Through a $575,000 National Science Foundation (NSF) Mathematical and Physical Sciences (CFDA 47.049) award, Cornell University will investigate ways of utilizing more abundant 1st row transition metals as alternatives to expensive precious metals commonly used in catalytic chemistry. The primary objective is to develop methods for modifying 1st row transition metal compounds with ligands to provide the chemical reactivity and covalency typically associated with 2nd and 3rd row transition...
Through a $497,704 Project Grant award from the National Science Foundation's Chemical Catalysis program (CFDA 47.049 Mathematical and Physical Sciences), Professor Ming-Yu Ngai of Purdue University is conducting research to develop new sustainable catalytic processes leveraging first-row transition metals. The project aims to expand understanding of radical migration mechanisms and enable site- and stereoselective functionalization of carbohydrates and other small molecule building blocks....
Under a $529,170 award from the National Science Foundation's (NSF) Mathematical and Physical Sciences (MPS) program (CFDA 47.049), Professor Robert Paton and his research team at Colorado State University (CSU) will develop new computational workflows to accelerate the discovery and optimization of highly selective catalysts. The project aims to advance mechanistic understanding and establish new quantitative descriptors for three key catalyst and ligand classes - hydrogen-bond donors,...
This $450,000 National Science Foundation project grant supports research at Cornell University from August 2022 to July 2025 under the Mathematical and Physical Sciences program (CFDA 47.049). Principal Investigator Kyle Lancaster and his team are developing new classes of two- and pseudo-one-coordinate transition metal complexes with applications as catalysts and for data storage technologies. Specifically, the researchers aim to synthesize hetero-leptic transition metal complexes using...
This National Science Foundation (NSF) Project Grant award under the Mathematical and Physical Sciences program (CFDA 47.049) provides $656,061 to researchers at the University of Virginia, California State University Northridge, and University of Virginia to develop new methods for synthesizing nanocrystals with controlled properties. The project aims to incorporate novel N-heterocyclic carbene (NHC) ligands as a new approach to precisely control the size, composition, and surface structure...
This $600,000 Project Grant from the National Science Foundation Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), supports research at Northwestern University to develop new atom-efficient catalytic transformations using earth-abundant metals. Professor Tobin Marks and his research group will discover, understand, and optimize f-element and d(0)-transition metal catalysts for three types of critical organic reactions, with the goal of making catalytic...
This Project Grant from the National Science Foundation Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), provides $400,000 to Arizona State University to develop heteratom dimer and cluster catalysts for chemical transformations from June 1, 2023 to May 31, 2026. Professor Jingyue Liu will research precision-designed dual atom catalysts containing pairs of different metal atoms, such as palladium-tin and platinum-copper, localized on isolated metal oxide...
The National Science Foundation (NSF) awarded a $600,000 Project Grant under the Mathematical and Physical Sciences program (CFDA 47.049) to Professor Bing Gong of the State University of New York at Buffalo. The grant, with a term from July 1, 2025 to June 30, 2028, will fund research into the function, properties, and catalytic behavior of short polyamides with spirally folded helical conformations, known as "hollow helices." The project aims to develop these synthetic enzyme-like...
The National Science Foundation (NSF) awarded Purdue University a $575,000 Project Grant under the Mathematical and Physical Sciences (CFDA 47.049) federal grant program. The grant supports Professor Christopher Uyeda's research on developing multi-metallic catalysts to improve the efficiency and sustainability of chemical processes used in medicine, agriculture, and polymer chemistry. Key activities include designing new ligands that can bind multiple metals to create more active and...
This Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences (CFDA 47.049) program provides $390,000 in funding to the University of Notre Dame and the University of Tennessee for a collaborative research project. The goal is to rationally design new N-heterocyclic carbene (NHC) ligands to improve the robustness and expand the applicability of NHC-functionalized noble metal nanoparticles. The researchers will perform isotope labeling experiments to...