal complexes that can efficiently harvest energy from light to catalyze chemical transformations. The $201,993 award will fund the creation and testing of bimetallic reaction centers, such as copper(I) complexes, that are encapsulated by naturally occurring...
This National Science Foundation award provides $146,276 to Professor Anoklase Ayitou of Illinois Institute of Technology under the Mathematical and Physical Sciences program (CFDA 47.049) from February 15, 2022 to May 31, 2023. The funding supports research to develop novel polycyclic anti-aromatic chromophores and their dyad derivatives for photon upconversion applications. Professor Ayitou and their team will utilize synthetic organic chemistry, computational modeling, advanced spectroscopy...
The University of Illinois received a $500,000 Project Grant award from the National Science Foundation Division of Chemistry to support research on the "Reactions of Arynes and Other Reactive Intermediates" from July 1, 2021 to June 30, 2024. Under the award, the University will conduct research to increase understanding of major problems confronting the Nation in the area of chemical reactivity and synthesis through investigation of highly reactive chemical intermediates....
This $463,149 National Science Foundation Division of Chemistry project grant supports research at Illinois State University exploring the synthesis, characterization, and reactivity of novel porphyrinoid architectures with extended conjugation pathways. Professor Timothy Lash and his students are developing new synthetic routes to fused aromatic ring porphyrin-like systems such as carborporphyrins, hydroxyporphyrinoids, and tripryolic porphyrins. These unique molecules have altered conjugation pathways and properties compared to naturally occurring porphyrins. The research aims to increase fundamental understanding of aromaticity and provide access to important new porphyrinoid systems. It also has potential applications in photosynthesis, oxygen transport, materials science, catalysis, and photodynamic therapy. This award falls under the NSF's Mathematical and Physical Sciences program (CFDA 47.049), which supports advancing the U.S. scientific enterprise through increasing knowledge and understanding of major problems.